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By Robin J. Hickson

The Ortiz Mine is operated by Gold Fields Mining Corporation, a subsidiary of Consolidated Gold Fields Ltd., one of the world's major gold producers. The Ortiz Mine is Gold Fields only heap leaching facility as well as being their first operating mine in the U.S.A. The hydrometallurgical processes utilized for recovery of gold and silver at Ortiz are discussed along with the several practical changes in operation adopted since start-up. Included are heap leaching by cyanidation, concentration of values on activated carbon, desorption, and the final electrowinning steps prior to shipment. Construction costs and pertinent technical data are shown.

Jan 1, 1981

By Paul H. Johnson

Heap leaching is a simple means of recovering copper from oxide and oxide-sulfide ores. Although this method requires relatively low capital investment, it suffers from low copper recoveries and relatively high acid consumption. The objectives of this study were (1) to determine what factors influence these shortcomings, and (2) to establish a basis of correlation. between laboratory and field testing. The principal methods of leaching copper ores at the present time are heap, dump, in-place, and vat. A number of references are presented in the bibliography on the theoretical and practical aspects of these methods. In the heap-leaching method, crushed or uncrushed oxidized copper ore is placed on a prepared drainage pad. Acid leach solutions are dis¬tributed over the top of the heap, caused to percolate downward through the ore bed by gravity, and are drained from its base. The leach duration is generally a matter of a few months. Dump leaching is used to recover copper from very low-grade oxide-sulfide pit-waste materials. Here again, leach solutions are, percolated downward through a heap. However, in this method, little or no acid is added to the leach liquors, prepared drainage pads are not used and the leaching cycle is generally measured in terms of several years. Leaching agents are usually autogenously generated by the breakdown of sulfide minerals within the dump.

Jan 1, 1970

By Thomas J. DeMull

Heap leaching was introduced to the precious metals mining industry approximately two decades ago as a simple, low cost method for recovering gold and silver from ores. Since that time, operational experience has contributed to knowledge and understanding of the process, making it a reliable alternative to conventional milling processes for low grade ores. At time of this writing, dozens of heap leach operations are active producing hundreds of thousands of ounces of gold and millions of ounces of silver annually. These successes have caused the popular press to acclaim heap leaching "high-tech" gold mining, but, despite the hype, the process remains a simple one. An example of simplicity in heap leaching is the operation established in 1986 at Amax Gold's Sleeper Mine. Starting with a simple goal, namely to produce gold from sub-mill grade ore at low cost, heap leaching was rapidly implemented at Sleeper; only five months after testwork started, leaching commenced on the first commercial scale, 50,000 ton heap of low grade ore. Sized at 600,000 tons per year to produce 10,500 oz gold per year, the low grade heap operation has performed beyond expectations. During the first year of production, 881,800 tons have been leached producing 15,665 oz of gold and 35,528 oz of silver. Operating ·costs for the first year have averaged $112 per oz gold produced ( or $95 per oz if silver credit is included). Successful implementation of heap leaching at Sleeper has had a dramatic impact on ore reserves and future operations.

Jan 1, 1998

By A. D. Hammond

Until recently, the volumes delivered and unloaded from heap-leaching pads have been estimated by manual methods at Wharf Resources' South Dakota operation. In August 1989, the Engineering Department acquired the MINE-SURVEY software developed by GEM COM Services, Inc. of Vancouver, Canada, as part of a mine planning/grade control software package. The implementation of MINE-SURVEY for pad control resulted in a cost-effective tool to provide accurate and prompt estimates of ore delivered or unloaded from the pads. Volumes can be calculated in a matter of minutes as opposed to hours or days. Another benefit is the ease of comparison of as-build and designed volumes, plotting cross-section in any orientation, importing into AUTOCAD, validation of ore densities and truck factors. This paper describes the application of the MINE-SURVEY systems in heap leaching pad volumetrics.

