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By GRANT COLLIGAN, BROCK O’KELLEY, Corby Anderson

With the world’s ever-growing push to expand technological capabilities, the need for specialized materials including rare earth elements has exploded. One source of rare earths found in the United States is bastnaesite, a rare-earth-bearing fluorocarbonate, mined at the Mountain Pass Mine in California. To increase production, it has been essential to optimize existing processes and create new ones to capture current reserves. This paper presents the results of a research program conducted to expand the understanding of the bastnaesite leaching system. With the help of prior knowledge and thermodynamic calculations, a novel single-stage hydrochloric acid leach system was created to optimize the extraction of rare earths from bastnaesite. Historically, this extraction has entailed the use of a two-stage leach system involving a high-temperature hydrochloric acid leach followed by a caustic crack. We ran a series of single-stage leach experiments by reacting locked-cycle flotation concentrate with hydrochloric acid to test common leaching parameters. The results of these single-stage tests showed significantly higher rare-earth recoveries than the reported recoveries of the historic two-stage caustic crack processes, all while decreasing the number and amount of reagents needed.

Feb 1, 2023

By GRANT COLLIGAN, BROCK O’KELLEY, Corby Anderson

With the world’s ever-expanding push to expand technological capabilities, the need for specialized materials including rare earth elements has exploded. One source found in the USA is bastnaesite, a rare earth bearing fluorocarbonate mineral, currently mined at the Mountain Pass Mine in California. To increase production, it is essential to optimize existing processes and create new ones to better utilize current resources. Therefore, a US Department of Energy Critical Materials Institute sponsored research program was carried out at the Kroll Institute for Extractive Metallurgy to expand the fundamental understanding of the industrial bastnaesite concentrate leaching system. With the help of prior knowledge, thermodynamic calculations and design of experimentation based lab testing, a novel single-stage hydrochloric leach system was created to optimize the rare earth extraction from bastnaesite. Historically, the existing industrial process has utilized a two-stage leach system involving a high-temperature hydrochloric acid leach with liquid solid separations followed by a caustic crack stage of the leach residues. A series of single-stage leach experiments were run by reacting locked cycle flotation concentrates with hydrochloric acid to test common leaching parameters. The results of these patent pending single-stage tests have shown rare earth recoveries significantly higher than reported recoveries of historic two-stage caustic crack processes, all while decreasing the equipment required and the type and amount of reagents needed.

Jan 31, 2022

By Abid Adekunte

Traditionally, designers and contractors provide additional external supports to retaining walls through the use of tie-back anchors or braces. Both approaches are known to have their shortcomings; braces limit working space within excavation areas, while tie-backs are seldom used in built-up areas where intrusion into adjacent property of non-cooperative owners has to be avoided or in situations where sensitive structures exist behind the wall. This paper focuses on the design, construction and monitoring of deep excavation support systems on two separate projects located in different ground conditions in the Republic of Ireland. On both projects, conventional ground anchorage and propping were inapplicable. This led to the development and application of two different novel solutions on both projects. Methods of wall performance monitoring on both sites also differ. Wall monitoring results show these innovative methods to be safe and effective. Advantages of the novel solutions over traditional approaches are highlighted.

