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By W. E. Wallace, B. L. Razzaboni, P. Bolsaitis, M. J. Keane

"Therma1 and chemical treatment of respirable size silica dusts samples is shown to induce marked changes in their hemolytic activity. The cytotoxicity of crystalline a-quartz (Min-U-Sil), and fumed silica (Cab-0- Sil) particles, as measured by a hemolytic activity protocol, is decreased by calcination and can be related to the dehydroxylation of the surface. The hemolytic activity of P-cristobalite particles of respirable dust si7.e was also determined and found to be lower than that of a-quartz. The change in the surface structure resulting from thermal treatment is detectable by photo-acoustic infrared spectroscopy and zeta-potential measurements. The absorption band in the 3200-4000 cm-1 frequency region of both Cab-0-Sil and MinU- Sil disappears upon heat treatment while a sharp band, identified with single silanol groups, at 3750 cm-1 increases in intensity. The zeta potential-pH profile, in the pH range of 4.0-7 .0, of the calcined, siloxane surfaced particles is more negative than that of material with a silanol surface.The cytotoxicity of the crystalline and fumed silica dusts was also found to be strongly dependent on particle size. Fumed silica of large surface area (small particle size) exhibits an initial increase in hemolytic activity upon calcination. This result confirms other experimental observations pointing to a particle size of maximum toxicity. INTRODOCTIONThe toxicity of silica and other mineral particles, as manifested by their role in inducing pneumoconiosis, fibrosis, silicosis and other pulmonary disorders is largely traceable to the characteristics of particle surfaces and to particle morphology. The great wealth of data on the physical and chemical properties of silica is still insufficient for a comprehensive understanding of the specific parameters to be associated with fibrogenic activity and, correspondingly, with the optimum means for characterizing and quantifying the toxicity of dusts, and the design of possible preventive or therapeutic methods.The great diversity of parameters that have been proposed and tested for correlation with cytotoxicity suggest that more than one mechanism may be involved in the fibrotic activity of silica particles. The crystalline structure of the material (more active tridymite versus less active crisobalite and passive stishovite), freshly formed surfaces and free radicals associated therewith, silicic acid adsorbed onto silica surfaces, the concentration of hydroxyl groups at silica surfaces, particle size and morphology, among other properties, have been investigated and found to conelate in tests of cytotoxicity."

Jan 1, 1990

By R. Holmestad, M. Gazizov, S. Wenner, R. Kaibyshev, J. K. Sunde

"Mechanical properties and microstructure of an Al-4.7Cu-0.74Mg-0.51Si-0.48Mn-0.10Cr-0.09Ti-0.02Fe (wt. %) alloy subjected to various thermomechanical processing (TMP) have been investigated and compared to conventional ageing at 170°C (designated T6). Three TMP routes involving cold deformation of solution treated samples were tested. These were (i) 3%-stretching (T8-3%), (ii) equal-channel angular pressing (ECAP) to true strain (e) of ~1 (T8-1) and (iii) ECAP to e~2 (T8-2), all with subsequent ageing at 170°C for 0-96 h. At peak age conditions, both yield stress, ultimate tensile strength and elongation-to-fracture decreased for the T8-3% state as compared to the T6 condition. Intermediate ECAP (T8-1 and T8-2) lead to significant increase in maximum yield stress, ultimate tensile strength and elongation-to-fracture. The changes in mechanical properties were related to microstructure evolution, encompassing changes in grain sizes, dislocation densities, precipitate morphology and phase fractions, which were characterised using transmission electron microscopy. Relations between TMP, precipitation behavior and contributions to different strengthening mechanisms are evaluated.INTRODUCTION Al-Cu-Mg-Si alloys are widely used as structural materials in aerospace industry due to their attractive combination of high specific strength, good fracture toughness and enhanced creep resistance. These properties are largely due to the formation of a large number of nano-sized metastable precipitates during artificial ageing (Polmear, 2006; Eskin, 2003; Gazizov, Dubina, Zhemchuzhnikova, & Kaibyshev, 2015). The precipitation behaviour in these alloys is complicated and depends among other things on Cu concentration and the Mg:Si ratio (Wolverton, 2001; Chakrabarti, & Laughlin, 2004). In general, the precipitation sequence has been presented in a prior study (Eskin, 2003) as follows:"

