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By K. K. Kelley

The collection and correlation of thermodynamic data concerning substances of metallurgical interest have constituted one of the major activities of the Pacific Experiment Station of the Bureau of Mines, at Berkeley, Calif., for the past several years. Earlier bulletins (32, 33, 34, 36, 36, 37, 38) s in this series are entitled: (1) Contributions to the Data on Theoretical Metallurgy. I. The Entropies of Inorganic Substances; (2) Contributions to the Data on Theoretical Metallurgy. II. High-Temperature Specific-Heat Equations for Inorganic Substances; (3) Contributions to the Data on Theoretical Metallurgy. III. The Free Energies of Vaporization and Vapor Pressures of In¬ organic Substances; (4) Contributions to the Data on Theoretical Metallurgy. IV. Metal Carbonates--Correlations and Applications of Thermodynamic Properties; (5) Contributions to the Data on Theoretical Metallurgy. V. Heats of Fusion of Inorganic Substances; (6) Contributions to the Data on Theoretical Metallurgy. VI. A Revision of the Entropies of Inorganic Substances-1935; and (7) Contributions to the Data on Theoretical Metallurgy. VII. The Thermodynamic Properties of Sulphur and its Inorganic Compounds. The present paper collects and discusses thermodynamic data relating to metal carbides and nitrides, with the view of obtaining usable heat and free energy of formation relationships. Pertinent data on both classes of substances are difficult to obtain experimentally and consequently are extremely rare; it is therefore necessary in many cases, if equations are to be derived, to introduce certain approximations and assumptions. Lack of adequate means of checking results by utilizing data of different types, such as was done frequently in the bulletins dealing with carbonates and sulphates, are readily apparent to anyone who has made even a cursory examination of the available information. Consequently, some of the relationships derived undoubtedly will be found to be inaccurate when more or better data become available. Nevertheless, in view of the importance of some of these substances, it appears worth while to consider the information available at present and to attempt the formulation of as complete a

Jan 1, 1937

By K. K. Kelley

The first bulletin (269) 3 in this series, which appeared in 1932, compiled the entropy values then available for the elements and in-organic compounds, results being listed for some 150 substances. Elaborations and revisions followed in 1936 (272) and 1941 (280), when over 500 usable entropy values were tabulated. The present bulletin constitutes a further elaboration and revision. The accumulation of data since 1940 has been marked, and 800 entropy values now are available. The present bulletin also contains all the pertinent explanatory matter that appeared in its predecessors. Thus, it retains the same dual purpose of assembling the available values of the entropies at 298.16° K. of the elements and inorganic compounds and giving enough explanation of methods of calculating entropies to make the results comprehensible.

Jan 1, 1950

By H. L. Monro

Contribution by B. K. Martust I congratulate the author on his interesting paper. In my view, the establishment of the level at which South African gold output is at some kind of optimum is an interesting though somewhat academic exercise. Contribution by D. M. Hawkins* The thesis of the paper is a very interesting one, but, before it is used as the basis of any firm proposals to restructure the mining industry, which changes may be irreversible, one should be very sure that the basis of the calculations is sound. Contribution by P. J. Niewenhuizen* The hypothesis advanced by Mr Monro that the demonetization of gold in August 1971 introduced a major new policy variable, namely the supply-pricejdemand-price relationships, into the decision making process touches on a matter that has never really been given serious thought by the industry. Contribution by B. G. Kingsman* As a co-worker on the development of an econometric model for supply and demand in the world gold market with Mr H. L. Monro, it would perhaps be useful for me to make some comments on the various points raised in the discussions on his paper.

Jan 1, 1984

By Elham Kordzadeh

As the world’s reserves of coarse and high-grade iron ores continue to shrink, beneficiation is becoming increasingly important. The resulting concentrates cannot be used directly as feedstock for iron making, but require an additional agglomeration step. Pelletizing is preferred, because the uniform chemical, physical, and metallurgical characteristics of pellets make them a more desirable feed for the iron making processes. The heat hardening or induration of pellets is typically done in shaft furnaces, grate-kiln systems or on straight grates. Rotary kilns were originally developed in the late 19th century for Portland cement production [1]. The main development work for the successful adaptation of the process to the thermal treatment (induration) of green balls from iron ore was performed by Allis Chalmers in Milwaukee, Wisconsin, USA in the 1960’s [2].The straight grate process, which was first used in 1955 at Silver Bay, Minnesota, was a dedicated development with the aim to pelletize and indurate magnetite (taconite) concentrate [2]. There are various important technical and economical distinctions between the two pelletizing technologies. The most important differences include that a grate-kiln has three distinct pieces of equipment, a preheat grate, a rotary kiln and an annular cooler, whereas in the case of a straight grate, the entire indurating process is done on one piece of equipment only. In addition, both technological solutions have differences in their recuperation systems, direction of air flow in drying, number of burners, form of pellet movement, etc., which cause differences in raw material suitability, process control, economical aspects, plant operation and product pellet quality.

