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By Dongxing Wang, Zhang Ting-an, Xiaolong Li, Yan Liu

Recent years, bottom blown oxygen copper smelting process has been widely used in China. Besides many advantages such as autothermal operation, this technology is still in developing stage. This topic aims at promoting the dispersion of materials charged into the bottom blown smelting furnace used in the process. Based on the similarity theory, a 1/5 scaled physical model of smelting furnace was constructed. Polypropene particles were used as charged materials. High-speed camera was used to record the phenomenon of the particles dispersion under different gas-flow rates, nozzle diameters and installation angles of nozzles. Image processing software was used for obtaining the particles concentration under different conditions. Results show that when the gas flow rate increases, charged materials disperse better. With the same gas flow, the increasing of nozzle diameter promotes the dispersion effect of materials. The effects of installation angles are opposite for nozzles with diameter of 2.50 and 5.92 mm.

Mar 1, 2017

By Kazuki Morita

A new route to produce solar grade silicon (SOG-Si 6N) from metallurgical grade (MG-Si 98%) has been developed in Japan, which may satisfy the increasing demand for solar cells in the near future. Since some elements such as P and B have very large segregation coefficients, solidification refining is not effective for their removal and costly processes, such as electron beam vacuum melting and oxidation plasma refining, are required. According to our previous results which showed the effectiveness of leaching procedure with Ca addition for Fe and Ti removal, possibility of P and B removal by acid leaching was focused expecting that their affinities for Ca in molten silicon might be considerable. Hence, the effects of Ca addition on the thennodynamic properties of P and B in molten silicon alloys have been investigated for overall control and optimization of the SOG-Si production process in the present study. The interaction parameters between Ca and P, and Ca and B were determined by chemical equilibration techniques at 1723 K. Although the interaction parameter between Ca and B was slightly negative, that between Ca and P showed a large negative value. Also, the results for the leaching test with various amount of Ca addition revealed that the removal fractions of both elements, especially P, drastically increased with increase in the Ca content, which showed very good agreement with the prediction from the interaction parameters derived in the present work. The present results suggest that the preliminary leaching procedure can reduce the processing time and energy for SOG-Si refining. Keywords: Silicon, Solar Cell, Refining, Acid Leaching, Thennodynamics. Interaction, Phosphorus, Boron, Calcium

Jan 1, 2003

By M. Hashimoto

The equilibrium distribution ratios of sulfur between molten copper and CaO-fluxes containing caF2 and caC12 were determined in the range of 1300° to 1400° C under carbon monoxide. The rate of approach to equilibrium is rapid and increases with increasing CaCll concentration. In CaO-CaFl-CaCl2 fluxes, the distribution ratio varies in a complex way with temperature and CaFl concentration. The results are compared with those obtained with the binary fluxes of CaO with BaFZ and MgFl ?

Jan 1, 1983

By D. I. Davidov, D. A. Shishkin, M. B. Rigmant, E. P. Romanov, N. N. Stepanova, N. V. Kazantseva

The Co-19 at.%Al-6 at.%W alloy was prepared by two methods of casting. We used arc melting under an argon atmosphere with casting into a copper water-cooled casting mold and induction melting furnace with casting into a ceramic Al2O3 mold. According to the X-ray and SEM analyses, phase compositions depend on the cooling rate of the ingot after melting. After arc melting, the cast alloy has a three-phase structure, consisting of  cobalt (FCC), intermetallic phases CoAl (B2) type, and Co3W (DO19) type. After the induction melting, the alloy has a three-phase structure, consisting of  cobalt (FCC), intermetallic phases CoAl (B2) type, and Co7W6 () type. All phases in the investigated ternary alloy at the room temperature are ferromagnetic. Curie temperatures of all obtained phases were defined. It is shown that the magnetic properties of the studied alloy are typical for soft magnetic materials.

Jan 1, 2015

By W. F. Marshall

This Bureau of Mines report discusses tests conducted with four different catalytic reactor designs to determine the influences of exhaust treatment systems on emissions from diesel engines. Although there was significant differences in oxidation efficiencies at light to intermediate engine loads, all four catalysts were very effective in reducing emissions at heavy loads. Compositional determinations included carbon monoxide, carbon dioxide, unburned hydrocarbons, oxides of nitrogen, aldehydes, sulfur dioxide, sulfates, and particulate loading. Particulate size, exhaust odor intensity, and the character of the unburned hydrocarbon component were also determined.