Jan 1, 2018

By Yun-Soo Lee, Su-Hyeon Kim, Hyoung-Wook Kim, Joon-Hyeon Cha

A7075 aluminum alloys have high strengths but poor corrosion resistance. In order to improve the corrosion resistance, a clad sheet is suggested, that is the A7075 alloy sheet bonded to A1XXX or A6XXX aluminum alloy sheets which are surface layers with good corrosion resistance. Mechanical properties of the clad sheets are determined by the combination of the component layer sheets, and thermomechanical treatment should be precisely designed when the strengthening methods of the core and the surface alloys are quite different. In the present study, three-layered A6022/A7075/A6022 clad sheets were fabricated by roll bonding process. Simplified processes incorporating a twin roll casting were also suggested in order to reduce the processing cost. Several temper methods composed of rolling, annealing, solution treatment, and aging were suggested in order to optimize the mechanical properties of the sheets. The strengths of the clad sheets were compared with the bare A7075 and bare A6022 sheets.

Jan 1, 2015

By R. P. van Hille, A. W. van Zyl

The BIOX® culture, aiding liberation of arsenopyrite/pyrite occluded gold, is inhibited by thiocyanate (SCN > 1 mg/L); precluding the recycling of tailings water up-stream of the bioleaching circuit. The activated sludge tailings effluent remediation (ASTERTM) process is a biological process that was developed to facilitate water recovery and treat waste water on-site (to achieve a SCN concentration < 1 mg/L) to be recycled or disposed of. The aim of this study was to investigate the effects of changing temperature and SCN loading on the SCN degradation ability of the mixed microbial population clue to seasonal temperature changes and fluctuations of SCN concentration in the waste water.

Jan 1, 2011

By K. Negishi, H. Izui, Y. Komiya

"Aluminum has the disadvantage of low strength. In order to obtain the high strength composites, crystals were refined in the composites. Grain refinement was approached at two process points, generating new grains and grain growth. It is important for refinement how to control the grain growth. Spark plasma sintering (SPS) technique and TiB2powder addition prevent grain growth. To investigate effects of strain and additives to the alloy, aluminum powder was sintered at 70 MPa and 80 MPa, changing the content of TiB2additive powder by SPS method. As the results, the crystal grain size was finer in the composite sintered at higher sintering pressure and with larger amount of additive, though over 1.0mass% TiB2addition dissuades grain refining. These grain refinements improve hardness and tensile strength of sintered aluminum alloys.INTRODUCTIONAluminum matrix composites have low density, high specific strength, and low cost. Their applications are growing continuously in the field of automotive and aerospace industries. Recent studies to improve their good mechanical and tribological properties use different ceramic materials such as Al2O3(Das, Munroe, & Bandyopadhyay, 1996; Ashwatha & Anthony Xaviorb, 2014),SiC(Hassani, Bagherpour, & Qods, 2014), B4C(Ehsan, Masoud, Touradj, Amir Hossein, & Ali, 2015),TiC(Ehsan, Ali, Masoud, Kamyar, & Touradj, 2017), and TiB2(Fei & Zhong-Hua, 2013).On the other hand, grain refinement is also an important techniques for improving the properties of aluminum alloys. Finer grains improve the mechanical properties of the alloy. For cast and wrought alloys, addition of grain refiners in molten alloys accelerates generation of nucleus and suppresses grain growth. Al-Ti-B alloy is generally added as grain refiners in the molten aluminum alloys(Easton & Stjohn, 2001). Especially, TiB2has very high melting point, low density, and excellent hardness. Therefore, TiB2was selected as additions into aluminum alloys. Liquids reaction leads to high cost, oxidation, discoloration of molten alloy, and clustering of additive powder as compared with solid reaction such as sintering. However, sintering of aluminum alloy powder with ceramic powders is difficult for oxide layer surface. Recently, we take attention to spark plasma sintering (SPS) as advanced sintering process. SPS process can easily sinter a high quality specimen at a lower sintering temperature and in a shorter time than conventional sintering processes. By SPS process, we have sintered titanium powders that are as difficult to be sintered by any other processes as aluminum powders, and improved mechanical properties by adding hard ceramic powders TiC and TiB(Kamegawa, Izui, Komiya, Kobayashi, & Arimoto, 2015; Sampei, Izui, Komiya, Shigimura, & Suzuki, 2015). Furthermore, it is important to consider not only pure aluminum but alloys for solid-solution or precipitation strengthening. Actually, pure Al does not have enough strength compared with the alloys. Al-Cu alloy and Al-Mg alloy demonstrate adequate strength for industrial and commercial sectors. Al-Mg alloy retains good formability, and has high resistance to corrosion. It is therefore used for many applications. We must consider alloying processes. The most cost effective process is blended elemental technology where alloying elements are added to base powder as elemental or master alloy powder (Smugeresky & Dawson, 1981; Yasue, Radjai, Miwa, & Sakaguchi, 2003; Bolzoni, Esteban, Ruiz-Navas, & Gordo, 2012)."

