Search Documents

By Price B. D, Staunton W. P

The Mineral Science Laboratory of the Government Chemical Laboratories has recently investigated various procedures for the analysis of the platinum group metals (PGMs). This investigation covered a number of methods for the extraction and preconcentration'of the PGMs from a wide range of geological materials. The nickel sulphide extraction technique proved to be overall the most applicable procedure. Flame atomic absorption spectroscopy (FAAS), electrothermal atomisation atomic absorption spectroscopy (ETA-AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS) were examined for their suitability in analysing platinum group metals in solution. ETA-AAS and ICP-MS proved to be the instruments of choice due to their low detection limits.

Jan 1, 1987

By Linda D. Raedeke

The main platinum-group metal (PGM) deposit in the Stillwater Complex is associated with a stratiform zone formed by magma mixing. In general, the intrusion is a large, layered body of Archean age which formed by repeated magmatic injections in- to a single, large, hypabyssal magma chamber. The Complex is broadly divided into the lower Ultramafic series of olivine ± orthopyroxene rocks (1000-2000 m thick) and the upper Banded series of predominantly plagioclase-rich rocks (24500 m thick). The latter is further divided into Lower, Middle, and Up- per Banded zones. The Ultramafic series, plus most of the Lower and Upper Banded zones formed from repeated injections of an olivine-saturated magma, the rocks accumulating from the floor upward with a crystallization order of olivine, or- thopyroxene, plagioclase, clinopyroxene. The olivine-bearing subzones of the Middle Banded zone formed predominantly from a magma which crystallized in the sequence plagioclase, olivine, clinopyroxene. Olivine-bearing subzone I, with which the PGM mineralization is associated, occurs generally -400 m above the Ultramafic series-Banded series contact. Ore grade mineralization is usually found in plagioclase or plagioclase-olivine cumulates. The platinum-group elements are associated with disseminated base-metal sulfides dominated by the assemblage, pyrrhotite-chalcopyrite-pentlandite. Olivine-bearing subzone I marks an interruption in the crystallization sequence of the Lower Banded zone, with the reappearance of cumulus olivine and an associated change of the crystallization sequence. These changes indicate the addition and mixing of a secondary magma of the same composition as that which later dominated in the formation of the Middle Banded zone. Characteristics associated with mixing include laterally discontinuous but well-developed layers, xenoliths of ultramafic rocks, and sedimentary-type structures such as slum- ping and graded layering. The influx of new magma caused sulfide saturation by one or more of several chemical changes including addition of sulfur, decrease in oxygen fugacity, decrease in FeO, or increase in SiO2. Once an immiscible sulfide liquid was formed, platinum-group elements were scavenged from the magma by the sulfide liquid and segregated.

Jan 1, 2013

By Distin P. A

The extraction of platinum and rhodium from scrapped honeycomb autocatalyst into hydrochloric acid/aluminum chloride/nitric acid solutions is described. Results are given for the effects of leachant composition, temperature and catalyst pre-reduction using hydrogen. Data are also presented for the recovery, by hydrogen reduction, of platinum and rhodium dissolved in the leach solution. Parameters studied include solution composition and temperature, hydrogen pressure, and platinum seed addition.

Jan 1, 1992

By I. Iwasaki

Precious metals are commonly believed to be recovered along with sulfide minerals in flotation, but a few neutron activation analyses showed that the recoveries of gold and silver were unexpectedly low. Recoveries of platinum group metals remained unresolved due to interferences in the analyses. Electron micro-probe, scanning electron microscope and scanning auger microprobe analyses have identified nickel arsenide minerals in the ore and confirmed a close association of platinum group metals with the arsenide minerals as minute inclusions. These results indicated a need for re-evaluation of flotation procedures which have so far ignored special problems related to arsenide minerals. The electrochemical and flotation behaviors of nickel arsenide and their implications to the flotation recovery of arsenide minerals from copper-nickel bearing Duluth gabbro are presented.

