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By K. Kashiwaya, N. Hiroyoshi, H. Furuya, N. Sumiya, M. Tsunekawa, M. Ito

"The number of hybrid vehicles is increasing and this is causeing an increase in waste nickelmetal hydride batteries. The cathode activating agent of batteries is made of nickel hydroxide and the anode activating agent is an alloy of nickel and rare earth elements. Conventional rotary kiln methods cannot recover the rare earth elements, and hydrometallurgical treatment of crushed product consumes large volumes of agent. The physical separation of the anode alloy from the cathode hydroxide would make it possible to reuse the alloy. The authors have reported separation of anode and cathode components in the large size fractions using a newly developed dry magnetic separation method. Wet magnetic separation has been applied to the powder fraction and about 90% anode purity was achieved. This paper reviews experimental results from previous publications and proposes an integrated treatment process for crushed nickel-metal hydride batteries.IntroductionEnvironmentally-conscious clean energy vehicles have attracted much attention in developed countries and particularly hybrid vehicles are increasingly mass-produced as low emission vehicles. Hybrid vehicles have both a gasoline engine and an electric motor to save on gasoline usage and a nickel-metal hydride battery is used to store electric energy. The battery contains Nihydroxide and Co as the cathode activating agent and an alloy of Ni and mischmetal (mM), a rare-earth element mixture consisting of La, Ce, and Nd, as the anode hydrogen adsorption component. In conventional recycling, the Ni and Fe are recovered with a rotary kiln-electric melting process and the Co and mM go to the slag component [1] and hydrometallurgical treatment of crushed product consumes large volumes of agent. Japan Oil, Gas and Metals National Corporation have proposed a low energy and low cost recycling treatment process combining the physical and chemical treatments and the authors are investigating the physical treatment process."

Jan 1, 2008

By Tatsuya Oki

Tantalum capacitors can be found mounted on printed circuit boards of domestic appliances such as personal computers. These capacitors contain a considerable quantity of expensive metal tantalum and can be detached and liberated from printed circuit boards by impact breakers. In this study, the size and density distribution of the liberated electronic devices were investigated. Then, tantalum capacitors were recovered from other electronic devices using size separation and pneumatic gravity concentration methods. More than 70% of Newton's separation efficiency was obtained for tantalum capacitors. High Newton's separation efficiency could be also obtained for other types of electronic devices such as chip resistors.

Jan 1, 2011

By Aichun Zhao, Rui Wang, Yihong Li, Yanping Bao, Yafeng Ji, Jiansheng Liu, Xiao Hu, Qingxue Huang

The slag entrapment under different conditions of 80t blowing argon ladle furnace was investigated by physical simulation. The water was used to simulate liquid steel and liquid paraffin was for slag. The processing of slag entrapment under different blowing structures was analyzed and the critical velocity and critical droplets diameter of describing it was obtained. Based on the experiments, the relationship between the interface flow velocity and the critical blowing rate CBR was deduced. In the real process, it is suggested that the bottom blowing rate is from 40 L/min to 180L/min when the interface tension is 0.12~1.2 N/m during the soft argon blowing.

Jan 1, 2016

Previous models describing the aggregation of polymer coated particles fail to take into account the fact that there are a limited number of sites onto which a polymer segment can adsorb, called ?active? sites. Thus, the collision efficiency is a factor not only of the fractional surface coverage, but also of the number of active sites. In this study, a physical model of the flocculation system was devised in which the number of these sites could be varied, in order to study the effect on particle aggregation.

Jan 1, 1987

By Qingxiang Huang

Shallow seam coal field has the largest coal reserve in China. Mining in shallow depth causes serious problems. One of them is subsurface dewatering. In this paper, the physical simulating model was performed to study overburden movement and aquiclude stability in the shallow seam mining of Yushuwan coal field, China. According to the characteristic of clay aquiclude in the overburden, the proper simulation materials and proportions of mixture for simulating the plastic clay aquiclude layers and brittle bedrock layers were determined by the stress-strain tests. The physical simulating model was carried out to simulate the failure and caving process of the roof and overburden. Based on the simulating tests, it was found that the movement of clay aquiclude follows the movement of the underlying bedrock layers. The basic caving mechanism of the overburden roof strata was also presented. The tests also showed that the best way to control the stability of aquiclude is to reduce the subsiding gradient Ts. This research provides a foundation for further study on mining dewatering and water conservation.