Jan 1, 1978

By S. Erçayhan, B. Derin, O. Yücel

In the present study, the production of low carbon ferrochromium (LC-FeCr) from chromite concentrates containing 55.09% Cr2O3 and 13.06% Fe via metallothermic process was investigated. For this aim, in the experiments, the aluminothermic reduction method was applied in an open crucible. 10% CrO3 + 10% NaClO3, 15% CrO3 + 5% NaClO3 and 20% CrO3 by weight of concentrate were added to the charge, respectively and the charge was reduced with aluminium. The experiments were done with the additions of 90, 100, 110, 120 and 130% of stoichiometric requirement of aluminium. The highest Cr content in alloys was found as 71.7% at 120% of stoichiometric Al whereas the highest Cr recovery in alloys was found as 71.8% at 130% of stoichiometric Al when the both charge contained 15% CrO3 + 5% NaClO3 by weight of chromite concentrate.

Jan 1, 2004

By B. T. Lu

The corrosion and wear properties of a series of chrome white iron (CWI) castings were study using electrochemical and low-stress sliding abrasion tests. The results confirm that the corrosion resistance of these materials is largely dependant on the quantity of chromium in the matrix, while the wear resistance is mainly controlled by the volume fraction of chromium carbides. A pseudo-wear/corrosion map is developed to identify alloy compositions that may be suited for erosion/corrosion conditions.

Jan 1, 2005

By K. McG. Bowling

A statistically-designed exper¬mental study showed how gangue minerals, flux additions, fineness of grind, firing temperature and time affect the properties of acid pellets made from a Western Australian hematite ore. Alumina has less effect than silica and lime, but various interactions between the six variables occur, which influence abrasion index, reducibility and cold compression strength. Finer grinding has little influence on reducibility but improves the other two properties. The major variable is firing temperature. It interacts with all other variables in its effects on pellet properties. Calculations based on the data show the implications for straight-grate pellet plants and optimum hood temperature range.

Jan 1, 1980

By P. A. Plunkert, D. E. Morse, Pui-Kwan Tse, W. D. Menzie, Lucy McCartan, J. F. Papp

China’s burgeoning economy is responsible for a major share of recent world mineral consumption increases. In addition to factors traditionally recognized in market economies1 and factors unique to specific commodities, Chinese consumption now plays a major and increasingly important role in energy and mineral markets for many commodities, such as aluminum, copper, iron and steel, and oil. China has the world’s second largest economy after the United States. And its long-term importance to the minerals markets is even greater than indicated by its gross domestic product (GDP), which is currently less than two-thirds of that of the United States (Table 1). This is because China’s rising standard of living is accompanied by rapid industrialization and urbanization. Its consumption of mineral materials for infrastructure development for its very large population is significantly greater per capita than that of such developed economies as the United States, the European Union and Japan. In other words, China’s per capita production is rising at a rapid rate and will probably continue to do so for many years.

Jan 1, 2006

By S. N. Monteiro, J. Alexandre, N. Cerqueira, B. C. Mendes, A. R. G. Azevedo, G. C. Xavier

Brazilian civil construction generates a huge amount of waste in different stages of construction, mainly due to the work methodology used in construction sites. The objective of this work is to study the inclusion of the residual of the civil construction in the sand mass in 0, 10 and 20%, with mortars used to cover masonry. For this study, the beneficiation of the material in crusher was obtained so that it obtained granulometry similar to sand and the most recurrent technological tests in mortars for this purpose, as the mechanical resistance (compression and flexion), water absorption and determination of the coefficient of Capillarity beyond the index of consistency, according to Brazilian norms, that define parameters of execution the technological tests. The results showed that the mortars after the incorporation presented value within the norm except the consistency and capillarity to the 20% that presented problems of fluidity and durability, hindering its use.

