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By T Baumgartl, A Costine, B Boshrouyeh, M Edraki

In mineral processing, the management of tailings may become increasingly more challenging with a change of ore type and the quality of water used in the plant. This, in turn, may affect the overall costs of the operation and water usage and, in the long-term, pose challenges for mine closure and rehabilitation. Depending on the applied treatment technique, the short and long-term properties of tailings are largely determined by the fine particles. Most clay materials and ultrafine particles exist in tailings from oil sands, coalmines and base metals, bringing about challenges in dewatering performance. Moreover, given the growing concern for water scarcity, the minerals industry is increasingly turning towards the use of saline water, which poses yet another challenge for tailings management. The high salt content alters the behaviour of clay particles, making dewatering a more complex process than in freshwater systems (Boshrouyeh Ghandashtani et al, 2022; Costine et al, 2018). High-density techniques for tailings management have been used for several years in the mineral industry. In this regard, one of the novel and promising dewatering methods is in-pipe or inline flocculation, where the polymer is added at high dosages to thickener underflows, giving additional (likely denser) aggregation, releasing more water on deposition compared to low solids thickening. Previous research in the field of flocculation has primarily focused on the process of flocculation itself, specifically the settling rate and size of aggregates, rather than the long-term impacts of the produced tailings materials (Liu et al, 2020; Jeldres et al, 2017). This is particularly true for the novel method of this technology, where polymer is added to the thickener underflow. Furthermore, these studies have used small-scale set-ups using buckets/beakers, plungers and mechanical stirrers for the flocculation process. Unfortunately, these methods lack the necessary control over the properties of the treated tailings, which can lead to irreproducible mixing and dispersion of viscous polymer solutions (Fawell, Costine and Grabsch, 2015). Consequently, a system that can work with a wide range of operational conditions for high-solid tailings material is essential for reliable and reproducible results. The objectives of this study were to determine the effect of different type of polymers in the presence of monovalent and divalent salts on the inline flocculation of artificial tailings. The next step was to evaluate the impact of high-dosage polymer addition on geotechnical properties such as settling rate, consolidated density, rate of consolidation and the hydraulic conductivity of tailings. In addition, this research aimed to fill a knowledge gap and investigate the feasibility of using polymer-treated tailing in removing the copper ions and then quantify the performance of produced aggregates under time-dependent processes.

Aug 2, 2023

By J Nemcik, E Baafi, I Porter, G Spinks

Spray-on liners used in the mining industry for ground support and stabilisation applications are either cement based (æshotcreteÆ) or polymer based (æthin spray-on linersÆ). Some thin spray-on liners are a blend of both polymer and cement (eg Tekflex). A small number of thin spray-on liners (TSLs) have been trialled in Australia as potential replacements for steel mesh in roadways and other underground mining applications; however, they were found to cure slowly and the cured coatings became brittle after an extended time in place. The University of Wollongong in collaboration with the Australian coal mining industry has shown that a viable polymer-based alternative to steel mesh in underground roadway support applications can be developed to eliminate the use and handling of steel mesh. The work to date has: established the feasibility of developing polymeric alternatives to steel mesh in underground roadway support applications; identified the physical and material constraints to be endured by any new polymeric skin reinforcement system by measuring the mechanical properties of steel mesh; identified materials that can be spray applied; and demonstrated that polymer mechanical properties can be optimised to produce similar mechanical properties (elastic modulus, yield stress, elongation-at-break, etc) to steel mesh. The identified materials will: allow the face support cycle to be fully automated, or at least remotely operated and installed; remove personnel from the immediate face area; and substantially improve underground roadway development rates.

Jan 1, 2008

By William Cowan, Robert Spencer, Lynn Carpenter

INTRODUCTION The Bureau of Reclamation is conducting a research program to investigate, develop, and test polymer-impregnated concrete tunnel support and lining systems for gravity flow, circular cross-section water conveyance tunnels. This system consists of segmented precast rings, backfilled with concrete. Polymer-impregnated concrete is conventional precast concrete which has been impregnated with a liquid monomer. The liquid monomer is subsequently converted to a polymer by thermal-catalytic or radiation methods. The polymer is a solid plastic which fills voids and microfractures within the concrete, resulting in greatly improved strength and modulus of elasticity and reduced permeability, which in turn increases the durability of the concrete. The immediate goals of the program are to develop techniques for the fabrication of precast concrete segments, test single segments to determine physical and mechanical properties, assemble the segments into a support and lining system, load and test the full-scale system, evaluate specific applications, and develop design criteria and construction procedures. NEED FOR THE TEST PROGRAM Modern rapid underground excavation technology emphasizes desirability of supporting and lining a tunnel closely behind the heading without reducing the excavation rate. Therefore,

