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By E. E. McGinley, L. D. Woodworth

DURING the past several years has occurred what, in the light of future events, may aptly be called the rebirth of the acid Bessemer process. The increased attention given to the technical and metallurgical details involved in the production of Bessemer steels has been exceedingly fruitful, and indicates the value of further research and plant development. In times like these, when the steelmaking capacity of the country is operating at a maximum rate to supply materials for the national defense program, it behooves the Bessemer operator not only to strive to increase production but also to maintain a high standard of quality. The opportunity is ripe, it seems, to recapture fields of application once considered the birthright of Bessemer steels, but supplanted in recent years by open-hearth grades. This involves cooperation all along the line, from the blast-furnace operator to the metallurgical contact man and salesman. The metallurgist's part in this program involves the study of the many steelmaking variables and the measures necessary to ensure constancy in the finished product. It is equally important that the knowledge gained be disseminated widely to ensure the wise application of Bessemer steels in new fields. The merits of Bessemer steels for certain work are well understood. The combined properties of good weldability, machinability and stiffness are unique and fully explain the strong entrenchment of Bessemer steels in certain fields; e.g., skelp for small butt-weld conduit, screw steels machined in automatics, and certain tinplate applications. It is the purpose of this paper to review briefly the physical properties of Bessemer steels as contrasted with those of open-hearth steels, to discuss control measures now employed in the making of Bessemer steel, and to consider the advantages derived from the use of these control measures. PHYSICAL PROPERTIES OF BESSEMER VS. OPEN-HEARTH STEELS A number of Bessemer blows and open-hearth heats were tested for tensile strength, ductility and impact strength. The steels selected were confined to sections from ¾ to 1 ¼ -in. diameter, inclusive, and the carbon content covered was sufficient to yield parallel ranges in ultimate strength for the comparison. Other factors, such as the extent of deoxidation of the steel and variations in chemistry, were kept as comparable as possible. Machined test pieces of 0.505-in. diameter with an 8-in. gauge length were pulled. The data obtained are shown in Fig. 1, ultimate strength being plotted against carbon content. This graph shows that for equivalent carbon content Bessemer steel has on the average 15,000 lb. per sq. in. greater tensile strength and, conversely, for the same tensile strength Bessemer steel requires on the average 0.14 per cent less carbon. The average phosphorus content for the Bessemer steel was 0.090 per cent,

Jan 1, 1941

By L. E. Djingheuzian

IN 1953, Lewis (1) published an article which brought forth a great amount of discussion by grinding engineers. In his contribution to discussion the present writer (2) suggested that, for the most efficient performance of a ball mill, there must be a .definite relationship between Cn, per cent critical speed, and V p, per cent mill volume occupied by the ball charge. Later, he ( 3) was able to publish some grinding data from Wright-Hargreaves milly which appeared to bear out this contention. It is with this view to establishing a fundamental relationship between Cn and Vp that the idea of this Forum was conceived. Accordingly, a questionnaire was prepared and copies of it were mailed to over eighty Canadian mill operators. This questionnaire did not include a question on dilution on the assumption that each mill operator was using the most efficient dilution for his operation, nor was a question on efficiency of classification included since it was thought that the inclusion of efficiency of dassification in the questionnaire at this preliminary stage might render the forum discussion,. while everybody was trying to find his bearings, too unwieldy. However, it is evident that, as discussions develop, this forum will have to define a uniform method for establishing most efficient classification in grinding circuits