Oct 30, 2017

By Martial P. Corriveau

The preparation of coal is essentially the same for export as it is for the domestic market. The big difference, I would say, is that, while coal for certain domestic uses (utilities, for instance) need not always be of the highest quality, as long as it is uniform, the buyer of coal for export invariably demands a well-prepared, top-quality product. And he is willing to pay for it, as long as he knows what he is buying. This is where quality control enters the picture. The day is long past since the export market was the dumping ground for coals which could not be sold on the domestic market. Today, the export buyer wants American coals not so much for a price but for the necessity of blending the American coals with foreign coals to achieve the desired chemical and/or physical characteristics, To blend intelligently, he must know in detail what are the qualities of the coals to be blended. Sampling and chemical analysis facilities at the piers provide the information on the coals exported, These facilities are maintained for the export buyer by independent laboratories; however, in one instance, the buyer operates his own laboratory. With very few exceptions, and Clinchfield?s Moss No. 3 mid-volatile coal is one, cargoes shipped overseas are loaded as blends of two or more coals. Up to now, foreign requirements have not been too clearly defined; therefore, shippers must be prepared to blend mixtures of the desired combination. Successful blending requires an accurate knowledge of the coals shipped. And this makes it necessary for the coal producer to maintain his own control laboratory.

Jan 1, 1959

The concentrated efforts now being directed towards the development and application of monitoring and control techniques have now resulted in their widespread use in UK mines together with evidence of benefits resulting from their application. There is little doubt that the longwall method of producing deep mined coal will continue but will be made more reliable and efficient with the aid of control technology. The major fields of research and development work are concerned with planning and design of mines and mining equipment; management and engineering information; and automation of coalface, tunnelling and transport systems. The principal achievements now in widespread use are: the standard computer system MINOS, widely applied to mine transport, coalfaces and mine environment; extensive use of machine condition monitoring leading to condition-based maintenance; underground automation of conveyor systems and guidance systems for ranging drum shearers and boom-type roadheaders are being widely introduced.

Jan 1, 1985

By R Shaw, T T. Neidel, C Adams

Sampling equipment manufacturers endeavour to ensure that the mechanical equipment installed in sampling systems are designed and manufactured to adhere to the requirements of the International Organization for Standardization (ISO) or other standards relevant to the application. The mechanical parameters necessary to achieve these standards can be well controlled and requirements such as constant speed can be met through good mechanical design and engineering. However, when the equipment is installed and put into operation, the ISO compliance of the system is out of the hands of the equipment manufacturer and handed to the operator, who may be a generalist control system integrator.Making a sampling system perform according to standards, and being able to monitor and report on compliance require that the sampling system knowledge and the control integration is combined and applied in an integrated approach. Using a dedicated library of control routines developed for sampling can change a system from having compliant equipment to being a compliant system. The library has to include monitoring of relevant parameters and control and reporting on sampling parameters.CITATION:Neidel, T T, Adams, C and Shaw, R, 2014. Control and monitoring of International Organization for Standardization compliance for industrial sampling systems, in Proceedings Sampling 2014 , pp 121–126 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 29, 2014

By Barry J. Morash

The over-all slope angle of between 55 and 60 degrees at the Adams Mine necessitates control blasting on the final pit walls. The control blasting techniques used are pre-shearing and buffer blasting. Pre-shearing with 2'I2-inch holes on 5-foot centers is used in areas where jointing and rock type are not conducive to smooth stable walls. Buffer blasting with 12'/4-inch holes is used in areas where the rock is competent. Control blasting adds to the operating costs, but can result in substantial savings in increased slope angle and reduced stripping.

Jan 1, 1978

By César Fuentes Líbano

El presente trabajo describe el tratamiento que realizó la refinería de zinc de Cajamarquilla en sus afluentes para preservar el medio ambiente. Para ello, la construcción de dicha refinería ha establecido una serie de reglas precisas basadas en el avance tecnológico y la acción contra el medio ambiente de los desechos. Es decir, la refinería fue diseñada y construida con la tecnología más moderna, garantizando que sus efluentes cumplan los requerimientos más exigentes de preservación del medio ambiente.

