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By P. Rusin

Many oxide silver and molybdenum deposits remain undeveloped because chemical extraction yields poor recoveries or is environ-mentally unacceptable. Bio-reductive leaching of such ore samples at MBX resulted in high recoveries of silver and molybdenum. When baseline 3-day cyanide bottle roll tests were conducted on manganiferous oxide silver ore, 13.7% of the silver was extracted. In contrast, 86% of the silver was microbially solubilized into the organic growth medium by bio-reduction with 99.8% dissolution of manganese. A follow-up cyanide bottle roll test yielded an additional 8.5% silver recovery for a total recovery of 94.5%. Baseline 3-day acid bottle roll tests of the iron oxide molybdenum ore yielded 1.8% moly. However, bio-reduction solubilized 93.3% of the moly into the growth medium. An additional 0.3% moly was recovered during the follow-up acid bottle roll test. Microbial treatment of refractory oxide ores with bio-reductive bacteria resulted in higher recoveries of silver and molybdenum than conventional chemical leaching. The bioleaching process occurred at a near-neutral pH at ambient temperatures. The bacterial solubilization of silver and moly was achieved without the use of cyanide or sulfuric acid.

Jan 1, 1992

By Mingchun Lu, Zhe Wang, Mingming Cao, Xiangdong Xing, Shan Ren, Jianliang Zhang, Zhengjian Liu

"The effect of reduction temperature on the vanadium titano-magnetite carbon composite pellets was investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM), and the discussion has put emphasis upon the enhanced reduction mechanism of additives containing CaF2 and NaF in this paper. The results showed that the reduction temperature of 1350°C was needed for the generation, mergence and growing up of metallic iron as well as monomer dissociation between metallic iron particles and slag phase in the vanadium titano-magnetite metallization pellets. The iron compound was completely reduced into metal iron, and Fe2Ti04 was mainly transformed into metal iron, (Fe,Mg)Ti205 and FeTi03 at 1350°C. The maximum metallization ratio was only 88.5% at 13500 for 30 min without any additive. However, with the addition of 3.0% CaF2 or NaF, the metallization degree of pellets could reach up to 94.8% and 92.5%, respectively.IntroductionVanadium titano-magnetite which is mainly distributed in the area of Panxi, Chengde and Maanshan in China is a kind of complex iron ore which contains various valuable metal elements such as iron, vanadium, titanium, etc. Among the above areas, Panzhihua (Sichuan Province in China) area possesses the largest deposits of vanadium titano-magnetite and the future reserves are more than 100x108t, and the reserves of Ti existing as Ti02 reach to 8.7x108t which occupy over 91% of the whole nation and ranked No.1 in the world[1]. Lots of researches on the comprehensive utilization of vanadium titano-magnetite have been conducted in the world. And many technological processes have been applied successfully in industrial production. Among these processes, the process of rotary kiln-electric furnace is employed to recover iron and vanadium in South-Africa, while the process of blast furnace-rotary furnace is widely used in Russia and China. Besides, many researchers have made efforts on employing new direct reduction process to realize the effective comprehensive utilization of vanadium titano-magnetite[2-4]. However, the direct reduction process is only researched in laboratory and it has not been used in industry."

Jan 1, 2013

By Adolfo Pillihuaman Zambrano

Fe-Cr-C production is a very high electrical energy consuming process. Decrease up to 10% of this electrical energy is expected when self-reducing agglomerates are used. This research aims to understand how the synergetic effects are when stronger reductant, like Fe-Si, is substituted for coke in self reducing pellets. Brazilian chromites containing 41.2%Cr2O3 were mixed with petroleum coke and agglomerated with cement as the binder. Small amounts of 1%, 2% and 4% of Fe-75%Si were substituted for the equivalent petroleum coke, and pure silica plus hydrated lime were added for adjusting the slag composition. The mixture was pelletized, dried and submitted at 1773K up to complete the reactions. The results showed that the reduction reactions were 1.4 and 2 times faster with 1% and 2%Fe-Si addition, respectively, than with no addition. The microscopic analysis showed that it was formed a liquid phase, but the pellet did not collapse what indicates that the coalescence of the metallic phase depends on the dissolution of the pre-reduced particles of the chromites into slag.

