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By Nam-Il Um

Bottom ash contains several ferrous materials (ferrous metals, Fe3O4, Fe2O3, FeS, etc.). In particular, ferrous metals contain heavy metal because Ni and Cr are chemically attracted to iron. Likewise, Cu is used to coat Ni and Cr metals as polish or to prevent corrosion. In this study, an Fe3O4-Fe2O3 double layer (similar to pure Fe) was found to have been formed in ferrous metal during air-annealing in an incinerator (1000°C). A strong thermal shock such as one that occurs during the water-cooling of bottom ash results in the breakdown of this oxidation layer, facilitating the degradation of ferrous metals and formation of corrosion products. Therefore, Fe-ion (heavy metal) oxides may be formed on ferrous metals and may be separated from bottom ash via magnetic separation. This study sought to investigate the separation ratio of heavy metals as magnetic separation and mineralogical formation of Fe-ion (heavy metal).

Jan 1, 2006

By Chao Zhang, Jian Guo, Chaoquan Yao, Leige Xia, Xinyu Li, Jianliang Zhang

In this research, analytical reagents were used for the sintering experiments. And the sinters were using X-ray diffraction, scanning electron microscope and mineralogical microscope analysis to study the effect mechanism of manganese on the silico-ferrite of calcium and aluminum (SFCA) bonding phase formation during the sintering process. The results indicated that the increasing content of manganese would greatly reduce the content of SFCA, and promote the formation of calcium aluminum silicate and the amount of pores and cracks. The existence of manganese inhibited the silicon form into the SFCA and a great deal of Fe2O3 was participated in the crystal transition to Fe3O4. When the ratio of the added manganese was less than 3% in the mixing, the calcium ferrite was in substantially interleaving corrosion with hematite and magnetite. Both the porosity and silicate glass phase content were low simultaneously, which contributed to the sintering production.

Jan 1, 2015

By C. C. Spencer

A CHARGE of 12,200 lb of scrap was used on all heats. The slag materials that were added to the furnace along with manganese ore were kept constant; that is, 230 lb Coxey sand was put on the banks at the slag line before each heat was charged, 35 lb limestone was added after the carbon boil. manganese ore was the only item varied in the four series described herein. I might add here that it is impractical for us to get the carbon clown in one boil, for the steel would come out through the doors and run over the floor. We take the carbon down in two vigorous boils.

Jan 1, 1947

By M. Moats, I. E. Paschalidou, K. Awuah-Offei

Tellurium (Te) is a rare metalloid that is predominantly produced from the treatment of anode slimes formed during copper (Cu) electrolytic refining. The US Government lists Te as one of the 50 critical minerals, partly, because of its use in thin-film photovoltaic (PV) technology. Given policy initiatives to increase Te production, it is important to evaluate the life-cycle environmental impacts of Te recovery as a by-product of Cu processing. The literature contains a few specific life cycle assessment (LCA) studies of groups of metals that include Te without proper regard to impacts per life-cycle stage of Te production or the effect of allocation on the results. This study builds an LCA model of the production system of Te from anode slimes treatment to evaluate the effect of allocation on life-cycle impacts. We build life cycle inventories using data from the Ecoinvent v3.7.1 database, literature, and engineering calculations and allocate impacts in proportion to products’ mass and economic value. The results show that economic value-based allocation yields greater impacts than mass-based allocation indicating the significant effect of the allocation approach on life-cycle impact estimates.

Feb 1, 2023

Effect of Matching Relationship Between Bubble Size and Particle Size on Kaolinite Flotation

