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By C. W. Won

a-etchant solution is the waste material obtained during the etching by ammoniacal solution of printed circuits for PCs. This material contains a substantial amount of copper (13-14%) but is usually discarded after neutralization. In this work, copper recovery from such solutions by electrowinning or cementation using iron scrap was tested. For each method, the effects of temperature, solution pH, initial copper-ion concentration, and reaction time were investigated to obtain optimal conditions for copper recovery.

Jan 1, 1993

By K. J. Cathro

A hydrometallurgical process is described for the recovery of copper from chalcopyrite concentrates. The process is based on a cupric chloride leach, the concentrate having first been "activated" by heating it with sulphur at a temperature near 400°C. This activation process converts most of the iron of the chalcopyrite to pyrite, which is insoluble in the cupric chloride leachant. The copper is converted to the mineral idaite, which dissolves readily in hot cupric chloride: at 106°C, 98% of the copper is extracted in a three-stage countercurrent leach, the leaching tirqe being 1 hour per stage. The sulphur of the chalcopyrite appears as elemental sulphur, which is recycled for the activation of further concentrate, the final leach residue consisting of pyrite, plus the gangue present in the original concentrate. The copper extracted can be recovered by electrowinning, using a diaphragm cell. Current efficiency (one-electron basis) is about 70% but the cell voltage is only about 1 V, so that power consumption is three times lower than for the conventional sulphate electrowinning process. The leachant is simultaneously regenerated in the anode compartment. The behaviour of minor elements in the concentrate has also been studied.

Jan 1, 1976

Extraction of copper from a chalcopyrite concentrate by means of a cupric chloride leach is described. Initially the concentrate is mixed with sulphur in a 9: 1 ratio, and heated to 350-400°C. This converts the chalcopyrite into more readily soluble sulphides, while the iron rejected from the chalcopyrite is transformed to pyrite, which is insoluble in the leach solution employed. A two-stage countercurrent leach using a leach solution of 1 M cupric chloride, 3.5 M sodium chloride, and 1 M hydrochloric acid extracts 98 per cent of the copper, if conducted at 105°C. Iron extraction is relatively low, the mole ratio of iron to copper extracted being 0.17, compared to 1.0 for unreacted chalcopyrite. After dissolution, copper can be recovered by electrolysis, cupric chloride leach solution being regenerated at the anode.Electrolytic power requirement is low, being approximately 0.5 kWh per kg of copper. The sulphur and, most of the iron entering as feed are rejected from the process in the form of pyrite, which remains in the leach residue.

Jan 1, 1974

By G. L. Craig

In order to meet the unprecedented demand for copper it has proven necessary not only to develop every primary source, but also thoroughly to exploit the vast reservoir of metal in use that is not directly serving the war effort. To accomplish this, industry has been called upon to use its resourcefulness for developing methods of recovery that have not been previously utilized. It is in this connection that we have been asked to review the methods suggested for recovering the basic constituents of various types of the so-called clad or composite steels. As a background for a discussion of recovery processes, it seems appropriate to consider clad materials in general and their processes of manufacture. A composite steel has been defined as one consisting of two or more component parts of which the smallest shall comprise at least 3 per cent of the total mass. Clad materials or composites are produced commercially by several different methods of which the most important may be classified as: I. The Blacksmith or Forge Weld Method. This method is limited to carbon steels or low-alloy steels as the presence of even small amounts of common alloying metals prevent the formation of a satisfactory weld. The principle is the application of pressure to sections in contact at elevated temperatures. Because of the tendency of the iron to oxidize, borax is generally used as a flux to absorb the iron oxide. 2. Casting Process-In this method a composite ingot, billet or cake is produced by pouring one metal onto or about another. The bond may be accomplished by the action of the molten metal against a solid, in which case the bond may be referred to as mechanical; while in other instances alloying occurs at the interface producing an anchor by the formation of component parts of the two materials. 3. Cementation Process.-In this process any number of combinations of metallic and nonmetallic constituents which are mixed together may be used as a bonding agent. The combinations, whatever they may be, are placed between the materials to be joined and subjected to pressures at elevated temperatures to produce the desired bond. 4. Fusion Welding Processes.-Gas and electric joining for direct use or subsequent fabrication. 5. The, Assembly Process.-This method involves the joining together of prefabricated bars or plates followed by hot and/or cold working the assembly to the desired finished form. This method is advantageous in many cases because of its flexibility on small quantities as compared to the casting method. It is also possible to control the relative proportion of components more accurately. In this discussion we are concerned only with the scrap resulting from the manufacture of clad materials and our interest,