Jan 1, 1997

By Yuchun Wang

In principle, supported liquid membranes could be an exceedingly elegant separation process. However they tend to fail by displacement and emulsification of the organic solution in the pores, which allows mixing of the feed and strip solutions. We have stabilized supported liquid membranes comprising moctylamine in nylon and PVDF supports by covering the pores with semi-permeable polyamide films, using an in-situ polymerization technique. Scanning electron microscopy demonstrates that the polyamide films are sensitive to production conditions and the nature of the support. The transport properties of stabilized supported liquid membranes for Cr(VI) are compared with those of unstabilized membranes.

Jan 1, 1998

By J. J. Robertson, D. M. Polizzotti

Cement is used as an established agglomerating agent in gold heap leaching operations to maintain heap permeability and prevent migration of fines. In addition to agglomeration, cement provides protective alkalinity control. However, the amount of cement needed for agglomeration is usually very different from the amount necessary for pH control. As a result, cement is usually added in excess. Overdose of cement can result in reduced gold recovery and/or lengthy detoxification. Betz Laboratories has identified polymeric agents that provide the benefits of cement without negatively impacting gold recovery when used alone or with lime. Independent laboratory tests also strongly suggest that the polymer/lime system can significantly reduce heap detoxification time.

Jan 1, 1992

By P. Braga, A. Chaves, S. França, A. Luz

"In Brazil, there are no official reserves of molybdenum, and the unofficial reserves are modest. Therefore, the molybdenum ore (molybdenite) produced as a co-product or by-product of emerald mining in the region of Campo Formoso, BA, has arisen as the only economic option. The flotation process is commonly used in Brazil for the recovery of molybdenite from emerald mining tailings, but it produces low-content molybdenite concentrates, thereby resulting in a product with low economic value. The molybdenite concentrate produced in Campo Formoso contains 83.5% MoS2 (50% Mo), which is less than the international standard product that contains > 90% MoS2 (54% Mo).This low value is due to the presence of talc, which is a naturally hydrophobic mineral that is also floated with the molybdenite during the flotation process. Separability studies were done in a Partridge-Smith cell using dextrin and quebracho as a molybdenite depressor in solution at different concentrations and pH values to produce a technical-grade concentrate (i.e., 90% MoS2). These basic studies were accompanied by measurements of the zeta potential and contact angle, which was determined by the capillary rise method. The results of these floatability studies were used in bench flotation tests, which were performed in a Denver laboratory flotation cell. A molybdenite concentrate of 93.4% MoS2 was obtained when dextrin was used at a concentration of 100 g/t."

Jan 1, 2014

By M. B. Freeman

Acrylic polymers have been found to be effective dispersants and stabilizers in a wide variety of mineral processing applications including rheology control in concentrated slurries. This paper will describe these low molecular weight, water-soluble polymeric dispersants and provide a basis for how they function in concentrated slurries based on computer molecular modeling and applications results. Data on homopolymers as well as copolymers of acrylic acid will be presented to demonstrate the optimization of a polymeric dispersant in preparing high solids slurries of inorganic materials such as kaolin, calcium carbonate, lime, and magnesium hydroxide.

Jan 1, 1996

By J. C. Franklin

The Bureau of Mines substantially reduced shale degradation in a coal mine by two spray coat applications of a water-base epoxy sealant. More than 12,700 square feet of passageways were treated, and in 18 months only one failure occurred. This failure was due to improper spray application, Material costs averaged 13 cents per square foot, and labor costs were 7 cents per square foot. Labor included moving all materials into the mine, the setup time for each of the areas coated, and application of coatings.