Jan 1, 2010

By Sridhar Komarneni

"Microwave-hydrothermal processing is a novel technique which combines the conventional hydrothermal processing with microwave field and we previously showed for the first time, that ceramic powders can be rapidly produced by this technique. This review paper deals with the synthesis of unary oxides such as Fe203, Ti02, Zr02, etc., binary oxides such as BaTiO3, SrTiO 3, PbTiO 3, SrZrO 3, KNbO3, etc., and ternary oxides such as NaTi2 (PO4)3 and pyrochlore phases of Pb(Mg1/3Nb2/3)O3, Pb(Zn1/3Nb2/3)O3 etc. and metal powders such as Cu, Ni, etc. below 195°C. This method can be adopted to the synthesis of a large variety of powders by the appropriate control of pH, Eh, temperature/pressure and concentration of chemical species. The main advantages of this method compared to conventional hydrothermal processing are (a) it increases the kinetics of reaction by one to two orders of magnitude, and (b) it can lead to novel phases especially those with layered structures.IntroductionConventional hydrothermal processing is a well-established synthesis technique which has been extensively used in the preparation of fine ceramic powders [1-5], large single crystals [6-8] and massive cement blocks [9]. Technologically important ceramic powders such as BaTiO 3, Al203 etc. made by the hydrothermal process are now commercially available. Although there are numerous methods for materials synthesis, hydrothermal method is truly a low temperature and environmentally benign process. For example, ZrSi04 (Zircon) which is extensively used in ceramic industry can be prepared hydrothermally at 150·C [10] compared to sol-gel or solid-state method [11,12] which require a temperature of about 1000·C. The hydrothermal method is environmentally benign because hydrothermal reactions are carried out in closed systems at low temperatures and the contents can be recovered and recycled after cooling to the ambient conditions. One of the disadvantages with any low temperature processing method is slow kinetics. For this reason we have combined the hydrothermal method with microwaves to enhance kinetics and we named this method as ""Microwave-hydrothermal"" processing [13- 16]. Although the combination of microwave and hydrothermal techniques has been used in the past few years to dissolve all kinds of inorganic (e.g. alumino silicate rocks) and organic materials rapidly for chemical analysis, we were the first to show its potential value for the synthesis of various ceramic powders [13-16]. In this paper, I show that this novel method is applicable to the synthesis of all unary, binary and multinary oxides by the appropriate control of pH, Eh, temperature, pressure and concentration of chemical species. In addition, this method is also found to be useful for the preparation of metal powders."

Jan 1, 1994

By Piet Halliday, Ellina Kharatyan

Conventionally, emulsion matrices (unsensitized) need to be sensitized to become detonable explosives. This is done either chemically or mechanically. Both methods have their advantages and disadvantages. Mechanical sensitization involves the addition of microballoons (plastic or glass) to the emulsion matrix, in order to create hot spots during detonation. This is usually done at the manufacturing site and poses a safety risk in terms of the storage, transportation and handling of a 1.1 type explosive. Many countries throughout the world make use of chemical sensitization as opposed to mechanical sensitization as this allows for the storage, handling and transportation of two 5.1 type products rather than the 1.1 type explosive. Chemical sensitization involves the addition of a small amount of a chemical that reacts with a component of the emulsion matrix causing the formation of gas bubbles that act as hot spots during detonation. The disadvantage of this is the lack of accurate density control (due to various factors affecting the reaction) and the lack of comprehensive understanding of the operators of the reaction. This can easily result in poor blast performance. Due to these disadvantages a pumpable, non-detonable (5.1 type) mechanical sensitizer was researched and developed. This product allows for pumping at a 50:50 volume ratio with the emulsion matrix, when loading into blast holes. The significance of this is that a 1.1 type explosive is formed in the blast hole. As such, the security and logistical issues of the transportation and storage of the 1.1 type explosive are eliminated. Another advantage is accurate density control of the final product, specifically in small diameter long hole applications. A cost effective, unique mini pumping system has been developed for the loading of this product. Moreover, this system can easily be used for secondary blasting applications and the on-site packaging of cartridged explosive products.

Jan 1, 2015

Thermo Fisher Scientific is the worldÆs leading supplier of analysers for laboratories and process industries. The companyÆs X-ray fluorescence (XRF)-based slurry immersion probes were originally developed by the acquired Amdel Instrumentation. These analysers have found limited application within wet beneficiation plants for measurement of iron. The recent trend of renewed efforts to maximise recovery from existing resources and lower costs has increased industry interest in online analysis. In the mid-1990s the company developed online analysers (the light element slurry analyser û LESA) for slurry applications using the prompt gamma neutron activation analysis (PGNAA) method. The company has successfully installed LESA for the direct measurement of lighter impurity elements in Brazilian plants using flotation for rejection of silica. A case study is presented. The PGNAA technique has the unique ability to provide elemental analysis of bulk materials on a conveyor belt. The company released its eighth generation cross belt Omni analyser using PGNAA in 2007. Results from a recent project with sinter are presented. The Niton range of hand-held XRF analysers is also supplied by Thermo Fisher Scientific. These handy devices are finding widespread use in the mining industry to provide quick and easy analyses in exploration settings. In contrast to PGNAA this is a surface technique. A prototype for light element analysis is being tested for iron ore.

