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By Carl A. Zapffe, George A. Moore

IN a previous publication from this laboratory1 the conclusion was drawn that the embrittling effect of occluded hydrogen on iron and steel must result from the precipitation of the gas within small openings through the crystal structure. A review of the literature then published indicated the real existence of crystal sub- structures of the mosaic type and gave presumptive evidence that the "rift openings" associated with hydrogen occlusion are the same as the "disjunctions" of the mosaic theory. Inasmuch as no clear conception of the actual nature of the crystal fragments and openings inherent in these theories has been established, it was considered desirable to obtain direct micrographic evidence of their true configuration. In this direction the standard methods of metallographic attack have proved useless. Recourse was had, therefore, to the direct examination of the surfaces upon which failure by cleavage had resulted from the presence of hydrogen. It was expected that such a surface, un- affected by chemical attack and undistorted by polishing, would reveal the fine openings penetrated by the gas and thus indicate the real nature of the substructures. MATERIALS STUDIED In commercial steels, defects caused by hydrogen take various external forms ac- cording to such factors as structure and purity, and to the extent to which hydrogen either occludes or produces chemical changes. The present work relates only to the well-known transcrystalline hydrogen embrittlement-"pickling brittleness"-in which elemental hydrogen occluded within the grain develops cleavage characteristics. For example, hydrogen embrittlement resulting from hydrogen reaction products is excluded from detailed study. It was also desirable, as far as possible, to have the study uncomplicated by other elements which themselves cause brittleness. Three types of iron were used. These included ingot iron, decarburized free- machining steel, and a specially prepared, aluminum-killed, electrolytic iron. This , choice allowed a comprehensive selection of unavoidable minor impurities and inclusions, which could subsequently be shown to have no specific effects on the structures within the grains. Carbon, and any other impurities free to react with hydrogen, were first removed by a preliminary annealing treatment in hydrogen. Subsequent treatment in vacuo extracted much of this hydrogen and its gaseous reaction products. The resultant ductile iron was then embrittled either by a second anneal in hydrogen, followed by rapid cooling, or by cathodic electrolysis. Group I: Prepared from Armco Ingot Iron As shown in Table I, the principal impurity in this iron was oxygen, which survived the purifying treatment to a large extent. Two series were prepared. The first (Nos. SIO-24) was purified only one day in hydrogen and dehydrogenized one day in nitrogen. Containing both hydrogen and its

Jan 1, 1943

By V. A. Marple, K. L. Rubow, S. M. Behm

"An eight-stage cascade impactor, with cut-sizes ranging from 0.056 to 18 um at a flow rate of 30 L/min, has been developed, calibrated, and tested in field programs. This impactor, called a microorifice uniform deposit impactor, has several features not normally found in cascade impactors. Ultrafine particles as small as 0.056 um are collected while keeping the pressure drop moderate by utilizing multiple nozzles (up to 2000) as small as 52 um in diameter. At each stage the collected particles are deposited uniformly over the entire impaction plate by rotating the impaction plate relative to the nozzles and by the correct radial placement of the nozzles. The particle cutoff characteristics (collection efficiency curves) of each stage and inter-stage losses were determined by means of monodisperse aerosols. The cutoff characteristics were found to be sharp and similar for all stages.Inertial impactors are widely used for the size-selective collection of aerosol particles. One reason for their wide usage is that the principle of operation is simple: a jet of particle-laden air is directed at a flat impaction plate. Large particles are collected on the plate while smaller particles follow the airflow out of the impaction region and are not collected. The division between the size of particles collected and those that are not is quite sharp. Secondly, the particles in an impactor are classified by their aerodynamic diameter (an important size parameter in many fields of study, including those related to respirable particle health effects). Thirdly, it is easy to collect particles in discrete size ranges by passing the aerosol through a number of stages (one stage consisting of a nozzle and impaction plae) in series, with each subsequent stage collecting particles smaller than the one before it. This is known as a cascade impactor. Finally, impactors can classify particles over a wide range of particle sizes: as low as 0.005 um (Fernandez de la Mora et al., 1990) and as large as approximately 50 um (Vanderpool et al., 1987).This paper describes a general purpose cascade impactor that has been developed in our laboratory and used in a variety of studies including visibility studies (McMurry et al., 1986; McMurry and Zhang, 1989), underground mine studies (Marple et al., 1986; Rubow and Marple, 1988; Rubow et al., 1988), and general atmospheric pollution studies (Macias et al., 1981; Dzubay et al., 1984). The impactor, called a microorifice uniform deposit impactor (MOUDI model 100, MSP Corp., Minneapolis, Minn.), is the integration of two earlier impactor de¬velopments: the microorifice impactor (M01) (Kuhlmey et al., 1981) and the uniform deposit impactor (UDI) (Marple et al., 1981).The MOUDI has several features normally not found in other cascade impactors. These include collection of particles as small as 0.056 um in aerodynamic diameter with a moderate pressure drop, uniform particle collection on the impaction plates, inter-changeable impaction plates to allow for the plates to be easily and quickly changed in the field, and covers for these substrates to provide a means for safe storage and/or transport of the collected particles to the laboratory for analysis."