Sep 13, 2010

By Donna Post Guillen

"Cyclopentane, a flammable hydrocarbon, is being considered as a working fluid for waste heat recovery applications using Organic Rankine Cycles with Direct Evaporators. A postulated failure mode consisting of a pinhole leak in a heat exchanger tube raises safety concerns due to autoignition of the working fluid. Experiments were conducted to determine the ignition delay time (IDT) of cyclopentane using an Ignition Quality Test™ (IQT™) device. Two sets of experiments were conducted per ASTM D6890 (with exception to charge pressure and temperature) to determine ignition delay of the fuel at atmospheric pressure for standard air (-20.95% oxygen) and vitiated air (13.3% oxygen) at a temperature of 803 K. Operation of the IQT device at a much lower pressure (1 bar) than normal operation (21.4 bar) with a standard injector led to very rich conditions and wetting of the stainless steel chamber walls. Catalytic effects are postulated to produce the small IDTs observed. Experiments were repeated with a modified injector to prevent wall wetting, resulting in average IDTs that are substantially longer.IntroductionCyclopentane is being considered for use as a working fluid in a Direct Evaporator of an Organic Rankine Cycle (ORC). In this configuration, the heat exchanger is placed directly in the flow of the hot exhaust gas, rather than using a secondary heat transfer loop to isolate the flammable working fluid from the heat source. This configuration offers the advantages of approximately 15% lower cost and improved efficiency over a standard ORC. However, placing a heat exchanger operating with a flammable hydrocarbon in the hot exhaust gas stream presents potential safety risks. If a pinhole leak were to occur in the heat exchanger, working fluid could leak into the hot exhaust stream. Gas turbine exhaust is provided to the Direct Evaporator at a temperature of approximately 803 K, whereas the autoignition temperature of cyclopentane is 634 K (Gallant and Yaws, 1993). Autoignition of the working fluid has been identified as the key risk for this type of system.Autoignition occurs when sufficient self-heating by chemical reactions takes place to accelerate reaction rates to produce full-scale combustion. This is in contrast to forced ignition, in which an external source (e.g., spark) is employed to initiate the combustion process. For combustion to occur, the fuel to oxidizer concentration must be between the lower (lean) and upper (rich) flammable limits. The reaction rate depends on the species concentration of the fuel and oxidant, the local temperature and pressure. Ignition processes are comprised of steps that take a fmite amount of time. This latent period prior to the start of combustion is referred to as ignition delay time (IDT)."

Jan 1, 2012

By W. G. Davenport

Chapter 11 determined the combinations of industrial oxygen, oil and blast preheat that will steadily produce 65% Cu matte from pure chalcopyrite concentrate. It showed that the . combinations are described by a flat plane. It also showed that the minimum energy requirement for making 65% Cu matte occurs with maximum oxygen enrichment, zero oil and zero blast preheat. This chapter examines the, effect of matte grade on industrial oxygen, oil and preheat requirements.

Jan 1, 2001

By I. Osvath, I. Gombköto, G. Mucsi, Z. Molnár

"In the present research, a deposited brown coal fly ash was used as raw material for geopolymer. The reactivity of the fly ash was altered using mechanical activation, which is one of the promising methods to improve bulk and surface reactivity. The mechanical activation experiments were carried out in a high energy density mill using 5 m/s circumferential speed, and various residence times (1, 3, 5, 10, 15 and 60 min). The effect of mechanical activation on particle size distribution was measured by a laser particle size analyzer and structural changes using FT-IR. Geopolymer samples were prepared from mechanically activated fly ash with an alkali solution. The progress of geopolymerisation was monitored using an Isothermal Conduction Calorimeter. The heat flow curve obtained indicated that reactions were more prominent and started much earlier in the mechanically activated samples. This observation is further supported by the compressive strength results which also improved in geopolymers using mechanically activated fly ash. Based on the obtained results, it can be inferred that mechanical activation is a possible way to enhance the reactivity of fly ash and consequently properties of resulting geopolymers.INTRODUCTIONCoal fired power plants generate fly ash and slag in huge amount worldwide, about 780 million tons/year (Heidrich et al. 2013). Due to the relatively low utilization rate, enormous quantities of these wastes are landfilled in ponds. The fly ash is the finest grained particle fraction of the solid ash, which is transported with flue gas, and removed by electrostatic or bag filters. The fly ash has pozzolanic activity, it does not react with water, but in the presence of calcium hydroxide solution hardens and solidifies, producing a reaction product practically insoluble in water (Opoczky, 2001). The most important property of the fly ash regarding geopolymerization is its reactivity, which depends on the chemical and phase composition, the dispersity (specific surface area, particle size distribution), and the morphology of the fly ash particles, and determined by the physical properties and chemical composition of the fly ash. Geopolymers concerning their chemical structure are polysialates, where the sialate (silicon-oxoaluminate) network is built up from the bonds of Si-oxide and Al-oxide by sharing oxygen atoms (Davidovits, 1988)."