Jan 1, 2006

By A. McCombs

Previous models describing the aggregation of polymer-coated particles fail to take into account the fact that there are a limited number of sites onto which a polymer segment can adsorb, called "active" sites. Thus, the collision efficiency is a factor not only of the fractional surface coverage, but also of the number of active sites. In this study, a physical model of the flocculation system was devised in which the number of these sites could be varied, in order to study the effect on particle aggregation.

Jan 1, 1988

By Sean Gallagher

Humankind's interest in measurement of human physical strength probably dates to the first humans. At that time, life was truly a struggle in which the fittest survived. To a great extent, fittest meant strongest. Interestingly, current interest in human physical strength in the workplace stems from 1970-1980s vintage research demonstrating that persons with adequate physical strength are less likely to be injured on physically demanding jobs. Survival in many modem workplaces may still be a case of survival of the strongest. There is, however, a flip side to this issue - that persons with limited strength are more likely to be injured on "hard" jobs. To address this problem, we can apply what we know about physical strength to job design. "Hard" jobs can be redesigned to be within the physical strength capability of most people. Since physical strength is important to these jobs, we must find ways to quantify it through testing. This publication concerns human physical strength testing. Its purpose is not to recommend any particular type of testing, but rather to describe the types of testing available and their uses. It is up to each individual user of strength testing to decide which testing technique is most appropriate for his or her particular application. This booklet discusses four types of strength testing: isometric, isoinertial, psychophysical, and isokinetic.

Jan 1, 1998

By Wm Price

THE object of this paper is to present a survey of some of the physical properties of sheet nickel silver when subjected to cold rolling and when annealed at temperatures extending from 350° C. throughout the commercial annealing range. A number of alloys were taken from stock and analyzed. Four of these, representing low nickel and high nickel both with and without lead, were chosen for the tests. The analyses were as follows: ALLOY COPPER, LEAD, IRON, NICKEL, MANGANESE, ZINC, PER CENT. PER CENT. PER CENT. PER CENT. PER CENT. PER CENT A 64.68 Trace 0.194 - 6.73 0.06 remainder B 65.82 1.27 0.227 6.17 0.06 remainder C 65.44 Trace 0.345 17.83 0.08 remainder D 65.60 1.08 0.238 17.77 0.06 remainder These alloys were rolled in accordance with regular mill practice to approximately No. 6 B. & S. gage. The bars (which were then coiled) were annealed together in a mill muffle and afterwards pickled in a 10 per cent. sulfuric-acid solution and cold rolled in stages of approximately .one number (B. & S.) at a time to No. 18 B. & S. gage. After each stage, suitable samples were set aside for physical tests. Additional samples were chosen for tests after the bars were rolled to Nos. 8, 10, 12, and 14 gage. These samples were annealed together in the mill muffle and, after pickling, were finished on 0.050-in. gage, yielding a series of specimens 2, 4, 6, and 8 numbers hard for the subsequent annealing tests. Tensile test pieces 9 by 1 in. (22.9 by 2.5 cm.) were cut from both lots and the central portion was milled to give a test section 2 ½ in. long by ;Z in. wide. A distance of 2 in. was marked off on the edge of each specimen with light punch marks. In the case of the annealed alloys, Erichsen test pieces 4 by 2 1/2 in. were also taken.

Jan 10, 1920

By A S. M A Haseeb

Zircon is the second in abundance among the heavy minerals occurring in the beach sand along the coastal belt of Bangladesh. In this study a detailed characterisation of Bangladesh zircon extracted at the pilot plant of the Bangladesh Atomic Energy Commission at CoxÆs Bazar has been attempted using chemical analysis, X-ray diffraction and optical microscopy. From the chemical analysis it is found that Bangladesh zircon has a purity of 95.88 per cent. The main impurity in Bangladesh zircon is titanium oxide (3.01 per cent). This is followed by iron oxide (0.42 per cent). A number of other oxides are also found. Microscopic study revealed that Bangladesh zircon has an elongated, prismatic shape with pyramidal termination in about half of the grains while the rest are more or less rounded. Some fractured and irregular grains are also found. Bulk sample of Bangladesh zircon in the as-received condition shows a yellowish brown color. However, individual zircon grains are seen to be almost colourless and transparent under polarised light. XRD study confirmed good crystallinity in the sample. Under the microscope it is found that zircon grains constitute 94 per cent while total impurities amount to six per cent in Bangladesh zircon. This result agrees fairly well with the chemical analysis results. Microscopic study identifies oxides of titanium (both rutile and ilmenite) to be the main impurity, in conformity with the findings of chemical analysis. Further, monazite was also identified as an impurity under the microscope. An iron bearing coating is also found on a few zircon grains. Most of the impurities found in Bangladesh zircon exist as discrete minerals.

