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By Hargraves A. J

At 4 MPa gas pres ure and 30°C the sorptive capacity of 10 selected Australian dried coal ranges from 17 to 23 m3/tonne of CH4 and 27 to 36 m3/tonne of CO2. Values for moist coals are about 25 per cent less. At 20°C, sorptive capacities are about 18 per cent greater. No clear relationship between coal rank and sorptive capacity was established.The permeability of coal to gas is dramatically reduced by progressive hydrostatic confinement. No single 'permeability' for a coal can be established because of relative affinities of coals and the gases (Ar, CH4 and CO2) used in experiments. Bedding plane permeability is significantly greater than permeability normal to bedding. Dependent on gas/coal combinations, permeabilities without confinement ranged from 150 to 0.05 millidarcies, and with 8 MPa hydrostatic confinement from 1.0 to 0.001 md. Generally, permeability is increased by reduction in temperature, and reduced by increase in moisture as one changes from Ar through CH4 to CO2. In retrospect, it is preferable to ubject permeability sample to 8 MPa hydrostatic stress only once, because changes occur in the samples and it is difficult to use other gases successively.The initial rate of desorption, DP, does not appear to be a reliable index of proneness to instantaneou outbursts for Australian coals.The methods used for determining quantitative gas-coal properties appear suitable and reliable for testing other coals.

Jan 1, 1985

By N. A. Warner

To filly secure the environmental and social acceptability benefits of making a sulphide smelting facility and its ancillary sulphuric acid plant or other means for fixing sulphur, a virtually zero gas emission operation, it will be necessary to utilise exclusively technically pure oxygen. The strategy proposed for preventing the smelter from overheating involves highly efficient energy transfer by promoting sulphur trioxide formation at a relatively higher temperature than normal. A closed-loop gas circuit uses an eductor system actuated by the process oxygen to recirculate sulphur trioxide and unconverted sulphur dioxide back to the smelter, the endothermic dissociation of sulphur trioxide becoming a major contributor to the removal of excess heat. The only gases leaving the system relate to the bleed of nitrogen impurity introduced in the tonnage oxygen.

Jan 1, 1998

By E. Watkins, S. J. Schatzel, K. Ajayi, V. Gangrade

The National Institute for Occupational Safety and Health (NIOSH) has been conducting research related to unconventional gas wells positioned in abutment pillars associated with active longwall mining in Southwestern PA. The Ventilation and Explosion Prevention Team at NIOSH is working toward predicting and characterizing a hypothetical casing breach and its effect on the safety and health of mine workers, gas well workers, and the general public. An important aspect of this research is to distinguish coalbed gas from shale gas in the mine environment as an indicator of a casing breach. Another noncoal gas source exists in the region in the form of underground gas storage fields which also have the potential to migrate towards mine workings. During a potential gas breach, the addition of excess natural gas to coal mine environments will exceed the anticipated ventilation loading and can create a mine explosion hazard. A methodology has been developed to distinguish these gas sources. Gas samples from the three sources were analyzed by gas chromatography, and interpretive methods were applied to distinguish the populations graphically and statistically. Bivariate plots using the hydrocarbon index and the normalized molecular ratios showed that the sources occupy different regions of the graphs. All samples of non-coal gas contained under 2% CO2, and all coal samples included greater than this amount. A multivariate T-squared (T2) test analysis relating comparing data in pairs showed a low p-value (dimensionality parameter) and a high T2 test statistic for all comparisons, indicating that these sources are different and distinct gas populations. Ultimately, stakeholders from the mining and gas production industries can utilize this method to identify gas sources and a potential casing breach.

Mar 2, 2022

By D. W. Gunkle

Processing of various ores and materials in a reducing atmosphere has been done for many years. However, the typical device currently used is a large, often high maintenance, expensive piece of equipment; the rotary kiln. While it is a very reliable and a proven technology, the rotary kiln also has its limitations. It is limited by its ability to process very fine materials without creating a huge dust loss to the air pollution control equipment. This leads us towards the development of an alternate technology; the Gas Suspension System. Gas suspension preheating of various materials has been in commercial use since the early 1950's, but recently has been expanded to include Gas Suspension Reduction. Laboratory experience has proven successful on several materials; Nickel Laterite Fines, Iron Ore Fines, Fluorspar, and Clays. The gas suspension reduction system has many advantages over the conventional reduction kiln when processing fines. They are; lower cost, more fuel efficient, able to process fines, less real estate required, etc.