Jan 1, 2018

By S. Kodama, G. Sasaki, K. Matsugi, K. Sugio, Y. B. Choi

"Pure aluminum (Al) matrix composites with changing the volume fraction of TiB2 particle content from 10 to 30% was fabricated by spark plasma sintering (SPS) process. Then the microstructure, density, dispersibility and thermal conductivity of the composites was estimated. As increasing TiB2 content, the dispersibility of particles and the density of the composites degraded slightly. And, the effect of the dispersibility of TiB2 particles on the thermal conductivity was quite little. The thermal conductivity of the composites was less than the theoretical value calculated by Maxwell-Eucken equation considering the effect of the density. It is due the influence of the interface heat transfer rate, because these composites have many small sized particles and have high interface density.INTRODUCTION Recently, metal matrix composites (MMCs) have been used widely in electric / electronic components, architectural materials, transportation equipment, aerospace and a precision instruments, because it’s superior properties have been greatly watched. Demand of MMC for industrial use has been increasing gradually. Furthermore, multifunction properties are required for the composites strongly. By integrating the dissimilar materials, the composites have various properties that we cannot get from monolithic materials. On the other hand, the response to the thermal management is required for materials, recently, and the need for the structural material controlling the thermal conductivity has been increasing. Especially, superior thermal conductivity and good mechanical properties from room temperature to high temperature are required for heat sink and heat exchanger at the same time. In late years, a study on the composites combining carbon materials and aluminum and copper has been developing, and actually the composites with high thermal conductivity which is not provided in the conventional materials is developed. On the other hand, non-oxide ceramics particles such as SiC and AlN, TiB2 have good thermal conductivity. Particularly, as TiB2 has good electrical conductivity, TiB2 containing MMCs is expected as innovative materials used as electric/ electronic components. Furthermore, as TiB2 has low density, high melting point, low thermal expansion and good deformation resistance, the development of high performance composites with multi-functional properties is expected. As thermal conductivity of pure Al and TiB2 are 225 and 66.4 W/mK, respectively, it is expected that the degradation of thermal conductivity by adding dispersant in Al matrix is suppressed. The authors have carried out a thermal conductivity, electrical conductivity, mechanical properties of 20 vol.% TiB2 dispersed Al composites (Sugio, 2016, Sasaki, 2016). In this study, the influence of quantity of addition of TiB2 on microstructure, thermal conductivity was studied minutely."