Jan 1, 2008

By J J. L du Plessis, A Spaeth

The objective of this paper is to demonstrate the efficiency of machine-mounted active explosion suppression systems (AESS). Their proven effectiveness against methane explosions is highlighted, as well as their additional potential when used as an early warning system should frictional sparks occur during the coal-cutting operation at the coalface.Methane and coal dust explosions remain one of the primary and unpredictable risks in underground coal mining. Although technologies such as proactive ventilation, methane monitoring and wet-head cutting systems are widely used as preventative measures, there are no fail-safe controls able to reduce the risk to zero. None of these controls is designed to be able to counter the negligence associated with human error or to deal with rapidly changing face conditions which could lead to flammable gas ignitions. Machine-mounted AESS have been installed on various continuous miners as an additional control to further reduce the risk of ignitions and to act as a safety shield when all the other precautions taken have failed. This was the primary motive for the development of AESS. As an additional feature, the ExploSpot® AESS is being enhanced to identify frictional ignition sources at the coalface that reach a predefined monitoring level. This functionality may serve as a further effective preventative measure.As part of ensuring coalmine operational safety, the detection of frictional ignitions can play a huge role in creating heightened awareness of potentially dangerous situations. By being able to process the frictional spark burning pattern, the AESS could support the decision-making process regarding whether to continue the coal-cutting operation, whether there is a need for maintenance or whether the operation should be stopped completely due to the increased risk of a flammable gas ignition and an ensuing explosion.CITATION:Spaeth, A and du Plessis, J J L, 2015. Enhanced risk reduction using early warning technologies embedded in active explosion suppression systems, in Proceedings The Australian Mine Ventilation Conference, pp 315–322 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By S. Behl

A major limitation in developing successful selective flocculation schemes is the difficulty encountered in adsorbing the polymeric flocculant only on the desired substrate. In this paper a correlation between selectivity of flocculant adsorption and separation efficiency is outlined and a potential technique to achieve selective adsorption of flocculants is discussed.

Jan 1, 1992

By A. Welty, T. Garn, K. Lyon, B. Jakovljevic, R. S. Herbst, M. Greenhalgh, Cytec Solvay Group

"Industrial rare earth separation processes utilize PC88A, a phosphonic acid ligand, for solvent extraction separations. The separation factors of the individual rare earths, the equipment requirements, and chemical usage for these flowsheets are well characterized. Alternative ligands such as Cyanex® 572 and the associated flowsheets are being investigated at the pilot scale level to determine if significant enhancements to the current separation processes can be realized. These enhancements could be defined as higher separation factors, reduced stage requirements, or reduced chemical consumption. Any of these enhancements can significantly affect the costs associated with these challenging separation proccesses.A mid/heavy rare earth element (REE) separations flowsheet was developed and tested for each ligand in a 30 stage mixer-settler circuit to compare the separation performance of PC88A and Cyanex® 572. The ligand-metal complex strength of Cyanex® 572 provides efficient extraction of REE while significantly reducing the strip acid requirements. Reductions in chemical consumption have a significant impact on process economics for REE separations. Partitioning results summarized Table 1 indicate that Cyanex® 572 offers the same separation performance as PC88A while reducing acid consumption by 30% in the strip section for the mid/heavy REE separation."

Jan 1, 2016

By R. O. Ifill

Alternating current electrocoagulation (AC/EC) may be an alternative to chemical coagulation in the thickening of tailings in the mineral, coal and petroleum industries. In the current study, ground silica (d50 as received, 20 µm) served as the model tailings solid with characteristically poor settling behavior. Its natural initial settling rate was 1.6 x 10-3 cm/min. This paper discusses the indirect application of AC/EC via aluminum electrodes to the enhancement of the settling behavior of the silica. ?Indirect AC/EC? means that the silica was coagulated upon dispersion in water that had been treated by AC/EC. The effect of AC/EC retention time on settling behavior is examined and the water chemistry is analyzed. Test results show that the initial settling rate of silica was enhanced by a factor of 4,000 at its maximum of 6.4 cm/min, under the conditions employed. Settling enhancement was achieved upon contact between the AC/EC-treated water and the silica, and the enhanced initial settling rate was dictated by the floc size. The aluminum dosage increased with AC/EC retention time, reaching a maximum concentration that was equivalent to 13.1% of that predicted by Faraday?s law. Complex aluminum ions are considered to have adsorbed onto the silica surface and an adsorption mass ratio of 0.3 mg Al/g silica was the most effective in enhancing settling behavior. Owing to pH change or slow kinetics, aluminum hydroxide precipitation did not lower the ion product ([Al3+][OH-]3) below the KSP of 6.3 x 10-32.