Jan 1, 1943

By G. M. Ritcey

The recovery of copper from low-grade solutions res ulting from dump leaching is well known, whereas the recovery from highly concentrated copper solutions has not been practiced. This paper discusses the use of Ashland Chemical's Kelex 100, a substituted quinoline, for the recovery of copper from solutions resulting from leaching copper-nickel concentrates. A flow sheet is described, and an economic comparison shows Kelex 100 to be superior to either the LIX 64N or LIX 70 reagents of General Mills for the recovery of copper.

Jan 1, 1973

By V. Prabhu, D. Mantha, R. Reddy

Secondary copper blast furnace slag was treated with carbon to derive the conditions for maximum recovery of copper with a minimum simultaneous reduction of iron oxide. Experiments were carried out to study the effect of temperature, carbon and CaO additions to the slag on the efficient recovery of copper. A two-stage reduction process was also employed to study the efficiency of copper recovery and the results were compared with those of single-stage reduction. The maximum recovery of copper in alloy phase was obtained with 5 % initial carbon in the slag, 2% CaO addition to the slag and at a reducing temperature of 1573 K. Higher grade of the alloy phase with respect to copper was obtained by employing a two-stage reduction process. The results obtained in this study are comparable to those of the earlier research on the recovery of copper from reverberatory furnace discard slags.

Jan 1, 2004

By L. G. Evans, W. W. Simpson, W. A. McKinney

In conventional dump leaching of strip wastes from open-pit porphyry mining operations, many years are required to extract a fraction of the copper from the contained sulfide minerals. Furthermore, none of the molybdenum, gold, or silver is recovered by current leaching practices. Because the copper sulfide minerals and molybdenite generally are distributed in the minute fractures throughout the host rock, the mineral values tend to concentrate in the finer fraction of the strip material. This suggests the possibility of segregating the enriched fines in as-produced or coarsely crushed strip wastes for blending with the ore grade flotation mill feed. In the past, extra handling or crushing of mine wastes to enable better leach extraction has been deemed uneconomical. However, recent articles on mobile crushing plants and conveyor haulage systems indicate possible cost improvements for these techniques over conventional truck haulage of ore and mine wastes. Another potential benefit from removal of the fines from copper-bearing mine waste derives from the increased permeability of the coarse dump material to leach solutions and air. Better permeability should result in faster oxidation of the sulfide minerals, less channeling of leach solutions, and fewer perched solution tables caused by compacted fines. Therefore, in addition to the metal values recovered by flotation, higher copper recoveries by leaching also might be achieved. The Salt Lake City Metallurgy Research Center of the U.S. Bureau of Mines undertook an investigation to determine the feasibility of removing enriched fines from strip waste material for separate treatment by froth flotation for early recovery of part of the copper, molybdenum, gold, and silver. Percolation leaching tests were made on mine-run and sized fractions of the dump material to determine the effect of fines removal on copper extraction. Samples Tested Three 10-ton samples of copper sulfide-bearing mine waste were obtained for the investigation. Partial chemical analyses of the samples are given in [Table 1] and the consolidated results of detailed screen analyses made on the samples are given in [Table 2]. The -1/4-in, fine fractions contain from 16 to 32% of the copper and 19 to 40% of the molybdenum in 11 to 18% of the total waste. The samples also were crushed to -3 in. to determine the feasibility of crushing to obtain a higher distribution of the metal values in an enriched fine fraction while providing a more leachable coarse fraction that could be transported by a conveyor system to a dump. The -%-in. fine fractions screened from the crushed mine waste were almost identical in grade to the natural fines. From 2 to 4% more1/4-in. fines were produced by crushing to -3 in. Copper distribution was increased by about 3% over that in the natural fines, while molybdenum distribution was increased by about 10%. The -1/4-in. fines screened from the mine-run and crushed strip waste were almost as high in grade as the ore being treated at the mills. In addition, the fines