Jan 1, 2016

By T. Guyaguler

An analytical technique using computer-based multiple-regression methods was employed to determine the relation between the dust-producing index and inherent rock properties of typical samples from a coal-producing area, one of the aims being to provide a preliminary predictive tool for practical use. The investigation demonstrated that factors varied in their influence under different conditions, the brittleness:toughness ratio and the hardness being the most significant inherent properties with hardness showing the highest positive correlation coefficient

Jun 13, 1905

By B. Hines

Grinding efficiency in a vertical stirred mill is affected by a wide range of process and mill configuration variables. Of these, the media fill, size, and intrinsic density have a significant effect on power draw and grinding performance. Media-related factors that influence grinding performance include, e.g.,a higher media filling providing additional particle breakage sites, or a lower bead density decreasing the running torque at a given media filling. It has been estimated that the grinding media can cause up to a 30% change in the specific energy required to grind. FLSmidth has generally recommended that the intrinsic density (specific gravity) of the grinding media be more than triple the slurry density. This density difference helps to ensure that sufficient stress intensity is generated in the mill to provide particle breakage. It also reduces the chance of media ?float? if there is a spike in either slurry density or slurry flow rate. The VXPmills have historically operated at slurry density values between 1.2 and 1.5 kg/L, which translates to nominal bead intrinsic density range between 3.6 and 4.5 kg/L. The current trend towards regrinding bulk flotation concentrates to even finer sizes, to improve recoveries of fine grained minerals, has provided motivation to consider closed-circuit operation of stirred media mills. The slurry density in this application is typically higher than in open-circuit operation due to the higher percent solids in cyclone underflows. An additional effect is that closed-circuit operation increases the potential for media float due to higher flow rates as slurry is recycled to the mill. The normal progression in extending the operating range of existing equipment is to carry out laboratory testing before pilot-scale and plant-scale trials. The results presented in this paper examine the media density to slurry density ratio and its effect on grinding performance.

Feb 23, 2014

By Shaik Jeelani, Mahesh Hosur, Esperidiana A. B. Moura, Rejane D. Campos, Emilia S. M. Seo, Kerry Kirwan, Francisco R. V. Díaz, Maria Sotenko

The use of natural fibers with polymeric resins has spread rapidly. In order to improve the mechanical properties of material, in this work, two variables were used: mercerization and electron beam irradiation. This paper describes the preparation and characterization of biocomposites that were prepared in two different routes using green high density polyethylene (HDPE) and Brazil nut pod fiber (BNPF): the first was to irradiate the composite with 150 kGy and the second was to irradiate the matrix with 15 kGy followed by composite preparation. In both cases mercerized and non-mercerized fibers were used. The irradiation process was carried out using a 1.5 MeV electron beam accelerator, at room temperature and in the presence of air. The material was characterized to evaluate the effect of treatment on mechanical properties of material.

Jan 1, 2015

By M. G. Eiselein, R. A. Smith, C. H. Sheerin

FMC Gold's Paradise Peak Mine was one of the top two producers of mercury metal in North America in 1988 and 1989. As a by-product, elemental mercury is produced from cyanide soluble mercury minerals, primarily to reduce the health risks incurred with the refining of precious metal precipitate containing elemental mercury and mercury amalgams. A discussion of the design, primarily the Merrill-Crowe units, and permitting for the safe production of mercury will be presented. Additionally, laboratory testwork to determine the effect of mercury on reagent requirements in the Merrill-Crowe process will be discussed.

Jan 1, 1990

By M. T. McDonough

THE data relative to the effect of metal depth on slag volume was obtained from the operation on two acid electric furnaces in which heats of various sizes were produced. The furnaces used were of 3 and 5-ton rated capacity; the heats investigated ranged from 6 to 8 tons. Heats of 7 and 8 tons were made in the larger furnace; heats of 6 tons in the smaller one. Bath depths and diameters were measured on the furnaces when cold and each is accurate to one inch. Both the metal charge and the slag were weighed on a track scale accurate to ± 25 lb. All other components added to the furnace were weighed on a wheelbarrow scale accurate to ±5 lb.