Jan 1, 2011

By Klaus Pronold

Once installed rolling mills can look forward to a long life. Around 40% of the 140 conventional hot strip mills presently in operation were built between 1960 and 1970. 17 of the 29 CSP®-plants were commissioned before the year 2000 and have automation platforms that are obsolete and/or have outdated rolling technology. Keeping pace with the market requirements is an ongoing challenge for producers of flat steel. It is a real balancing act keeping production facilities performing at necessary levels, safeguarding the investment and keeping outage periods to a minimum. To overcome these demanding factors and strike the right balance allowing for the production of higher grade steel that meets the current market price the installation of mechanical equipment as well as automation platforms and process technology must meet the latest technology standards. Being discussed in this paper are the different motives for modernizations along with their impact on project handling and commissioning philosophies. Experience gained during recent modernization projects in the field of flat steel rolling relating to Steckel / plate mills or current CSP® modernizations will be shared and demonstrate that each modernization has its own individual solution. Specific strategies are explained to help optimize production, increase plant agility and maximize the return on investment.

Aug 17, 2017

By Yi Luo, Jian Yang

Subsurface strata movements and deformations associated with longwall mining operations in underground coal mines could cause various disturbances to subsurface mine structures, ground water bodies, and coalbed methane reservoirs. In order to assess those disturbances correctly and to design effective and efficient mitigation measures, it is necessary to develop an accurate prediction model for subsurface strata movements and deformations. Decades of research have demonstrated that variations of stratification and lithology in the overburden have significant influence on the subsurface strata movements and deformations during ground subsidence process. The key strata theory states that the thick and hard key strata serve as the backbone of the overburden and control the movements of the thin and soft weak strata located above them. From an engineering standpoint, the overburden strata are subdivided into several individual groups by the key strata with each group consisting of a key layer at the bottom and weak layers overlying it. A new subsurface subsidence prediction model considering the key strata effects on subsurface strata movements and deformations has been proposed. In this method, elastic modulus, specific weight, tensile strength, and uniaxial compressive strength (UCS) of each layer are used to identify the key layers and to determine the needed subsurface subsidence parameters. The influence function method, proven to be accurate and versatile for surface subsidence prediction, was employed to predict the subsidence on each of the overburden layers from mining horizon progressively upward to ground surface with the assumption that the predicted subsidence on a given layer serves as the subsidence source for the layer immediately above. The enhanced subsurface subsidence prediction model has been demonstrated with an actual case to show its applicability and improvement.

Jan 25, 2021

By A. Noble, R. Q. Honaker, J. Werner

Recovery of rare earth elements (REE) from coal-related resources has recently received significant interest due to supply concerns and their key roles in critical industries and defense-related technologies. An integrated flowsheet consisting of sorting, crushing/grinding, physical separation, acid leaching, solvent extraction, and selective precipitation was designed to achieve continuous production of rare earth products from various coal-related resources such as coarse refuse and acid mine drainage. A pilot plant was constructed that enabled continuous testing of the circuitry on a range of different coal-based feedstocks. Despite achieving significant success in producing high-grade rare earth oxide products, low REE recovery values and high operational costs necessitated a re-evaluation of the process flowsheet. This article describes the circuitry improvements that were based on both laboratory and pilot plant test results. Roasting as a pre-leach treatment was found to significantly improve the leaching rate and overall REE recovery values. After roasting West Kentucky No. 13 and Fire Clay coal refuse materials at 600 °C, REE recovery increased by 60 and 40 absolute percentage points, respectively. Rare earth concentration in the pregnant leachate solution (PLS) was increased to around 700 ppm prior to solvent extraction using a staged precipitation method. REEs in the precipitate were re-dissolved, purified, and extracted from the PLS using solvent extraction and selective precipitation to values of around 80%. As a result of the improvements, chemical consumption in the acid leaching and solvent extraction processes was significantly reduced. A techno-economical assessment of the improved flowsheet indicated significant commercialization potential.

