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By Güldane Atesoglu, İsmail Atilgan

The changes in the elemental contents and the structural properties of chalcopyrite concentrate when roasted were studied, and the main reactions contributing to the leaching process revisited. Firstly, TG/DTA measurements were performed to identify the roasting temperatures that influenced the type of species reacting with sulphuric acid leaching liquor. The temperatures of main reactions, whose output may affect the subsequent leaching process, were analysed for the concentrate at hand, and concluded to be generally lower than those reported in literature. Secondly, the obtained results were confirmed by images and XRD measurements on the roasted concentrate at temperatures in between 350 and 600 °C with increments of 50 °C. Finally, the leaching behaviour of the roasted specimens in a stirred sulphuric acid solution examined and the Cu/ Fe selectivity investigated that the maximum Cu/Fe ratio in the pregnant solution would nearly be achieved for the roasting temperatures lower than 500 °C, since the oxidation temperature of iron sulphate is found lower than that of copper sulphate.

Aug 11, 2022

By K. J. Shoop

An analysis of an iron ore processing plant showed that its performance was affected by seasonal temperature variations, resulting in reduced grinding efficiency in the winter months. Laboratory and pilot plant studies were conducted to determine the cause of the observed loss of efficiency at lower temperatures. Experiments were divided into two groups: 1) Drop testing, which was performed to determine the effect of brittleness and frozen pore water on the breakage characteristics of the ore. 2) Wet grinding, which was further divided into laboratory tumble tests and pilot plant scale tests. Laboratory tumble tests were performed to determine the effect of temperature on the grinding of iron ore. This was done by varying the percentage of fines and percentage of metamorphic clay material added to the iron ore grinding charge. The pilot plant scale tests were conducted as a scale-up of the laboratory tumble tests and to determine the effect of temperature on slurry rheology, and how this changing rheology affected the grinding of iron ore. The combined results of drop testing and wet grinding were used to make some predictions of the performance of plant scale autogenous grinding. In drop tests the breakage characteristics of the iron ore had no noticeable change in size stabilities for dry and water saturated samples over the temperature range studied (-25°C to 25°C). The effect of frozen pore water was not observed due to the low apparent porosity of the iron ore. The addition of fines to the test charge caused a decrease in the amount of new fines produced for both the laboratory tumble tests and pilot plant scale tests. The production of fines further decreased when tests were performed at the colder temperature. The increased energy consumption at lower temperatures was dominated by rheology phenomena. The addition of metamorphic clay material to the iron ore test charge resulted in more fines being produced in the laboratory tumble tests. This was due to the metamorphic clay material grinding easier than the iron ore. This caused an increase in the amount of fines in the mill, which in turn, would prematurely slow down the grinding of iron ore because of an increase in the viscosity of the slurry.

Jan 1, 1995

By Xihuai Gong, Hongshuang Di, Jianping Li, Ning Yan

In this work, we investigated the effect of the rolling process (warm-rolled or cold-rolled) on microstructure evolution and mechanical properties of 9Mn steel. After intercritical annealing at 670°C for 10min, both cold-rolled and warm-rolled microstructures are composed of ultra-fined austenite and intercritical ferrite. The austenite in warm-rolled sample includes two types of morphology, namely equiaxed and lamellar, which exhibits a wide distribution of grain-size. The incomplete recrystallization or recovery behavior of ferrite in warm-rolled and annealed sample results in higher yield strength and shorter yield point elongation. Moreover, the warm-rolled and annealed sample extends the TRIP-related work hardening over a broad strain range, resulting in a better combination of ultimate tensile strength and total elongation.

Oct 1, 2019

The stability of mine roofs in permafrost zones is determined mainly by temperature and ice content. The deformation resulting from creep and temperature dependent physical properties of frozen rockmass is the dominant component of total deformation. Roof bolts can consolidate the roof and control its deformation. In this paper, a finite element model for analysis of the effects of roof bolting in a frozen rockmass is presented. The model includes the variables normally encountered when analyzing the effects of roof bolting in rocks. It also accounts for properties unique to frozen rockmass, creep deformation and the change in Young's modulus with changing temperature. The model shows that, as bolt spacing decreases, there is a trade-off between increased roof stability from increased mechanical support and decreased stability from increased conduction of heat into the frozen roof. This result was expected, and shows that, for a given set of rockmass conditions, including ice content, temperature, particle size, etc., there is an optimum bolt length and bolt density for minimum roof deflection.