Jan 1, 1947

By N. R. Andrade-Gonzalez

In this paper, the effect of magnesium and strontium additions on the heat treatment behaviour of cast A319,2 alloy was investigated, Permanent mold samples were heat treated at 495 °C for 4 and 24 h, then quenched in hot water and aged at 180 °C and 220 °C for different temperatures, It is found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu alloys, mainly when Mg and Mg-Sr are added, The results of electron probe microanalysis (EPMA) observations reveal that the age-hardening behaviour is related to the precipitation sequence of alloys, For the Al-Si-Cu alloy, the first aging peak is the result of the high-density GP zones, while the subsequent peaks arise from metastable phases, Obvious intervals during the transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks, It is seen that addition of Mg (-0,40 wt %) leads to the precipitation of coarse Al5Mg8SioCu2 particles. When modifying the high Mg alloys, Cu-intermetallics segregate in areas away from the growing Al-Si eutectic regions, Modification with strontium retards the precipitation of the silicon out of the matrix.

Jan 1, 2005

By H F. Yu, S Ueda, J Diao, W F. Gu, Y Sasaki, H Qin

The main reason for the underutilisation of steelmaking slags is their instability, which is influenced by their complex phase structure. Recycling and sustainable steelmaking slag face challenges due to the presence of magnesium oxide (MgO), a crucial component in steelmaking slag. This study investigates the phase evolution of steelmaking slag during the cooling process with different MgO contents, using high-temperature experiments and FactSage™ software, ver 8.1, (by Thermfact/CRCT and GTT-Technologies) thermodynamic equilibrium calculations. X-ray diffraction (XRD) and scanning electron microscope - energy dispersive x-ray spectroscopy (SEM-EDS) analyses identified main phases in steelmaking slag, including Ca2SiO4 (C2S), RO (MgO-FeO solid solution), Ca2Fe2O5 (C2F), and Ca3SiO5 (C3S). The study reveals that RO phase increases as the MgO content increases. C3S precipitates from steelmaking slag with a 12 mass per cent MgO content at a reduced temperature of 1400°C. It is important to note that C3S remains in the steelmaking slag even after slow cooling. This may be due to the substitution of Ca2+ in C3S by Fe2+ and Mg2+ ions. Intriguingly, the precipitation of f-CaO in steelmaking slag with 10 mass per cent of MgO content occurred after one year, while there was no manifestation of f-CaO precipitation in the steelmaking slag with 12 mass per cent of MgO content even after one year. This discrepancy suggests a potential stabilising effect of an appropriate amount of MgO in steelmaking slag. However, it is crucial to emphasise that this inference lacks supporting data, necessitating further research to validate this hypothesis. The significance of this work is in uncovering the complexities of steelmaking slag behaviour, providing essential insights for optimising recycling processes. The research sheds light on the factors that influence the phase composition and stability of steelmaking slag, contributing to the utilisation of steelmaking slags, promoting environmental sustainability, and enhancing the overall efficiency of metallurgical processes in the current industrial landscape.

Jun 19, 2024

By Cheng Pan, Xuewei Lv, Guibao Qiu, Chenguang Bai, Meilong Hu

"Physic-chemical properties of slag at high temperature play an important role in the pyrometallurgical process of production of ferronickel alloy. It determines the operation efficiency, metal recovery ratio, energy consumption and the distribution of elements like S and P between the slag and metals. In the present work, the effect of MgO content in the slag on melting features and viscosity of the slag was investigated. The MgO content in the SiO2-CaO-MgO-Al2O3 -FeO in the quinary slag system varied from 14.5% to 22.5%. The results shown that all slag samples begin to softening at the same temperature, the softening temperature, melting temperature, flowing temperature decrease with the increase of MgO content when the MgO content is in range of 14.5 and 20.5 pct mass, and when MgO content up to 22.5 percent, the temperatures increase sharply. Besides the inflection point temperature of viscosity-temperature curve increase with the increase of MgO when the MgO content is in range 16 and 22.5 pct mass.IntroductionNickel is very important to modern society, without it, we would not be able to share many things in our daily life, such as airplanes, computers and many stainless steel appliances in our homes and workplaces1.. It is the essential element of the stainless steel making, and about 65% of the nickel consumed in the world is used to make stainless steel2., so with the increase of stainless steel, the nickel production and demand has continued to increase3.Nickel is produced from two distinct ore types: nickel sulfide deposits and oxide nickel laterite deposits. The great majority of world’s known nickel resources are contained in laterite deposits3.. The laterite ores are normal classified into two groups: the high-iron laterite ore and high-magnesia laterite ore1. Typical composition of high-magnesia laterite ore is in the range 1-3%, and these ores are suitable for pyrometallurgical process to produce ferronickel4."