By Thenepalli Thriveni, Seong-Young Nam, Nam-Il Um

New modern water treatment technologies required for arsenic removal from waste waters contaminated extensively by various background sources from mining, industrial waste, agricultural waste, painting industry and natural geological bed rock system etc. Arsenic is a widely dispersed element in the earth's crust and exists at an average concentration of approximately 5 mg/kg. Arsenic (As) and heavy metals may be released from the mine wastes to the ground and surface water systems, as well as the geological environment due to their solubility and mobility. This research focuses on the effect of accelerated carbonation process for successful removal of heavy metal arsenic anions from artificial waste water and mining waste waters. This accelerated carbonation process is a simple and novel method with 85 ~ 88% removal efficiency. Carbonation has been studied as a process to further improve immobilization of solidified/stabilized waste and granular waste. After successful removal of arsenic anions from solid mining waste and its potential benefits for producing construction materials. Besides, the industrial and urban management systems are generating bulk solid mining wastes, and most often dumping them in open fields. To prevent the landfilling with mining waste, many efforts are being made for the recycling of different types of mining solid wastes with a view to utilizing them in the production of various construction materials.

Jan 1, 2014

By P. Rusin

A new bacterium, Thiobacillus cuprinus, can extract copper from chalcopyrite as rapidly as T. ferrooxidans. On solution with and without nutrient amendments and bacterial growth media were supplemented with T. ferrooxidans or T. cuprinus in shake flask studies. Both species extracted -42% of the copper using growth media. In one case, T. cuprinus solubilized approximately twice as much copper as T. ferrooxidans utilizing a seeded On solution. Thiobacillus prosperus also oxidizes chalcopyrite and tolerates high chloride concentrations. These sulfide-oxidizing bacteria are representatives of the mixed microbial community found in sulfide dumps. Rates of biological copper extraction from sulfide ores, using the native microbes, have been significantly enhanced by amending On solution with PGM.

Jan 1, 1994

By A. M. Raichur, S. P. Vijayalakshmi

Fine coal dewatering is a major problem in the coal industry because the fines hold significant amounts of water and account for two-thirds of the product surface moisture. Present methods include flocculation using polymeric flocculants followed by filtration. But the kinetics of filtration are not favorable with such flocculants. In this study, a novel method involving flocculation with microorganisms for improving the settling rates and dewatering kinetics has been investigated. Two Gram-positive microorganisms, Mycobacterium phlei and Bacillus subtilis were used as bioflocculants. The effect of time, pH and ionic strength of the electrolyte used on adhesion and flocculation were studied. Adhesion tests showed that maximum adsorption occurred in 20 minutes in the pH range of 2-7 and the total amount of bacteria adsorbed was almost the same with both the flocculants. Nearly 98% of the coal flocculated with both the microorganisms in about 5 minutes. The filtration rate of fine coal almost doubled with addition of bacteria and electrolyte and maximum filtration occurred near the point-of-zero-charge of the bacteria.

Jan 1, 2003

By Timo Niitti, Antti Rinne, Janne Turunen, Sami Grönstrand

"This paper describes novel methods to enhance the flow dynamics of a mechanical flotation cell that can be applied to an existing installation. There are several reasons to alter the flow dynamics. The most common motivation is to improve the metallurgical performance of the cell, for instance, to improve the flotation recovery in particle size ranges that are normally difficult to recover.The flow dynamics enhancements are associated with the geometry of the rotor-stator area and additional features in the tank. The rotor-stator area has been modified to provide more concentrated turbulent kinetic energy or respectively more pumping efficiency with less attrition to the slurry. The tank can be fitted with various geometrical features, aimed to create a desired particle suspension profile. Depending on the targeted particle size range and application, badly selected or designed features can also have a negative effect on the metallurgical results.Besides new flotation equipment, the enhancements can be applied to existing flotation cell installations, thus enabling improvements in the mixing profiles, solids suspension, tank sanding and metallurgical performance of operating flotation circuits. Results of several tests carried out in existing plant operations are presented, concerning both flow variables and metallurgy.The common factor to above-mentioned enhancements is the use of modern computational fluid dynamics tools in the design phase, as well as the validation of the obtained CFD results in laboratory and production scale. Validated variables include mixing profile, power draw and local air hold-up.The paper demonstrates the effects of various flow geometries on the mixing profiles and metallurgical results of existing mechanical flotation cells. It shows how modern computational fluid dynamics analysis can be used to screen and select different approaches before carrying out costly trial-and-error experiments in plant scale."