Jan 1, 1957

By D. C. McLean

Early studies in the carbonate leaching of uranium ores led to the investigation of pressure leaching as a method to enhance the dissolution of the metal values in this system. The initial investigations conducted at the University of British Columbia supplemented by the work done by the group at the A.E.C. Grand Junction pilot plant, all established the higher efficiency and better economics of the alkaline pressure leaching system. This work was conducted either in laboratory autoclaves using oxygen overpressures, or in pilot plant sized horizontal autoclaves with air as an oxidant. Both of these testing vehicles utilized agitation provided by relatively high speed impellers (300 to 700 rpm), which apparently enhanced the oxidation of the uranium to the hexavalent state. The installation of vertical autoclaves on a production scale, which through design considerations require relatively slow agitator speeds (68 rpm), led to the studies of the utilization efficiency of the air addition and the use of catalytic type oxidants to effect a greater usage of the oxygen added through the aeration system. In addition to investigating the effects of the chemical additives, studies were also conducted on the effect of different impeller configurations on the extraction of uranium, which in itself is a measure of oxidation efficiency. The material presented in this paper was compiled in the Ambrosia Lake district of New Mexico, and the majority of the data was obtained in the Homestake- Sapin Partners mill, located at Grants, New Mexico.

Jan 1, 1960

By B. P. Faulkner

In 1974, Allis-Chalmers, in corporation with several iron ore operating companies, began to evaluate direct firing of coal in the GRATE-KILN System. Several coals were ground at the Allis-Chalmers Process Research and Test Center and shipped to Cleveland Cliff's pilot plant near Negaunee, Michigan, where they were used as fuel to pelletize Empire magnetite concentrates in the CCI pilot-scale grate kiln. Pilot plant tests were sufficiently favorable to warrant testing in a commercial-scale pelletizing plant. These tests were conducted at the Empire Mine in the late summer and fall of 1974 and again in the summer and early fall of 1975. In the fall of 1975, Allis-Chalmers Mining Systems Division started a program, in the Advanced Technology Center, designed to develop a laboratory test procedure for the evaluation and study of various parameters associated with the direct firing of coals in a GRATE-KILN System. The initial results of this program were presented at the 50th Annual Meeting Minnesota Section, AIME, January, 1977. This paper will briefly review the initial laboratory work and discuss the latest results obtained.

Jan 1, 1977

By H. Kasaini

Batch wise adsorption tests for platinum (Pt) on the surface of activated carbon pellets (Norit RO 0.8 BET surface area 1100 mg/g) were carried out in mixed chloride solution. The purpose of this study was to assess and compare the adsorption performance of amine-treated activated carbons (AACs) and native activated carbons (NACs) in terms of adsorption capacity and selectivity. The effect of pH and temperature on adsorption capacity and selectivity was established. The amine- treated ACs were prepared by anchoring the amino groups (butyl amines) on the surface of AC pellets in aqueous media and the UV-Vis was used to determine the amount of amine sequestered from solution by ACs. The dosage of butyl amine on the surface of ACs averaged 0.15 g/g, carbon. The adsorption mechanism was described by the ionization and complexation model whereby interaction between the protonated AAC surface and the anionic chlorocomplex ions (PtCl5 [H2O]-, PtCl62-) proceeded by either electrostatic attraction or/and by covalent bonding [(NH3)2PtCl6 or (CH2COO)2PtCl6]. By comparison, the adsorption capacities of Pt on amine-treated ACs and native ACs were 53.8 mg/g and 33.03 mg/g, respectively which highlight the benefits of anchoring functional molecules on ACs. The selectivity of AACs was influenced by solution pH. Pt adsorbed selectively on the surface of amine-treated ACs at pH<1.5. The highest separation factor that was recoded pertained to Pt and Fe species (ßPt/Fe = 90) then followed by Pt and Ni species (ßPt/Ni = 30) or Pt and Cu species (ßPt/Cu = 15). The lowest separation factor was recorded for Pt and Cr ions (ßPt/N= 5). Adsorption kinetics of Pt on amine-treated AC surfaces, according to the first and second order reactions, were investigated and results showed that rates were in the order 10= 5). -4 min-1 and 102 g?min/mg, respectively. The pseudo 1st order kinetics predicted the adsorption capacity of 51.81 mg/g which was almost similar to the experimental value (53.8 mg/g) while the second order rate equation predicted Pt adsorption capacity of 40.1 mg/g. Both The Langmuir and Toth isotherm fitted the Pt adsorption at pH < 1.0. The Freundlich isotherm tended to underestimate the adsorption capacity of AACs.