Mar 1, 2018

By A. B. Pederson, G. E. Bartlett

As a part of our study of how coal mine dusts injure the lung we have studied the effects of dusts and dust-exposed pulmonary alveolar macrophages (PAMs) on the growth of lung fibroblasts (LF). Fibroblasts were cultured near confluence in low-serum medium, either alone or in the presence of dusts, dusts plus PAMs, dust leachates or superriatants of dust-exposed PAM cultures. We report here provisional conclusions, based on initial observations. Rat LF were relatively unresponsive to direct effects of dusts, showing weak stimulation in only a few cultures, and there was no evidence that dust-exposed rat PAMs had released any growth-regulatory products. In contrast, guinea pig cells were more responsive to the dusts. The pattern of responses was quite complex. Three of the dusts stimulated LF directly (with no mediation by PAMs). Two dusts were essentially inert when added directly to fibroblast cultures, either with or without PAMs, but their leachates were active: 867 leachate was inhibitory and RF leachate was stimulatory. Dust 1361, either directly in the cultures or as an aqueous leachate, was stimulatory, and it activated cocultured PAMs to stimulate LF growth; however, supernatant products of 1361-stimulated PAMs were inhibitory. Direct exposure to 1192 stimulated LF, but its leachate was inert; cocultured PAMs exposed to 1192 had weak stimulatory effects, but supernatants of 1192-exposed PAMs were mildly inhibitory. MP3-3 had effects similar to 1192, except that the cocultured, dust-exposed PAMs had no effect on growth. We conclude 1) that guinea pig lung cells are more responsive to dusts than are rat lung cells, 2) that dusts can influence growth of LF by four kinds of interaction (by direct dust-cell interaction, by release of soluble dust components into the culture medium, by activating P AMs to exert direct cell-cell interactions, and by activating P AMs to release growth regulatory products into the culture medium), 3) that each kind of interaction may be neutral, inhibitory or stimulatory, depending on the dust tested, 4) that four of the dusts tested were neutral, inhibitory or stimulatory, depending on the assay (the fifth <lust was either neutral or stimulatory), and 5) that the effects of soluble mediators (leachates or products of activated PAMs) frequently did not correspond with the direct dust-cell or PAM-fibroblast effects. These results suggest that the nature of the dust-lung interaction at the level of cells and molecules is exceedingly complex. These observations need to be confirmed and extended to determine what characteristics of the dusts determine the nature of the cellular responses, and to determine which patterns of responses are detrimental and which are beneficial in the overall health of the dust-exposed lung.

Mar 1, 1989

By Ingrid Engeset, Solve Hov, Arnfinn Endal, Per-Anders Mortensen, Priscilla Paniagua, Bjørn Kristian Fiskvik Bache

During the last decades, it has become common practice in the Nordic countries to use dry deep mixing in soft clays with lime and cement in for example deep excavation pits in soft clay, or as a reinforcement of the passive zone within sheet pile walls. The shear strength of stabilised soils is affected by the stress conditions during curing and shearing. However, this is normally not taken into consideration. As the strength of the stabilised clay is stress dependent, excavation of the overlying soil will lead to a reduction of the confining stresses in the underlying stabilised soils which means that the shear strength will also be reduced. Under embankments on the other hand, the effect is reversed as the shear strength will be increased. In this study, laboratory tests have been performed on stabilised soils cured and tested under different stress conditions to quantify the stress effects in a Norwegian sensitive clay. In addition, direct simple shear tests on samples from in situ columns have been made with varying normal stresses. Results are presented showing an increase of shear strength of the stabilised soil with increased curing stresses, and an even higher increase with increased confining stress during shearing. The results are compared to field measurements along with a discussion of practical application of the findings.

May 1, 2022

Cyanide is reactive to copper minerals and is not suitable to extract the gold from the copper bearing ores. Ammoniacal thiosulfate is considered an excellent alternative lixiviant for leaching copper bearing gold ores. Unfortunately the results of high reagent consumption and poor gold ex-traction were found by thiosulfate leaching of synthetic gold ores containing chalcopyrite, chalcocite or bornite and a mild refractory copper-bearing sulfidic gold ore. In this investigation, several processes have been applied to reduce the impacts of these minerals on gold leaching. The process included: the pre-oxidation of copper sulphide minerals in water or ammonia solution, the reduction of dissolved oxygen in the lixiviant (0.3 ppm DO or 0.7% oxygen), adding phosphate anion in the leach or pre-leach stage, and the addition of a strong copper ligand (e.g., EDA and DETA). The results indicated that the gold extraction could be improved to 93% with the thiosulfate consumption being reduced to less than 8 kg/t. The dissolution of copper minerals was found to be the major reason for increased consumption of thiosulfate and the highly reductive leached surfaces are responsible for the reduced gold extractions.