Mar 1, 1992

By S. Oppenheimer, P. Au, R. M. Kearsey, J. Tsang, E. McDevitt

A new superalloy, ATI 718Plus® Alloy (718Plus), has been developed to have a 55oC higher temperature capability over the traditionally used Alloy 718, while maintaining favourable processing characteristics and intrinsic raw material costs. The fatigue and dwell-fatigue behaviour of four microstructural variations of 718Plus are evaluated and compared to Waspaloy: 1) standard heat treated condition (HT1), 2) standard heat treated condition with thermal exposure at 732ºC (1350ºF) for 1000 hours (HT2), 3) fine grain condition with a modified d phase (HT3), and 4) fine grain overaged through modified heat treatment (HT4). The results show that the steady-state fatigue crack growth rates of each microstructural variation and both alloys are identical, with all of the 718Plus variations showing a clear advantage over Waspaloy in the fatigue crack threshold regime. Dwell-fatigue results show that Waspaloy has better resistance to crack propagation under dwell conditions; however, optimization of the precipitate phase shows vast improvement in the dwell-fatigue resistance of 718Plus.

Jan 1, 2010

By Richard A. Shulkosky

The American Iron and Steel Institute (AlSO, in conjunction with the U.S. Department of Energy (DOE) jointly funded the development of a mechanical properties model for Hot Strip Mills. INTEG process group, inc. validated an enhanced version of the model under a project funded by the AlSI/DOE Technology Roadmap Program (fRP). The Hot Strip Mill Model (HSMM) version 6.0 allows users to easily set-up their mill configuration, simulate a rolling mill schedule and calibrate the model for a variety of grades of steel. Starting from reheat furnace drop out, the model simulates roughing mill stands (reversing and continuous), heat retention equipment (coil box and covers), finishing mill stands (tandem and Steckel mills), the run out table and the mill exit area. The HSMM uses a series of physical models to calculate both the thermo-mechanical and the microstructure evolution of steel being processed in a hot mill to predict its final mechanical properties. The enhanced HSMM was validated using a multitude of samples from several steel companies. Excellent agreement was obtained for tensile strength. The supporting steel companies have utilized the model for a variety of practical applications. Keywords: Process Modeling, Microstructure Evolution, Mechanical Properties

Jan 1, 2003

By S. A. Matthes

This Bureau of Mines report describes a system for the dissolution of metal and mineral samples using a microwave heat source. Samples and an acid mixture are placed in sealed polycarbonate vessels. The vessel contents are heated using microwaves, digested for 2 min, and quickly cooled. After the solution is brought to a final volume, the vessel contents are heated an additional 2 min in the microwave oven. Using this method, a slag, a feldspar, and a Ni-Cu alloy were dissolved and analyzed by atomic absorption spectroscopy. Values obtained for Na, K, Cu, Ni, Si, Mg, Mn, Ca, Al, and Fe agreed with certified values and had an average relative standard deviation of 1 pct. This system results in a significant savings in time and expense over traditional methods of sample dissolution, and is ideal for preparing solutions for analysis by atomic absorption, plasma optical emission, or X-ray spectroscopy.

Jan 1, 1983

Reduce the time, complexity and expense of dissolving metal and mineral samples in solution in preparation for chemical analysis. Approach In earlier research, the Bureau of Mines developed a rapid and inexpensive method for the dissolution of mineral and metal samples in plastic pressure bottles heated in a boiling water bath. Using this technique, samples could be prepared for chemical analysis in less than one hour compared with several hours by traditional dissolution methods (see Technology News No. 85, December 1980 for further details). By heating in a microwave oven, sample dissolution time can be reduced to approximately 5 minutes.