Jan 1, 2014

"In a continuing investigation into the development of uranium alloys for armament applications, some complex base alloy corn positions were modified by varying the amount of alloying elements and by removing one or two of the alloying elements in turn from the base alloys. These uranium-base alloys were specially formulated in a search for heat-treatable, high-strength, ductile, high-density alloys. All alloys studied were ternary, quaternary or more complex alloys of uranium with molybdenum, zirconium, niobium and vanadium. Each cast alloy was studied under three different heat-treatments, and its mechanical and corrosion properties were determined. It was found that although most of the alloys studied had the hardness and strength required, they were extremely brittle and notch-sensitive under tensile stresses."

Jan 1, 1968

By L. E. Djingheuzian

Introduction Cylindrical grinding mills have been used for a long time, but during many years of testing no methods were established that gave consistent results. The work by both scientific investigators and operators led very often to contradictory conclusions, and each millman was very much &apos;on his own&apos; when trying to find the limits for working of his ball-mills. Fred C. Bond, in the introduction to his paper on Wear and Size Distribution of Grinding Balls, freely states that the mathematical immaturity of the grinding process "is the cause of many inefficient designs and installations as well as of much poorly oriented experimental work", and evidently he sees the solution of all our grinding problems in the discovery of the fundamental laws "which can change the empirical art into a mathematically exact science". While the writer is in complete agreement with Mr. Bond that grinding is governed by fundamental laws which can be expressed by mathematical formulae, there are so many variables in grinding, all interwoven with each other and mutually influencing each other, that the coalescing and merging of all these variables into a harmonious mathematical whole appears to be a homeric job. However, a light appeared on the horizon when it was proposed that power be used as an index of the grinding operation. It is pertinent to quote Gow, Guggenheim, Campbell, and Coghill from their paper on Ball Milling, in which they say: "Much of the past literature devoted to the subject has been concerned with the Kick-Rittinger dispute over evaluating grinding, or with dissertations on ball paths and the closely allied impact versus attrition hypotheses or with the exclusive consideration of certain specific variables, such as mill speed or circulating load, irrespectve of the other factors in operation. Such subjects may be dismissed with but little discussion in what may be called, by comparison a new philosophy in the stud of ball milling. Briefly this &apos;new philosophy&apos; consists &apos; of using power as an index of the mill operation, and investigating grinding from the standpoint of set and induced variables with emphasis on the latter". But it is safe to assume that it was the work by E.W. Davis, H. E. T. Haultain, F. C. Dyer, A: M. Gaudin, J. Gross, S. R. Zimmerley, and others, that cleared the path for the authors of Ball Milling and induced them and A. W. Fahrenwald to look farther afield and thus to establish a far-reaching relationship between the power and capacity and the diameter of the ball-mills.

Jan 1, 1949

By C. Pelley, A. Piche

"The Canadian mining industry faces the prospects of a severe shortage of graduate mining engineers over the next decade. This arises from three factors: first, a growth in industrial activity; second, the average age of company engineering and management staff; and third, the reduced number of students in engineering faculties around the world. This paper aims to identify the critical factors underlying the trend of inadequate recruitment into higher education for mining and to examine means of alleviating the problem.This paper is based upon surveys of potential and current students and graduate mining engineers from four mining schools. An attempt is made to understand institutional and industrial images, career prospects and what is required to attract enough high-calibre young people into mining education over the next decade.IntroductionThe mining industry has started to experience a severe shortage of graduate mining engineers which is likely to persist and even worsen in the short- to medium-term.This arise s from three principal factors:1. a recent and strong growth in mining activity, which surpasses that experienced through the 70s, before the recent international industrial recession; .2. an increasingly older average age of mine engineering employees, at least in the industry&apos;s larger companies; and3. problems associated with maintaining adequate mining undergraduate recruitment levels ."