Jan 1, 1998

By M. Van Hecke, Y. Berube, L. M. de Smecht

Nitrogen solubilities in water at 100, 200, and 400 psi, in the temperature range 100 to 175C, were determined using an automated system involving flash evaporation and gas chromatography. Rates of gas transfer into a standard laboratory auto-clave were measured by the same technique. The rates at which a gas can dissolve into such a reactor were found to be close to the rates of oxygen consumption observed during the oxidation of several mineral sulfides, indicating that gas transfer might be a rate-limiting step in autoclave leaching.

Jan 1, 1977

By B. L. Moreau

Certain gas wells tend to form hydrates in the production tubing. This paper outlines a method developed and used by the Author's company to overcome the problem. The injection of glycol to control hydrates results in sufficient dehydration to allow the gas to be trans-ported through a field-gathering system b a treatment plant. Sub-surface injection of glycol also offers a method of introducing corrosion inhibitors into the gas stream. The major operating difficulties have been overcome and the system is now in use in the northeastern part of British Columbia.

Jan 1, 1958

By AIME AIME

A discussion of the Papers by Prof. H. Hubert, Liege, Belgium ; Mr. Tom Westgarth, Middlesbrough, England ; and Mr. K. Reinhardt, Dortmund, Germany, presented at the London Meeting, July, 1906, and printed in Bi-Monthly Bulletin, No. 12, November, 1906; pp. 910 to 930, 971 to 987, 1037 to 1163. MR. ADOLPH GREINER, Seraing, Belgium :-I have nothing special to add to Professor Hubert's paper except to say that there are some little things that it would be well to have cor-rected when the paper comes to be published. In dealing with the thermal efficiency of the engine, you will find that the 29.84 per cent was a very high one. Professor Hubert has forgotten those engines built under the Cockerill type, but he has referred to them in Appendix II. At our works at Cockerill we have built 63 engines, giving 63,000 h.p., and the other companies who have received licenses have built 113 engines, making 103,000 h.p., and aggregating 176 engines and 166,000 h.p. Eight years ago I had the pleasure of giving to the Institute the results obtained up to that time. Since then a good many engines have been constructed. In 1898 I thought a blast-furnace producing 100 tons of pig iron would allow 3,000 h.p. Professor Witz and Professor Hubert show that with the same production of pig the new engines take 3,800 h.p. out of the gas. At present at Cockerill we make 700 to 800 tons of pig iron per day, and we hope to have 26,000 h.p; in a few years. At present we have only half of that in gas-engines, but we hope to have in five or six years all the gas out of these furnaces to the number of 25,000 or 26,000 h.p. MR. Tom WESTGARTH, Middlesbrough, England:-My contribution is not a paper in the ordinary sense of the word, because I am sure you will agree with me that what I have written is only supplementary to the other two papers. The notes are schedules of the larger-size gas-engines built by the engine-makers, of 500 h.p. and upwards. If you look at the schedules you will find that in England gas-engines have be-

Jan 1, 1907

By A. D. Pienaar

The aqueous chemistry of niobium and tantalum compounds with hydrofluoric acid is a mature field of investigation. In contrast, very little attention has been paid to reactions of these compounds in non-aqueous environments. Similarly, reactions of elemental fluorine with niobium and tantalum compounds have received little more than cursory attention in literature. This work discusses the isothermal reaction kinetics derived from thermogravimetry, using a less redundant approach than is currently the standard. We also discuss the most likely kinetic models for this reaction.

Jan 1, 2012

By A. D. Pienaar

The aqueous chemistry of niobium and tantalum compounds with hydrofluoric acid is a mature field of investigation. In contrast, very little attention has been paid to reactions of these compounds in non-aqueous environments. Similarly, reactions of elemental fluorine with niobium and tantalum compounds have received little more than cursory attention in literature. This work discusses the isothermal reaction kinetics derived from thermogravimetry, using a less redundant approach than is currently the standard. We also discuss the most likely kinetic models for this reaction.