Jan 1, 1983

By John A. Baker

S EVERAL FACTORS have brought about a vastly greater interest in the gold-mining industry in the last two or three years. Outstanding is the fact that there is an open market at a fixed price for all that can be produced. a condition that holds for no other commodity. Costs of production have decreased greatly, owing to lower prices of supplies and equipment and lower wages. Improved metallurgical processes and equipment are also available. To big new gold district is being opened up but virgin ground is being prospected with some success in many of the more remote parts of the world and right here in the United States many old properties are being reopened 111 the light of present condition<, tailing dumps are being re- worked, and profitable leases taken on abandoned property. Many of the men who are becoming interested in gold are mining engineers whose experience has all been with base metals heretofore: some are engineers with no mining experience; some are not engineers at all but men who cannot find profitable employment in their usual field of activity and are attracted by the age-old lore of the yellow metal. Some are business men with a little money and an idea that under present conditions gold mining offers a safer investment for it than most other kinds of business. It is to those more or less inexperienced new- comers in the gold-mining industry that this article i4 ad dressed. Those who are connected with the large gold mines or who have had rears of experience with the small ones will find in the following pages little or nothing of interest but it is hoped that the newer generation of small mine operators, on whom the healthy growth of the industry depends so much, may find here some helpful hints.

Jan 1, 1932

By E. O. Magnusson

THE orebodies of the Preston East Dome mine show a considerable variation in size,? shape, dip, and ground condition. They vary from small and large irregular masses being mined by shrinkage, cut-and-fill, and square set-and-fill mining methods to narrow veins being mined by open stoping. Standardization of mining operations has necessarily been difficult. This considerable variation in mining condition prompted the development of a bonus system which would give more equitable bonus payments through-out the mine than those obtained by the usually accepted methods of calculating mine bonus. PRINCIPLES ON WHICH THE SYSTEM IS BASED Under an incentive bonus system, performance (efficiency) and a price per unit of work done are inter-related. It is in the application of this? principle to working conditions .in the Preston East Dome mine that the system to be described differs from the standard methods of calculating mine bonus. It was found that the method of paying a fixed price per unit of work done, under the &apos;contract&apos; system, gave satisfactory results in development, less satisfactory results in timbering, and results which were not satisfactory in stoping. Under the fixed price system, bonus payments, in timbering and stoping particularly, were very erratic and did not necessarily represent fair payment for the work done. A fixed price in development is satisfactory because the work done, and the conditions under which the work is done, are uniform. The drilling and blasting cycle is completed in one shift, the size of heading is con-trolled, and a minimum number of holes are required in order to obtain a satisfactory break. The performance possible under these conditions has been found to be confined to a fairly narrow range. By performance in development is meant the efficiency of the working crew as expressed in terms of the two variables of feet of advance per round and pounds of ex-plosives consumed per foot of advance. A change in rock formation, how-ever, may alter to a marked degree the performance possible, quite independent of the skill and energy of the working crew. The changes in working conditions that affect development performance from the standpoint of bonus calculation are usually easily apparent and are satisfactorily met by establishing several fixed prices.

Jan 1, 1944

By G. T. Lineberry

A systematic, comprehensive, balanced approach is presented for underground coal mine design, capable of being standardized and generalized. This approach epitomizes professionalism and must preceed the physical product. Design involves a varied senior staff and requires extensive selective input data. Engineering follows a total systems approach, operating in and for a constricting geologic setting, heavily constrained for safety, health, and environmental protection. It must also anticipate execution and operation. Engineering prominence and momentum are maintained, with sub-optimizations balanced by judgments--the "art and science" of engineering. The flow-chart starts with organized input data: Company Capabilities, Property Description, Geologic Analysis and Reserve Analysis. Engineering combines Ground Control with Excavating and Bulk Handling to map feasible Mining Methods, the crucial Milestone Diagram. Layout and Sequencing follow, with numerous alternatives examined. Scheduling is performed on the best designs, using predicted advance (performance) rates. Active and mined-out areas are isolated into time-related parcels, or increments, for the mine life. Bulk Handling, Life Support (especially ventilation and drainage), and Normal Support systems occupy each parcel. Regulations are then checked. Management concerns are covered, and an Economic Analysis is performed for profitability. This and the design represent an Initial Tentative Solution. Continued iterations produce multiple and improved choices.