Jan 1, 1989

By A-A. Bogno, M. Rappaz, J. Valloton, H. Henein

"Rapid solidification of Al-Cu droplets of eutectic composition was carried out using Impulse Atomization in an argon atmosphere, to study the microstructures forming at different cooling rates and undercoolings. Two distinct morphologies were observed within the investigated Al-33wt%Cu droplets microstructures: (i) A regular lamellar morphology and (ii) an undulated morphology. The volume fraction of each type of morphology was measured as a function of the droplet size and the nucleation undercooling was deduced using the hypercooling limit equation. The scale of the microstructures was determined through measurements of inter-lamellar spacing across and along the growth direction. Growth velocity and undercooling were deduced using Jackson and Hunt (1966) eutectic growth theory. Finally, mechanical properties were estimated through micro-hardness analysis using a Vickers hardness tester, revealing exceptional properties for an aluminum-copper alloy. Indeed, the hardness values, increasing with growth rate and undercooling, were 3 times higher than the values obtained in hypo-eutectic Al-Cu alloys.INTRODUCTION Eutectic alloys are very attractive due to their good fluidity allowing ready shaping of parts in casting processes as well as in thermal spray deposition. In addition, they yield microstructures with high mechanical properties, by the virtue of their scale/size which is defined by the solidification parameters and the thermodynamic and thermophysical properties of the given alloy. Therefore, it is important to understand the relationship between the microstructures and the solidification parameters of eutectic alloys in order to control their solidification path and mechanical properties. The latter could be improved by either adding an appropriate strengthening component to a base eutectic material (Böyük, MaraslI, Kaya, ÇadIrlI, & Keslioglu, 2009) or by refining the microstructures for more effective dislocation pinning (Campbell & Campbell, 2003). Tailoring the microstructure can also be beneficial to chemical (Freitas, Osório, Spinelli, & Garcia, 2014; Osório, Freire, Caram, & Garcia, 2012) or electrical (Kaya, 2012) properties of the material. Eutectic-type microstructures, usually formed from liquid (eutectic transformation) or solid (eutectoid transformation), are made up of two or more different phases, generally of lamellar or fibrous (rod like) morphologies (Kurz & Fisher, 1998). In general, a binary eutectic structure can be regular (when both phases are non-faceted) or irregular (one of the two phases is faceted), the two solid phases having roughly the composition of the liquid from which they are formed."

Jan 1, 2017

By Ashish Agarwal

For a correct evaluation of the performance of any process, it is important to reconcile the data gathered in the plant from the material balance point of view for all the streams flowing in and flowing out of the process unit. There are two main approaches to reconciliation of data, which involve minimization of the sum of the squares of: (i) the closure residuals and (ii) the component adjustments; both weighed with the estimated variances of the components. Though, these approaches have served us well, it has not been possible to ascertain if the reconciled values for various components and the split factors obtained using these approaches are truly the best estimates. In this paper, this aspect has been investigated by analyzing pseudo-experimental data of known error structure on size classification of particles in a hydrocyclone. Three types of basic error structures were considered for the measured component values: absolute error, relative error and chi-square error. The error structure was modified by adding a random component of error using normally distributed random numbers corresponding to zero mean and different levels of variance. By carrying out a large number of simulation experiments, it has been shown that in the presence of random errors, irrespective of the basic error structure of data, which is usually unknown, the chi-square error minimization criterion can be used to obtain most reliable results. Keywords: data reconciliation methods, chi-square error minimization

Sep 1, 2012

B. F. TILLSON,* Franklin, N. J.-A preliminary study of this paper did not, in my case, succeed in checking with the shovel dimensions of one of the large shovel manufacturers. I therefore raise a question as to there being some difference in standards used by different manufacturers in regard to the dimensions of the shovels for similar sizes and styles, so it may be rather confusing to some of us when we attempt to use the table in this paper and classify the capacity of the shovels as given here with some that are on the market.

Jan 4, 1919

By M. Boucraut

The authors investigate the influence of the basicity index CaO / Si02 on the sintering properties of hematite ore mixtures. The experimentation was performed with three different mixtures of ores from Tazadit, Nimba, Mano-River, Itabira, Marcona, Goa, Mapawa and Cassinga. Increasing the basicity index CaO / Si02 between 0.1 and 3, chiefly through limestone admixture makes possible to reduce the thermal consumption of sintering and to improve the physical and chemical properties of the sinter. In the case of a plant using hematite ores, it seems interesting to produce an hyperbasic sinter and to complete the blast furnace burden with calibrated ore or acid pellets.