Jan 1, 2012

By Samuel S. Wyer

THE installation of the gas-producer power-plant in America has been so unusual that all engineers have viewed it with in¬terest; a large majority, however, regard it with a lack of con-fidence and many with positive distrust. Despite the fact that European engineers have usually been less inclined to take the initiative along experimental lines than are Americans, they have, nevertheless, developed the gas-producer plant to a very high state of efficiency to which they were forced by the neces¬sity of economy in fuel-consumption. The gas-producer power-plant is so common in Europe that engineers as well as the general public regard it with the same degree of confidence that is now universally placed in steam¬plants. Gas-engines, both small and large, are in general use there, and central stations, aggregating several thousand horse¬power, are quite numerous. The fact that gas-producer power-plants have received so little attention in America may be attributed to five conditions:-1', ignorance and prejudice; 2, newness of work; 3, in-

Mar 1, 1905

By Tateo Usui

In the course of carbonization of coal under a rising temperature condition, volatile matter (V.M.) is released. The kind and amount of V.M. released depend on the kind of coal. Components of V.M. are tar, hydrocarbons (CH4, C2H4, C2H6, C3H8), CO, CO2 and H2, which are released in this order as a function of carbonization temperature. When the carbonization of coal under a rising temperature condition is interrupted at a certain temperature, TC, max, semi-coal-char with residual V.M. is obtained. If some optimum interruption-temperature is chosen, small but most suitable amount of V.M., namely H2, is retained. When the semi-coal-char thus obtained is heated again under the same rising temperature conditions but up to more than TC, max (1), the residual V.M. is released from just around TC, max (1). We propose novel iron ore agglomerate bearing such semi-coal-char with some strength. While simple iron ore agglomerate bearing coal char will start the reduction reaction as solid-solid reaction at somewhat higher temperature, the proposed one will start the reduction reaction as gas-solid reaction at somewhat lower temperature but a little higher than TC, max. Samples of semi-coal-char and novel iron ore agglomerate bearing such semi-coal-char have been prepared and evaluated.

Jan 1, 2006

By Ricardo Morales

Reactions between solids and a gas phase have many interesting theoretical aspects as well as technological applications. The present group had carried out experimental investigations as well as theoretical studies of a number of gas-solid reactions over the past decade and was able to derive interesting results. Studies of the decomposition of alkaline earth carbonates were carried out by thermogravimetric analyses. The experiments were carried out using thin powder beds as well as iso-statically pressed compacts with thermocouples embedded in the same. The investigations revealed the complexity of the reactions and the impact of the heat- and mass transfer aspects on the reaction kinetics. In the case of BaCO3, the kinetics of decomposition was complicated by the formation of a liquid phase. In the case of SrCO3, the reaction kinetics could be simulated by theoretical modeling. Gas-solid reactions were also employed as a versatile process tool towards the production of alloys and intermetallics involving transition elements by hydrogen reduction of complex oxides involving transition metals. Thin powder beds were employed to examine the micro-kinetics, while fluidized bed technique was utilized to produce bulk alloys. Preliminary correlations could be drawn between the thermodynamic stabilities of the oxides and the activation energies of chemical reduction steps. Adjusting the process parameters, products at nano-scale could be produced. The structural, mechanical and thermal properties were investigated in the case of these products. The potentialities of this method as a green route to produce industrially important alloys and intermetallics with unique properties are demonstrated.

Jan 1, 2006

By Clinton M. Young

(Pittsburg Meeting, March, 1910.) I. INTRODUCTION. THE experiments herein. described were carried on in 1908-9 . by the State Geological Survey of Kansas. Some months before taking up work on black powder the Survey had resumed work on an interrupted investigation of explosions in coal-mines, a subject which is engaging the attention. of numerous investigators. An unusual number of serious disasters has directed to. the subject a study which discloses the disquieting fact that, in the. United States, the ratio of lives lost per ton of coal mined has been on the increase. Methods of coal-mining have changed to some extent with the great increase of output, attained in, comparatively recent years. These changes involve the working of very extensive mines, with increased difficulty of ventilation, increased accumulation of coal-dust, and. a very great increase in the amount of explosive used.. . This last point assumes truly startling proportions when it is carefully observed. In the fields of the Middle. West it is not now uncommon for a miner to use six ,kegs (150 lb.) of black powder in a "pay" of two weeks, while within the memory. of men still active, one keg (25 .lb.) would last two men for a " pay." So. great has . the use of explosives become in some fields that the skilled coal-miner is hard to find, and the coal is not mined, but blasted. A preliminary study of the subject. of explosions in coal-mines has. led to the belief . that the use of, large -quantities of explosives, in some cases by slightly-trained men, had not been * Associate Professor- of Mining Engineering, University of Kansas, Lawrence, Ran.