Jan 1, 1974

By W. A. McKinney

In conventional dump leaching of porphyry mine strip wastes, many years are required to extract up to 20 percent of the copper from the contained sulfide minerals. Furthermore, none of the molybdenum, gold, or silver in the strip wastes is recovered by current leaching practices. Because mineralization occurs predominately along fracture planes, breaking of the rock during mining operations liberates and concentrates some of the metal values in the fines. Research shows that upgraded fines can be screened from mine wastes and froth floated for early recovery of copper, molybdenum, gold, and silver. For example, screening a dump sample assaying 0.35 percent copper as chalcopyrite removed about 20 percent of the copper as minus 1/4-inch material that analyzed 0.6 percent copper. About 35 percent of the molybdenum and 20 percent of the gold and silver also reported in the fines. Crushing the mine dump sample to minus 3 inch before screening increased the distribution of copper and molybdenum in the minus 1/4-inch screen fraction to 28 and 50 percent, respectively. Similar results were obtained by screening fines from two other large samples of mine waste dump materials. Flotation studies established that the enriched minus 1/4-inch fines from the three dump samples could be effectively concentrated. Comparative testing revealed that the combination of froth flotation of fines and acid-ferric sulfate leaching of the coarser fraction enabled doubling the recovery of copper over direct leaching of the samples. In addition, significant amounts of molybdenum, gold, arid silver were recovered by flotation.

Jan 1, 1970

By J. F. Edwards

In situ extraction of copper through borehole injection presents a new technology for the mining of copper. For the successful application of this technology, copper recovery at the surface must be specifically designed for borehole injection and the general conditions of the well field. This paper describes the design of a solvent extraction / electrowinning facility specifically designed for in situ leaching of copper. This design is based on commercial solvent extraction / electro-winning with considerations of the requirements of this specific application.

Jan 1, 1988

By R. G. Reddy

Industrial copper reverberatory furnace slags were treated by high temperature techniques (sulfide and carbothermic reduction) to recover copper in alloy or matte phase at 1473K. Recovery was investigated for the condi¬tions of varying amounts of metallic sulfide, carbon and CaO additions. The results showed that recovery of copper increased with increasing amounts of carbon addition, and also is strongly dependent on the initial concentration of copper in the slags. Copper recovery for both carbothermic reduction and sulfide treatment were modeled with linear relationships as follows: for carbothermic reduction (%Cu recovery) = 9.0 (%Cu in slag)initial 73.8 and for sulfide (%Cu recovery) = 7.1 (%Cu in slag)initial 82.2 Higher copper recovery was obtained with sulfide treatment than with carbothermic reduction of slags.

Jan 1, 1983

By G. H. Sedahmed, S. A. Nosier, M. H. Abdel-Aziz, A. A. Mubarak, M. A. El-Naggar, E. G. Abdel-Aziz

The performance of a rotating fixed bed reactor in recovering copper from industrial waste solutions by cementation is studied under various conditions. The rotating fixed bed is made of stacked woven steel screens to take advantage of two features of screens: the ability to present large area per unit volume and their ability to promote high turbulence. Variables studied are initial CuSO4 concentration, bed rotation speed, mesh number of the screens and bed thickness. The presence of baffles was found to increase the rate of cementation. The data were correlated by a dimensionless mass transfer correlation suitable for the design and operation of large scale cementation reactors.

By K. N. Han

Copper and nickel are extracted from their elemental state, complex sulfides, ores, and other materials such as scrap by leaching them with a solution containing halogen salts - bromine/bromide, and/or iodide/iodine, oxygen and sodium or potassium nitrate. This US patented process is extremely effective yielding 98% recovery in15 minutes for the treatment of chalcopyrite and pentlandite in an autoclave at a temperature of 100°C - 150°C.

Jan 1, 2003

By Chowdhury P. J R, Biswas S. K

Recovery of metallic values from lean-grade raw materials as well as from secondary/intermediate industrial products is of immense importance to a country like India which is not endowed with extensive sources of copper and nickel. The results of a few studies carried out in this area are described in Part-I and Part-II in this article. A novel anode casting system, specially designed for a small copper refinery which had been set up to produce copper wire bars/rods is described briefly in Part-III.