Nov 8, 1982

By A. Musschoot

"The paper will review general types and designs of vibratory feeders, describing briefly the design features and characteristics that apply to the application of specific types. Control considerations for selecting types will be dis• cussed, such as fixed or adjustable, manual or automatic, individual or multiple bank, and process requirements. Design parameters for hopper openings and installation geometry will be discussed, including consideration of material size distribution, segregation, moisture content and other characteristics, based on practical applications and experience as well as theory. Pan designs and the selection of pan materials will also be discussed with reference to wear, corrosion, impact and practical economic factors."

Jan 1, 1972

By Patrick Sullivan

Over the past few years, successful operations for processing phosphates employing the Grate-Kiln System have been achieved. Control and instrumentation philosophy followed in these installations are described and analyzed. Concepts utilizing digital techniques and computer systems appropriate for similar installations are also discussed.

Jan 1, 1967

By Jacques LeBel

After a brief definition of asbestos and a review of regulations, the elements of asbestos dust control are outlined for various asbestos manufacturing industries. To prevent the asbestos dust to become airborne, the general procedure is to control the dust at the source by enclosure and exhaustion. The asbestos dust is collected and removed from the air with bag filter collectors of high efficiency (better than 99%) to ensure that the air emitted to the general environment or returned to the workplace are below the existing asbestos emissions regulations. Dust control systems should be regularly inspected and serviced to maintain at all times the efficiency and reliability of the equipment. Other effective procedures for asbestos dust control are also considered.

Jan 1, 1984

By Getliffe RK

It is becoming more and more difficult to operate mineral and metal processes profitably, as operating costs rise, quality demands in-crease, international competition becomes more fierce and Government charges remain at their current levels. Profitability today depends upon efficient operations, which can only be achieved through precise and dependable con-trol of each process unit comprising thetotal plant.Modern process control systems utilise distributed architecture with microprocessor-based controllers, data acquisition devices and VDU operator stations. Honeywell intro-duced this control technology in 1975 with the "Total Distributed Control" System. Now, building on the proven performance and re-liability inherent in TDC hiway modules, Honeywell has extended the TDC system to inte-grate both management information and control by providing distributed processing modules on the new TDC 3000 Local Control Network (LCN).

Jan 1, 1985

By Kazuhiro Nisizono, Takashi Kuroki, Nobuyuki Mori, Keisaku Ogi

"The improvement of critical current density and mechanical property is essential to the practical application of the superconductive oxides. A solidification technique is developed in this study for the growth of columnar or single Y123 crystal with finely dispersed Y211 and Ag particles through a monotecto-peritectic reaction of Li.(Ba-Cu-Ag-0 rich liquid)+ Y211-+ Y123+Lz(Ag rich liquid). The large solidification rate and temperature gradient can refine the Ag and Y211 particles. But Ag-free region is widely formed along the crystal growth direction in the central part of the Y123 cell. Since this phenomenon occurs because of the cellular growth, it is necessary to narrow Y123 cell width or to grow Y123 crystal with flat freezing interface. By controlling crystal growth direction using a seed crystal, Y123 columnar or single crystal with uniformly dispersed fine Ag particles are obtained. The· behavior of Ag and Y211 particles during the solidification of Y123 crystal is simulated by the peritectic growth model of faceted Y123 crystals.IntroductionY-Ba-Cu-0 superconducting oxide (YBCO) with high critical temperature also has excellent superconducting characteristic under the high magnetic field. The critical current density (Jc) has been enhanced by ·using unidirectional-solidification technique, which can overcome the weak-link problem at grain boundaries and control the crystal orientation and the distribution of Y211 particles which give effective magnetic flux pinning centers in the Yl23 matrix [1-4].In addition to improving superconducting properties, it is necessary to improve mechanical property for the practical application. The silver addition to the melt-textured YBCO superconducting oxide has been reported as the effective method to improve mechanical properties without degrading superconducting properties. Since the material properties are considered to be largely affected by silver particle size, form, dispersion state etc. in the Y123 phase, it is important to control Ag distribution in YBCO/Ag composites. Besides, it is also reported that the silver addition improve the corrosion resistance to the water and CO2 [5,6]. Nishizono et al. [7-9] have reported that the silver distribution in the YBCO/Ag composites is largely affected by the solidification condition, but yet some unclear points are also remained. YBCO has been also fabricated by the zone melting method [10-12], and Furuya et al. [5] and Hirano et al. [13] have reported the fabrication of silver added YBCO composites, but the distribution and behavior of Ag are not investigated in detail"

Jan 1, 2000

This paper describes techniques that have been used at RixÆs Creek Colliery to control blast vibration from throwblasts that face a residential area 4 km in front of the face. The paper describes blast design, face control including laser profiling, selective loading of blastholes after borehole camera surveys, and techniques used to assess the effect of burden variation, the cumulative effect of drilling and delay sequence, and the effects of meteorology.