Aug 1, 1910

By Y Zhang, X Yi, J Deng, J Zhao, J Song

To obtain the combustion process of a coal fire, a high-temperature programmed system is used to simulate the spontaneous combustion process of fresh and weathered coals. Both fresh coal and weathered coals from Liulingou, Inner Mongolia, China, were used to examine the gas releases from constant temperature to 650°C. Moreover, gas release rate was used to calculate the characteristic temperatures. The results showed the coal samples lasted to oxidise under high temperatures, and released plenty of heat to assist self-heating. The humic acid contained inside the weathered coal went through thermal decomposition as temperature rising and generated gases. This resulted in increasing concentrations of CO, CO2, CH4, C2H4, and C2H6. Changes of CH4, C2H4, and C2H6 gases were also similar. For weathered coal, concentrations of three gases were kept in balance under low temperatures, increased rapidly with the temperature rising. After the ignition temperature, the concentration of hydrocarbon was reduced. In addition, particle size affected coal spontaneous combustion. Coal samples with less than 0.9 mm in size produced much more CO than others. This study has examined coal spontaneous combustion caused by coal weathering during mining and its impacts on self-heating and pyrolysis in the process.CITATION:Deng, J, Song, J, Zhao, J, Zhang, Y, Yi, X and Zhang, Y, 2017. Gaseous products of weathered coal during the process of spontaneous combustion, in Proceedings Australian Mine Vent Conference 2017, pp 79–84 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017

By T. A. Larssen

The efficiency in production of manganese ferroalloys is dependent on the gaseous reduction of the higher manganese oxides in the ores used as raw materials. The materials, descending in the furnace, will meet the furnace gas that contains significant amounts of CO(g) and reduce in subsequent steps, the last step being reduction of Mn3O4 to MnO. This step may to varying extent occur at temperatures exceeding 800 °C, i.e. in the active region of the Boudouard reaction. The gas reduction of Assmang and Comilog manganese ores were investigated in CO-CO2-atmosphere at temperatures up to 1000 °C. It was seen that decreasing ore size correlates to a lower reduction temperature and increasing reduction rate. Similar effect was observed with increasing CO-content in the gas atmosphere. Further, it was found that Comilog ore obtained a complete prereduction at 600 °C, whereas reduction of Assmang ore was not complete at 800 °C for the majority of the experiments.

By O. W. Ellis

THE writer has dealt with the effect of various methods of melting copper upon the gas content of the metal.1 The copper referred to in his in his earlier paper was melted in the foundry both in the oil furnace and the electric furnace. As the metal, did not measure up to conductivity FIG. L -INGOT OF OVERPOLEP COPPER. standard, the term "casting copper" was applied to the material in the title of the paper. It was thought that some information in regard to the gases in a sample of overpoled copper might also be of interest, and through the courtesy of C. R. Stevens, superintendent of the copper mill of the Westinghouse Elec. & Mfg. Co., such a sample was obtained. The metal was chill-cast in the form of an ingot about 7 in. long, 2 ½ in. deep (from the base to the raised surface of the ingot) and from 1 3/8 to 1 7/8 in. wide. A photograph of part of the ingot is shown in Fig. 1. The effect of overpoling on the surface of the metal is here quite clearly shown.

Jan 1, 1929

By Paul D. Merica

DURING the Dark Ages, when metallurgy was practiced by the alchemists, any unusual or disturbing variation in metallurgical operations was ascribed to the, presence, in the metals or ores, of an evil spirit, and it was necessary to exorcise and drive it out "by suitable incantations. In this day of science and of engineering, things still incomprehensibly go wrong in the metallurgist's work shop. The metallurgist is even now not unwilling to lay the blame for many such experiences at the door of something which intellectually- much resembles an evil spirit, "gas in the metal." The presence of gases in his metal, he knows, occasions him many very definite troubles which he can clearly distinguish and diagnose-why may it not be also responsible for those which he cannot so well understand?