Jan 1, 1996

By Rajagopala Reddy Kallu

After the Sago and Darby No. 1 mine incidents, the new regulatory standards for the design of mine seals in underground coal mines of the United States require the mine seals to withstand higher explosion standards. This necessitated for the development of new design approaches and standards. For development of any new design standards or approaches a detailed understanding of effect of key influencing parameters on the stability of mine seal is a must. This paper attempts to address one of the factors, i.e. roof convergence, that play an important role in the stability of mine seal under explosion loading. Initially a couple of three dimensional numerical models were built and tested for different levels of roof convergence. These models confirmed that roof convergence has great influence on seal stability. A detailed study is undertaken, with some simple assumptions, to establish typical influence of roof convergence on the stability of mine seal under different levels of static explosion pressures. Three dimensional distinct element code 3DEC is used for this purpose.

Jan 1, 2007

The stability of mine roofs in permafrost zones is determined mainly by temperature and ice content. The deformation resulting from creep and temperature-dependent physical properties of frozen rock mass is the dominant component of total deformation. Roof bolts can consolidate the roof and control its deformation. In this paper, a finite-element model, for the analysis of the effects of roof bolting in a frozen rock mass is presented. The model includes the variables normally encountered when analyzing the effects of roof bolting in rocks. It also accounts for properties unique to frozen rock mass: creep deformation and the change in Young's modulus with changing temperature. The model shows that, as bolt spacing decreases, there is a trade-off between increased roof stability from increased mechanical support and decreased stability from increased conduction of heat into the frozen roof. This result was expected and shows that, for a given set of rock-mass conditions, including ice content, temperature, particle size, etc., there is an optimum bolt length and bolt density for minimum roof deflection.

Jan 1, 1997

By P. Fawell, C. Castillo, C. Ihle

"The need to reduce fresh water consumption has pushed many Chilean mining companies to utilize seawater obtained from distant locations. At the same time, increasing amounts of fine particles in copper tailings raise new operational challenges, in particular, the thickening and transport of tailings featuring significant fine fractions, which are predominantly clays. In the present paper, we study the role of salinity – using seawater and NaCl – on the flocculation efficiency of copper sulphide tailings to which kaolinite was added. To mimic the water recovery stage in thickeners, flocculation has been induced in jar tests and the corresponding aggregate size distribution has been estimated from chord length distribution data obtained using a focused beam reflectance measurement (FBRM) probe, at various mean turbulence intensities. Results show that for constant flocculant dosing, a measurable influence of the salt on the resulting aggregation exists. For each case, resulting optimal turbulence levels are also reported, a particularly interesting feature when comparing flocculation efficiency of the coarse and fine fraction. INTRODUCTION The concentration of copper minerals through comminution and flotation is intensive in the use of fresh water. The need to reduce the consumption of fresh water and the environmental standards associated with increasingly demanding mining operations have driven improvements in the techniques of recovering water from tailings. The challenges are even greater when required to treat minerals with high clay contents. In Chile, kaolinite is one of the most important clays to consider due to its abundance in the tailings from many operations. The most common and highest throughput unit operation in the mining industry for the recovery of water from tailings is gravity thickening, with sedimentation of fine particles assisted by flocculation. Flocculation is the process of forming aggregates by contacting the suspended particles with a flocculant. The flocculant is typically a water-soluble synthetic long-chain polymer, where copolymers of acrylamide and sodium acrylate are the most common types used in the Chilean mining industry. The aggregation mechanism includes the following key steps: (1) flocculant distribution through the suspended particles, (2) flocculant adsorption onto particle surfaces, and (3) collisions between particles leading to polymer bridging to form aggregates, but concurrently (4) breakage of aggregates becomes a factor under prolonged shear (Gregory, 1988)."