Jan 1, 1977

By G. L. Schroeder, C. H. Summers, D. B. Lindsay

INTRODUCTION The requirement that is placed on owners and operators of underground mines to protect workers against the health hazard of inhaling radioactive materials which are short-lived decay products of 222Rn can be satisfied by applying a considerable variety of what we may call "engineering" solutions as well as a number of "administrative" remedies to the problem. The most obvious of the "engineering" approaches has always been that of forced ventilation, in which relatively clean (i.e., radon-free) air from aboveground is drawn or pushed through the mine workings by a system of fans and ducts. This relatively clean air, in sweeping through the drifts, stopes and haulageways, dilutes the radon and radon-daughter concentrations in the air of the mine, and performs the added beneficial function of removing the daughter-mixture quickly enought to limit grow-in of the longer-lived nuclides in the group that make up the "toxic trio" on which the Working Level (IM) unit is based. Effective as the dilution-ventilation method is for control of WL in most underground mining situations, however, the increasing strictness of control measures that have been imposed on the mining industry over the last two decades have demanded measures of even greater effectiveness. In times of poor markets for yellow-cake and other products of the mines, mine operators are pressed to reduce operating costs, and the installation of additional primary ventilation capacity can be a severe burden on a mine that is already laboring under an unfavorable earning power. When traditional dilution-ventilation systems alone cannot meet the requirement for WI, control, radiation safety engineers and ventilation engineers begin to look at alternatives and auxiliary methods. Since the radon which produces the toxic daughter products originates in the rock of the mine walls, and since, in most United States mines, that rock is a porous sandstone through which air can move under the effect of atmospheric pressure gradients, and through which radon can diffuse relatively freely, one way to help control the growth of WL would be to hinder the escape of radon from that reservior of porous rock. An appealing; method for hindering that natural flux of radon-polluted air from the walls of the mine has long been apparent; namely, to apply a low-permeability coating over the surface of the rock, thus sealing the radon in place and, in theory at least, preventing its escape into the mine air. Our 1970 report to the U.S. Federal Radiation Council on the subject of cost impacts of proposed changes in the occupational standards for exposure of underground uranium miners to airborne radon daughters noted the possibility of using polymeric wall sealants as a means of controlling radon-pollution of mine air. Since that time a number of reports have appeared in the technical literature advocating this technique for restraining the escape of radon from building materials, mill tailings, and other materials containing 226Ra, in addition to the surfaces of underground mine workings. During this period, some controversy has occurred over the question of the probable effectiveness of wall sealants in limiting the escape of radon from the rock. Our 1970 report speculated that flaws (cracks and "pinholes") in the coating might be all but unavoidable in practice, and that even a conservative estimate of the frequency of such flaws would lead to a prediction of ineffectiveness. Hammon et al, in a laboratory evaluation of radon sealants conducted by Lawrence Livermore Laboratory of the University of California in 1975 on behalf of U.S. Bureau of Mines, concluded that a wide variety of polymeric coatings would provide "nearly 100% effectiveness" in restrain¬ing escape of radon from mine wall surfaces if applied in "thicknesses between 5 and 10 mil" (125-250 [y]pm). John Franklin and co-workers at the U.S. Bureau of Mines laboratories in Spokane, Washington, have carried the experiments with polymeric sealants through additional laboratory tests and into actual mine environments, reporting that selected sealants could provide attenuation of radon flux by a factor of four (75-80% reduction). Robert Bates and John Edwards of USBM developed a computer-assisted mathematical/physical model that predicts a relatively small effect of flaws in a low-permeability coating on the radon flux from a sandstone-type matrix. FIELD TEST Since all actual experimental work with wall sealants showed some beneficial effect on radon attenuation (even if not as exciting as the "nearly 100%" predicted by Hammon), USBM was encouraged to extend its evaluation to an actual operating uranium mine, and awarded a contract for that work to Arthur D. Little, Inc. in September 1979. We were fortunate in obtaining the voluntary cooperation of Atlas Minerals Division of Atlas Corp., who operate a mill and several underground mines in and around Moab, Utah. Atlas made available for our use a small T-shaped drift in their Pandora Mine in LaSal, Utah, and provided space for instrumentation and recordkeeping by our field crew in a surface building near the mine entry. Atlas also provided electricity and water to the test site, together with assistance in establishing necessary ventilation, removing rubble from the site, conducting periodic WL surveys and furnishing auxiliary man-power for the heavy hard work of coating the walls with gunite prior to application of the polymeric sealant. The generous coopera-