Jan 1, 2007

By H. P. Schlanger, L. Paterson, B. H. G. Brady, B. E. Hobbs

A novel principle for a waste repository, based on a backfilled thermosyphon as the functional unit, is proposed. Such a unit reduces temperatures and temperature gradients in the vicinity of a waste package and in the repository near field, reducing leach rates from packages and thermomechanical disturbance of the rock mass. Preliminary analyses confirm the mode of performance of the system, and reveal some interesting features of material transport and sealing in backfill and rock fissures. The thermosyphon combines attractively with the prospect of developing a near-field geochemical trap with chemical specificity for radionuclides. It is proposed that a thermosyphon repository may provide superior performance of engineered and natural barriers compared with conventional designs. The achievement of the ability to predict accurately the performance of the thermosyphon, relative to other isolation schemes, will represent a benchmark in the understanding of the absolute performance of any repository.

Jan 1, 1986

By C. Keefe, O&apos

Measurements of the quantity of entrained air within processes have challenged instrumentation developers for years. This is particularly true in the unique and demanding operating environment and applications seen in minerals processing. In minerals processing applications, entrained air plays a role in errors seen within nuclear density gauge measurements and in pumping efficiency. It is also the major component of flotation processes. The measurement of the quantity of entrained air, known as the gas void fraction, can now be performed from the outside of a process pipe through CiDRA?s patented passive sonar array-based technology. Within column cells, the need for a robust, no maintenance, accurate means of measuring the entrained air, known as gas holdup, has resulted in a submersible version of this technology. CiDRA?s meter technology calculates the gas void fraction by first measuring the speed at which naturally occurring sound in the process slurry propagates past an axial array of sensors. These sensors are incorporated in a band that is wrapped around the outside of the pipe, resulting in no process downtimes for installation and unprecedented reliability. A known relationship between this speed of sound and the entrained air captured in the form of bubbles within the slurry is then applied in CiDRA?s meter to calculate the gas void fraction. This paper will present the measurement technology, its operation, its calibration and its application in a variety of gas void fraction and gas holdup measurement situations such as pumping efficiencies, hydrocyclone operation, external sparging, and column cells.

Jan 1, 2008

By C. G. Anderson

The treatment of concentrates for the recovery of the precious metals imposes many processing and environmental challenges. Hydrometallurgical technology for recovery of values from refractory precious metal materials has been developed at Sunshine Mining and Refining Company. Historically, conventional pyrometallurgical methods have been used for to recover values from refractory precious metal materials. However, enhanced environmental awareness has worked to constrain typical refractory material processing methods. This hinders and limits the ability of established smelting or roasting technologies to fill the needs of new sources of refractory materials. An alternative is to treat refractory precious metal bearing materials by hydro metallurgical techniques. These methods are considered more environmentally appropriate since they do not produce gaseous pollutants like sulfur dioxide. Industrially, Sunshine Mining and Refining Company employs hydrometallurgical technology to process refractory precious metal materials. The Sunshine antimony leach uses a mixture of sulfur and caustic under ambient pressure and boiling conditions. The Sunshine oxidation leach uses a mixture of sulfuric acid and a minimal amount of sodium nitrite under relatively mild oxygen pressure and temperature conditions. These conditions result in a nitrogen species catalyzed sulfuric acid pressure leach. Since hydrometallurgical technologies provide industrially proven processing options for many types of refractory precious metal containing materials, their usage should be considered. Ample work has been conducted to prove the effectiveness of Sunshine refractory processing technologies on various materials. This has included platinum group metal materials, refractory gold concentrates, silver materials and indium materials. In some cases, complete process flowsheets have been designed to recover both base and precious metals from these materials and to treat the generated waste streams in environmentally sound manners.

Jan 1, 1996

By D. W. Wu, M. T. Haque

A novel impedance probe was commissioned specifically for capturing fast dynamic information about filtration processes. It provides an attractive alternative to more complex measurement techniques in situations where the slurry system is primarily one-dimensional. The probe can monitor mudline, slurry densification and drainage. Dynamic variations in cake permeability are obtained by combining dynamic mudline information obtained with the probe and filtrate rate data derived from a leaf test apparatus. The measurements are reviewed in relation to micro structural measurements obtained on iron ore filter cakes. The practical significance of these measurements for optimization of the filtration process is discussed.