Jan 1, 1931

By AIME AIME

ON Thursday a most interesting symposium on "Gases in Metals" was held, with both morning and afternoon sessions. The morning was devoted principally to the considerations of the steel maker, the nonferrous field being taken up in the afternoon period. Dr. John Johnston, as chairman, introduced the subject with "A Short Analysis of the Gas-metal Problem and Its Practical Importance." He then introduced P. H. Brace who explained in considerable detail the various vacuum fusion and other methods in use at present, both here and abroad, in the study of "gases" in metals. He was fol¬lowed immediately by H. W. Graham on "The Effect of Oxygen in Steel." The papers elicited considerable discussion, the point being particularly noted by both Dr. Rawdon and Dr. Sauveur that a knowledge of "total oxygen" alone is not sufficient information for the metallurgist, distribution of oxygen being probably the more important. Dr. Johnston, in commenting on the lack of agreement among many of the methods now in use, such as the Ledebur and vacuum fusion, spoke of the contemplated plan of the Iron and Steel Division to have a number of standard samples analyzed by many laboratories by the various methods, the Bureau of Standards acting as a clearing house, so that more definite information may be obtained on the comparative accuracy of the method.

Jan 1, 1933

By D. Harrington

When the word "gas"' is mentioned in connection with mining almost invariably it is inferred that the explosive gas, methane, is in mind and that the reference is to coal mining. Although methane is likely to occur in any coal mine the metal mines of the world contain by far a greater variety of gases than do the coal mines. Often the gases in metal mines are as dangerous as the gases likely to be found in coal mines, and sometimes are even more deadly. A coal mine is more likely to contain methane than a metal mine. In rare instances it may contain high percentages of nitrogen or carbon dioxide or it may be deficient in oxygen where the air is confined in a blind end or in a sealed region. Much more rarely relatively small percentages of ethane or other hydrocarbons with an odor of ether, gasoline, or kerosene, or minute percentages of hydrogen sulphide are found in a coal mine. During a coal-mine fire or explosion carbon monoxide content is likely to be high (4 per cent or more), and if the coal contains much sulphur the high fumes may contain some sulphur dioxide.

Jan 1, 1931

By J. W. R. Rayner

THE conventional method of making water gas involves individual plants for the separate carbonization of coal to coke and the subsequent gasification of coke with steam. The process demands lump coke, preferably made from the best quality of coking coals. The ash in the coke should have a high melting point and the gasification process suffers a loss of efficiency when cokes with law ash-melting points are used. In Britain, these coals are generally the most expensive and they are readily available only in certain localities. The coals not suitable for making lump coke, or yielding only poor quality coke, are much more widely available and are generally cheaper. DEVELOPMENT OF ALTERNATIVE PROCESSES In Germany, processes have been developed and operated commercially for the production of water gas from very low-rank coals such as brown coal and lignites, but much less effort has been spent on processes to use coals of intermediate rank, which are widely available in Britain. The brown-coal processes use coal in the form of either dust or briquettes. The most successful of the dust-gasification methods is the Winkler process, which made a substantial contribution to German oil production during the war. It uses coal in the site range 0 to 8 mm and the fuel bed is blown with a mixture of oxygen and steam at a rate high enough to give it a characteristic boiling motion or, in present-day phraseology, at a rate more than sufficient to fluidize it (Fig. 1). Air cannot be used to provide the heat required for gasification, for various reasons. In the first place, to make the process continuous by mixing air and steam would involve the production of a lean gas-containing much nitrogen. If a separate blow were used, a large amount of potential heat would be lost because the blow gas in such a process would contain a very high percentage of carbon monoxide. Oxygen is necessary therefore and oxygen remains relatively expensive for use in gasification. In the Winkler generator, formation of clinker caused by local overheating does not occur, because of the mobility and high heat transfer of a fluidized bed. These properties of fluidized dusts have been used most successfully

Jan 1, 1953