Jan 1, 1985

By K. J. Reid, I. Iwasaki, T. Sabelin

Introduction Occurrences of platinum group minerals (PGM) in mafic and ultramafic rocks in association with Cu-Ni mineralization are well known. Yet for the Duluth Complex, a large body of dominantly mafic igneous rocks in northeastern Minnesota with significant Cu-Ni mineralization (Bonnichsen, 1972; Boucher, 1975; Watowich, 1978; Weiblen and Morey, 1980), little has been published concerning its platinum group element (PGE) contents and mineralogy. In a previous study of massive sulfide rock, sperrylite (PtAs2) was found in nickel arsenide and recovery of arsenide minerals by flotation has been investigated (Iwasaki et al., 1986; Ryan and Weiblen, 1984). Recently, an announcement was made of the discovery of significant quantities of platinum and palladium [peak assay values of 9 g/t (0.27 oz per st)] in an interval of a drill core with disseminated sulfide mineralization 16 km (10 miles) southeast of Ely, MN (Anon, 1985; Sabelin, 1985). This paper describes PGM from the Pt-Pd-enriched zone and evaluates their potential for concentration. Geologic setting The Pt-Pd zone occurs in the South Kawishiwi in¬trusion near its basal contact at 734 to 737 m (2408 to 2418 ft) depth. The South Kawishiwi is one of several minor mafic intrusions that constitute the western margin of the Duluth Complex near Ely, MN (Fig. 1). It is com¬prised of a 70.1- to 350.5-m (230- to 1150-ft) thick sul¬fide-bearing basal unit of troctolite with minor amounts of anorthosite, norite, picrite, and oxide layers overlain by a troctolite unit with interlayered anorthosite (Bonnichsen et al., 1980; Foose, 1984; and Foose and Weiblen, 1986). The basal unit, in which the Pt-Pd zone is found, is markedly heterogeneous in rock type, lacking any coherent internal stratigraphy, and shows evidence of both pre- and post-consolidation faulting (Foose and Weiblen, 1986). Geochemistry Chemical analyses were made on 0.3-m (1-ft) intervals of crushed drill core material (1/4 core, BX size) at 731.5 to 740.7 m (2400 to 2430 ft) depth and the results are presented in Fig. 2. The analytical techniques used were atomic absorption spectrometry for silver, chromium, copper, and nickel; a coulometric titration method for sulfur; and a combined fire assay-DC plasma technique for gold, palladium, and platinum. Figure 2 shows the significant enrichment of platinum and palladium at 734 to 737 m (2408 to 2418 ft) depth; it corresponds to a stratigraphic interval rich in oxide minerals. Average values for platinum and palladium contents over the 3-m (10-ft) interval are 2520 and 2580 ppb, respectively, or 5.1 g/t (0.15 oz per st) platinum plus palladium. Platinum plus palladium contents from individual 0.3-m (1-ft) intervals are as high as 9120 ppb or 9.1 g/t (0.27 oz per st) and average 7.4 g/t (0.22 oz per st) in a 1.5-m (5-ft) interval in the richest part of the zone. The Pt-to-Pd ratio is nearly 1:1 over the entire 9.1-m (30-ft) interval and the platinum and palladium correlate closely with chromium, which ranges from 1.9% to 5.3%. Copper, nickel, and sulfur contents for the drill core interval are also given in Fig. 2. In¬terestingly, the Pt-Pd high corresponds to a depletion in copper, nickel, and sulfur. Mineralogy of the Pt-Pd zone The Pt-Pd zone occurs within an oxide-rich zone or layer that consists essentially of oxide minerals, plagioclase, and olivine. The oxides may constitute as

Jan 1, 1987

By R. C. Hochreiter

The paper gives a technical review of the history, occurrence, mining, metallurgy, and end-uses of the platinum-group metals in South Africa, with most emphasis on platinum and palladium. The platinum industry has grown, from the first discovery of the metal in South Africa (in the central Transvaal) in 1923, to the present time, when the country is the largest producer of platinum 10the world, supplying almost 70 per cent of the platinum on the world market.