Jan 1, 2018

By G. A. Reinhardt

THE Youngstown Sheet & Tube Co. has produced a large tonnage of 0.35 to 0.45 carbon forging steel, the acceptance of which was based on the physical properties of test specimens obtained by forging the original 5 3/4 in. (14.5 cm.) square bloom to a ¾ in. (1.9 cm.) round. Annealed and tempered specimens were required. The test bars were annealed by heating from 900 ° to 950° C. and cooling slowly in mica. The test bars were tempered by heating to 825° to 875° C., quenching in water, and drawing to 515° to 535° C. Immediately after heat treatment, the test pieces were machined to a diameter of 0.534 in. (1.38 cm.) and tested. Very good physical properties were obtained and no difficulty was experienced in meeting the specifications called for. ULTIMATE STRENGTH, ELONGATION, LB. PER SQ. IN. PER CENT. IN 4 IN. NOT LESS THAN Annealed specimens 78,230 to 92,450 18 Tempered 120,000 to 149,350 9 After experience oil this material, production of slightly higher carbon forging steel was started. The method of testing this material required that test blooms be either normalized or annealed. The normalizing consisted in heating to 850° to 900° C. and cooling in still air; the annealing, in heating to 850° to 900° C. and cooling in the furnace or in mica. From the treated bloom, the test pieces were taken either by core drilling or by sawing from points midway between the edges and the intersection of the diagonals. The cores or blocks were turned to a standard 2-in. test piece with a diameter of 0.564 in. and tested without further treatment. The physical requirements of the test pieces were:

Jan 7, 1919

WALTER N. CRAFTS,* Toronto, Canada (written discussion?).-During the forging of 9.2-in. shells -for the United States Army, it was noticed that better results were obtained in certain instances when test bars had been held sometime before pulling. An investigation, therefore, was made by our metallographer, Mr. F. M. Arnold, to determine the effect of seasoning. The forging consists of a single operation, piercing a solid cast blank. The test sections were cut from the walls by an oxyacetylene flame, one piece from the nose end and one from the base on the opposite side. The test pieces were not heat treated in any way and the tests and seasonings were carried on at normal atmospheric temperatures. The specifica-tions were as follows: Standard 2-in. test bar, 0.505 in. in diameter; elastic limit, over 19 long tons, or 42,500 lb.; ultimate stress, 39.6 to 49.1 long tons, or 87,500 to 110,000 lb. per sq. in.; elongation, over 13 per cent. As a preliminary test two heats were selected; BP555, which was tested and reported failed on elongation on Aug. 20; and B01771, which was tested and reported failed on Aug. 24. On Aug. 29, retests were cut and machined from the same shells and held till Sept. 3 (5 days) when they were pulled. Both sets of results are given below.

Jan 12, 1919

By C. R. Hayward

CARLE R. HAYWARD.-I do not want it understood that I think that the conclusion that the time of tempering temperature is immaterial has been definitely proven, but since these are the first definite figures put out, I thought before continuing on more work ourselves, it would be well to present them as progress and for information. J. A. MATHEWS, Syracuse, N. Y.-I think that if Prof. Hayward would consult the paper of Profs. Barus and Strouhal,1 1885, he would find about 250 pages, mostly figures, on this subject, in which they investigated the tempering effect by electrical and magnetic methods. There are so many figures in the paper that it is very difficult reading. One point particularly brought out was that even at a low temperature, such as the boiling point of alcohol, about 60° C., there is a tempering effect, increasing up to 4 hr. One reason they obtained those results, with which the present authors are at variance, was that they started with a high-carbon steel which hardens thoroughly, whereas the steel Prof. Hayward and his collaborator used was a comparatively mild steel which does not take a great deal of hardening. About 3 years ago Mr. Stagg and I published 2 a few figures bearing on the same subject, but we used .a low-carbon alloy steel of high tempering qualities and found a great deal of improvement, particularly in ductility, by continuing the drawing up to 4 hr. We used a chrome-vanadium steel showing after heat treatment 250,000 tensile strength. On short drawing, we got almost no ductility, but by continuing to 4 hr., we raised it to 12 per cent. I believe Prof. Hayward&apos;s results are due to using comparatively mild steel, whereas Prof. Barus used drill rod and carried out a, wonderfully exhaustive