Jan 1, 1991

By N. Ogbonna, D. G. Dixon

Although heap bioleaching has been recognized as an economic alternative for treating low grade mineral ores, the underlying physical, chemical and biological processes involved are complex. A detailed investigation into the dynamics of heap bioleaching processes has provided much insight into the underlying complexities, and has led to the development of a sophisticated modelling tool - HeapSim. This tool can be of great help in the design and operation of heap bioleaching processes. In this paper, the mathematical model implemented in HeapSim is examined. The model takes into account mineral kinetics, particle level effects, bacterial growth, oxidation and adsorption, gas absorption, pore diffusion, bulk advection, gas balance and heat conservation. Three case studies where the model has been applied are briefly discussed. Computational Analysis in Hydrometallurgy 35th Annual Hydrometallurgy Meeting held in conjunction with the 44th Annual Conference of Metallurgists of CIM Calgary, Alberta, Canada Edited by

Jan 1, 2005

By David C. Byrne

PURPOSE: Evaluate practical technological advances in hearing protective devices for use in different mining environments. RESEARCH SUMMARY: Previous NIOSH research shows that miners develop hearing loss much more quickly than nonoccupationally noise-exposed individuals and that miners experience a greater severity of hearing loss than would be expected for nonoccupational noise-exposed persons of the same age and sex. As described in the National Occupation-al Research Agenda, problems created by occupational hearing loss include(1) reduced quality of life due to social isolation and unrelenting tinnitus,(2) impaired communication with family members, the public, and coworkers, (3) diminished ability to monitor the work environment (i.e., warning signals, equipment sounds, etc.), (4) lost productivity and increased accidents resulting from impaired communication and isolation, and (5) expenses for workers’ compensation and hearing aids. Although eliminating hazardous noise is the long-term solution to the noise problem, miners will likely need to rely on personal hearing protection in certain situations for quite some time. However, it is well known that noise attenuation provided by hearing protectors as they are worn during everyday use is usually quite different (i.e., worse) than when tested under lab conditions. In addition, workers may refuse to wear their hearing protection for any number of reasons. This project was initiated to evaluate practical technological advances in hearing protectors, with an emphasis on optimizing the balance between effectiveness, comfort, over protection, and communication ability. The recently completed auditory research facility is now under-going the accreditation process conducted by the National Institute of Standards and Technology under the National Voluntary Laboratory Accreditation Program. Experiments are planned to investigate the factors that affect a miner’s ability to hear hazard and warning sounds (e.g., roof working, alarm signals, spoken communications, etc.). A service contract has been initiated to record and digitally store samples of typical warning sounds heard in an underground coal mine. This information will be analyzed in the lab to develop recommendations that can be offered to the mining community regarding correct earplug/earmuff usage to maximize there cognition of hazard and warning sounds while adequately protecting the miners’ hearing.

Jan 12, 2001

Reduce fire warning time and avoid activation of false alarms in underground mines. Approach A heat activated stench/tracer gas system was developed which automatically releases the gas mixture into the mine ventilation air. How It Works A canister approximately 12 inches long and 3 inches in diameter is charged with 50 grams of ethyl mercaptan or other appropriate stench gas and 500 grams of instrument detectable Freon. The canister is then pressurized to 100 psi with nitrogen. A disc is used to seal the contents of the canister. A low-temperature alloy designed to melt at a predetermined temperature is used to restrain a spring loaded plunger. Upon exposure to heat, the alloy melts and the plunger is released. The plunger ruptures the disc and the mixture of stench and tracer gas is released from the canister. Canisters are mounted in areas of a mine which are susceptible to fire such as near

Jan 1, 1983

By P. Somasundaran, D. W. Fuerstenau

Adsorption isotherms for dodecyl sulfonate on alumina were determined at 45°C and 25°C and the data was used for calculating the partial molar heat and entropy of adsorbed ions under various concentrations. Changes in OH and AS observed at certain concentrations agree with the postulate of interaction of surfactant ions to form two-dimensional aggregates at the solid-liquid interface. Values of the total OH and AS for the aggregation process calculated using the Clausius-Clapeyron equation is used to interpret the interactions of surfactant ions with each other as well as with the solvent molecules.