Jan 1, 1981

By Michael A. Markowitz, Alok Singh

"Molecular self-assembly of phospholipids and other amphipathic molecules offers a versatile approach to form self-organized microstructures in various morphologies. Stabilization of microstructures in specific morphologies by polymerization renders them useful for practical applications in areas ranging from controlled release technology to template mediated synthesis of metals. Our efforts are focussed on the development of polymerizable biomembranes derived from phospholipids, their properties and utility e.g., as stable templates for studying chemistry at the lipid interface. Polymerized vesicles formed from mixtures of 1,2-bis(tricosa-1 O,12-diynoyl)-sn-glycero-3-phosphocholine, 1, with corresponding lipids having phosphohydroxyethanol,2, or -hydroxypropanol,3, headgroups have been used in electroless metal plating of vesicle surface with gold utilizing selective binding of Pd(NH3)4 2 + to 2 or 3. The surface bound palladium ion served as catalyst for metalization. Metalization of polymerized vesicles constructed from charge neutral diacetylenic phosphocholine,1, did not occur using this process. The headgroup structure of the negatively charged phospholipids and the degree of vesicle polymerization had an effect on the stability of the vesicles after metalization. Vesicles formed from a mixture of 1 with polymerizable diacetylenic phosphatidic acid, nonpolymerizable 1,2- dipalmitoyl phosphohydroxyethanol or 1,2-diacyl phosphohydroxyethanol (from soy lecithin) were not stable to metalization process. The metal coating of the vesicles was examined by electron diffraction and revealed that the gold metal on vesicles was polycrystalline and face centered cubic. The results demonstrate the utility of polymerized synthetic membranes as template for easy and efficient synthesis of nanoparticles. IntroductionPhospholipids, synthetic or natural, provide a simple and straight forward route to construct membranes in a variety of morphologies due to their inherent property of selforganization in the presence of water[1]. Vesicles are closed spherical structures comprised of concentric walls made from lipid bilayers. Vesicles are morphologically simple structures with enormous technological potential. Polymerizable phospholipids prepared by incorporating a polymerizable group in the molecules demonstrate physical properties comparable to their non-polymerizable counterparts and have the added virtue of providing enhanced physical and chemical stability to the membranes[2,3]. The size, shape and properties of the organized assemblies are dependent on the lipid structure and the nature of the aqueous environment[4,5]. The headgroup geometry, surface charge density, and spatial arrangement of the phospholipids are known to affect the surface behavior of the lipid membranes, which is evident through their interaction with other molecular (hormones, antigens, antibodies etc) or lomc species. Since phospholipid headgroup structure and charge can be modified either synthetically or by chemical perturbation of the aqueous medium (e.g., pH or ionic strength), phospholipid membrane surfaces offer a potential for developing novel strategies in those areas which involve the use of molecular reactive sites. One such strategy which could be envisioned explores the use of molecularly engineered phospholipid assemblies to design and prepare template structures to regulate formation of ordered materials [6]."

Jan 1, 1994

By Rosario Lunar, Jesús Martínez-Frías, Egidio Marino, Trinidad Torres, Jose E. Ortiz, Juan A. Martín-Rubí, Luis Somoza, Ricardo León, Teresa Medialdea, Javier González

Seamounts, submarine banks, volcanoes and undercurrent channels are prominent geomorphic features that have become an important target for minerals research and exploration with the goal of future exploitation. Polymetallic ferromanganese deposits are common types of mineralization on these settings. Co-rich ferromanganese crusts are important as potential resources of Mn and Co, but also Ti, Ni, Tl, REEs, PGEs, and other metals. Many seamounts and channels along the Atlantic Spanish continental margin are known to hold mineral deposits but are poorly studied. This work presents and briefly describes the most recent activities of the Spanish Geological Survey (IGME) on exploration and investigation of ferromanganese deposits along the Atlantic Spanish continental margin. Different submarine areas from the northwestern margin of the Iberian Peninsula to the west off Canary Islands have been surveyed by geophysical, sampling and underwater observations from 89 to 4000 m water depth. The mineral deposits cover a large diversity of submarine geological and geomorphical features: mud volcanoes and diapirs related to hydrocarbon seeps, seamounts associated with hot spot volcanism, hydrothermal vents in active magmatic volcanoes, structural basement highs and banks or contourite channels. Considering the collected dataset, we present the preliminary results of the study of these mineral deposits, including ferromanganese nodules and crusts and phosphate pavements and nodules, which can be considered as potential sources of raw materials.