Jan 1, 1968

Of the many organic impurities present in Bayer liquor, sodium oxalate is known to have one of the most detrimental effects on the Bayer process. Because of its limited solubility, it will co-precipitate with gibbsite during the precipitation stage which results in many operational challenges for the refinery. Despite the importance of this phenomenon, the interaction mechanism between gibbsite and sodium oxalate is not well understood. In this study, the growth of sodium oxalate on three main morphologies (random agglomerates, prims and hexagons) of water-washed and caustic-washed gibbsite was observed under synthetic Bayer conditions using in situ optical microscopy. After a short induction period, oxalate started to nucleate on gibbsite crystals, and grew with a needle-shaped morphology which eventually developed into oxalate bundles. In addition, the results indicated that caustic washing was able to partly decompose gibbsite crystals and thus make the gibbsite surface rougher, which provides more potential sites for oxalate nucleation and growth. The growth rate of oxalate crystals on the basal (001) face of water-washed gibbsite was 1.33 µm/min determined by the time-lapse imaging of in situ optical microscope.

Jan 1, 2014

By W. E. Kuhn

Introduction The work, of which some of the results are described in this paper, was started with the object of investigating the properties of certain binary alloys of titanium made from powders. Our main interest was in the possible use of such alloys in gas turbines. We were attracted to titanium, as have been others, by its high melting point (I,724° ± 11°C.), its low density (4.54), and the likelihood that, if a relatively wide use could be found for the metal, it might become available in commercial quantities at a fairly reasonable price. The readiness with which the metal reacts with hydrogen, oxygen, and nitrogen was recognized from the very beginning. At the same time there seemed a good chance that alloys could be produced which, because of the formation of protective films, would resist the attack of these and other corrosive agents. No specifications were drafted to cover the &apos;quality&apos; of the titanium hydride powder which was used in our work and which was, to judge by the results of a few preliminary experiments, the most useful source of titanium then (1944) available in sufficient amount for our purpose. During the course of our work, the need for such specifications became very clear (see Sections 9 to 12 of this pa per). Even today, lack of knowledge regarding the effects on titanium of impurities, some of which may later be looked upon as essential elements in commercial alloys of titanium, and difficulties in manufacture, make the preparation of specifications for commercial titanium and titanium compounds a doubtful procedure. The papers presented at the 1948 Symposium on Titanium, sponsored by the U.S. Office of Naval Research lend colour to this view. At the time our work was commenced, one had to depend upon the manufacturer to supply what he considered to be his &apos;best&apos; material. It may be some time before we can ask for more than this, the question as to what is his &apos;best&apos; being left to the manufacturer to decide. However, in this connection the results of our study may be of some value and on that account we are constrained to publish them.

Jan 1, 1950

By W. L. Price

The intelligent selection of wire cloth and perforated plate for screening surfaces seems a rather confusing subject to the newcomer in aggregate processing. The proper application of various screening surfaces is a complicated one and one could consider himself an expert only after many years of working with all applications. However, part of the subject matter could be simplified considerably for, the average screen user. In this paper an attempt will be made to do this, by presenting some comparative specification data along with cost figures Unfortunately, it is impossible in the limited scope of this paper to give actual service comparison records between different cloths or cloth and plate. Anyone who has considered making actual service comparisons for competing screening media is well aware of the almost insurmountable problems Their solution would form the basis for a separate paper on that subject alone. Therefore, this paper will be limited to comparative data up to the point of installation.