Jan 4, 1917

By Carle Hayward

AT THE February, 1916, meeting of the Institute, a paper presented by Hayward and Raymond gave the results of a study on the effect of time in tempering medium-carbon steel, when the following conclusions were reached: It is not fair to consider the question settled when only three specimens were used for each treatment, but the results obtained indicate that for reheating quenched medium-carbon steel to temperatures below 500° it is only necessary to heat it through. Longer heating has little or no effect on the tensile strength, ductility, or hardness. At temperatures above 500°, increasing the time of treatment causes a slight falling off in hardness and tensile strength with a corresponding increase in ductility. In the discussion of the paper these conclusions were attacked and evidence presented that seemed to throw doubt on their accuracy. The authors, however, showed that this evidence was based on high-carbon or alloy steels and no facts regarding medium-carbon steel were presented. During this study the heat treatment was carried out in a small electric resistance furnace. It held nine specimens, but when these were placed in the furnace the temperature was lowered to such an extent that 30 to 40 min. were required to reach the desired heat. The authors pointed to this as a weak point in the investigation and it seemed wise to supplement the research by work on similar steel but using a different method of heating. This has been done and the results are given in the present paper. The Rhode Island Tool Co. cooperated by furnishing the steel and turning the tensile specimens.

Jan 1, 1922

By R. H. Frank

IN the investigation of the effect of the time of heat on slag volume, no attempt was made to vary the usual practice at the Bonney-Floyd Co., such as selecting special-purchase scrap or cleaning foundry returns. The data were collected from seven normal heats, including four medium carbon, two medium manganese-molybdenum and one nickel-chrome-molybdenum. These heats were made with our normal practice and no special instructions were given the melters except to make sure that all slag-making materials were weighed and that no slag was lost during the melting, refining or tapping. After the stopper was set in the ladle, it was carefully weighed and the heat was tapped. As soon as the heat was slagged on the pouring floor, the nozzle was plugged with mud, to preclude the possibility of losing any slag while the ladle was being conveyed to the scales. The ladle, containing all of the slag, was weighed and the difference between this weight and the original weight was taken as the slag weight.

Jan 1, 1947

By Clarence E. Jackson, George G. Luther

THE ever increasing array of information concerning the measurement of the effect of the welding process on the properties of a steel is an indication of the tremendous effort that is being expended in this field. The methods that have been considered may be divided into two groups: first, those that measure directly the effect of welding on the ductility of a steel, and, second, those that observe the change in some property, such as the hardness of the heat-affected zone, and assume a direct correlation between this change and the resultant ductility. The nick-bend test is a direct method designed for studying the effect of welding on the ductility of a steel. The test specimen (Fig. I) consists of a bar cut from a plate with a bead weld on the surface. The specimen is prepared with a saw-notch placed so as to restrict deformation to the heat-affected zone under the bead weld when tested as a static bend. Failure is caused by rupture of the low-ductility metal in the heat-affected zone. The angle at maximum load is used as an index of the effect of the welding process on the material. In the development of the nick-bend test considerable scatter was noted in some of the results, although the agreement of duplicate specimens welded at the same time and tested consecutively was excellent. Upon further investigation it was found that the change in ductility was dependent upon the interval of time between the welding operation and the testing of the specimen. For the six steels of Fig. a, the angle at maximum load in four cases was doubled and in one case was tripled. All steels that have been studied show an improvement in the angle of bend for longer intervals between welding and testing. This same behavior has been found in weldability tests using the Navy T-bend

Jan 1, 1945

By Zhengde Pang, Xue-wei Lv, Guibao Qiu, Chenguang Bai, Zhiming Yan

The viscous behavior of molten slags has played an essential role in determining the performance and productivity of the ironmaking process. In this paper, the viscosity and free running temperature in CaO-SiO2-Al2O3-9 mass% MgO-TiO2 slag has been measured at different content of Al2O3 and Al2O3/SiO2 ratio. In addition, the slags viscous activation energy has also been calculated. The results show that the TiO2 as a basic oxide content from 1 to 5 mass% can reduce the viscosity and free running temperature, and moderate content of TiO2 in high alumina blast furnace slag remains effective for reducing viscous activation energy and free running temperature.

Mar 1, 2018

By Zhanjun Wang, Mei Zhang, Zuotai Zhang, Min Guo

In this study, the viscous flow and crystallization behavior of CaO–SiO2–MgO–Al2O3–FetO–P2O5–TiO2 steelmaking slags have been investigated over a wide range of temperatures. The results indicated that the viscosity of the slags slightly decreased with increasing TiO2 content. The constructed non-isothermal continuous cooling transformation (CCT) diagrams revealed that the addition of TiO2 lowered the crystallization temperatures. This can mainly be ascribed that the addition of TiO2 promotes the formation of [TiO6]-octahedra units, thereby MgFe2O4–Mg2TiO4 solid solution is formed. Moreover, the decreasing viscosity has a significant effect on the diffusion of ion units, such as Ca2+ and [TiO4]-tetrahedra, from bulk melts to crystal-melt interface. The crystallization of CaTiO3 and CaSiTiO5 was therefore accelerated, which can improve the phosphorus content in P-enriched phase.