Jan 1, 2000

By Akram Salah Eddine Belaidi, Lakhdar Azzouz, Benchaa Benabed

"The dunes sand is a material of a large availability in Algeria. This material is practically unexploited. The introduction of this material as a new element in the construction can be more relieve the domain of building, and contribute to the development of the southern regions of Algeria, which are very rich in this material. The main objective of our work is to exploit a largely available material in the Algerian south which is the dunes sand, as a material of construction in the region of Laghouat.In this study, first we investigated the effect of the curing environment and the nature of the sand on the mechanical properties of the mortar, such as; flexural and compressive strengths. Then after, we studied the durability of the mortar under cycles of wettingdrying and the chemical attack of sodium sulfate (Na2SO4 5%).According to the results, we note that the mortar of the sand mixes (river sand plus dunes sand) present the best mechanical performances under different environment of curing. In addition result of durability studies put forward that the mortar of the sand mixes is more resistant to the sulfates attack."

Jan 1, 2008

By Clarence S. Ross

INTRODUCTION THIS chapter on the rô1e of physical-chemical processes in ore deposition presents unusual difficulties because it attempts to discuss the theory of processes that are very imperfectly under- stood, but which are among the most fundamental problems now before the student of ore formation. It is generally believed that a great variety of ore deposits are in some way derived from igneous rocks; but we desire to know the mechanism of their splitting off from the parent magma, the physical and chemical character of the material that acts as a medium for transfer from magma to the point of deposition, the manner of deposition, and the methods of replacement and removal of the invaded rocks. This problem is difficult for the field geologist because it concerns forces that for the most part have long since ceased to act. It involves a complex system of which the time for completion extends from the first development of the parent magma through its intrusion, its slow cooling and crystallization, and the final escape of its last residuum, a time probably represented by millions of years. In space the processes extend from profound depths of the abyssal magma which can never be directly observed, through the horizons characterizing deep-seated igneous rocks and ore deposits; those formed at moderate depths; and ends with surficial ones and surface thermal springs. The geologist usually can study the effect at but one of these horizons: he must attempt to fit his puzzle together while seeing but a few parts at a time. Thus he must deal with many isolated phenomena, as if they were the result of many physical and chemical systems; when in fact his problem involves a single exceedingly complex system, and will only be understood when that entire complex system is understood. The geophysicist is handicapped because he must attempt to interpret an extraordinary complex system, involving physical and chemical conditions which he can never hope to duplicate fully, through the study of many exceedingly simple systems.

Jan 1, 1933

Physical/Chemical Treatment of Mercury-Contaminated Wastes from Former Chlorine-Alkali Electrolysis Plants - Application of Flotation Technologies in Soil Washing Plants

Sep 13, 2010

By A. Yehia, M. I. Al-Wakeel

Flotation behavior, of magnesite and dolomite pure minerals was studied separately. Rice bran oil (a source of fatty acid ) was used as a collector for both minerals . The aim of this study is to find a separating zone in the flotation of these pure minerals to be used in the separation of their mixture. Factors affecting the flotation process, such as pH and collector, were studied. It was found that magnesite can be separated, from its mixture with dolomite, in the pH range of 5-7. At this pH range flotation recovery of dolomite reaches~98% where magnesite reaches ~20% only. Besides, the effect of collector concentration on the flotation shows that the separation of magnesite from dolomite is feasible at a collector concentration of 3x10-4 M. At such concentration, dolomite recovery reaches ~98%, where magnesite reaches 25%. The differences in the flotation behavior of dolomite and magnesite were investigated by studying the adsorption isotherms of rice bran oil on magnesite and dolomite surfaces. The adsorption study indicates that while there is an excessive adsorption on dolomite surface, the adsorption density on magnesite was restricted to be lower than monolayer capacity. The adsorption behavior of dolomite and magnesite was discussed in the light of their solubility and crystal structure. It was found that due to the higher solubility of dolomite than magnesite, Ca2+ and Mg2+ ions are available and more reactive on dolomite surface increasing collector adsorption. In addition, it was indicated that dolomite mineral has a crystal lattice structure more compatible to the geometry of the fatty acid carboxylic group than magnesite. However, the adsorption of collector on dolomite surface is more compact and more regular than on magnesite surface.