Jan 1, 1987

By J. E. Urosek

In October, 1990, a fire started in a large underground coal mine in Western Pennsylvania. During fire-fighting activities, an explosion occurred and all personnel were evacuated. Safe re-entry into the mine was not possible and the mine was sealed. Recovery efforts began in January, 1991 and continued until March, 1991, when permanent underground seals were installed between the fire area and the mine openings. This paper describes an extensive atmospheric monitoring program conducted by the Mine Safety and Health Administration (MSHA), Pittsburgh Safety and Health Technology Center (PS&HTC) including the analysis of mine fire gases, natural ventilation, fan pressure and air quantity distribution.

Jan 1, 1993

To quickly and more reliably measure the alignment and deflection of mine guides used to run skips and cages into a mine shaft. The Problem Conventional mine guide alignment measuring systems require the use of a plumb bob and tape measure. This method is not only laborious, but it is time consuming as well. Approach Aware of the drawbacks of the current measuring method, the Bureau of Mines designed a self-contained instrument system that can accurately perform vertical guide alignment and deflection measurements by remote control. How It Works The Bureau-developed instrumentation system, called the Guide Alignment Measuring System (GAMS), is based on conventional mechanical electronics using inclinometers and displacement transducers. The instrumentation system is attached to an operating skip or cage where it functions as a completely self-contained measurement system, operating in conjunction with nor-mal travel of the skip or cage. An on-board tape recorder or a mini-computer with memory can be used to record all telemetry.

Jan 1, 1987

By G. H. Blackwell, N. I. Norrish

"At most operating mines, geostatistical are reserve estimation methods have been implemented by head office or consulting groups . With recent advances in small computer technology it is now possible for a remotely-located mine department to independently implement a geostatistical package.This paper describes the evolution of geostatistical routines to calculate the mineral inventory for porphyry type copper/ molybdenum or similar are bodies. The problems encountered in down sizing the geostatistical routines to run using limited minesite computing facilities are discussed. The high quality of the results, in spite of some compromises to geostatistical theory, is emphasized.The first stage entailed the development of a mineral inventory based on diamond drill data. The difficulties in fitting variogram models to two metals, copper and molybdenum, and the shortcomings of the mineral inventory due to the mixing of lesser quality exploration data with data from more recent diamond drilling are discussed.To improve the ore reserve estimates for short-term planning, a mineral inventory was produced using both the diamond drill and production blast hole drilling data. This inventory, when compared to actual grades, was found to be quite satisfactory for short-term planning. The inventory also provided a reliable data base for long range pit design and financial planning. By regularly updating the mineral inventory, many of the uncertainties of mining a low-grade orebody were minimizedIntroductionThe comparatively low grades of many Canadian mineral deposit s, the escalation of mine operating costs, and the volatility of metal prices in recent years, has required improvements to both short- and long-term mine planning.One of the prerequisites to improved planning systems is the need for accurate grade prediction. This paper describes the on-site implementation of geostatistical techniques for grade estimation of a porphyry I vein type copper/molybdenum ore body ."

Jan 1, 1987

By W. J. Douglas

The mine manager in today&apos;s environment is faced with a wide variety of problems and challenges which must be addressed if efficient and profitable operations are to be achieved. Expansion of operations has, in many instances, resulted in inexperienced work crews, face supervisors, and superintendents. The complexities of a mining system preclude rapid movement through the learning curve for moat personnel. The management of production suffers both from this inexperience and the lack of standard procedures and methods for planning, schedul ing and analyzing production systems. The lack of visibility of information, as well as of the operations themselves, due to their remoteness, adds to the problem of production management.

Jan 1, 1980

By R. W. Lake

The decision to develop an ore body can lead to multi-million dollar profits, or equally substantial losses. Accordingly, the effort required to adapt a valuation model to the specific proposal at hand, or even the development of a new model from basic principles, is clearly warranted. In the formulation of a model of this nature, one is faced with some major questions. For example, with the long term obligations that it implies, on what basis should a decision to initiate mining operations be made? Furthermore, how can the vagaries of inflation and the uncertainties that shroud the future be accommodated? Beyond the general principles by which mineral deposits are evaluated, specific cost behaviour is a function of the geology of the deposit, and of the mine design. Moreover, mine design, during the life of the mine, must be a continuing process somewhat akin to dynamic programming. An initial, apparently optimal, design is selected and mining commences. With production, a continual process of information updating leads to revisions. Thus if the maximum value is to be obtained, the mine design must be adjusted to conform to the changed conditions.