Mar 1, 2017

By S Hapugoda, J Manuel, N Ware, A Dehghan-Manshadi

The effect of titania (TiO2 ) addition on the sintering performance of hematite iron ore has been studied by doping pure TiO2 into a sinter blend. The results of laboratory-scale compact sintering tests confirmed the considerable effect of TiO2 addition on sinter strength and mineralogy. The tumble index measurements confirmed an improvement in the strength of the sinter in response to TiO2 addition. The melting point of the sinter was also affected by increasing the TiO2 content, indicating a possible relationship between coke breeze consumption and TiO2 on industrial-scale sintering of Ti-bearing ores. Analysis of the sintered structures using optical and scanning electron microscopes confirmed a general improvement in the overall pore structure and sinter melt characteristics with the addition of TiO2 to the sinter blend. An important feature of the sinter structure was the formation of a perovskite phase (CaTiO3 ) and an increase in the proportion of this phase in the structure as TiO2 levels increase.CITATION:Dehghan-Manshadi, A, Manuel, J, Hapugoda, S, Ware, N and Donskoi, E, 2015. Effect of titania on the sintering performance of hematite iron ores, in Proceedings Iron Ore 2015, pp 29–34 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By L. S. Linda, P. G. H Pistorius

Ferritic stainless steel is utilized to fabricate automotive exhaust systems using a ferritic weld metal. Ductility of the weld metal is higher if its microstructure contains a significant proportion of equiaxed grains. The formation of equiaxed (rather than columnar) grains is favoured by a higher titanium weld metal content. In this study, the Ti content of ferritic stainless steel weld metal was changed by using Tifree (Type 436) and Ti-containing (441) ferritic stainless steel as base metals. The metal-cored welding consumable contained 0.4% Ti. Gas–tungsten arc welding and gas–metal arc welding processes were compared. The weld metal Ti content ranged from zero to 0.5% Ti, as determined from scanning electron microscopy supplemented by inductively coupled plasma optical emission spectroscopy. Cross-sections of the weld beads were subjected to point counting (to estimate the fraction of equiaxed grains) and image analysis (to estimate the average grain size). Point counting proved to be more reliable. The fraction of equiaxed grains was sensitive to the Ti content, but not to the welding process. Below 0.4% Ti, the fraction of equiaxed grains gradually increased with an increase in the weld metal Ti content; above 0.4% Ti, the fraction of equiaxed grains rapidly increased with increasing Ti content. The transition in behaviour at 0.4% Ti corresponded to a Ti content at which Ti-rich precipitates became stable at the estimated liquidus temperature of the weld metal.

Jul 2, 2022

By Z. Zhang

Aluminum boron carbide particulate reinforced composites have found new applications in nuclear industry due to their special capability to capture neutrons, Recently, Alcan successfully developed a liquid metal mixing process to fabricate Al¬B4C metal matrix composite instead of powder metallurgical technology. In the process, titanium is added into the composites to control interactions between boron carbide particulates and aluminum matrix, To understand the effects of titanium on the composites, the solidification microstructure of Al-16%B4C without or with titanium was examined by optical and electron microscopes. The results show that titanium can improve the uniformity of the particulate distribution within aluminum matrix if the titanium content in the composites is more than 0,5%, Furthermore, it is found that the layer with rich titanium on the surface of the particulates can limit the formation of AlB2 type compounds, which may greatly deteriorate the fluidity of the composites, In addition, it is also found that the amount of the reaction products in the composites increases with the increase of holding time. However, the rate of the increase is mitigated by the increase of the content of titanium in the composites. Besides, a procedure was proposed and implemented for the evaluation of uniformity of particulate distribution within aluminum matrix.

