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By Li Qian

Mechanisms of bio-dephosphorization from iron ore was investigated in this Paper. The results show that there are two bio-dephosphorization ways from iron ore, the one is that Acidithiobacillus ferrooxidans directly derive phosphorus from the ore, the other is phosphorus is able to be leached acid produced during metabolizing of Acidithiobacillus ferrooxidans, and the latter is more important than the other. Adding suitable pyrite can enhance the bio- dephosphorization process through providing nourishment and producing acid directly due to S 3oxidized or indirectly due to Fe3 as oxidant. The potential varies in the range of 0.434~0.498V and pH is in the range of 2.5 ~ 1.25 during bio-leaching process. It can be founded that, according 2+to the E-pH graph of Fe-H2O system, Fe wouldn?t be oxidized under sterile system in this potential and pH ranges. It can be obviously concluded that the Acidithiobacillus ferrooxidans are 2+able to reduce the potential for the oxidization of Fe and make the oxidization occur in the above pH and potential zone, so the bio-leaching process can proceed. the investigation of E-pH graph of P-H2O system show that H3PO4 can exist steadily.

Jan 1, 2009

By Mario G. Karfakis

Mining related subsidence is a major concern over abandoned shallow coal mines. Many of the subsidence prone areas are presently used or will be used in the future for residential housing development. Concern over mine subsidence is inhibiting the development of surface land uses on previously mined area. This concern prompted public officials to realize the need to develop guidelines which can be used to assess and reduce the risk of mine subsidence damage to building and other improvements. Subsidence and the associated ground movements must be defined before one can relate them to building damage. Surface movements resulting from underground coal mining occurs in two phases termed as: active subsidence and residual subsidence. Active subsidence refers to all surface movements occur in^ simultaneously with the mining operations, while residual subsidence is-that part of the surface deformation which occurs following the cessation of mining. Residual subsidence is the major concern over abandoned mine lands. The duration of residual subsidence is of particular importance from the standpoint of damage at the surface to structures built after the mine has been abandoned. Time spans during which surface subsidence may occur, vary markedly with the mining method being used. In total extraction methods, such as longwalls, subsidence is induced rapidly, beginning almost immediately after mining. Subsidence concurrent with coal extraction is desirable for a safe longwall mining operation. Usually subsidence is complete within a relatively short time. The remaining settlement occurs as residual subsidence due to the gradual compaction of the subsided ground. The relative proportion of the residual subsidence movements is dependent upon the presence of remnant pillars and roadside packs. rate of face advance and depth of workings. In partial extraction methods, such as with room-and-pillar systems. major occurrences of surface subsidence may be delayed for decades until the support pillars and/or the roof have substantially deteriorated and collapsed. The actual time involved depends on a number of factors such as the strength of coal, roof, and floor, extent of fracturing. presence of water, depth of workings, pillar size and percentage extraction. Consequently residual subsidence is more likely to occur over abandoned room-and-pillar mines. The following sections define subsidence over abandoned mines, review the proposed mechanisms, identify the controlling factors and examine the prediction methods.

Jan 1, 1987

By M. K. Quinn, N. P. Reddy, A. W. Khair

"An analysis of coal fragmentation due to the action of a continuous miner is presented. Underground coal cutting by a drum-type continuous miner was simulated in the laboratory using a specially designed unique automated rotary coal cutting simulator (ARCCS). The rotary coal cutter provided the versatility of varying the operating and in-situ parameters to provide information on the effects of generating 37 pm (0.0015 in) particles. In these tests, coal blocks with an approximate dimension of 50.8 x 35.6x 20.32 cm (20x 15x 8 in) were first subjected to confining pressures equivalent to in-situ conditions. The blocks were then cut by the rotary cutting head of the ARCCS, thus simulating the action of the continuous miner in underground coal mining. During the tests under a particular set of in-situ and operating parameters a number of other parameters such as (1) penetration of bit into coal, (2) penetration resistance (thrust and cutting pressures), (3) rotating velocity of' cutting head, and (4) acoustic emission activity in the coal block were monitored. During the test, all the cut products were collected for size distribution analysis. After each cutting cycle the fractured surfaces were photographed and a velocity survey was conducted using a sonic technique. At the end of each experiment the cutting paths of the bits in coal were photographed using a camera attached to an optical microscope.The results led to a better understanding of the mechanisms of the fragmentation process during coal cutting and the effect of operating parameters, in-situ conditions and coal type on the size distribution of the cut product:"