Jan 1, 2002

By Zhi-yong Liu

A novel process, which includes hydrochloric acid leaching, iron powder cementation, sulphide precipitation and spray pyrolysis, was proposed to treat iron concentrate recovered from zinc kiln slag for comprehensive utilization. Treated by two-stage hydrochloric acid leaching, the leaching extents of Ag, Pb, Cu, Fe and Zn are 96.78%, 95.14%, 97.72%, 94.51% and 87.74%, respectively. More than 99% Cu and Ag are recovered from the leach liquor when iron powder is 25% higher than the stoichiometric requirement. More than 96% Pb and Zn is removed with three times of theoretical consumption of FeS, and the concentration of impurities of the final solution is less than 500 mg/L. Fe2O3 powder, which is spherical with a mean size of 12 μm and purity of 99%, is prepared with final solution at 700 °C. In this process, not only the metal values can be recovered effectively, but also the iron resources of zinc kiln slag can be converted into high purity Fe2O3, thus, the comprehensive utilization of iron concentrate recovered from zinc kiln slag can be realized.

By Yuanbo Zhang, Zhixiong You, Daoxian Duan, Guanghui Li, Tao Jiang

"Manganese is mainly consumed by steel and battery industries. In recent years, it is essential to utilize the low-grade manganese oxide ores with total manganese grade below 25%, as the high quality manganese ore resources are becoming scarce with the rapid development of the steel industry. Conventional pyro-metallurgical processes for utilizing manganese oxide ores are characterized by high production cost and energy consumption, low productivity, serious environmental pollution, etc. In this study, reduction thermodynamic of MnO2 reduced by sulfur was firstly carried out. Then, a novel process of reduction roasting with sulfur followed by acid leaching was developed to recover manganese from the very low-grade manganese oxide ores. Effects of main factors, including temperature, reduction time and S/Mn mole ratio, were investigated, and a high leaching efficiency of Mn above 95% was obtained under optimal conditions.IntroductionHigh/middle-grade manganese oxide ores are generally used in the metallurgical industries, particularly in steel plants and ferro-alloy units. The consumption of metal manganese in the ferro-alloy industry accounts for 85- 90% of the total Mn demanded [1]. Therefore, high quality manganese ore resources are becoming scarce with the rapid development of steel industry. It is essential to make good use of large quantity of low-grade manganese ores (TMn < 25%) presently available."

Jan 1, 2012

By Chenming Liu, Xiao Lin, Bo Wang, Hongbin Cao, Xingang Li

Over 2 million tons of NH3-N were discharged in China per year recently, rare earth industry contributed 7.03% of NH3-N pollutant from industrial wastewater in 2007. Wastewater containing NH3-N and heavy metals mainly produced in RE extraction saponificated with ammonia and precipitated by ammonia bicarbonate. Generally, 1 ton REO cost 0.6-1.2 ton ammonia for extraction and 1.6 ton ammonia bicarbonate for precipitation, and produce 35-100 ton wastewater. Processes, like Na-saponificated, Ca-saponificated and Non-saponificated technique, are widely studied to reduce the adverse environmental effect of RE industry, while traditional processes still have advantage in production cost, process stability and product quality. In this study, a novel process that combines distillation and air-stripping is developed. NH3-N is removed and recovered based on relative volatility difference of NH3 and H2O. Phase equilibrium, heat equilibrium are calculated to determine process parameters. Hydrodynamic performance like flow field distribution is also simulated. Then, design parameters for distillation trays or structured packing are determined based on calculations and simulations. Besides, the phase diagram of (NH4)2SO4-NH4Cl-H2O in 30°C - 100°C, the typical salts composition of nonferrous wastewater, is studied to ensure commercial plants’ continuous operation. Ammonia removal tower (ART) with different high efficient column internals is designed to fit RE wastewater treatment requirement. The novel process has been commercialized in RE industry in Jiangxi, China. The commercial project operation results show the novel process reached a nearly zero-emission with >99.5% NH3-N was removed and then recovered as ammonia. Combined the novel process, the traditional REO separation process using ammonia and ammonia bicarbonate could achieve NH3-N reuse and the effluent quality meets the discharge standards.