Jan 1, 2018

By B. Q. By

TiO2 is an ideal material for catalytic technology due to its unique properties. In this paper, Sm3+ doped TiO2 photo-catalyst was developed to improve the efficiency of TiO2 and to use the natural light as irradiation source, which was made from Titanium Tetrabutoxide and Samarium Oxide with the Sol-Gel process. The Sm3+-TiO2 photocatalyst was used to degrade reactive orange 4 (RO4) in Azo Dyes. The effects of solution pH, Sm3+ concentration and catalytic time on the degradation rate of RO4 were studied. The characteristics of the catalyst were analyzed with XRD and TEM. The experimental results show that the catalyst has high activity in the degradation of RO4. The Azo bonds of RO4 are active and easily broken by oxidation. The catalytic activity of the Sm3+ doped catalyst greatly depends on the pH of solution. The catalyst has high photo-catalytic activity at both neutral and alkaline conditions. The degradation mechanism of the Sm3+ doped TiO2 photo-catalyst was also discussed.

Jan 1, 2014

By S. Chander

The effect of sample storage in argon and in air on kinetics of oxidation of pyrite from a coal source was studied using accelerated weathering test in laboratory columns. Prior to the weathering tests the samples were crushed, ground, and stored for various time periods in argon and air. The results showed a dramatic difference in the rate of oxidation of the aged samples. The differences were interpreted based on the hypothesis that the aging of pyrite led to the formation of surface coatings which changed with time. The significance of these results in pyrite/reagent interactions in flotation and in evaluating the acid mine drainage potential of pyritic waste materials is discussed.

Jan 1, 1993

By I. Pérez-Rey, J. Arzúa, L. R. Alejano

"The decrease in strength with increasing rock specimen size is usually associated to the increase in the number of defects inside the specimens at small scale (centimeters) but also to the role of the rock mass structure at the rock mass scale (meters to decimeters).This matter of concern was particularly focused when determining the size of pillars in underground mines. Some formulae regarding strength of pillars have been proposed but they usually consider only the size and shape of the pillars and the strength of the intact rock. The structure tends to be overlooked or hidden behind the scale, but it is probably very relevant. For standard tunnel design, the approach by Hoek and Brown (1997), taking the structure into account in terms of the GSI, is commonly used. However, this approach does not specifically consider the size of the tunnel. Thus, a size larger than the so-called representative elementary volume is implicitly contemplated.The authors have recently performed a lab study on the effect of the structure in the strength, deformability and post-failure characteristics of granite at lab scale (NX size) extended here. This experimental program included intact and artificially jointed rock specimens. Obtained results permit to observe the changes in strength, deformability and post-failure behavior of this “small scale rock masses”, associating the role of the structure to the observed complete stress-strain response of the specimen, which can improve our understanding of the actual complete mechanical response of rock masses."