Jan 1, 1989

By M. Ghoreychi, M. Fauueau, P. Lebitou, P. Berest

A brief study of the history of gas caverns in salt formations enables us to consider creep mechanism in a cavity as a phenomenon of dissymmetrical deformation. Among different parameters affecting such a phenomenon, gravity forces, especially in large caverns, seem to be responsible for important bottom heaves as compared to roof releases. This fact is demonstrated here by means of certain theoretical considerations concerning elasto-viscoplastic constitutive laws relevant to rocksalt rheological behavior.

Jan 1, 1986

By B. R. Palmer, G. Gutierrez B., M. C. Fuerstenau

Selective flotation in nonmetallic systems is often complicated by the presence of iron-bearing silicates occurring as gangue. Minerals such as augite, diopside, hornblende, and tourmaline respond readily to flotation under the same conditions as ore minerals. Mechanisms by which these minerals respond to flotation with anionic collectors must be established if selective separations are to be made in these systems. It was the objective of this investigation to determine the mechanisms involved in the flotation of two pyroxenes, augite and diopside, with potassium oleate. Experimental Materials and Methods Pure potassium oleate, prepared by neutralization of oleic acid with KOH, was used as collector, while reagent-grade HC1 or KOH were used for pH adjustment. Conductivity water, made by passing distilled water through a mixed-bed ion exchange column, was used in this investigation. Two pyroxenes, [ ], were involved in this work. One member of this class of minerals was augite and was found to contain 3.3% calcium, 4.6% iron, and 9.6% magnesium. The source of this mineral was Tillamook County, Ore. The other pyroxene involved was diopside which contained 8.3% calcium, 2.7% iron, and 7.6% magnesium. The source of this sample was Bancroft, Ont. Microflotation experiments were conducted with a Hallimond cell. Mineral samples were ground dry and sized to 100 x 200 mesh. One-gram charges were conditioned for 3 min in the presence of various additions of potassium oleate. Flotation was conducted for 1 min with a nitrogen flow rate of 50 cm3/min. The electrophoretic mobilities of these two minerals were measured with a Zeta Meter in the absence and presence of [ ] salts and in the presence of an indifferent electrolyte, NaC1, added to maintain ionic

Jan 1, 1978

By F. D. S. Marquis

An investigation of the mechanisms of formation of two types of porosity-primary and secondary-their characterization, evolution during processing, and effects on the mechanical behavior (fracture, fatigue, and failure) of 7X50 and 2X24 alloys has been conducted. The mechanisms of formation of three forms of primary or cast porosity were investigated, and each form was characterized: (a) macroscopic shrinkage porosity-MSP); (b) microscopic interdendritic porosity (MIP); and (c) hydrogen gas porosity (HGP) or primary hydrogen porosity (PHP). The mechanisms of formation of four forms of secondary or thermal/thermomechanical porosity were investigated, and each form of porosity was characterized: (a) high temperature oxidation (HTO). internal hydrogen precipitation (IHP), or secondary hydrogen precipitation (SHP); (b) preheating blistering porosity (PBP); (c) eutectic melting porosity (EMP);and, (d) dissolution micro void formation (DMF). The evolution and interactions of the primary and secondary types of porosity (w.ith special emphasis on PHP and SHP) during industrial and laboratory processing and their effects on the fracture and failure behavior of both types of alloys (with special focus on fatigue crack initiation and propagation) were investigated.