Jan 1, 2016

By Bourne R. W, Smith T

This paper presents initial findings of a project examining novel processes for the treatment of refractory sulphidic gold concentrates. Non-oxidative roasting of such concentrates for 12 hours at 750¦C resulted in the finely disseminated gold agglomerating to form discrete grains. The pyrite and arsenopyrite decomposed to form pyrrhotite, whilst the labile sulphur and arsenic driven off was collected on a condenser as a mixture of elemental sulphur, metallic arsenic and various arseneous sulphide compounds. As a result, the cyanide solubility of the gold contained in sulphidic refractory gold concentrate from the Emperor mine in Fiji improved from 54.5 per cent to 98.4 per cent; from the Fimiston mine in WA (65.2 per cent to 96.6 per cent), from the Windarra mine in WA (69.6 per cent to 91.3 per cent), from the Harbor Lights mine in WA (20.4 per cent to 60.7 per cent), and from the Wiluna mine in WA (12.6 per cent to 28.0 per cent). The non-oxidative roasting conditions have not been optimised for each of these minerals. Subjecting the non-oxidatively roasted minerals to mild oxidative acidic iron sulphate pressure leaching (with typical temperature of 100¦C and typical oxygen overpressure of 500 kPa) to remove iron and so further liberate finely disseminated gold, resulted in the cyanide solubility of the gold exceeding 96 per cent for each of these five concentrate types (including those from Harbor Lights and Wiluna). Thiourea leaching of the sulphur-rich residues under acidic conditions resulted in remarkably high gold extractions being achieved. These novel processing options need to be optimised, and their economic viability established.

Jan 1, 1991

By X. S. Yuan

With the production increase of Oil Sand in Fort McMurray Alberta, more efficient tailings disposal has become a priority for Syncrude Canada Ltd. A lot of work on tailings research and development has been compiled to determine the most effective deposition to increase reclamation options, water re-use and thermal energy recovery. Efficient flocculation of fine oil sand tailings is the key technology for thickening. It was identified that flocculation of fine transition/marine ore tailings using a single flocculant was not effective. The thickener overflow contains 1-4% solids content compared with the target solids content of <0.5% obtained with Estuarine ore. As a result, novel processes for treatment of fine transition/marine ore tailings have been developed at Syncrude Bitumen Production Development since June 2004. While the conventional processes using a single flocculant, a single coagulation, or a coagulant-flocculant combination was ineffective for transition and marine ore tailings, the new processes including Coagulation-Flocculation-Coagulation (CFC), Flocculation-Coagulation (FC) and Flocculation-Coagulation-Flocculation (FCF) were acceptable options. The key components of these technologies consist of the recipe of chemicals and their adding sequence. With these technologies, almost all sub-micron clay minerals are aggregated together and settle as a whole, resulting in a clear supernatant of less than 0.1% solids.

Jan 1, 2006

By F. L. Wang

The purification process of water-mining carnallite and rough potassium chloride concentrate from Qinghai Salt Lake Industry Group Co. Ltd. are investigated by the preprocessing-reverse flotation technology respectively. The results show that the impurities such as calcium sulfate and sodium chloride can be effectively removed from water-mining carnallite ore and rough potassium chloride concentrate by the new technology, the low-sodium carnallite is obtained and the final potassium chloride product greatly upgraded. The content and the recovery of KCl in the low-sodium carnallite are 25.78% and 97.50%, meanwhile the content of NaCl, CaSO4 in the low-sodium carnallite are 0.56% and 0.24%, and the removal of sodium chloride and calcium sulfate in the low-sodium carnallite are 97.48%, 85.10% respectively. The KCl content and recovery of high quality potassium chloride product are 98.25%, 96.70%, and CaSO4 content is 0.40% with 83.24% calcium sulfate removed in the high quality potassium chloride product.

Jan 1, 2014

By Z. Zhang, D. Bouchard, H. Blanchette, A. Lemieux

This paper describes quality control methodologies for the production of semisolid A356 aluminum slugs with the SEED process. A methodology based on destructive tests carried out with an apparatus measuring the force to slice the slugs is presented. The force measurements were correlated with the solid phase morphologies of the slugs and were validated against a non destructive methodology that consisted in monitoring the temperature evolution of crucibles to produce the slugs and the drained metal. Results from the destructive and non destructive methodologies are compared and discussed.