Jan 1, 2015

By N. S. Aouad

"Gaseous explosions are one of the most hazardous incidents in process and mining industries. Experimental research in this area is shown to be high risk and expensive. Computational Fluid Dynamics (CFD) techniques are reasonable alternatives to experiments; specifically when testing large scale gaseous explosions such as methane explosion in underground mines. The dimensions of a confined space where explosions could occur vary significantly. Thus, the scaling effect on explosion parameters is worth to be investigated using CFD tools. In this research paper, the impact of scaling on the explosion overpressures is investigated by employing two scaling factors. These two factors are the Gas-fill Length scaling factor (FLSF) and the Hydraulic Diameter scaling factor (HDSF). The combinations of eight HDSFs (1, 2, 4, 8, 16, 32, 64, and 100) and five HDSFs (0.5, 1, 2, 4, and 8) will cover a wide range of space dimensions where flammable gas could accumulate. Experiments were conducted to evaluate the selected premixed combustion and turbulence models. Large Eddy Simulation (LES) turbulence model was used because it shows accuracy compared to the widely used Reynolds’ averaged models for the scenarios investigated in the experiments. Researchers also simulated methane explosions in both deflagration and detonation regimes using different numerical schemes. Three major conclusions can be drawn from the simulation results. (1) The overpressure increases with both FLSF and HDSF within the deflagration regime; (2) in an explosion duct with length to diameter ratio greater than 54, detonation is more likely to be triggered for stoichiometric methane/air mixture; (3) overpressure increases as an increment hydraulic diameter of a geometry within deflagration regime. INTRODUCTION The most typical category of gaseous explosion accidents is methane explosion accidents in the mining industry. It normally leads to significant economic loss and massive amount of casualties (McPherson, 1993). It could occur in unconfined spaces, such as combustion due to flammable gas leakage, as well as confined spaces, such as inner-combustion in process equipment and methane explosions in airways of underground mines. Gaseous explosions in confined spaces are more intensive compared to unconfined spaces provided that the total energy of explosives is the same. In addition, explosion characteristics are also affected by the geometry of a selected confined space. The size of confined spaces commonly encountered in process and mining industries could differ as much as an order of four (Catlin & Johnson, 1992). A better understanding of the scaling effect on gaseous explosions could contribute to explosion mitigation and prevent operation activities within high risk regions. This research paper has investigated this scaling effect and its impact on explosion propagation. The approach to investigate explosions is either experimental or numerical. Large scale explosion experiments are often costly and dangerous (Catlin, 1991; Zhang, Pang, & Zhang, 2011). Lab scale experiments and numerical methods are common alternatives. However, it is not yet clear if the findings in lab scale experiments can be used to represent the explosion characteristics or not. On the other hand, CFD modeling has been used to simulate chemical combustions and, thus, can be used to evaluate the scaling effects in methane explosions."

Jan 1, 2015

By PERCY E. BARBOUR

SECONDARY copper1 has &come more or less of a bugbear generally. What is its influence is often the subject of heated argument. The inedapable fact usually quoted is that since in 1929 primary production of copper in the United States was 1,026,348 tons and secondary production was 626,550 tons, there- fore, 0.6 lb. of secondary is produced for every pound of primary, and "How can you get around that?" The matter seems very plain, now that I have reached my conclusions, but they are the result of much laborious study and research. I shall show that' the production of secondary copper is not 0.6 per lb. of primary, in spite of statistical appearances; that the production of secondary is a function of primary production rather than of price; that secondary production has 'only a sub-. ordinate influence on the price of copper and then only in abnormal times; that there is not an accumulating reservoir of secondary from which the country is some- time to be drowned in copper, as is believed by some, or a reservoir from which we are going to draw much needed and more or less inexhaustible stores in the future, as is believed by others; and finally, that the United States always produces more copper than it uses and exports the surplus. These are all controversial points, and for that reason and to anticipate argument I have set forth my reasoning in considerable detail.

Jan 1, 1931

By R. H. Marshall, J. Welchner, E. S. Rowland

THIS paper presents results on an exten¬sion into the realm of high-carbon steels of some work recently published' on the effects -of time at temperature, quenching temperature and prior structure on the hardenability of one 0.20 and four 0.40 per cent carbon alloy steels. It was shown at that time that unless the conditions of time, temperature and prior structure are substantially the same in performing the hardenability test as in conducting harden¬ing of parts in production, the correlation of hardenability information with the [ ] hardness and properties of production parts is often not of satisfactory accuracy. The general effects of these variables on the austenitic grain size, distribution of excess carbides and critical cooling rate have been known for many years and one or more have been investigated by Shepherd ,2 3 Davenport and Bain,4 Digges,5,6 Digges and Jordan,7 Post and associates' and Roberts and Mehl,9 to mention only a few. There has been no systematic investigation, however,' into the quantitative variations produced on the hardenability of commercial high¬carbon steels by changes in these factors of time, temperature and prior structure. PROCEDURE A plain carbon hypereutectoid steel, S.A.E. 52100 and Graph-Mo, a molyb¬denum-bearing high-carbon steel contain¬ing some graphite, were chosen for this investigation. The chemical analyses of these electric-furnace steels are given in Table I. [ ] The procedure used was exactly that reported previously,' hence the details will not be repeated here. Normalized (1650°F.) and spheroidized prior structures were utilized on all steels with hot-rolled and quenched (1600°F. oil) prior conditions added for the plain carbon steel. The end-quench test developed by Jominy10 was selected for use in this investigation and, with the noted exceptions, the American Society for Testing Materials standard. procedure was followed. The effect of time at temperature was examined at intervals of 0, 10 and 40 min. and 4 hr., and a few i6-hr. tests were run. Salt-bath heating of the specimens was employed to control and minimize the