Sep 1, 2014

By M K. de Brodtkorb

Late Cenozoic ore deposits æPrecious and base metal-richÆ and æSn-Ag-polymetallicÆ ofNorthern Puna are associated either with Middle Miocene dacitic volcanic-dome complexes or with Upper Miocene dacitic-andesitic volcanic centres.   Ore mineralogies and their related volcanism are discussed. A strong link is observed between the Cenozoic Metallogenetic Province of Northern Puna and the Southern Bolivia Tin and polymetallic provinces.  

Jan 1, 1995

By de Brodtkorb MK

Late Cenozoic ore deposits "Precious and base metal-rich" and " Sn-Ag-polymetallic"of Northern Puna are associated either with Middle Miocene dacitic volcanic-dome complexes or with Upper Miocene dacitic-andesitic volcanic centers. Ore mineralogies and their related volcanism are discussed. A strong link is observed between the Cenozoic Metallogenetic Province of Northern Puna and the Southern Bolivia Tin and Polymetallic provinces.

Jan 1, 1995

By Tracey A. Conrad, Mark E. Mussett, Max Kaufmann

The varied benthic habitats of the Pacific Ocean are comprised of different types of seafloor geology. These geologic domains generally consist of sedimented abyssal hills, high relief features such as seamounts, and polymetallic nodule fields that vary in spatial extent and abundance. Nodules represent a deep ocean habitat type, and are of economic interest owing to their metals content. Multibeam data can be used to classify seafloor geology. The wide swath of hullmounted multibeam systems used in deep water provides efficient coverage of large areas of seafloor. Our research examines how multibeam backscatter and bathymetry data, with regional environmental parameter assessments and GIS analysis, can help identify probable polymetallic nodule fields in the deep remote ocean prior to groundtruth seafloor observations. A workflow for processing 30 kHz hull-mounted multibeam data within QPS Qimera and FMGT software was developed to facilitate multibeam processing, while also generating a terrain model and backscatter products. An additional GIS protocol for evaluating multibeam data products, including cluster analysis, was also developed. These methods were applied to a test case of publicly available multibeam data collected by the Ocean Exploration Trust and NOAA. Processed multibeam products were used to identify areas exhibiting coarse sediment backscatter characterization with low relief; filters for water depth at or below the regional CCD, seafloor age, and sedimentation rate were then applied. Sophisticated GIS cluster analysis further identified trends within the data to forecast where coarse sediment domains, potentially including nodule occurrences, exist. The test case multibeam data allow determination of the composition and variability of seafloor geology. This analysis can further identify where previously unexplored nodule fields may exist and edify estimates of nodule extent throughout the ocean. The research methods and outcomes contribute to marine spatial planning, ecosystems modelling, and mineral resource management initiatives.

Feb 22, 2026

By Jan Magne Markussen

The aim of the paper is to analyze the viability of commercial exploitation of polymetallic nodules, the time aspect for exploitation and the probable organization of commercial projects. METHOD My methodological point of departure is to view the various factors in context, and to differentiate between the various groups of actors. This involves taking as my starting point the interaction that exists between economics, technology, politics, law, the environment, and even psychology and ideology, and acknowledge that the various actors may well have differing motives for their engagement.

Jan 1, 1992

By U. Schwarz-Schampera, C. Rühlemann, H. -R. Kudrass

Within 2006 BGR will conclude a contract with the UN International Seabed Authority (ISA) for the exploration of polymetallic nodules. The contract covers an area in the Pacific nodule belt between the Clarion and Clipperton fracture zones, that which is about 75.000 km2 in size at water depths between 4200 and 5000 m (see Fig. 1). Up to now, 7 consortia or state parties have acquired similar exploration “licenses” for polymetallic nodules in the central Pacific Ocean and the Indian Ocean. These licenses of the UN authority are required according to the UN convention on the law of the sea (UNCLOS) as the areas of interest are located outside of national EEZs. The “licenses” then reserve exclusive rights to the applicant for a time span of about 15 years.