Jan 1, 2001

By André Pomerleau, Michel Grégoire, René del Villar

"The operation of industrial flotation columns requires the control of at least two variables, the interface position and the bias rate, by manipulation of some appropriate operating variables. Problems arise due to the reliability of existing methods of measuring the bias (i.e bias = tailings water - feed water), a situation which has often forced the industry to disregard this control loop. Moreover, when using such a measuring approach, the identification of the process dynamics is impossible. A second problem arises from the possible interaction between both control loops that might call for the use of a more complex multivariable control strategy.Recent work done at Lava1 University has demonstrated the feasibility of an independent sensor for bias, which models the relation between the conductivity profile across the interface and the bias value using a neural network algorithm. A 250 cm height, 5.25 cm diameter Plexiglas laboratory column was equipped with a series of conductivity electrodes in its uppermost part (across the interface) to measure both interface position and bias rate. Using such equipment, the flotation column dynamics were identified. The results thus obtained permitted the design and implementation of a distributed PI control strategy, where bias was associated to wash water rate and froth depth to tails rate. Both PI controllers were tuned using a frequency-response tuning method. Results of both identification and process control are presented and discussed.INTRODUCTIONFlotation columns are used for the separation of valuable minerals from a carrier gangue. Typically, this device is a tall (9 to 14 m height) cylinder (1 to 3 m in diameter) although other cross sectional shapes are also used. Finely ground ore is fed as a pulp at about 2 m from the top of the column, and pressurized air is introduced through a sparger at the bottom. If the pulp has been properly conditioned with adequate chemical reagents (collectors and modifiers), the valuable mineral particles falling by gravity will attach themselves to the rising air bubbles, and the air-particle aggregates will rise to the top of the column where they overflow as a stream called the concentrate. The gangue particles,, that do not attach to the air bubbles, fall down the column being withdrawn at its bottom in a stream called the tails.A particular characteristic of flotation columns is the addition of a fine spray of water at the top. As the water flows down through the froth zone, it washes out the entrained gangue particles from the mineralized bubbles, thus improving the quality of the concentrate recovered at the top. As a result of its cleaning action, this water stream is called the wash water and the upper zone, the cleaning zone. In order to ensure a downward flow of wash water, a proper water balance must be kept in the froth zone, otherwise the water added at the top might shortcircuit to the concentrate without performing any cleaning action. This net downward flow of water inside the froth zone is called the bias and represents an important operating variable of a flotation column."

Jan 1, 1999

By Hector O. Romero, Paulo C. Fernández A, Christian Rees Prado, Claudio C. Gajardo

In open-pit mining, estimating post blasting displacement and spillage accurately is essential to guarantee operational efficiency, ensure alignment with production plans and their associated key performance indicators. The absence of predictive modeling tools on blasting operations results in several critical challenges, including operational reworks due to deviations in material displacement, significant discrepancies between mine and plant (ore grade dilution included), misalignment with the reported production plan, and increased operational costs due to inefficient use of resources. This study, conducted at Los Bronces Mine operated by Angloamerican, Chile, addresses the application of a three-dimensional simulation tool that, through numerical modeling, is capable of predicting post blast rock displacement. The implementation was carried out in a pit phase characterized by blasts near the pit boundaries, with a high risk of material spillage and potential blockage of the only access ramp to the extraction levels. By the integration of key design parameters, such as blast pattern geometry, detonating time, explosive charge distribution and pre and post blast survey, an optimal calibration was achieved and validated in seven blasting events to date, reaching an accuracy greater than 80% in estimating post-blast rock displacement and spillage volumes. Furthermore, this study allowed the evaluation of different pattern alternatives with and without spillage mitigation measures (use of air decks near the free face), obtaining a high correlation and accuracy exceeding 95% in predicting the selected design outcome, supporting optimal design selections. The result highlights the usefulness of the model as a decision-support tool for blasting engineers and short-term planning, by reducing the need for unnecessary operational reworks, improving geological and operational reconciliation, and ensuring the alignment of the extracting plan with production targets. The current average deviation is 15%, with higher deviations observed in blasts with smaller volumes of spill or where the simulated sequence was changed before blasting. The use of this type of three-dimensional numerical modeling represents a significant advancement for blast engineering and the optimization of key performance indicators in open-pit mining operations.