Jan 1, 1977

By Diogo Fonseca, José Manuel, Nuno Fernandes, Blessing Taiwo

This research focuses on enhancing the synergy between blasting and primary crushing operations in quarries. A blast operation at dstgroup aggregate quarry in northern Portugal was simulated to fine-tune blasting techniques aimed at optimizing fragmentation indicators. The methodology involves conducting precise blast drill hole surveys, generating detailed terrain 3D models, and integrating these models into blast simulation software to enhance accuracy and optimize production efficiency. The study applies these simulations to test blasts, evaluating improvements in cost-effectiveness, crusher power consumption, and fragmentation efficiency using both aerial and terrestrial image analysis technology. The quarry key performance indicators (KPIs) guide the blast design simulations, ensuring practicality and relevance. The case study blast revealed that implementing optimum blasting techniques can enhance crusher throughput, reduce operational costs, and improve safety. This paper is part one of a three-part technical series where we aim to create a sampling procedure and establish a reliable baseline for the current state of operation. This baseline will be used in subsequent follow-up technical papers to make recommendations and improvements. The outcome of this study provides a framework for quarry operations seeking to enhance their efficiency.

Jan 21, 2025

By Diogo Fonseca, José Manuel, Nuno Fernandes, Francisco Monteiro, Andrew Palangio, Blessing Taiwo

This study aims to enhance the integration between blasting and primary crushing operations in quarrying by optimizing the size of oversize and bypass fragments, ultimately reducing energy consumption. Using simulations of multiple blast rounds at the dstgroup aggregate quarry in Portugal, the research seeks to refine blasting practices and improve crushing efficiency. Part 1 of this study, presented at the International Society of Explosives Engineers' 51st Annual Conference, introduced a baseline framework for assessing the compatibility between blasting outcomes and crusher requirements. This methodology was applied to two blasting rounds, revealing discrepancies between expected and actual fragmentation results. The assessment raised key questions, including the root causes of fragmentation mismatches and the identification of controllable parameters that can be adjusted to align the particle size distribution (PSD) with the crusher’s optimal input range. Based on these findings, six key modifications were proposed to improve blast performance: (1) reducing the drill and blast pattern to limit boulder formation in the overlapping regions of hole influence, (2) increasing both the size and length of stemming material to enhance energy confinement, (3) decreasing subdrill depth to prevent toe burden issues from toe deviation, (4) modifying inter-hole timing to relieve back hole burden, and (5) improving drilling accuracy. Part 2, presented at Fragblast 14, explored advanced modifications to the initial blast design. The first adjustment was reducing subdrill and altering stemming material resulted in an 11% reduction in D80, a 19% decrease in maximum fragment size, and a 21% improvement in blast fragmentation efficiency. These changes shifted the PSD by 15% closer to the crusher compatibility envelope established in Part 1. Despite these improvements, boulder generation persisted in the front and back rows of the blast. This third part of the study focuses on implementing the remaining recommended modifications from Part 1 to further enhance blast efficiency and ensure crusher compatibility. The findings contribute valuable insights into the benefits of integrating blasting and crushing optimization strategies to achieve more consistent and efficient fragmentation outcomes.

Jan 26, 2026

By William A. Fuchs

A study of carbonaceous ore at the Santa Fe mine (Corona Gold Inc.) shows that there is no quantitative relationship between organic carbon content and preg rob, although much of this material preg robs. However, there is a relation between K20 and preg rob. Preg rob generally occurs only in those samples with greater than 2% K20. X-ray diffraction and chemical . studies show that the critical factor is the illite content of mixed (possibly interstratified) illite-smectite. Apparently illite, at a certain threshold, "geo-activates" the carbon. The potential for easily monitoring preg rob using a gamma ray spectrometer is discussed.