Jan 1, 2000

By A. M. Amdur, A. N. Matushkina, G. I. Gazaleeva

"The article highlights results of theoretical and practical studies on the enlargement of fine gold in the process of heat treatment. The object of research is refractory gold silicate-carbonate ores of Vorontsovskoe Deposit (Northern Ural), containing fine gold. For setting up experiments and analyzing the results were used the methods of applied mathematics, mathematical statistics, mathematical and physical modeling. Modeling and calculations were performed using the software package HSC Chemistry 6.0, MatLab, setting up a full factorial experiment and other modern modeling methods. Using a scanning electron microscope, the distribution of fine-dispersed ore gold particles by size was studied. It was found that gold particles smaller than 0,4 µm smoothed the vertices and edges, i.e. they are of globules with an amorphous structure. Amorphous materials are nonequilibrium phases with high thermodynamic activity. The physicochemical properties such as melting temperature, diffusion coefficients, the content of metal impurities differ from the properties of the solid phases. In the course of the research were formulated the following scientific bases of the mechanism of enlargement of the gold particles: - the movement of dispersed droplets of gold in the process of external heat to the surface of the ore particles in the pore occurs under the action of thermocapillary pressure; - after melting of the host rock occurs flotation of molten droplets by the bubbles of gases and coagulation of fine gold; - the conditions of flotation drops of gold in oxide melts; floated drops of radius R = 1-100 µm. Analysis of the equilibrium at the perimeter of wetting a drop of gold-oxide melt-gas showed that the scheme of the tension will not significantly differ from the case of solid gold, while the radius of the gas bubbles should be at least 2 times greater than the radius of drops of gold. The proposed method of predicting the results of the enrichment of the proposed scheme, including heat treatment and gravitational centrifugal concentration of crushed ore. Experimental verification of the proposed scheme in the laboratory showed a satisfactory convergence of experiment and prediction. Gold recovery in the concentrate was 33,84 against 33,7 percent forecast. The increase in overall gold recovery to a gravity concentrate after heat treatment is more than 20 %."

Jan 1, 2018

By B. Orberger, J. M. Milazzo, S. B. Blancher, J. Lützenkirchen, J. L. Dubos

"Industrial dusts are commonly agglomerated using empirical recipes with binders such as bentonite, while Sludges are agglomerated into mixes. Those materials contaminate the products, are expensive and generate significant amounts of slag. Achieving cold dust agglomeration with little or no binder requires understanding the controlling parameters in order to predict and optimize the process behavior. This in turn necessitates comprehensive dust characterization to base predictions on measurable characteristics. In the present work we collected 13 Mn-rich dusts over all the process chain: feed fines, smelting, and refining dusts, as well as ferromanganese alloy dust. This is the first systematic study of dusts along the Mn-processing chain for chemical, physical and mineralogical parameters. X-Ray Diffraction, Qemscan® and laser granulometry analyses show that the mineralogy, Particle Size Distribution (PSD) and morphology evolves from complex heterogenous to simple, homogenous along the process chain: The mineralogy of the primary ore dusts shows various hydroxides, oxides, carbonates, tectosilicates and phyllosilicates. The furnace dusts contain oxides, tectosilicates and carbonates with volatiles, while the refining dusts present only oxides and metal. Finally, the Metal dust is nearly pure metal. Particle morphologies and PSD vary from jagged, irregular particles with broad PSD (>1 mm to <0.3 µm) to smooth and spherical with narrow PSD (100 µm to <0.3 µm). The Metal dust is an exception with angular particles. The Cationic Exchange Capacities (CECs) of all samples range from 0 to 22 meq/100g. Specific surface areas (SSAs) range from <0.1 to 27m²/g, and seem to decrease with from ore feed to Metal dust. This may be due to the disappearance of hydrated and/or sheet-bearing minerals, since a smaller grain size usually implies an increased SSA. The zeta potential varies strongly over the range of the samples tested. However, beside the Gabon ore which has an Isoelectric Point (IEP) ~ 4.1, the other IEP ranges between 2 and 2.5."

Jan 1, 2018

By M. Misra

A sample of thorium-contaminated soil from Kirtland Air Force Base (AFB) was subjected to froth flotation for removing thorium contaminants. A series of flotation tests were conducted to screen and evaluate the reagents. Among the collectors used, sodium oleate exhibited to show the promising results. Preliminary tests showed that a concentrate having activity as high as 5300 pCi/g can be obtained from the contaminated feed soil having activity 800 pCi/g. The volume reduction obtained was 89% and the activity recovery in the concentrate was 68%. The paper discusses the physico-chemical characterization data and the potential physical separation decontamination schemes for the thorium contaminated soils.