Jan 1, 1985

By L. C. Stilwell

The paper will place into perspective the contribution that platinum makes to the South African economy. It will use statistics from official sources, namely the Department of Minerals and Energy, the Department of Customs and Excise, the South African Reserve Bank and Statistics South Africa. Surprisingly few people are aware of these statistics, especially Supply and Usage tables, published by Statistics South Africa, and trade statistics, published by the Customs and Excise division of the South African Revenue Service. The paper will therefore contain a concise explanation of input-output tables and supply usage tables, as well as the derivation of gross domestic product and an outline of the System of National Accounts, of which Input-Output Tables and supply and usage tables are components. GDP is a commonly used, but poorly understood, measure of the wealth of an economy. The paper will explain the methods used by SSA to calculate this indicator and its place in the System of National Accounts (SNA). South Africa exports almost all its platinum production (87.5% in 2002). Exports are a final demand, as opposed to intermediate demand from secondary industries, and therefore do not enter the value-adding process, which is the essence of GDP. By definition, therefore, platinum on its own is not a major contributor to GDP. The platinum industry does, however, have an impact (known as the multiplier effect) on other sectors of the economy. The paper will explain the meaning and derivation of these multipliers, using a model based on an Inverse Leontief Matrix.

Jan 1, 2004

By R. S. Botsford

SPECULATION as to when and under what conditions mining may be resumed in Russia by foreign interests is becoming more interesting. Circumstances have changed so completely that all new projects must give careful consideration to the conditions as they exist at this time. For example, it is now estimated that a certain copper company in Russia can produce copper and put it on board ship at seaboard for 8 1/2c. per lb., crediting the copper with the value of precious metals contained. It is further estimated that in some places gold can be produced at a cost of about one-half of its value; platinum can be produced even more advantageously. Transportation, which is absolutely necessary for mines of coal, iron or manganese ore, as well as for an industry consuming either coal or coke, is not so essential for the operation of a gold or platinum dredge when the dredge has once been put into operation; after that, food is the principal material for which transportation must be provided. During 1922 the operators in the Urals, who had combined in a so-called platinum trust, expected to produce about 2340 lb. of crude platinum but the amount actually recovered during that season was reported as only 1620 lb., most of which came from hand workings; Nicolo Pavda had the principal dredges in operation during that year. In preparation for 1923 operations, about $400,000 worth of repair parts were obtained in England. At least two American-built dredges and one Putiloff dredge are reported in operation at Nicolo Pavda and it is supposed that most of the better dredges in the platinum district are now working.

Jan 12, 1923

By G M. Mudd

The growing popularity of platinum and platinum group metals (or PGMs, including palladium, rhodium and others) for a wide range of applications leads to some interesting issues for mining and sustainability. The uses for PGMs includes catalytic converters for air pollution control in vehicles, growing jewellery use, catalysts for various purposes (especially petroleum and chemicals processing), hydrogen fuel cells and many others. Given the growing importance of most of these PGM uses in more sustainable technologies or in making industrial processes more efficient, it is critical to understand the complex sustainability issues which surround platinum and PGMs. At present, South Africa is the dominant PGMs producer and holds about 88 per cent of estimated global resources, with important but relatively minor production and resources in Zimbabwe, Russia, Canada and the United States. Given the concentrated location of PGM resources, what are the likely trends in PGM mining with respect to environmental sustainability? That is, what are the costs in terms of energy, pollution, greenhouse gas emissions, water, land use impacts, social impacts, economic aspects associated with this globally important industry? This paper compiles and analyses a range of data on platinum-PGM mining, focusing primarily on South Africa. It synthesises a unique combination of data which relates typical production aspects such as ore grade and scale with sustainability aspects such as greenhouse, energy and water costs. The findings are critical in understanding the debate about the increasing environmental and social costs of some materials and technologies which are considered crucial for sustainable industries based on PGMs. Overall, the paper represents a valuable insight into the platinum-PGM sector, providing a range of useful data for understanding the environmental sustainability of this particular group of precious metals.

Jan 1, 2009

By Patrick H. O’Neill

The Choco placers, mined continuously since the earliest expeditions of the Spanish conquistadors, were exploited by the Indians prior to the conquest. Platinum is found in varying percentages with gold throughout the Choco placers and is found in minor percentages in some placers in other parts of Colombia. The Choco Department is on the west coast of Colombia between the western range of the Andes and the Pacific Ocean and extends from the San Juan River north beyond Panama to the Caribbean. The first reference in European literature to platinum was by Julius Caesar Scaliger in 1557. He did not assign any name to it but referred to it as an infusible metal found in the mines in the New World. The Spaniards had given it the name platina, which is the diminutive for plata, the Spanish word for silver. Don Antonio de Ulloa first recorded the name while on an official visit to the Choco from Spain in 1735.