Jan 1, 1973

By A. De, J. S. Zuback, T. Mukherjee, T. DebRoy

For successful commercial applications of additive manufacturing, metallic parts need to be defect free, structurally sound and reliable. However, additively manufactured metallic parts are susceptible to distortion, lack of fusion defects and compositional changes. Methods to measure susceptibilities of various alloys to these defects are needed but not currently available. Here we show that the necessary theories can be developed based on a well-tested numerical heat transfer and fluid flow model and decades of research in the field of welding. The proposed theories are validated with experimental results reported in the literature.

Jan 1, 2016

By J. McKelliget, J. Szekely, Oreper. G. M.

"1. INTRODUCTIONThis paper is concerned with heat and fluid flow phenomena in arc welding operations. Fig. 1 shows a schematic sketch of a typical arc welding arrangement. It is seen that an arc is being struck between an inert electrode and a metal surface and that the resultant current and energy flow will case the formation of a molten weldpool.It is clearly appreciated that the weldpool shape and the nature of circulation in the weldpool may play an important part in determining the ultimate weld quality. It is known, furthermore,· that the weldpool behavior in turn will be affected by the spatial distribution of the current and the heat flux it receives from the arc. Indeed, the inherent coupling between the arc and the weldpool is a key feature of welding operations.Up to the present useful work has been done on the modelling of heat transfer and melt circulation in weldpools (1,2,3,4) and also on the description of arcs, including welding arcs (5,6,7,8). However, the coupling between these two sets of phenomena is relatively unexplored in a qualitative sense. The purpose of the present paper is to examine the interaction between welding arcs and weldpools. The actual material will be presented under the following headings:"

Jan 1, 1986

By Antti Roine

Sulfidic zinc concentrates are usually roasted in a fluidized bed furnace into sulfur-free oxide form. Metallic zinc is produced from this oxidic calcine using hydrometallurgical leaching, solution purification and electrowinning stages. The roasting step is necessary because zinc oxides are easier to dissolve using traditional leaching methods than zinc sulfides. The Kokkola Zinc smelter uses various types of zinc concentrates and secondary materials as feed mixture. This makes it difficult to find optimum process parameters for the roaster when the composition and particle size distribution of the feed mixture varies even on a daily basis. Certain conditions may even cause difficult accretion problems or increase the amount of calcine in the process off-gas line excessively. A thermochemical heat and material balance model was developed for process advisor, in order to estimate the effects of different process parameters (temperature, process air coefficient, concentrate feed, oxygen enrichment, water feed, etc.) on the heat balance, roasting temperature and calcine composition. This model was constructed using the heat balance module of HSC Chemistry 4.0 software. The prevailing chemical compounds in the concentrate and calcine were verified using mineralogical analyses and equilibrium calculations. The roasting process seems to operate near chemical equilibrium conditions, if the behavior of the main components is considered. This paper describes briefly the basic principles of the calculation model and outlines the results with several diagrams and discussion. The calculated results were in reasonable agreement with the recent process air oxygen enrichment and water feed test campaigns carried out at Kokkola in 1999.

Jan 1, 2000

Au airway hteat and moisture exchange .,Jgorithm is described which is generalised to suit most mining situations and can be run separately on a microcomputer or used within a network simulation. The main difference between this technique and other simplified methods is that a non-uniform boundary condition is allowed for. This permits radiative heat transfer between surfaces of different wetness in addition to evaporative and convective heat and mass transfer.

Jan 1, 1988

By I. Longson

As a longwall coalface advances a caved goaf or waste region is left behind. Air flow takes place through this permeable goaf due to the pressure differentials existing across it and en route this leakage air picks up both heat and moisture. A marked deterioration in climatic conditions occurs in the face area at all points downstream of where this leakage air rejoins the main air-stream. This goaf heat source can make a very significant contribution, typically 30-40% to the rate of total heat pickup on an advancing UK longwall coalface with a VST of 40°C and hence on the climatic conditions that prevail at the return end and in the return gate of the face. The magnitude of the rate of heat collection from the goaf depends on a number of factors but it has been established that it is particularly influenced by the prevailing virgin rock temperature and the total flow rate of the leakage air. This paper proposes a model for the goaf based on a packed bed analogy and other assumptions required in order to evaluate the rate of heat pickup are identified. The outlet condition of the leakage air predicted by the model have been shown to correlate with underground measurements taken for a range of different production patterns with the face cutter at various locations on the face. The sensitivity of these predictions to variations in the input data has been tested and is commented on. At this stage of the development the capabilities and predictive limitations of the model are discussed. Further areas of investigation are suggested in order to improve the predictive ability and to extend the versatility of the model.