Jan 1, 2006

By W. Mirihange

Considerable mechanical property decline is always observed at the Heat Affected Zone (HAZ) of AA 5083, This occurred as a result of the thermal effect on the hardened material, It is highly beneficial to have a prospective metallurgical procedure to overcome this decline of properties. Therefore, experiments were set to evaluate the effectiveness of a quick post weld heat treatment process with the AA 5083, Optimum results were obtained at 473K and with approximately 600 seconds time, The interplay between the time, temperature and mechanical properties are possible to explain by the Lifshitz-Slyozov-Wagner (LSW) theory and by considering the composition of the material.

Jan 1, 2005

By G. Mahieu, L. Perez-Barnuevo, P. Barbeau-Verreault, O. Gravel

Raglan mine is a copper-nickel mining operation, part of Glencore, and located at the northern border of the province of Quebec, in Canada. The concentrator is fed by a mix of four different underground mines, thus it must accommodate periodic variations in run-of-mine mineralisation and composition. In order to concentrate nickel and copper sulphides, the flotation circuit also includes a regrind step at the cleaner stage. This leads to challenges in maintaining optimal recoveries and in diagnosing potential disturbances. This paper advocates for the combination of automated mineralogical analyses, reconciliated mass balances from diagnostic sampling campaigns and innovative multidimensional visualisation to assist in tackling these challenges. Through this approach, it has been possible to quantify the regrind step influence on the liberation of valuable mineral particles in the final flotation concentrate. The methodology also allows for virtual sieving of the products in order to track unit loss in the flotation process. The proposed analysis scheme presents an opportunity to easily diagnose flotation circuit performance based on mineralogical information. Keywords: Flotation diagnostics, multi-dimensional visualisation, mineral liberation analysis

Jan 1, 2020

By Eric J. Grimsey

Steady state Excel models for a copper flash smelter and an iron blast furnace are used to enhance the teaching of pyrometallurgical smelting principles within a fourth year level process engineering unit delivered at the Western Australian School of Mines. A lecture/workshop approach has been adopted in which student teams undertake process simulation assignments that illustrate the multifaceted responses of process outputs to variation of inputs, the objectives being to reinforce their understanding of smelting principles. The approach has proven to be popular with students, as evidenced by the consistently high ratings the unit has received through student feedback. This paper provides an overview of the teaching approach and process models used.