Jan 1, 2005

By A. W. Khair

In 1985, an extensive longwall mining research project was initiated by the West Virginia University Research Center entitled "An Improved Longwall Mining Technique" with the purpose of providing operational guidelines for the mining industry to enable efficient operation of its existing and projected longwall installations. One task involved in this extensive research project was monitoring ground movements due to longwall mining and evaluating their impact on surface and subsurface structures. This paper presents an analysis of the effects of topography on quasi-static and dynamic ground movements and the severity of damage inflicted on surface structures. The site was chosen for the study with an attempt to obtain a representative account of the topography experienced in the Northern Appalachian region, and more importantly to contain a substantial number of varying topographical features i.e., mountains, hillsides, valleys, and flat bottom land. The study was made possible by typical subsidence monitoring technqiues, however subsidence monuments were surveyed on a frequent basis, intermittently during face advancement. Ground movements were investigated under both quasi-static and dynamic conditions. This provided insight into the propagation of subsidence and the dynamic affects it has upon surface structures.

Jan 1, 1987

By Mingfei He, Jianhua Chen, Yingchao Liu, Yuqiong Li

Pyrite is one of the most common sulfide minerals on earth, which is usually grown with chalcopyrite and other sulfide minerals. In flotation practice, pyrite from different mines or different sections in a same mine may have different flotation behaviors. This is because the pyrite crystal contains lattice defect, including ionic vacancy and lattice impurity. The present work investigates the effects of three typical 3d transition metal (Co, Ni, and Fe) on the adsorption of CH3OCS2 −, OH−, and CN− on pyrite surface by density functional theory (DFT) calculations. Calculated results show that Co impurity reduces the adsorption energies of CH3OCS2 − and CN− on the surface of pyrite, while Ni and Cu impurities significantly increase the adsorption energies of CH3OCS2 − and CN− on the surface of pyrite. Co impurity has small influence on the adsorption of OH−, but Ni and Cu impurities significantly increase the adsorption energies. Calculations on Mulliken charge population of Co2+, Ni2+, and Cu2+ indicate that the Mulliken charges of Co2+, Ni2+, and Cu2+ after OH− adsorption are more than those after CN− adsorption. This suggests that the ionic property of the M-OH- coordination bond is greater than that of M-CN- coordination bond, while covalent bonding of M-CN- coordination bond is greater than that of M-OH- coordination bond. The adsorption results are discussed based on coordination field theory (CFT).

Oct 6, 2020

By D. Lui, B. G. Thomas, B. Ho

"Results from mathematical models and plant experiments are combined to quantify the effect of transverse depressions and oscillation marks on heat transfer in the continuous casting mold. A heat transfer model has been developed to calculate transient heat conduction within the solidifying steel, coupled with the steady-state heat conduction with the continuous casting mold wall. The model features a detailed treatment of the interfacial gap between the shell and mold, including mass and momentum balances on the solid and liquid powder layers. The model predicts the solidified shell thickness down the mold, temperature in the mold and shell, thickness of the resolidified and liquid powder layers, heat flux distribution down the mold, mold water temperature rise, ideal taper of the mold walls, and other related phenomena. The important effect of non-uniform distribution of superheat is incorporated using the results from previous 3-D turbulent fluid flow calculations within the liquid cavity. Results from plant experiments confirm that transverse surface depressions and oscillation marks form at the meniscus and move down the mold. Measurements of mold thermocouple temperatures and breakout shell thickness were used to calibrate the models. The results indicate that the surface depressions and oscillation marks are filled with mold flux, but still have a significant effect on decreasing heat transfer. The predicted mold temperature fluctuations are consistent with measurements. If the depressions become filled with air, their effect is greatly increased. These results should be useful in the difficult task of interpreting transient mold thermocouple signals for on-line quality monitoring.IntroductionMany different types of intermittent surface defects on steel slabs arise during initial solidification in the mold of the. continuous casting machine. These defects include deep oscillation marks, surface depressions, and cracks. They may lead to quality problems, such as slivers, in the final rolled product. In severe cases, breakouts may occur, where liquid steel bursts through a thin section of the shell and drains over the casting machine below the mold."

Jan 1, 1997