Jan 1, 1989

By J. E. Lamar, J. S. Machin

INSULATING materials include a wide variety of nonmetallic mineral products such as exfoliated vermiculite, expanded gypsum, 85 pct magnesia, diatomite, asbestos, perlite, cellular glass, pumice, silica aerogel, expanded aggregates and mineral wool. Except mineral wool, most of these products, or the materials from which they are manufactured, are described in other chapters of this book. PROPERTIES OF INSULATING MATERIALS The insulating properties of the materials considered in this chapter result in general from entrapping extremely small pockets of air in such a manner that heat is not transferred by convection. The minimum heat conductivities of such insulating materials are slightly greater therefore than the conductivity of still air. In addition, conductivity varies with the overall density of the material, the temperature range in which the measurements are made, and the form into which the material is fabricated. However, the numerical value of heat conductivity should not be the sole criterion of an insulating material; for a particular application it may be advantageous to use a material of somewhat higher conductivity in order to secure other desirable engineering properties. This is especially true with certain materials that are used because of their refractoriness. Comparative insulating values of some commonly used insulating materials are shown in Table 1. In comparing the values presented in this table it should be borne in mind that heat conductivity varies with the mean temperature, with the overall density, and with the amount of moisture present. With fibrous or granular materials it varies with fiber or grain size and with the amount and kind of binder, if any is used. Under some circumstances it may vary with the arrangement of

Jan 1, 1949

By T. Kho, W. Zhang, M. E. Reed

The control of flash furnace heat balances is critical. Suspension smelting control and stability comes from stable operation of the heat balance, and this leads to a stable reaction shaft exit temperature. A number of flash furnace operations have been reviewed to determine if the application of this approach is beneficial for their operation. The cause and effect relationship between reaction shaft exit temperature with uptake and throat buildup is being enhanced with this work program. Our operating personnel are exposed to the operational hazards of cleaning this buildup from the throat and it is imperative that as an industry we continue to look for repeatable solutions. WorleyParsons has reviewed operational data from a number of flash furnaces and looked at the possible improvements that can be made to decrease variation in the reaction shaft exit temperature. The data assessed for each operation illustrate the need to fully understand the process inputs to the particular operation and to ensure that the control changes are correctly impacted. In the plant data that have been assessed for a number of operations combinations of feed changes and inappropriate process decisions have lead to changes in reaction shaft exit temperature which impact the overall furnace operation and the uptake shaft condition, and ultimately the boiler. INTRODUCTION In 2016 WorleyParsons jointly prepared a paper outlining the effects of heat balance control on the Olympic Dam flash furnace (Reed et al, 2016). That paper investigated the importance of heat balance control in flash furnaces and demonstrated the changes made at the Olympic Dam operation to control the heat balance in the furnace and the impact that change had. The operation is still using the tool to assist in trouble shooting performance and pinpointing problems that may lead to issues in the furnace throat and Waste Heat Boiler (WHB). As a result of the interest in the methodology and due to the issues surrounding safety and process performance caused by WHB throat buildup and damage, WorleyParsons approached a number of flash furnace operators to discuss the application of the approach at their operations.

Jan 1, 2019

By D. J. Burkhardt

Newer copper SX/EW facilities often incorporate hot water heating for the cell feed electrolyte to obtain the necessary plating temperatures of 40 to 50°C. Heating is most necessary in oxide heap leaching, however it may also be required in bioleaching of secondary sulphides in colder climates or higher altitudes where most of the heat gain in the heap is lost to the environment. Given that the solution flows in the leach, organic circuit and electrolyte circuit are circular in nature, and the fact that the hot lean electrolyte is often exchanged with cooler rich electrolyte, it can be difficult to access the heating requirement for the cell feed. There are energy losses in piping, tankage, raffinate, and energy gains through the PLS and electrowinning process itself; some of these are significant and others are not. This paper discusses the overall heat balance, the relative significance of the various energy gains and losses, and describes a methodology to develop a heat balance to assist the engineer in sizing the heating equipment.