Jan 1, 1996

By Yaroshenko YuG, Bokovikov BA, Gordon YaM

Problems of the effect of the number of tuyeres and their parameters on the uni- formity of gas distribution are invest- igated with the use of the authors' devel- oped mathematical model of the movement of gases and materials in the blast furnace. It is shown that the improvement of uni- formity of gas distribution with an increase in the number of tuyeres has a damping character. An analysis of the errors of the specified assumptions of the hypothesis concerning the potentiality of the gas movement in the bed is carried out. It is established that the potential approach model gives good results with the determination of the discharge of gas and its stress field, but is not useful for the calculation of local velocities of gas in the raceway. The results of trials of calculation investigations of the dynamics of form- ation of the raceway and the voidageòfield in beds of burden materials are presented in the concluding part of the paper.

Jan 1, 1981

The effect of addition of a flotation collector (dodecylammonium chloride) on grinding of quartz has been studied. The data obtained are correlated with the results of tests conducted under similar chemical conditions to study influence of these additives on relevant basic sub-processes (primary breakage, pulp fluidity, and dispersion and flocculation of ground products). Such correlations suggest that the role of chemical additives in grinding is determined by their cumulative influence on the above mentioned basic properties of the system.

Jan 1, 1982

By N. S. Dalal, A. H. Hoffman, X. Shi, D. E. Banks, J. K. H. Ma, Y. Rojanasakul

Excessive production of reactive oxygen radicals by alveolar macrophages is proposed to play an important role in oxidative lung injury. A major product of oxygen radical formation is the highly reactive hydroxyl radical (•OH) generated via a biologic Fenton reaction. In addition to its known ability to induce lipid peroxidation, recent studies have suggested that the •OH may exert its cytotoxic effect through the alteration of [Ca2+], homeostasis. To test this potential mechanism as well as to investigate the relationship between •OH and Ca" overloading in cytotoxic injury, isolated rat alveolar macrophages were exposed to externally generated radical system, H2O2 (0.01 to 1 mM) and Fe (1 mM) and their [Ca2+] levels and cell injury were monitored using quantitative fluorescence microscopy with the aid of the specific Ca" indicator, Fura-2, and membrane integrity indicator, propidium iodide. Electron spin resonance measurements using the spin trap 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) confirmed the production of the .OH radical by this system. Upon the addition of the radicals, the macrophages displayed a rapid initial rise in [Ca2+] which was followed by a slower but more pronounced [Ca2+], elevation that reached a level 3 to 5 times higher than the basal level. This process preceded cell death as evident by nuclear propidium iodide fluorescence. Depletion of extracellular Ca" inhibited both the [Ca2+], response and cell injury. Preincubation of the cells with the Ca" channel blocker verapamil or .0H radical scavenger mannitol similarly inhibited the [Ca2+], rise and loss of viability. Firefly luciferase assay of cellular ATP content demonstrated that the alterations in [Ca2+], following .0H treatment preceded the depletion of ATP. Changes in membrane potential caused by Na* substitution with K* had no significant effect on either the unstimulated or stimulated [Ca"], levels. Taken together, these measurements indicate that .OH-induced injury in alveolar macrophages is associated with the alteration in [Ca2+], homeostasis. The mechanism of •OH-induced [Ca2+] loading is not due to nonspecific membrane damage or energy depletion, but mainly due to an increase in Ca2+ influx through Ca2+ selective channels. This Ca2+ over-load state as well as energy depletion caused by the oxidant may activate certain cellular degradative processes leading to cell injury and death.