Jan 1, 2014

By M. Kadiyski, V. Stoyanova, E. Visariev, V. Stoilov

"The present study deals with copper losses in slag from copper smelting. Copper slag cooling at Aurubis Bulgaria is traditionally done in pits. A new type of slag-cooling is introduced in the site, involving cooling ladles. In a previous study, the ladle cooling process was studied in detail, showing an improvement in the recovery of copper in the slag after flotation. The main reason for better recovery of copper is the increased cooling time, which allows for the accumulation and aggregation of copper droplets. The effects of the newly introduced slag cooling process are studied using optical microscopy and scanning electron microscopy. Cooling in pits and in ladles is compared, based on copper droplet size, distribution and content. Specialized image processing software is employed on images taken with an optical microscope. The results are then compared with a similar technique, available in SEM software. The availability of phase-analysing image software in combination with electron dispersive X-ray spectroscopy makes it possible to study the morphological properties, distribution and chemical composition of the copper droplets. The obtained results confirm the initial conclusions about size, distribution and composition of the copper-bearing particles. A large amount of copper particles is examined showing an obvious increase in their size from pit- to ladle cooling. The results show an increase in the average size of the droplets, which doubles from pit-cooling to ladle-cooling. There is a well-pronounced tendency of decrease of the percentage of droplets in the smallest fraction (<5 µm) in the ladle-cooled slag. In addition, the number of droplets in the larger fractions increases, compared to the ones in the pit-cooled slags. It is believed, that the developed methodology for analysis provides a relatively quick and reliable solution for comparison of the cooling rates in the slag. INTRODUCTION In the process of copper smelting and converting, iron-silicate slags are produced that contain various amounts of dissolved and entrained copper. Different physical and chemical techniques are employed for the valorisation of the remaining metals in the slag – magnetic separation, leaching, roasting, flotation, etc. According to Gorai et al (2003), about 2.2 tons of slag is produced per ton of metal. In 2016, about 20 million tons of copper have been produced globally (www.icsg.org). At an average of 0.5 percent copper content after treatment, these slags contain more than two hundred thousand tons of copper which is lost due to inefficient processing."

Jan 1, 2018

By D. J. Benton, S. Finley, D. T. Orr, A. J. Chambers, M. A. Stepan

"Corrosion of ground support can lead to falls of ground that pose a significant risk to miner safety. To address this problem, the National Institute for Occupational Safety and Health (NIOSH) is investigating corrosion at the Hecla Mining Company’s Greens Creek Mine, located near Juneau, Alaska, USA. Field studies have used photogrammetry surveys to document welded-wire mesh corrosion, and laboratory studies at NIOSH’s Spokane Mining Research Division (SMRD) have investigated the effects of corrosion on ground support integrity. Findings show that (1) corrosion monitoring through photogrammetric methods may be effective for qualitative measurements of welded-wire mesh corrosion, and (2) there is a relationship between loss of load-bearing capacity and the diameter loss due to corrosion in welded-wire mesh. Photogrammetry results thus far have measured an apparent bulking of the corroded welded-wire mesh, and preliminary laboratory tests have investigated the relationship between the larger bulked and effective wire diameter. If this relationship is verified, these results may indicate that photogrammetry, when combined with the models produced in laboratory tests, could offer a means of monitoring corrosion levels, as well as rock rib deformation. INTRODUCTION Reducing the number of rock fall injuries and fatalities is an important part of the mission of the National Institute for Occupational Safety and Health (NIOSH) Spokane Mining Research Division (SMRD). Ground control using support systems to protect miners from rock falls is one of the oldest mining sciences, and considerable research has led to a variety of modern tools and methods in use today. Among these tools are rock bolts and welded-wire mesh, which are made from increasingly higher-strength steel grades to meet the increasingly demanding requirements of underground mines [1]. However, the benefits of these higher-quality support elements may be negated in corrosive mining environments. A better understanding of how corrosion affects the support capacity of ground support systems will assist engineers in determining when an opening is at a greater risk of falls of ground. Accelerated corrosion has been occurring in some areas of the Hecla Mining Company’s Greens Creek Mine near Juneau, Alaska, USA. Corrosion of ground support has resulted in two falls of ground occurring between April 2015 and March 2016. While these falls of ground did not injure any personnel, mine management recognized the high risk to miner safety and responded by actively undertaking a ground support rehabilitation program. Rehabilitation measures include the installation of both galvanized and coated, corrosion-resistant bolts and welded-wire mesh, depending on local conditions."