Jan 1, 2006

By Prakash Venkatesan, Yongxiang Yang, Seshadri Seetharaman, Aida Abbasalizadeh, Jilt Sietsma

Electrolytic production of metallic neodymium is carried out in fused fluoride salts containing neodymium oxide. Two major challenges pertaining to neodymium production are (a) low oxide solubility and (b) possible fluorine gas evolution. A novel iron-based reactive anode is proposed and tested to overcome fluorine gas evolution during electrolysis of neodymium oxide in molten fluoride salts.

Mar 1, 2017

By Baseer Abdul, Edouard Asselin

Hydrometallurgical leaching of sulfide concentrates of copper and nickel at medium temperature (150°C) produces residues that contain sulfur and iron bearing minerals and phases. During leaching, and depending on various process parameters, iron may be precipitated as hematite, goethite, jarosite or other oxyhydroxides, which may be more or less crystalline. Hematite is the favored precipitate because it is the most environmentally stable and does not ad/absorb as much copper, nickel or other solution constituents during precipitation. However, the low solubility of iron during the medium temperature processing of sulfide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. In some cases these phases have been positively identified as the metastable ferrihydrite, which transforms into iron oxides such as goethite, hematite and magnetite over time. A better understanding of what may help drive this transformation during leaching would ultimately result in lower valuable metal losses and more stable leach residues. Higher acid concentrations result in increased copper extractions and favor the formation of hematite during concentrate leaching, rather than other metastable phases. Furthermore, commercially available water displacement formula “WD40®” and other novel reagent(s) affect Fe precipitation and sulfur chemistry, leading to very different process outcomes such as improved extractions and larger, more easily separated, sulfur particles.

Jan 1, 2017

By J. O. Roux

The Impala Platinum Limited Base Metals Refinery in Springs, South Africa, refines convertor matte containing base metals and PGM?s (platinum group metals) using a hydrometallurgical process. In addition to a PGM-rich concentrate that is further refined, the Base Metals Refinery produces nickel (in powder or briquette form), copper cathodes and cobalt powder. Five leaching stages are utilized to remove the base metals and impurities from the PGM concentrate. The project described in this paper involves a radical redesign of the second stage leach autoclave with the aim of reducing maintenance costs and downtime, increasing throughput and ensuring a safer working environment. The second stage leach process at the Base Metals Refinery, produces a PGM-rich residue through the extraction of copper and any remaining base metals from the first stage leach solid residue material. Leaching is performed in an autoclave operating at a pressure of 600 kPaG and a temperature of 140°C to 150°C. Concentrated H2SO4 is added to the feed to produce a solution with a free acid content between 10 and 30 g/L and a pH of less than 2. Oxygen is passed into the 1st and 2nd compartments of the autoclave. As a result of the aggressive, highly oxidizing conditions within the autoclave, the original design utilized a heavy wall carbon steel shell with lead lining and two layers of acid bricks. The bricks acted as a wear resistant material and ensured a low surface temperature at the skin of the lead lining, whereas the lead lining acted as a corrosion barrier to protect the steel shell. These brick lined autoclaves were heavy, maintenance intensive and prone to catastrophic failure. A radical autoclave redesign was needed to reduce the high costs of manufacturing, installation and operation. Finite element modelling was used to optimize the design and various high alloy materials were investigated for the application. Based on extensive test work, the carbon steel shell was replaced with duplex SAF 2205 stainless steel in the new design. The use of this highly corrosion resistant material, eliminates the need for the lead and brick linings and reduces the wall thickness requirements substantially, resulting in an increase in the available volume for the same external shell dimensions. The vessel is welded in circular sections to form an elongated, impermeable, cylindrical body, with several agitator nozzles and compartments. The first new duplex stainless steel unit has been in continuous operation for more than 24 months and its performance has exceeded the highest expectations. The design was so successful that a patent has been registered. The major benefits of the new stainless steel design include increased throughput, improved performance, less downtime and a safer working environment. Lead has been eliminated and replaced with a more environmentally safe material, and the total lifespan of the vessel has been extended. In addition, the autoclave project has made significant developments in advancing the field of welding and optimizing the integrity of welding quality standards in South Africa.

Jan 1, 2009