Jan 1, 1961

By Gordon A. Irons, Diancai Guo

"Uneven movement of scrap during melting in an Electric Arc Furnace causes operation problems: cave-ins interrupt electric power input. The movement also influences the radiation heat loss to water-cooled side panels and roof. An apparatus has been built to simulate the flow of scrap that may be interlocked. It has been observed that flow starts at the point where the suspended length of the pile bottom reaches the average scrap size, and proceeds in the form of cave-ins, but scrap pieces slide with each other as ordinary granules. After a cave-in, the pile angle usually remains much larger than the normally observed angle of repose. The force balance of a partially suspended scrap pile has been analyzed, and the equivalent cohesion due to interlocking estimated. A numerical model has been developed to simulate the scrap flow. Simulated results agree reasonably with observed phenomena.IntroductionWhen one considers the melting of steel scrap in an electric arc furnace (EAF), it is helpful to understand the movement of the material during meltdown. As industrial experience demonstrates, scrap movement greatly affects EAF operation. In a typical operation, scrap is dropped into the furnace from scrap buckets. The roof and electrodes are swung into position, and power is applied to the electrodes situated over the scrap. The electrodes ""bore"" into the scrap by melting into the steel in the immediate vicinity of the electrodes as they are lowered. If solid scrap pieces gradually slide towards the arc area, the electric power supply can be maintained at a high level, with few interruptions or drastic electrode adjustments. This results in a high production rate and low power consumption per tonne of steel produced. On the other hand, if the charge moves down unevenly, i.e. in large surges, usually called cave-ins, the electrodes must be drastically raised, and power supply frequently interrupted. This is also accompanied by a high level of harmonics induced in the power network, deteriorating the quality of electricity supplied to other users.In addition, the movement of scrap in an EAF also influences the furnace heat efficiency, as the scrap pile is much closer to the electric arcs compared to the furnace wall and roof, and absorbs more radiated heat. Early exposure of the wall and roof to the arcs will increase the heat loss due to radiation, and reduce the service life of the furnace."

Jan 1, 2004

By G Zahary

THE most acceptable approacl1 to analyzing rock behaviour, at the present time, is based on the application of principles of mechanics and strength of materials. Analyses have been made in which the criterion of failure is based on maximum stress (1) and on Mohr&apos;s rupture theory (2). If such analyses are to be carried out, the mechanical properties of the rock must be known within acceptable limits. Although an adequate correlation of laboratory test results with field conditions has not been established, test results have been published (3) on the basis of their comparative value. That is, test results may be useful for comparing the behaviour of different rocks under similar loading conditions or of a particular rock under different loading conditions. This study aims at establishing some of the mechanical properties of an andesite rock by testing specimens cut _from diamond drill core. Drill core (EX) was provided from run-of-mine drilling by New Dickenson Mines Ltd. and Campbell Red Lake Mines Ltd.

Jan 1, 1963

By M. Dosoudil

"Continuous pressure filtration is a modern process for the mechanical dewatering of flotation concentrates of coal and similar coal slurries. This method will give a lower moisture content than classical vacuum filtration, the improvement lying in the range 5% to 15%. Eighteen coal slurries have been examined in this survey. They are representative of a wide spectrum of filtered slurries. IntroductionDuring the last five years, a number of coal slurries have been tested either in the laboratory or with a pilot plant. The test pressure ranged from one to six bar. The results have been evaluated by mean s of a computer. Determination of the filter capacity and the resulting moisture content and energy consumption has been made with respect to the continuous pressure filter, Amafilter construction-type KDF (Fig. I) . Standard sizes of these filters are 60 m2, 90 m2 and 120 m2.The continuous pressure filter is a horizontal filter with a level tank. Six filter axles are mounted on a rotating main shaft, each with a particular number of elements attached. The elements rotate on their axes and move along a circular trajectory. Periodically the elements submerge into and emerge out of the slurry. A constant air pressure is maintained above the suspension, thus providing the pressure gradient necessary for filtration. The filtrate together with the dewatering air flows through the elements into the hollow axle and out of the filter."