Jan 26, 2026

By V. R. Manukonda

Selective flocculation of iron ores is extremely sensitive to the type and the amount of soluble salts in pulp solutions. Chemical precipitation of alkaline earth ions combined with ultrasonic treatment deactivates their adverse effects without using any environmentally ill-defined reagents. The manner in which ultrasonic treatment affects starch adsorption on hematite, dissolution of quartz, and selective flocculation process was investigated. Selective flocculation tests were conducted in the presence of up to 400 ppm calcium ion on a quartz-hematite mixture by precipitation as calcium carbonate, and the role that silicate ion generated by ultrasonic treatment plays in achieving the selectivity of separation is discussed.

Jan 1, 1987

By Raja V. Ramani

Worldwide, promulgation and enforcement of health and safety laws and regulations have been the primary means of ensuring minimum and uniform standards of health and safety in the mining industry. In U.S. coal mines, a new era was ushered-in in 1969 for the control of health hazards from respirable coal mine dust. Since then significant progress has been made on all aspects of the respirable dust problem-its definition, monitoring, reduction, and control. In the intervening years, our ability to monitor, analyze, and characterize the mine atmospheric environment and the health of miners has increased many fold. Also, advancements in production technology have far outdistanced enhancements in environmental control technology. Therefore, questions are continuing to be raised on the adequacy of the characterization and control measures with regard to both the airborne respirable dust in mines and the health effects of respirable dust. Late in 1995, the Secretary of Labor appointed an Advisory Committee on the Elimination of Pneumoconiosis Amona Coal " Mine Workers (Dust Advisory Committee) to review the progress towards elimination of coal worker's pneumoconiosis (CWP) and silicosis, and in the program to control respirable coal mine dust in underground and surface mines, and make recommendations including improved standards and other appropriate measures for the control of exposure to airborne coal mine dust. The Committee's report was released in October, 1996. In this paper, a summary of the recommendations of the Committee is presented. A brief discussion of the background, and the issues and findings leading to the recommendations is also presented. The Committee concluded that the progress made towards making mines safer from the health hazards of respirable coal mine dust is substantial but that it is not sufficient to achieve the intent of the 1969 Coal Act. The Committee's recommendations encompass a wide range of issues addressing permissible exposure limits (PELS), sampling, dust control plans, hazard and medical surveillances, role of miners, training, and research and development.

Jan 1, 1997

By T. S. Spicer, C. C. Wright

A CHARACTERISTIC property of bituminous coal is that upon being heated the coal becomes plastic, evolves volatile gases, and finally solidifies into coke This fundamental characteristic is of utmost importance and is utilized in the production of the high-temperature coke upon which the steel industry is so dependent, but from the standpoint of operation in the domestic underfeed stoker this coking tendency seriously interferes with efficient combustion When the coke formed has too strong a structure, certain difficulties result, such as low rate of burning, slow response to heat demand, and, in extreme cases, extinction of fire The plastic mass prevents uniform distribution of air through the fuel bed and, With strongly coking coals, large dense pieces of coke are produced which have much less reacting surface thin was possessed by the original coal In both ignition and combustion of solid fuels, the extent of the reacting surface is an accelerating factor Poor combustion permits a surplus of fuel to accumulate in the furnace because the rate of feed and the rate of combustion are not in equilibrium, and this produces an unbalanced condition detrimental to continued) automatic service In order to burn strongly coking coals satisfactorily in a conventional stoker during the three requisite types of operation continuous, intermittent and hold-fire, frequent attention is necessary Domestic stokers are defined by the industry as residential stoker heaters that burn 60 lb of coal or less per hour With a few exceptions, these units employ the underfeed principle of combustion in which both air and coal move in the same direction up and through the fuel-bed Domestic combustion equipment has difficulty in meeting the problems presented by the several variations in ash and volatile matter, in ash-clinkering tendencies, in coking properties, and in the particle size of bituminous coals The work of Bituminous Coal Research Inc at Battelle Memorial Institute has shown that, of these, coking characteristics and the clinkering tendencies have the greatest effect upon the operation of the conventional clinkering type of stoker Typical coke formations in a clinkering type of underfeed domestic stoker are illustrated in Fig. I, which shows (A) the ideal fuel bed obtained with a noncoking or free-burning coal, (B) the type of fuel bed formed -with, a coal that produces a weal coke, and (C) the type of fuel bed obtained with a strongly coking coal C is characteristic of the fuel bed developed when the average Pennsylvania bituminous coal is ,burned in an underfeed stoker of conventional type It is apparent from these pictures that the formation of coke trees will seriously interfere with the efficient automatic combustion of Pennsylvania bituminous coals

Jan 1, 1942