Jan 1, 2017

By Shunhong Huang

To improve understanding the effect of heavy metal chromium on soil biota, laboratory incubation experiment was carried out in the soils contaminated artificially with five concentrations of chromate (50, 250, 500, 1000 and 2000 mg kg_1 soil) over time (35 days). The population and diversity of bacteria, fungi and actinomycetes in soils were measured as indicators of soil microbial processes in the disturbances mentioned above. Incubation experiment results elucidated that the population and diversity of microorganisms decreased with increasing Cr (VI) concentration. Furthermore, various microorganisms showed different sensitivity to total Cr contamination. The sensitivity of microbial population to chromium contamination was in the order: actinomycetes >bacteria>fungi. The resulted implied that the microorganism can be used as an indicator of chromium contamination.

Jan 1, 2008

By Xiao Long, Ting Wu, Lilong Zhu, Qian Wang, Shengping He

"During the continuous casting of peritectic steel slabs, mould fluxes with high crystallization capacity are usually chosen for improving slab surface quality. However, the lubrication condition of casting shell also could be deteriorated. Since precipitation of crystals within liquid slag film can change the composition and property of liquid slag over solid-liquid slag film interface region, its impacts on continuous casting process also are not clear. In order to clear this phenomenon, an experiment method was put forward, and mould fluxes for peritectic steel slabs continuous casting were selected and examined. The results reveal that after crystals have been separated, the crystallization capacity of leftover liquid slag increased with different levels, which could deteriorate the lubrication condition of casting shell and cause a series of problems. Thereby, mould fluxes with high crystallization capacity at beginning for heat transfer control and then weaker after crystallization should be considered in the future.IntroductionIn the continuous casting of peritectic steel slabs, contradiction between heat transfer control and slab shell lubrication by mould fluxes has been treated as a key problem for maintaining a smooth manufacturing process [ 1]. Strong and uneven horizontal heat flux over the meniscus region will cause uneven solidification of casting shell, especially for peritectic steel slab with enormous volume change caused by phase transition. All of those could cause surface defects like longitudinal crack [2-4]."

Jan 1, 2013

By Rodney D. Lamond

The need for blast vibration monitoring can be attributed to a combination of three factors: Structural damage, Blast design and Human annoyance. Traditionally, vibration damage criteria are prescribed in terms of peak particle velocity (PPV), as measured or predicted in the ground surrounding a blast. The PPV in the vicinity of a blasthole is strongly influenced by the quantity of the explosive per delay. In general, the existing prediction models give reliable results but fall short of addressing the change in PPV when the charge is decoupled and/or distributed.

Jan 1, 1995

By A. B. Walker

The effects of the injection of dry limestone additives into boilers for the sorption of sulphur dioxide have been studied in pilot and full-scale systems. The effects of such injections on boiler mass particulate emissions as well as collectability characteristics of the fly ash and reaction products are presented. Implications of the effects on the design and economics of particulate collectors, in particular electrostatic precipitators, are discussed.

Jan 1, 1971

By Aleksandar D. Bugarski

Three types of uncatalyzed diesel particulate filter (DPF) systems, three types of high-temperature disposable filter elements (DFEs), and one diesel oxidation catalytic converter (DOC) were evaluated in underground mine conditions for their effects on the concentrations and size distributions of diesel aerosols. Those effects were compared with the effects of a standard muffler. The experimental work was conducted directly in an underground environment using a unique diesel laboratory developed in an underground experimental mine. The DPF systems reduced total mass of aerosols in the mine air approximately 10-fold for light-load and 20-fold or more for high-load test conditions. The DFEs offered similar reductions in aerosol mass concentrations. The efficiency of the new DFEs significantly increased with accumulation of operating time and buildup of diesel particulate matter in the porous structure of the filter elements. A single laundering process did not exhibit substantial effects on performance of the filter element. The effectiveness of DPFs and DFEs in removing aerosols by number was strongly influenced by engine operating mode. The concentrations of nucleation mode aerosols in the mine air were found to be substantially higher for both DPFs and DFEs when the engine was operated at high-load modes than at low-load modes. The effects of the DOC on mass and number concentrations of aerosols in mine air were relatively minor when compared to those of the DPF and DFE systems.

Jan 1, 2009