Jan 1, 1987

By Frances Hurd, Clark

Iv 1897, Roberts-Austen(l)$ found an arrest in the thermal curves of alloys of 60 per cent. copper and 40 per cent. zinc. This break occurred from 450° to 470° C. Shepherd, (2) working in 1904, was unable to detect any change in the direction of the thermal curve. In 1911, Carpenter and Edwards(3) confirmed the work of Roberts-Austen and called this a eutectoid transformation of beta to alpha plus gamma. Hudson&apos;) in 1914, showed that the beta constituent could be produced synthetically at temperatures below the transformation point. He believed the change in the beta was polymorphic in nature rather than a eutectoid. The work of Matsuda(32) in 1922 demonstrated this break by thermal analysis, microscopic investigations, dilatation, electrical resistance measurements, and a thermoelectric study. He believed the transformation to be continuous from 300° to 480° C., and comparable to the A 2 transformation in iron. Later, in 1924, Andrew and Hay, with electrical resistance measurements, confirmed Matsuda&apos;s work. Imai(28) showed the transformation to be progressive and therefore a function of the temperature rather than the time. He stated that it was neither a eutectoid nor an allotropic change of phase. Atomistically expressed, it was a change, not of atomic configuration, but of atomic energy of some kind; and again it was compared to the A 2 transformation in iron. Imai believed that his analyses by X-rays led to the same conclusion. In order to study this change, at 470&apos;C., in homogeneous 60:40 brass, Homerberg and Williams «0> and Homerberg and Shaw(41) quenched their material in iced brine to obtain the beta solid solution and reheated at various temperatures. At 200° C., a change in the microstructure and physical properties occurred. A fine-grained structure, which they termed alpha and which had the appearance of a sorbitic steel, appeared, with an increase in the tensile strength to 82,750 lb. per sq. in., and a Brinell ball hardness of 240 with 3000 kg. load. At 470° C., the alpha

Jan 1, 1927

By D. An, J. Withers

A nano-scale investigation has been carried out by applying an AFM (atomic force microscope) to study in situ the adsorption of various collectors, i.e., oleic acid, octanohydroxamic acid (HA), and salicylhydroxamic acid (SHA), on bastnaesite in aqueous solutions. The obtained AFM images show that the surface morphology of bastnaesite changes greatly after it contacts the solutions of the collectors, suggesting that all these collectors can effectively adsorb on bastnaesite. Increasing temperature can help increase the adsorption of oleic acid on bastnaesite. FTIR (Fourier transform infrared) results also show that all these collectors adsorb strongly on bastnaesite with a strong absorbance spectra being detected, which confirms with the results obtained with AFM imaging analysis. In general, hydroxamic acid collector (HA and SHA) adsorbs on bastnaesite mainly in the form of insoluble metal hydroxamate. This specific adsorption mechanism explains that a high selectivity with a moderate collectivity will be achieved with a hydroxamic acid collector for the flotation of bastnaesite. INTRODUCTION Rare earth metals, which are very important to modern industry, are generally extracted from numerous rare earth minerals. In practice, however, the actual extraction of rare earth is mainly from bastnaesite, monazite and xenotime. The Mountain Pass mine is one of the largest rare earth mine in the world, at which the main rare earth mineral is bastnaesite. In the past years, froth flotation has been applied to the beneficiation of Mountain Pass ore. In practice, the rare earth ore is usually crushed, milled and further separated from calcite, barite and other gangue minerals by froth flotation, in which the rare earth oxide-bearing minerals stick to aerated bubbles in the pulp and float to the surface, leaving the gangue at the bottom of the flotation cell and disposed of as tailings.(Bulatovic, 2010) In spite of the fact that froth flotation has been applied to treat the bastnaesite ore at the Mountain Pass mine, the rare earth oxide (REO) recovery is still low,(Anderson, 2015) especially compared to the one obtained with sulfide flotation. For example, the typical recovery obtained at the Mountain Pass mine was only about 70%. This may be due to the low selectivity of the collector (oleic acid). In addition, to enhance the flotation selectivity, the pulp in the mine circuit has to be heated up to 70 to 90°C and it involves a lot of energy consumption. Last but not the least, a lot of depressants have to be added to improve the selectivity of flotation process. Therefore, it is critical to re-examine the existing flotation process at the Mountain Pass mine and seek any chance of improvement. (Anderson, 2015)

Jan 1, 2019