Aug 24, 2006

By Darryl Thorburn

The Cook Islands are 15 islands located in the Southwest Pacific (between 8-23°S latitude and 156-167°W longitude). The total land area is about 200 km2. However, because its islands are widely scattered, the EEZ of the Cooks encompass an area about 2 million km2. The Cook Islands government exercises sovereignty and jurisdiction over its EEZ according to international law and convention as a member state under UNCLOS1. Accordingly, the Cook Islands government exercises full control over resources in its EEZ, including minerals on the seabed. Decision making on allocating licences for exploration and ultimate mineral recovery is by the Cook Islands government and will be set out in relevant statutes. Seabed minerals investigations within the EEZ of the Cook Islands and adjacent waters were first carried out by, USSR, US, and New Zealand research vessels in the late 1960 early 1970?s and indicated the presence of high concentrations of manganese nodules. This early work was followed by a number of Government funded surveys in and adjacent to the Cook Islands EEZ These surveys have identified a world class resource of manganese nodules within the Cook Islands EEZ (CI EEZ), containing significant

Sep 14, 2011

By Alexander Malahoff

Mineral zonation studies were conducted on hydrothermal vents of two hot spot volcanoes. One study site is located within the Axial Caldera of the axial hot spot volcano of the Juan de Fuca Ridge. The young high-temperature hydrothermal vent field consisting of two polymetallic sulfide chimneys, five meters high, located at 130°01.5'W, 45°56.5'N, along a fault complex at the base of the southwestern wall of Axial Caldera was sampled during four ALVIN dives in 1983. Temperatures of up to 270°C were measured within the orifice of one of the chimneys, which was then broken off and recovered with the submersible. Both black and white "smoke" was observed to be emanating from the one chimney sampled. The high-temperature chimney extends directly from a field of broken lobate lavas which are located at a water depth of 1,550 meters, about 200 meters east of the caldera wall. The chimney makes one of the shallowest active high-temperature vents studied to date. The vent is surrounded by clumps of vestimentiferan worms and is located within an elongate field of red-colored iron smectite blankets and chimneys. The low-temperature field forms a ribbon 150 meters wide, extending for about 1,300 meters at the base of the wall. Chemical analyses of the hydrothermal deposits ranging from the polymetallic sulfides of the chimney to the outer zones of the low-temperature field show a range of elemental assemblages consistent with temperature zonation around the vent. Chemical zonation within the high-temperature

Jan 1, 1988

By J. P. Mogan, E. D. Dainty

Polynuclear aromatic hydrocarbon (PAH) levels were measured in underground mines in the vicinity of diesel vehicles equipped with several types of emission control hardware. In general, the emission control devices appeared to reduce PAH levels, but the companion mutagen study suggested that the reduction might not always be beneficial. All underground PAH concentrations were below the threshold at which a significant impact on health might be expected, but recent animal exposure studies have indicated that PAHs may not be the primary hazard from chronic diesel fume exposure.

Jan 1, 1994

By A. J. Faulds, K. C. Westaway, Z. Waszczylo

"PAH compounds have been found in the exhaust from all types of engines burning hydrocarbon fuels . They have also been found in the air over cities and in water. The authors report on a study to assess the concentrations of twelve different PAH compounds in several different environments in dieselized underground mines. In addition, the differences in the PAH levels and distributions in different mines will be demonstrated. Finally, the influence of blasting and the type of diesel engine used as well as the effect of catalytic converters in the exhaust system on the PAH concentration in the mine will be discussed.IntroductionMining methods have been altered significantly in the last 25 years; i.e ., the tools and machinery used underground have changed from electrically operated trains and other equipment to diesel-powered equipment. This has been done for several reasons: 1) economics, 2) convenience and 3) safety. Today, most mines are heavily committed to using diesel equipment.Although the introduction of diesel equipment has revolutionized mining methods and has been a tremendous boon to the mining industry, it has also created new problems. These problems arise because the exhaust from diesel engines contains several pollutants which can be hazardous to the health of the miners. These pollutants are CO2, CO, NO., SO2, oxygenated hydrocarbons produced during the buring process and unburned hydrocarbons. There are two classes of hydrocarbons, of which polynuclear aromatic hydrocarbons (PAHs or PNAs) are a part."

Jan 1, 1981