Jan 1, 1944

By E. Nejati, S. Khoshkooei, V. Firouzdor, M. Akbari, F. Khomamizadeh

In this study the effects of Si content on mechanical and thermal fatigue properties of Al-Si casting alloys were investigated. Repeated heating and cooling cycles were applied on the samples at 230°C to develop thermal fatigue cracks. Crack growth mechanisms and microstructural influences were investigated by optical and scanning electron microscopy. Thermal fatigue behaviors were improved successively by increasing of silicon content up to 7wt%. However, addition of more than 9wt% silicon decreased the thermal shock resistance of the alloy. Silicon contents of about 9wt% presented the best mechanical and thermal fatigue resistance in the alloy.

Jan 1, 2006

By M. B. Shongwe, G. Freemantle, M. Botha, S. Brill, J. D. Steenkamp

During steelmaking, one important factor for production efficiency is the free opening of the ladle nozzle during continuous casting. Free opening occurs when the well filler sand and the steel flow freely when the slide gate is opened. Well filler sands are used for the slide gate of a ladle to separate the slide gate refractory and the molten steel. The well filler sand is partially sintered by the heat of the molten metal, which can result in the ladle nozzle failing to open if the sand is not sintered to an appropriate extent. It is therefore of great importance that the sintering behaviour of well filler sand is understood. We studied the effect of the well filler sand chemistry on its sintering properties. Samples of well filler sand with various chemical compositions were sintered in a high-temperature chamber furnace. Quantitative X-ray diffraction (XRD), inductively coupled plasma optical emission spectrometry (ICPOES), and wavelength dispersive spectrometry (WDS) by electron microprobe analysis (EMPA) were used to analyse the various well filler sand mixes. Points of analysis were indicated on backscattered electron (BSE) micrographs. Quantitative element mapping was undertaken by energy dispersive spectrometry (EDS). Thermodynamic calculations in FactSage predicted the percentage liquid phase present for the various well filler sand compositions at equilibrium conditions. The results of this work show that the degree of sintering of chromite-silica well filler sand depends strongly on the silica content. The amount of liquid phase formed increases with increasing silica content.

Feb 2, 2022

By J. H. Sokolowski, R. I. MacKay

The level of Si and Cu in the 3xx series of alloys affects the volume fraction of the a-Al dendritic phase and the Al-Si eutectic phase. The volume fraction of these phases in turn affects the feeding conditions during solidification and ultimately the Area Fraction Porosity and Mean Pore Diameter measured in the as-cast structure. This work sets out to establish the relationship between the volume fraction of the a-Al dendritic phase and the Al-Si eutectic phase and the resulting porosity that forms on the Monotonic and High Cycle Fatigue properties. The alloys in question are the Al-9%Si-l %Cu and a Al-7%Si-4%Cu alloys which were cast into V8 performance engine block castings and then heat treated to achieve desired mechanical properties. The engine block castings provided the mechanical and metallographic test samples analyzed for this work.