Nov 1, 1995

By D. Malovichko

Seismic events and pillar failures observed in two platinum mines in the Rustenburg area, South Africa, were investigated. We studied the sources of approximately 300 largest seismic events recorded in 2009. Moment tensors of these events were estimated from amplitudes and polarities of P- and S-waves. The inverted mechanisms contain isotropic implosive components in many instances. Analyses of uncertainty of the moment tensor solutions confirmed the significance of the implosive component in general. Several documented cases of pillar failure were considered in detail. For each of these a seismic moment tensor was calculated from an elastic stress model assuming an instant removal of a failed pillar. The geometries and magnitudes of the theoretical seismic moment tensors are in agreement with the observed (i.e. inverted from seismic data). The results indicate that either pillar failure or fracturing in the proximity of the reef (within a fraction of the dominant wavelength of seismic waves) are responsible for a significant portion of the large events recorded in these mines.

Jan 1, 2012

By D. Malovichko

Seismic events and pillar failures observed in two platinum mines in the Rustenburg area, South Africa, were investigated. We studied the sources of approximately 300 largest seismic events recorded in 2009. Moment tensors of these events were estimated from amplitudes and polarities of P- and S-waves. The inverted mechanisms contain isotropic implosive components in many instances. Analyses of uncertainty of the moment tensor solutions confirmed the significance of the implosive component in general. Several documented cases of pillar failure were considered in detail. For each of these a seismic moment tensor was calculated from an elastic stress model assuming an instant removal of a failed pillar. The geometries and magnitudes of the theoretical seismic moment tensors are in agreement with the observed (i.e. inverted from seismic data). The results indicate that either pillar failure or fracturing in the proximity of the reef (within a fraction of the dominant wavelength of seismic waves) are responsible for a significant portion of the large events recorded in these mines.

Jan 1, 2012

By Paul Worsey, Braden Lusk, Seokbin Lim

This paper discusses the theory and experiment involved in the discovery of the mechanisms of Linear Shaped Charges, which are much different from those for Conical Shaped Charges. Linear Shaped Charges (LSC) have been assumed to function in the same manner as Conical Shaped Charges (CSC) in the published literature on the subject. Much work has been done on CSC for military purposes, but there is limited information about the mechanics of LSC. Previous theories have cited the formation of a Monroe Jet as the dominant process. The Monroe Effect describes what happens to a target below the charge following detonation of the charge, and prescribes a fluid jet process for penetration. The fluid jet comprised of the liner material is the cutting device in CSC and has been extensively studied. Recent work at the University of Missouri at Rolla (UMR) cutting concrete with LSC has surprisingly shown that there is not a fluid jet process in LSC. After completing several reinforced concrete penetration tests, minimally deformed copper blades were found in the debris. Initially, the blades were suspected to be misfires or malfunctioned charge remnants. However, results were good and blades were found after every single test. Upon closer inspection, the ribbons were found to be folded copper and they were suspected to be the bottom liner of the LSC. A test series was conducted to verify the new theory by experiment.

Jan 1, 2005

There are a number of different mechanisms by which wetlands can immobilise the metals in mine drainage. Here, the biogeochemistry behind four of these mechanisms (adsorption, biological uptake, precipitation as oxyhydroxides, and precipitation as sulfides) is discussed from the perspective of sustainability. Moreover, treatment wetlands are considered as part of a larger system, also taking into account the source of the drainage and various aspects of the receiving waters. The biogeochemistry of different metal immobilisation mechanisms in wetlands determines what kind of drainage can be treated with success, and it also places an upper limit on the amount of metal that can be removed from the water phase per unit of time. This has important implications for the design of treatment wetlands, perhaps particularly in colder climates. A thorough understanding of the prevailing biogeochemical processes is essential when attempting to establish treatment wetlands after the closing of a mine. If a wetland is to be used as a sustainable æwalk-awayÆ solution, the anticipated change in treatment efficiency over time (as pollutants accumulate in the system) must be considered in relation to the expected changes in drainage quality. It is also important that the total metal immobilisation capacity of the wetland is not exceeded and that the integrity of the system is maintained, in order to minimise liberation of previously immobilised metals.