May 1, 1956

By G Ryan, Yu Nazimova

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. This paper aims to highlight the global exploration opportunities that exist in connection with Ural-Alaskan (UA)-type intrusions. The key economic importance of UA intrusions is the existence of metallic platinum (mainly iron-platinum alloys) associated generally with chromite mineralisation and located within a dunite core, especially its coarse-grained part. Being very dense and resistant to erosion, platinum can form rich placers as the intrusion erodes. Big multimillion ounce placer platinum deposits of this type have historically been successfully mined for many years (eg Russia, Colombia and Alaska).However, large-scale exploration and mining of platinum placers currently occurs only in the Russian Far East. Outside of Russia, there is now little or no understanding of this type of deposit and its economic importance. Using successful operations in Russia as examples, it is demonstrated that there are many opportunities for similar discoveries all around the world, especially around the Pacific Rim, where such intrusions tend to be concentrated. Examples of highly prospective areas in eastern Australia and New Zealand are given. There is also excellent potential in British Columbia (BC) Canada, South-East Asia (Philippines, Indonesia, Papua New Guinea and New Caledonia) and South America (Colombia and Ecuador).CITATION:Nazimova, Y and Ryan, G, 2015. Platinum potential of the pacific rim of Ural-Alaskan-type intrusions, in Proceedings PACRIM 2015 Congress, pp 665–670 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By M. Royker

Gold has been demonstrated as a possible catalyst for oxidation reactions. Some evidence for a possible promotion effect of platinum has also been recorded. The influence of platinum as promoter for Au/?-Al2O3 prepared via anionic ion-exchange for the oxidation of glycerol was investigated in a batch reactor at 60°C. It is inferred that the addition of platinum reduces the catalytic activity and therate of deactivation, resulting in an overall higher final conversion of glycerol with increasing platinum loading. The addition of platinum to the catalyst favours the formation of the desired product, glyceric acid.

Jan 1, 2012

By M. Royker

Gold has been demonstrated as a possible catalyst for oxidation reactions. Some evidence for a possible promotion effect of platinum has also been recorded. The influence of platinum as promoter for Au/?-Al2O3 prepared via anionic ion-exchange for the oxidation of glycerol was investigated in a batch reactor at 60°C. It is inferred that the addition of platinum reduces the catalytic activity and the rate of deactivation, resulting in an overall higher final conversion of glycerol with increasing platinum loading. The addition of platinum to the catalyst favours the formation of the desired product, glyceric acid.

Jan 1, 2012

By Shuchen Sun, Ganfeng Tu, Chuan Liu, Xiaoping Zhu

The hydrometallurgical residue generated during the hydrometallurgical processing of waste automotive catalysts is valuable as a secondary resource. In this study, a process of platinum recovery from the hydrometallurgical residue by high-temperature smelting process was proposed. Results of lab- and pilot-scale experiments show a high recovery of more than 98% of platinum and glass slag was successfully obtained by controlling the Fe3O4 addition, C/Fe3O4 mass ratio, CaO/SiO2 mass ratio, smelting temperature, and holding time at 15 wt%, 0.4, 0.6, 1500 °C, and 120 or 60 min, respectively. Results from the pilot-scale show that the platinum contents in the glass slag and alloys were less than 4 g/t and more than 0.6 wt%, respectively. Therefore, the process proposed in this study is a prospective and effective approach for reutilization of hydrometallurgical residue containing platinum.