Jan 1, 2003

By Anjali Talekar

Low temperature heat capacities of pentaerythritol [PE: C(CH2OH)4], pentaglycerine [PG: (CH3)C(CH2OH)3], and 2-amino-2-methyl-1,3-propanediol [AMPL: (NH2)(CH3)C(CH2OH)2]have been determined by adiabatic calorimetry from 3 K to 300 K. To the best of our knowledge, this is the first reported heat capacity measurement below 280 K for PE and AMPL. The Debye temperatures for these organic crystals have also been determined and compared with other alcohol derivatives of neopentane.

Jan 1, 2006

By M. Kawakami, K. Suzuki, T. Takenaka, S. Yokoyama

Molten NaNO3-NaNO2-KNO3mixture is used as a heat transfer medium at high temperature. One of the most important properties of this mixture is the heat capacity. In the present work, the enthalpy change with temperature was measured by the drop calorimetric method to evaluate the heat capacity. The results are summarized as follows: The enthalpy of the mixture increased linearly with the temperature. From the slope of the line, the heat capacity was evaluated. The heat capacity of pure NaNO3, NaNO2and KNO3was 0.129,0.110 and 0.142 kJ/mol/K, respectively. These values are in fairly good agreement with the published data. In the binary and ternary systems, the molar additivity of heat capacity, which is well known as Neumann-Kopp’s law, was obtained. The heat capacity of HTS1and HTS2, which are well known ternary mixtures of practical use, were in the range of published data.

Jan 1, 2004

By Harry Seltz

SEVERAL investigators have measured the heat capacity of cementite, using different methods of attack, but the agreement between the values obtained cannot be considered good. Naeser1 has made measurements of "average heat capacities" of iron carbide between 1026° and 85° K., using a water calorimeter. His computed true specific heat at 78.1° K. is 11.22 cal. per gram-formula mass, which, if correct, is much too high for any reasonably accurate extrapolation to 0° K. The cementite used by Naeser was obtained from a steel containing 0.9 per cent carbon, by electrolytically dissolving out the iron in a neutral bath of ferrous chloride. The cementite remained as a coarse, crystalline, gray powder. Andes" has measured the specific heat of iron carbide, from 102° to 323° K., as it exists in steel. The specific heats of several slugs of steel of known iron carbide content were determined, and the specific heat of the iron carbide (Fe3C) calculated by plotting specific heat versus percentage of carbon, and extrapolating to pure Fe3C (6.7 per cent C). The heat-capacity values for temperatures below 100° K. were obtained by comparing the temperature-specific heat curve for Fe3C to that of Fe. Since the two were very similar in the range examined experimentally and approach more closely at low temperatures, it was assumed that near the absolute zero the form of the curve for Fe3C would be similar to that of Fe. Andes calculates for the entropy of Fe3C, S298 = 23.55 e.u. The heat of formation of Fe3C has been studied by several workers. Kelley' has reviewed these measurements and calculations, and selects those of Roth4 and Naeser5 as worthy of most consideration. Roth has given ?H = 5400 cal. ± 30 per cent as a result of his own and other work. Naeser has determined the heat of formation from Fe and different forms of carbon, and for graphite (ß) he finds OH = 5600 cal. Kelley accepts the rounded figure ?H = 5500 as the heat of formation at 298.1° K., but this value is quite uncertain.

Jan 1, 1939

By Ignacy A. Lipiec

The advantage of microorganisms used in bioleach systems to conventional chemical reaction systems is that these apply the available energy more precisely where it is needed, either directly onto the mineral of interest or by efficiently catalyzing the production of a reactant. The literature cover the range from empirical models used in describing macro heat balance in heaps to detailed studies relating the micro heat effects of bacteria adhesion energy to the surface of minerals. In this paper, the heat effects are reviewed in a general way describing bioleaching in two macro systems, heap leaching and slurry bioreactors. The micro scale heat effects is the reactions and conditions at the microorganism scale, including the mechanism of leaching and bacterial behavior.

Jan 1, 1998