Jan 1, 1990

By Graham J

The successful processing of arsenopyritic ores is difficult and will be facilitated by a better understanding of the mineralogy of gold within arsenopyrite and the type of arsenopyrite in which gold is taken up. Solid solution gold in arsenopyrite is now well documented, and is a significant cause of refractory behaviour in gold processing. Investigations of the crystal structure and stoichiometry of arsenopyrite by X-ray diffraction, electron microprobe analysis and convergent beam electron microscopy have been carried out in order to understand how the gold is incorporated into the structure. Variations in stoichiometry, particularly the As:S ratio, of arsenopyrite leads to variations in structural parameters. These variations result in slight changes in thermal behaviour. The distribution of invisible gold in an arsenopyrite grain is generally non-uniform and synthesised samples contain up to 2 wt per cent gold. A transmission electron microscopy (TEM) technique called ALCHEMI is being used to identify the substitution site. The process of gold agglomeration together with evidence of an ordered breakdown of arsenopyrite to pyrrhotite has been documented with the use of TEM. An arsenopyrite grain containing invisible gold was heated with an electron beam resulting in recrystallisation of arsenopyrite to pyrrhotite with arsenic being expelled. The gold is mostly insoluble in the pyrrhotite lattice and therefore exsolves out and combines with other gold atoms to form droplets at the boundary of the pyrrhotite.

Jan 1, 1992

By K. E. Waters, C. Marion, T. Grammatikopoulos, A. Jordens

"The Nechalacho deposit, located in the Northwest Territories, Canada, is a heavy rare earth element (REE) deposit. The main REE-bearing minerals in the deposit are zircon, allanite, bastnäsite, synchysite, columbite (Fe) and fergusonite. Previous work investigated the use of gravity and magnetic separation in the processing of this ore and showed that coarse particles following grinding were enriched in zircon, suggesting the potential for selective comminution. The current work investigates the possibility to selectively comminute gangue minerals and concentrate REE-bearing zircon into coarser size fractions. The ore was ground wet in a laboratory rod mill for various lengths of time (0, 10, 20, 30, and 40 min). The resultant products were analyzed using ICP-MS, to determine the distribution of zirconium and REEs in the different size fractions produced after grinding, and QEMSCAN, to identify mineral phases, mineral liberation and the distribution of minerals. Optimum grind sizes for the upgrading of zircon due to selective comminution were then proposed, and dense medium separation was investigated as a means to further concentrate zircon.It is important to note that this process is not representative of the currently selected process design or recovery for the Nechalacho deposit. Any application of this process to this deposit would require optimization in order to ensure appropriate grade and recovery targets are met.INTRODUCTIONThe rare earth elements (REEs) are the fifteen elements in the lanthanide series of the Periodic Table, as well as yttrium (scandium is excluded in this work). Traditionally, REEs are categorized into two groups: the cerium sub-group of “light” rare earth elements (LREEs); and the yttrium sub-group of “heavy” rare earth elements (HREEs) (Golev et al., 2014). The LREEs comprise the first six lanthanides (lanthanum through samarium) and the HREEs comprise the remaining nine lanthanide elements (europium through lutetium) coupled with yttrium (Golev et al., 2014). HREEs are much less abundant in the earth’s crust and on average are more expensive than LREEs (Seredin, 2010). Of the fifteen REEs, the production of neodymium, europium, terbium, dysprosium and yttrium has been determined to be most critical due to their scarcity, high demand and criticality in many high-technology and clean energy applications, such as in illuminated screens for electronic devices and permanent magnets in wind turbines (Seredin, 2010; U.S. Department of Energy, 2011). These five elements are classified as critical rare earth elements (CREEs) (U.S. Department of Energy, 2011)."

Jan 1, 2016

By T. T. Chen

Gold in the Twin Creeks ore is primarily associated with arsenian pyrite. During pressure oxidation, the sulphides are solubilized, but part of the dissolved iron reprecipitates as jarosite and as an iron sulphate-arsenate-phosphate phase. The pressure oxidation products are subjected to cyanide leaching. The cyanide leach residues consist of quartz, gypsum, bassanite, anhydrite, small amounts of jarosite, an iron-sulphate-arsenate-phosphate phase, as well as trace amounts of orthoclase, rutile, pyrite, hematite and monazite; all these particles are dispersed in a fine grained matrix of illite-muscovite. The autoclave leach residues contain a small amount of carbonaceous matter. Many gold grains are detected on the surfaces of the carbon particles, and these gold particles are not leached during cyanidation. The gold particles are typically 0.1-0.2/Lm in size and commonly are embedded in the carbon surface or are coated with a K-AI-Si-S-O phase on the surface of the carbon. The gold grains are consistently associated with elevated CI contents (50-300 ppm Cl). The poor gold cyanide leach recoveries, which initially occurred in the Twin Creek developmental circuit under certain operating conditions, are attributed to the presence of chloride in the feed. This results in the formation of soluble gold chlorocomplexes in the autolcave and the subsequent sequestering of the gold on the surfaces of the carbon particles.

Jan 1, 2000