Oct 12, 2020

By W Akpan

The Royal Bafokeng community in South AfricaÆs North West Province represents a unique case in Sub-Saharan Africa in terms of its positioning in the natural resource economy. It receives royalties directly from mining firms for the extraction of Platinum Group Metals, which include platinum, ferrochrome, rhodium and palladium. In 2007, royalty income of about R290 million (approximately US$32.2 million) was reported. Such direct revenues have enabled the community to invest in educational, medical and other social infrastructure, thus complementing governmentÆs social provisioning efforts. Indeed, the Bafokeng community owes its present-day modernisation efforts to mineral rights, and in particular, the legal-institutional arrangement that has enabled it to play an active role in South AfricaÆs lucrative extractive economy. However, the distribution of platinum wealth in this community is not only uneven, but also appears to have had little impact on the broader socio-economic conditions in the community. Despite claims by community leaders of heavy investment in education and skills development, the community continues to be faced with very high levels of unemployment, illiteracy, sprawling informal settlements, poor access to medical facilities and malnutrition. This paper examines the sociological paradoxes and contradictions thrown up by the approach adopted to involve community members in the mobilisation of mining royalties for developmental ends. The central argument is that the current æmodelÆ contradicts the communityÆs stated goals of using platinum wealth to drive up broad-based development and modernisation. This is mainly because it leaves out the vast majority of community members, who are uneducated and unskilled. The core analysis is based on pilot data from an ongoing study in the Royal Bafokeng community.

Jan 1, 2009

By A. C. Dunham, Y. D. Drakapoulos, P. W. Scott

The Pt and Pd occur alloyed with copper in small, irregularly-shaped grains, 0.25-5.0 micrometers in maximum dimensions. Grains of unalloyed native copper are also present. The grains are completely surrounded by or marginal to magnetite with inclusions of Ni-Fe-Co sulphides and native Ni-Fe, which is apparently a product of the serpentinisation process. Crystallisation of the Pt-Pd-enriched copper probably occurred at the same time, at low temperature, but the previous form of the Pt and Pd is unknown as no earlier PGE phases have been found. While Pt and Pd minerals are usually important in early-magmatic base-metal sulphides, Pt alloyed with Cu is extremely rare and apparently occurs only very late in the paragenetic sequence. A Cu alloy with Pd dominant over Pt and only minor amounts of other elements appears not to have been reported

Jun 14, 1905

By L. A. Cornish, L. H. Chown, S. N. Prins, R. Süss, L. Glaner, A. Douglas

Platinum-based alloys are being developed for high temperature and special applications for good corrosion and oxidation resistance. The microstructures are similar to those of nickel-based super alloys, and comprise ~Pt3Al particles in a Pt-based matrix. After assessing binary alloys, the best candidate system was found to be Pt-Al. Testing and selection of alloys based on Pt-Al were undertaken, where the ternary additions comprised Ru, Cr, Ta, Ir and Ti. As well as phase characterization work, mechanical and oxidation tests were undertaken. The best alloys were found to be Pt-Al-Cr and Pt-Al-Ru. However, the volume fraction of the ~Pt3Al was only around40 per cent instead of the ~70 per cent found in Ni-based super alloys. To increase this, trials were conducted on a range of Pt-Al-Cr-Ru alloys, the optimum composition being Pt80:Al14:Cr3:Ru3.Currently, further additions are being made to the quaternary alloys to change selected properties. As well as developing the alloys themselves, another part of the project is to compile a thermodynamic database using Thermo-Calc?. Phase diagram work has been undertaken so that the results can be input to Thermo-Calc? so that the descriptions of the phases can be optimized. The final database will allow the phases and compositions of selected alloys to be derived, thus predicting the alloys? components without necessarily undertaking further experimental work. This will aid the development of the alloys and will be a useful tool to the final developers of the alloys. Good agreement with experimental data has been observed, which is very encouraging for usefulness of the database. Keywords: platinum-based alloys, intermetallic compounds, high temperature