Jan 1, 2003

By J J. McNee and, J Crusius, T F. Pedersen

The use of water covers is a globally-applied method for minimising acid rock drainage (ARD) and metal leaching. Although the subaqueous disposal of potentially acid-generating materials has been shown to effectively limit ARD, under certain scenarios, metal remobilisation can occur at circum-neutral pH. The following paper presents data from four case studies in which metal mobility from submerged mine waste resulted in degradation to water quality in the overlying water cover. Subcentimetre resolution profiling of dissolved constituents across the tailings-water interface (dialysis arrays), in conjunction with mineralogical information, were used to elucidate the controls governing metal mobility. The data illustrate four pathways of metal remobilisation, including: the release of zinc via the oxidative remineralisation of metal-rich organics at the tailings-water interface; enhanced remobilisation of arsenic as a result of anthropogenic eutrophication; the release of copper resulting from the pH-driven dissolution of treatment sludges; and the release of radium from uranium mill tailings due to the dissolution of radiobarite [(Ra,Ba)SO4] by sulfate-reducing bacteria. The results highlight the conclusion that the chemical stability of submerged tailings reflects both: the solid-phase characteristics of the tailings material; and the physical, chemical and biological characteristics of the depositional environment. In particular, the data illustrate that rigorous characterisation of both the waste solids and receiving environment must be performed in order to assess their compatibility. The results have relevance to the management of tailings repositories including constructed impoundments, pit lakes and natural lakes.

Jan 1, 2003

By Nils Eivind Kamfjord, Mari K. Næss, Halvard Tveit, Edin H. Myrhaug

"As a part of the FUME research programme being done by the Norwegian Ferroalloy Research Association (FFF), the SINTEF Group and NTNU, several measurements towards quantifying the gaseous and solid emissions from the draining of the silicon furnaces for metal have been carried out.Based on the measured size distribution of the formed fume particles and known particle growth theory, an estimate of the growth time for the given particles has been calculated. The formation time for the measured NO amount has also been calculated based on the fume measurements and a thermodynamic model of the furnace gases combusting with air. The two “formation” times are in the same order of magnitude and they are therefore used as parameters in a CFD model, modelling that the formed fume particles are heating up the surrounding air and thereby forming NO according to the Zeldovich mechanism. The measurements show an approximately equal constant NO formation per fume particle. The CFD model shows results in the same order of magnitude, supporting that the particle growth and NO formation happen under near stoichiometric conditions and are controlled by the formation of SiO2 fume.IntroductionNOx is the common notion for the two gases nitric oxide (NO) and nitrogen dioxide (NO2) formed during combustion of fuels. The main sources for human made NOx emissions is on-/offshore transportation industry, power generations based on fossil fuels, agriculture and other industries [1]."

Jan 1, 2012

By S. Mathur

Oxide particles are commonly used as fillers in plastics, paper, rubber, etc. (particulate composites). The successful fabrication of such composites is dependent upon the adhesive strength of the filler particles to the matrix. The compatibility of the matrix and the filler particles is generally enhanced by the adsorption of surface modifiers such as surfactants and polymers at the particle-matrix interface. To develop a scientific basis for the selection of the appropriate modifiers it is necessary to understand their adsorption mechanisms. specifically, the adsorption of polymeric additives is attributed to a combination of chemical and electrostatic interactions, hydrogen bonding and van der Waals forces. Hydrogen bonding has been suggested to be the primary adsorption mechanism for nonionic polymers. However, a literature survey of the Poly(ethylene oxide) (PEO)-oxide system suggested that PEO, a nonionic polymer, was substrate specific. A systematic study was undertaken to investigate the adsorption mechanisms of PEO on oxide particles. It was determined that strong Bronsted acid sites on the surface interact with the ether oxygen, a Lewis base, of PEO to induce adsorption. In this work, characterization of PEO binding sites on oxides is reported and the mechanisms of PEO adsorption are discussed.