Jan 1, 1996

By A. I. Okunev

The investigation results are submitted on separation into layers in the systems Cu (Ni) - Fe - Ca - 0 - S - (Si), as well as on physico-chemical properties of oxide - ferrite, oxide-sulfide melts (density, surface tention, viscosity, electric conductivity), on kinetics and oxidation macromechanism of iron and sulfur in the oxide-silicate, oxide-ferrite and oxide-sulfide melts, kinetics of reduction of oxide-silicate and oxide-ferrite systems. Conditions are discussed for copper, nickel and zinc recovery from oxide-silicate and oxide-ferrite slag in liquid and solid states. Some promising technique is the technique of future, as is considered.

Jan 1, 1988

By M. Chettibi

The interaction and galena flotation with xanthenes and dexanthogen regularities have been de-fined. So, using thermodynamic method of analysis, the thermodynamic stability of [galena - xanthenes - water] system and the behavior of lead xanthenes surface state in solution were devised. Thus, results of cared out calculations and experimental investigation completely coincide with-out depending on witch product of sulfur oxidation is formed in the solution. In additional, was obtained quantitative physico-chemical models for the necessary xanthenes concentration of lead sul-fide complete flotation in the tuning fork of: at ?? values from 7.0 up to 9.0 (or at the formation of lead carbonate PbCO3 ) and at ?? values from 9.0 up to 12 (or at the formation of lead hydro carbonate Pb3(OH)2(CO3)2 Physico-chemical models derived can be used as the criteria for functional units of automation systems to control and regulate the flotation process in mineral processing plants.

Jan 1, 2014

By H. Hamma, R. Fehrmann, M. Gaune-Escard, G. Hatem, S. B. Rasmussen, K. M. Eriksen

The molten salts M2S2O7and MHSO4, the binary molten salt systems M2S2O7-MHSO4and the molten salt-gas systems M2S2O7-V2O5and M2S2O7-M2SO4-V2O5(M = Na, K, Rb, Cs) in O2, SO2and Ar atmospheres have been investigated by thermal methods like calorimetry, Differential Enthalpic Analysis (DEA) and Differential Scanning Calorimetry (DSC). Fundamental thermodynamic data like temperatures and molar heats of solid-solid transition and fusion, phase diagrams, heat capacities of solids and liquids, heat of mixing, and heats of complex formation have been obtained and are reviewed here. Also EPR spectroscopic evidence of V(IV) complexes and their structure are reported and the results are discussed in relation to the mechanism of SO2oxidation by V2O5based industrial catalysts. Keywords: Alkali pyrosulfates, alkali hydrogen sulfates, vanadium pentoxide, EPR spectroscopy, complex formation

Jan 1, 2004

By E. Pothas, P. R. Jochens, L. B. McRae, D. D. Howat

SYNOPSIS The phase equilibria, viscosities and sulphur capacities of titaniferous slags were determined in the composition range of CaO = 30 to 0 per cent, MgO = 0 to 30 per cent, SiO2 = 19.69 per cent, AI.O. = 13.12 per cent and TiO2 = 37.19 per cent. The phase equilibria were determined by high temperature microscopy, the viscosities were measured using a rotating outer cylinder viscometer and the sulphur capacities were evaluated from the results obtained by equilibrating the slag in a gas stream of CO, CO2 and SO2. The behaviour of these titaniferous slags under reducing conditions was examined. Possible use of the slags for aggregate, or slag-cement, and the possibility of extracting the TiO2 are discussed. CONTENTS INTRODUCTION PHASE EQUILIBRIA VISCOSITIES DISCUSSION OF THE PHASE EQUILlBRIA AND THE VISCOSITY VALUES EFFECT OF REDUCING CONDITIONS SULPHUR CAPACITY DISCUSSION OF THE SULPHUR CAPACITY VALUES POSSIBLE USES CONCLUSIONS ACKNOWLEDGEMENTS REFERENCES INTRODUCTION The latest phase in the exploitation of the mineral wealth of the Bushveld Igneous Complex is the erection of a plant by the Highveld Steel and Vanadium Corporation Limited near Witbank to produce steel and vanadium-rich slag from the titaniferous magnetites occurring in this rock formation. These titaniferous magnetites occur as segregations in the gabbro body and the TiO2 is mainly present within the structure of other constituent minerals but also occurs in smaller amounts as ilmenite and ulvospinel. The vanadium is thought to be present in the iron oxide phase due to isomorphous replacement of the iron. Until very recently, it was feared that the high titania content of these titaniferous magnetites would militate against their value as useful iron ores. However, the design of an integrated plant to produce both steel and vanadium-rich slag, and in which the iron-making process is conducted in submerged arc furnaces instead of in