Jan 1, 2012

By Huijun Shao, Qiang Liu, Zhengming Yi

The increase of the proportion of high Al2O3 content iron ore fine in iron and steel enterprises has brought about a series of problems such as the increase of the viscosity of blast furnace slag and the difficulty of the separation of slag and iron. In order to solve this problem, the effect of increasing MgO content on the technical and economic index, the cold strength, and metallurgical properties of high basicity and high-alumina sinter was studied through sinter pot test. Nova400NanoSEM field emission scanning electron microscope was used to analyze sinter microstructure. The experimental results show that when the MgO content fraction in the sinter with high basicity and high aluminum increases from 1.72 to 2.49%, the vertical sintering speed decreases by 4.38mm/min, the utilization coefficient decreases by 0.51t/(m2 h), and the low-temperature reduction degradation index increases by 6.7%. When MgO content in sinter is 2.11%, drum index and reducibility index are the highest, reaching 61.93% and 86.39% respectively. Mg2+ is mainly solid dissolved in the magnetite lattice and replaces Fe2+, up to 3.64%. The generated magnesie-containing magnetite inhibits the phase transition from Fe3O4 to Fe2O3 oxidation process in the sinter cooling process, which reduces the generation of secondary hematite and is conducive to improving the low-temperature reduction degradation performance of sinter.

Jul 4, 2021

By Han Yihua, Zhang Caijun, Zhu Liguang, Zhang Qingjun, Wang Shuoming, Wang Yan

An industrial test on 210 t converter-LF-CC production line on high heat input welding shipbuilding structure steel DH36 has been taken in a factory in north China, the effect of adding microalloy elements V and Mg on casting billet microstructure has been researched. It was found that when the composition of V was between 0.03 and 0.05% and the composition of Mg was between 0.002 and 0.005%, a large number of acicular ferrite precipitate in austenitic crystal in as-cast structure and cross into a net structure. The inclusions size which induced intra-granular ferrite are mainly less than 4 lm, especially those between 2 and 3 lm account for 50.80%, in these inclusions the composite inclusions mixed with Mg accounted for more than 60%.

Mar 1, 2017

By Hüseyin Aydin

TWIP (Twinning-Induced Plasticity) steels have exceptionally good combinations of strength, ductility and damage tolerance which satisfy the recent requirements of automotive industries. Firstly, TWIP has the most beneficial effect on the work-hardening. It is believed that deformation twins increase the work-hardening rate by acting as obstacles against gliding dislocations. Moreover, TWIP steels have low to intermediate stacking fault energy and hence undergo extensive mechanical twinning during deformation, which in turn leads a good combination of both strength and ductility. To explain the mechanical characteristics and the mechanical behavior of the TWIP steels, we have been made some investigations and experiments that show the effects of microalloying elements and deformation mechanisms. In this study, three different compositions of TWIP steels have been produced. The microstructure and mechanical properties are characterized by using optical, electron microscopy and mechanical tests.

Jan 1, 2009

By Wen-long Zhan, Zhe Ning, Jun-hong Zhang, Ji-hui Liu, Zhi-jun He, Qing-hai Pang

The influence of microwave irradiation and ultrasonic vibration on granularity of 0.074 mm pulverized coal was investigated in this research. It is indicated in the results that the granularity of coal decreased after microwave treatment, which led to the increased in specific area of pulverized coal in combustion reaction and consequently optimized the kinetic condition of combustion reaction. Higher ultrasonic power may lead to better performance of PC in combustion. The optimum condition for ultrasonic treatment is 10 min under 350 W microwave power.

Mar 1, 2017