Jan 1, 2006

By F. Chiesa, Jeremy Carignan, B. Duchesne, D. Levasseur

"Aluminium A206 (AlCu4) is one of the strongest aluminium casting alloys with tensile properties approaching those of ferritic ductile iron. If the specification on the silicon content (< 0.05%) is easy to achieve during alloy ingot production, it is not the case in a foundry, where returns are used which are not perfectly cleaned from the silicate containing molding sand (Olivine). In alloy A206, the Si content is controlled in order to avoid the formation of a low melting point intermetallic phase (such as phase Q Al5Cu2Si6Mg2); these phases will melt during the solutionizing heat treatment to which alloy A206 must be subjected to develop its outstanding mechanical properties. This incipient melting may deteriorate the mechanical properties of Alloy A206 if the solutionizing treatment is applied at the standard temperature of 530°C.In the present study, a lower temperature solutionizing (520°C) was applied to a high Si content 206 alloy in order to reduce or eliminate the possible incipient melting. This was carried out on a complex shape industrial casting weighing 14 kg (31 lb) and 560x410x250 mm (22x16x10”) in size poured in aluminum 206 with a high silicon content (0.22% vs 0.05% max for alloy A206). Twenty ASTM E8 subsize tensile specimens were excised from two locations in the casting in order to compare the tensile properties for the two solutionizing temperature used (530 and 520°C). Optical and SEM microscopy allowed to investigate the causes of the differences in the properties observed between the 2 zones of the casting studied for 3 different heat treatments. INTRODUCTIONIn spite of their “textbook” outstanding mechanical properties (Up to twice the strength and elongation of the widely used A356 alloy), aluminum-copper alloys of the 2xx series are seldom used because of their propensity for hot tearing [Li, 2011], the segregation of copper [Cho, 2003], and their sensitivity to stress corrosion cracking [Jean, 2009, p. 113)]. Also, because of their wide freezing range and high thermal conductivity, a wide mushy zone makes feeding difficult, unless strong temperature gradients are created by liberal use of chills and risers in the critical zones of the part. Because they are prone to hot tearing, grain refining of Al-Cu alloys is particularly important, titanium playing a major role in the process [Sigworth, 2003]; grain refining has also been shown to be beneficial to fatigue strength [Jean, 2009, p. 103]. The practical basis of foundry practices pertaining to these alloys is outlined in an AFS webinar [Weiss, 2014]."

Jan 1, 2016

By Zhiqiang Zhou, Shengnan Zhou, Zizong Zhu, Yuchuan Ding

The effect of silicon on removal of phosphorus from high phosphorus Si–Mn alloy was investigated at 1673 K by CaO-based slag. It was found that the dephosphorization efficiency increases significantly as increasing the silicon content, which is due to the reaction between silicon and CaO at slag/alloy interface. The relation between silicon content with oxygen activity and phosphorus activity coefficient of Si–Mn melt was determined respectively as follows: lg aO = -1:55xSi - 1:67; ln rP = 9:26e xSi 0:0433 + 11:0839 The carbon content in Si–Mn melt decreases continuously with the increasing silicon content, meanwhile, the decreasing rate of carbon content becomes rapid when the mole fraction of silicon is about 0.32. Si addition is beneficial for both dephosphorization process and low carbon Si–Mn alloy production.

Mar 1, 2017

By Champoux. G., E. Ghali, W. Zhang, G. Monteith, A. -M. Lafront, G. Houlachi

The efficiency of the electrowinning process of zinc depends on the performance of oxygen evolution reaction, anode quality and corrosion resistance of lead anodes. Original surfaces of rolled commercial lead-silver anodes were examined using conventional polarisation methods in acid zinc sulfate electrolyte with manganese sulphate at 38 °C. The self-discharge method (potential decay) following 5 h polarisation at 50 mA cm-2 was considered to evaluate electrochemical activity, oxygen overpotential and anode stability. The influence of silver content is compared to that of the microstructure, the fabrication process and the composition of the corrosion products. Polished anode samples have also been examined for microstructural and corrosion performance studies. The experiments show that the duration of the plateau at 1600 mV versus SHE, the potential level (active corrosion state/stationary state) and the rate AEco/At during the decay could be a good indicator to compare the corrosion rates of the anodes in industrial zinc electrolytes.

Jan 1, 2008

By W. D. Madeley

Synthetic minerals were made from pure starting materials and galena samples were doped with the title metals. Microscopic, microprobe and X-ray examination confirmed that the dopeants were in solid solution. Paired flotations in a Hallimond-tube apparatus were performed to determine relative flotation response using Aerofloat 238 promoter. Results of these tests show that silver-doped galena floats more readily than pure galena and that galena doped with bismuth floats less readily than pure mineral to a 95% confidence level. Galena doped with both silver and antimony as AgSbS2 shows no detectable effect. Antimony-doped galena followed the expected trend, but not to 95% confidence. The results are consistent with the theory that flotation by thiol-type anionic collectors is enhanced by p-type semiconduction.

Jan 1, 1978