Jan 1, 2014

By Erik S. Bernard

"INTRODUCTION Reinforced Concrete (RC) members such as beams and columns are usually required to include stirrups to maintain post-crack shear capacity, and some may include stirrups that act as confining steel to maintain structural integrity during a seismic event (eg. NZS3101, ACI 318). To achieve seismic resistance, the spacing between stirrups is usually required to be much closer than is ordinarily prescribed for non-seismically resistant structures. Each stirrup must also fully enclose the longitudinal reinforcement with long end-hooks to ensure that the contained concrete is sufficiently restrained during reverse-cycle loading and the reinforcing bars are confined to prevent buckling. The close spacing between stirrups can lead to congestion of reinforcement within members, and can also be expensive to construct due to the labor-intensive nature of steel fixing. A possible alternative to closely-spaced stirrups is the use of fibers to provide restraint and confinement during a seismic event, although this is not yet recognized in codes. Previous experimental research (Jiuru et al, 1992; Filiatrault et al, 1995; Bayasi and Gebman, 2002; Billington and Yoon, 2004) has demonstrated that steel fibers are relatively effective in this application, but suffer the problem that their stiffness can make them difficult to consolidate within an already tight reinforcement cage, especially if they are relatively long (>40 mm). Moreover, steel fiber reinforced concrete (SFRC) is subject to embrittlement with the passage of time, leading to a steady loss of ductility beyond crack widths of 1-2 mm (Banthia and Trottier, 1994; Bernard and Hanke, 2002; Bernard, 2014; Bjontegaard et al, 2014; Bernard, 2015). Since cracks during seismic events are generally much larger than this, embrittlement may present a challenge to the long-term efficacy of SFRC during seismic events. An alternative to steel fibers for enhancement of seismic resistance is the use of macro-synthetic fibers. This type of fiber usually offers the advantage of being flexible so that consolidation is easier between reinforcing bars. They also offer superior durability compared to steel fibers and can reduce flexural crack widths (Bernard, 2016). Several recent small-scale investigations (Ma et al, 2012; Carnovale, 2012; Osorio et al, 2014) have indicated that macro-synthetic fibers can produce meaningful improvements in seismic resistance if used in combination with conventional steel reinforcing bars. The present investigation has extended research in this field by examining whether embossed macro-synthetic fibers can be used to increase the spacing between stirrups while maintaining seismic resistance."

Jan 1, 2016

Ilmenite (FeTiO3) is the primary global source of titaniumdioxide which is commonly used as a whitening agent in papermanufacture and a pigment in paint manufacture. In WesternAustralia ilmenite is processed by the Becher process (Becher,1963, Becher et al, 1965) where ilmenite particles are feddirectly into the furnace with coal and heated to form acomposite of elemental iron and TiO2. The mechanism of thecarbothermic reduction of ilmenite has been extensively studied(Grey, Jones and Reid, 1973; Jones, 1973; Grey and Reid, 1974;El-Tawil, Morse and Francis, 1993) and is reasonably wellaccepted.

Jan 1, 1997

By N. F. Faria, F. Monteiro, B. O. Taiwo, A. Palangio, D. Fonseca, J. Manuel

This paper explores the interpretation and application of Particle Size Distribution (PSD) curves in optimizing blast design and enhancing downstream operations. The study looks at important factors like D50, D80, fines content, and the uniformity index to show how PSD curves affect the efficiency of different mining processes. The first section of this paper discusses the impact of blast design parameters such as burden, spacing, and explosive energy on the resulting PSD, highlighting their significance for downstream operations like crushing, and material handling. The section concluded that proper alignment of PSD with downstream size classes, like primary crusher inlet sizes, among others, can result in substantial cost reductions and productivity gains. The second part presents a case study from dstgroup aggregate quarry in northern Portugal, utilizing fragmentation analysis to evaluate blast performance and promote continuous improvement. The section specifically examines the effect of stemming material size on blast fragmentation, comparing the impact of using aggregate with a D80 of 12.32 mm versus a D80 of 21.94 mm. The D80 value represents the particle size at which 80% of the stemming material is smaller, making it a critical parameter in evaluating the stemming's effectiveness in confining explosive energy. The drilling and blasting designs were meticulously planned using O-PitDev and O-PitSurface software to ensure accuracy in blast parameters and layout. To assess the fragmentation resulting from these different stemming material sizes, the study utilized WipFrag 4 software. The software allowed for precise measurement of particle size distribution after the blast, as well as a detailed comparison between the two stemming sizes. Results from the analysis indicate that using bigger-sized stemming material led to improved blast confinement, which in turn resulted in better fragmentation compared to the smaller-sized material. The reviewed blast videos demonstrate that the larger aggregate effectively contained the explosive energy within the borehole, thereby reducing premature venting and directing more energy towards breaking the surrounding rock mass. This led to finer fragmentation with D80 = 1240.1 mm, D50 = 685.9, and Dmax = 2580 mm, which is advantageous in downstream operations like crushing and milling. On the other hand, the smaller stemming material (D80 = 21.94 mm) did not confine the explosive energy as efficiently, resulting in coarser fragmentation (D80 = 1327.37 mm, D50 = 750.76, and Dmax = 2370 mm) and reduced overall blast efficiency. These findings highlight the significant influence of stemming material size on blast performance and fragmentation outcomes. 

May 4, 2025