Jan 1, 2004

By J Mavrogenes, C J. Spandler, S M. Eggins, K Worden

Major occurrences of platinum group minerals (PGM) are in crustally-contaminated, huge, layered igneous complexes (Bushveld and Stillwater) and gabbroic intrusions (Norilsk); relatively minor occurrences include arc-related æzoned Alaskan ultramaficsÆ. In terms of arc-related provenances, the recognition of alluvial PGM in river and beach deposits of southern South Island (Mitchell, 1995), in situ in the Longwoods (Cowden et al, 1990), and the ultramafic-mafic layered Greenhills Complex at Bluff (Spandler et al, 2000) raise the possibility that some economically-significant PGM deposits may exist in New Zealand. The Longwoods and Greenhills are in the Brook Street Terrane which is a remnant of a primitive intra-oceanic arc system of Late Permian-Early Triassic age. The Terrane comprises volcanogenic sequences containing plagioclase- and clinopyroxenephyric basalts, high-MgO ankaramite and dolerite dikes, trondhjemite plutons, and basaltic to andesitic volcaniclastic and sedimentary rocks. The cumulate complexes contain early-formed olivine- and clinopyroxene-rich ultramafic cumulates overlain by anorthite and hornblende-bearing gabbros. Primary (isoferroplatinum) and secondary (sperrylite) platinum group minerals are preserved in chrome-rich spinel pods in basal dunite of the Greenhills Complex. Saturation during early fractionation of primitive high-MgO magmas rather than magma mixing seems likely for the primary PGM. Together with correlative terranes in Queensland and New Caledonia, the Brooks Street Terrane is an exposed cross-section of an extensive Permo-Triassic island-arc system. Most parental magmas were primitive island-arc tholeiites, but other primary magma-types include high-MgO ankaramites and trondhjemites û the latter formed by partial melting of lower crustal clinopyroxene-rich cumulates and gabbros, respectively. The parental ankaramites fractionated to form mafic-ultramafic cumulates and primitive to evolved melts of high-Al basalt to andesite compositions (Takitimus). The Brook Street Terrane is an analogue for modern intra-oceanic islandarc systems and allows detailed study of subvolcanic arc processes.

Jan 1, 2005

"10.1. IntroductionAs discussed by Westland (1981), the six platinum-group elements (PGE) belong to the Group VIII transition metals, to which iron, nickel and cobalt also belong. The chemical similarity between these nine metals accounts for the fact that they tend to be concentrated together as a result of geological processes. These processes started to effect the distribution of these metals at the very beginning of the earth's history.The first line in Table 1 gives the concentration of nickel and certain other Group VIII transition metals in carbonaceous chondrites, those meteorites with a composition that is believed to reflect best the composition of our planetary system apart from hydrogen and helium. The second line is the estimated concentration of the same elements in the earth as a whole. It is seen that these two estimates are quite similar, the earth being perhaps 2 to 3 times richer in these particular metals than the planetary system as a whole. The reason for this is not fully understood, but it may be due to the earth being formed by the accumulation and capture of a greater proportion of iron (and therefore siderophile-rich) than stoney (and therefore siderophile-poor) planetesimals than the planetary system itself.The third line in Table 1 is the average composition of the crust of the earth. With the exception of iron, all of the Group VIII transition elements are rare in the crust, present at concentrations of It tOO to Itt ,000 of that of the bulk earth. This is because the outstanding chemical characteristic of this group of elements is their siderophile nature; that is, their tendency to alloy with metallic iron. Because of this, once the earth became molten very early in its life history, these elements dissolved in the molten iron present at this stage and were removed from the outer accessible parts as this dense liquid sank to the centre of the earth to form the core. Although iron was the main instrument of concentration of the Group VIII metals, its much greater over-all abundance and its ability to combine with oxygen more easily than the others in the group means that significant amounts still remain in the oxidized portions of the earth.The fact that most of the Group VIII metals are available to use in workable concentrations at all is that they are 5 to 30 times more concentrated in the earth's mantle than the crust, as shown in line 4 of Table I. There has been a constant, if slow, interchange of matter between the mantle and the overlying crust throughout most of the earth's history and, under certain circumstances, this interchange has given rise to economic concentrations of metals."

Jan 1, 1979

By David D. Lambert

REE analyses of cumulate plagioclase from the PGE ore zone of the Stillwater Complex indicate that pressure fluctuations in the magma chamber acting on a single magma can- not be responsible for features such as the reappearance of Mg-rich olivine on the liquidus. The data is more consistent with a model involving multiple injection and mixing of geochemically distinct magmas. The PGE bearing sulfides of the J-M Reef are associated with such a re- appearance of olivine, indicating that the unusual location of the ore zone may be related to the addition of new magma, compositionally distinct from magmas that produced cumulates in the Ultramafic zone of the complex.

Jan 1, 1981