Jan 1, 1999

By Sadegh Firoozi

Experiments measuring the kinetics of oxidation and making visual observations of the oxidation of approximately 6 g static lead baths containing arsenic, antimony and tin were conducted in the temperature range from 500 to 600 oC. A range of repeatable behaviours were observed, notably: the formation of a coherent, solid oxide layers on pure lead and lead-tin alloys; the formation of liquid oxide droplets during the initial oxidation of lead-arsenic and lead-antimony alloys and the eventual formation of a complete oxide layer covering the entire free surface of these alloys. Thermogravimetric measurements revealed that the rate of oxygen uptake was strongly influenced by the form of oxides being generated at the melt/gas interface. Compared to the rates of oxidation of pure lead, arsenic increased the rate of oxygen uptake throughout the temperature range via the formation of liquid oxidation products. The presence of antimony resulted in a moderate increase in the rate of oxygen uptake as compared to arsenic. Tin was effective in lowering the rate of oxidation even in the presence of arsenic because the oxidation product was always a coherent layer that acted as a physical barrier to oxygen transport to the underlying alloy.

Jan 1, 2006

By A. W. Khair

This paper presents an analysis of respirabie dust generation due to the action of a continuous miner. Underground coal cutting by a drum-type continuous miner was simulated in the laboratory using a specially designed unique automated rotary coal cutting simulator (ARCCS). An analysis of -400 mesh particles was done on gravity collected material. Samples of entrained dust were collected through the use of cascade impactors. Both samples were analyzed for size distribution and particle shape. Using the simulated coal cutter permitted variation of operating and in-situ parameters to provide information on the effects on generation of -400 mesh particles. In these tests coal blocks with an approximate dimension of 18 in. x 15 in. x 6 in. (45.7 cm x 38.1 cm x 15.2 cm) were first subjected to confining pressures, equivalent to in-situ conditions. Such blocks were then cut by the cutting head of the ARCCS, thus simulating the action of the continuous miner in underground coal mining. During the tests under a particular set of in-situ and operating parameters a number of other parameters such as 1) penetration of bit into coal, 2) penetration resistance (thrust and cutting pressures), 3) rotating velocity of cutting head, and 4) acoustic emission activity in the coal block were monitored. After each cutting cycle the fractured surfaces were photographed and a velocity survey was conducted by using a sonic technique. At the end of each experiment the cutting paths of the bits in coal were photographed using an optical microscope with an attached camera.

Jan 1, 1985

By Shuangsuo Yang

Coal ribs can roughly be divided into three types: (1) roof and floor rocks are similar to ribs, (2) roof and floor rocks are stronger than ribs, and (3) roof and floor rocks are weaker than ribs. Different types of roof/floor and ribs will exhibit different types of ground pressure around an entry. Most coal mines belong to the 2" type with ribs fractured or even broken. In this case the mine ground pressure depends on the occurrence and development of deformation and fracture of the ribs. If it's not properly controlled, the following deteriorating process will follow: the roof bent downward > the ribs squeezed and broken > rib sloughing and collapse > rib support to the roof reduced > the roof bent downward further > the ribs broken further. In this paper rib instability is divided into four types: compression/shear sliding rib fall, gravity sliding rib fall, cross arch rib fall, and cleavage rib fall. Since failure in thin walls is largely of tension type whereas that of thick walls by compression or shear, a concept is proposed here to utilize a thick bolted rib to stabilize entry ribs, i.e. the thickness to height ratio of the thick bolted ribs

Jan 1, 2005

By M. P. Fahey

A significant amount of silca is recovered in the rougher stage of anionic flotation of Florida apatite. This recovery, in the past, has been attributed to both entrainment and cation activated flotation. This study shows that by using a transport factor, it is possible to determine the contribution of each mechanism towards silica recovery. Further, it is shown that the concentration of cations in the conditioning water significantly affects both the amount of silica recovered due to entrainment and true flotation. Further confirmation of this phenomenon was obtained by Ca++ doping of the conditioning water and by using a sodium silicate depressant.

Jan 1, 1996