Jan 1, 1992

By J. A. S. Tenorio, A. B. Botelho Junior, I. A. Anes, D. C. R. Espinosa, M. A. Caralho

Recovery of metals from reserves with low grade and from waste with high presence of contamination is a challenge to be overcome. Metals like nickel, cobalt and copper could be recovery from nickel laterite leach waste by many different processes. Among recovery processes that could be applied are ion exchange, solvent extraction and precipitation. The aim of this work was recover copper from liquor of nickel laterite by precipitation using chemical reduction. Copper concentration in liquor was 146 mg L −1 and reducing agent used was sodium dithionite 1 mol L −1. Influence of stirring speed was studied between 0–200 rpm. Results indicated a selective precipitation of copper on solution with others metals at 240 mV. The analyzes were conducted in SEM, energy-dispersive X-ray spectroscopy and XRD, that indicated presence of copper and sulfur.

Mar 1, 2018

By Gary A. Kordosky

Winning copper from oxide ores usually involves hydrometallurgical techniques. The processes involved are the leaching of copper from the ore and the recovery of the leached copper from the aqueous solution.

Jan 1, 1981

By G. B. Harris

A process for the recovery of copper from the waste oxide copper of a mined-out sulphide orebody is described. Hydrometallurgical recovery of copper from this and similar wastes has been tried several times previously without success. Leaching is carried out by sulphuric acid in columns under conditions that minimise the iron content of the pregnant leach liquor, and copper is then recovered by ion exchange rather than the more conventional solvent extraction. The resin is stripped by spent electrolyte and copper is electrowon. Results are presented for testwork originally carried out in 1993, and repeated in 2006, and the novel aspects of the process, leaching and ion exchange, are discussed. Finally, preliminary order of magnitude capital and operating costs are given, demonstrating that the process is cost effective.

Jan 1, 2007

By M. Tanaka, T. Oishi, K. Koyama, S. Alam

"A novel hydrometallurgical process for copper recovery from waste printed circuit boards has been proposed, which consists of selective leaching of copper metal as Cu(I) by Cu(II) in ammoniacal alkaline solution, purification, and electrowinning. The distinct feature of this process is much lower power consumption during the electrowinning than that during the conventional one from acidic copper sulfate media, because the deposition of copper metal from Cu(I) at the cathode and the oxidation of Cu(I) to Cu(II) at the anode take place in the present method. In the laboratory-scale tests using waste printed circuit boards, high purity copper which contains 1.1ppm of impurities was obtained in a chloride system. INTRODUCTIONThe recovery of various metals from waste materials is an important issue in order to conserve the environment and metal resources. Copper is used for cables, electric appliances, etc., and is currently a very important material for industries and will continue to be in the future. Among the wastes that contain copper, one of the most complex recycling materials is electronic scrap like printed circuit boards (PCB), which generally contain 10-30% copper as well as plastics, fibreglass and other metals. There are two ways to recover copper, either pyrometallurgical or hydrometallurgical. Hydrometallurgical treatments generally have more flexibilities in the process scale and control. The separation processes tend to become complicated because of the poor selectivity during the leaching in the sulphuric and hydrochloric acid media. On the other hand, the use of ammonia as a complexing agent, gave a higher selectivity for copper leaching (Nigo, Majima, Hirato, Awakura, & Iwai, 1993; Majima, Nigo, Hirato, Awakura, & Iwai, 1993; Zhou, Shinme, & Anezaki, 1995; Koyama, Tanaka, & Lee, 2006) .In this study, recycling process containing leaching, copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) is introduced. Furthermore, copper recovery from a waste printed circuit boards and impurity behaviour was examined in ammonia-ammonium sulfate (sulfate system) and ammonia-ammonium chloride (chloride system) systems."

Jan 1, 2012

By Jorge Alberto Soares Tenório, Denise Crocce Romano Espinosa, Luciana Harue Yamane

"The present work investigated the influence of Fe+2 initial concentrations in the bioleaching of copper from printed circuit board using Acidithiobacillus ferrooxidans-LR. Printed circuit boards were collected from obsolete computers and mechanically processed through size reduction followed by magnetic separation. The bacteria Acidithiobacillus ferrooxidans-LR were grown and adapted in presence of printed circuit boards. A shake flask study was carried out on the printed circuit boards samples (non-magnetic fraction) using a rotary shaker under the following fixed conditions (185 rpm, 30°C). The bioleaching efficiency was evaluated by comparison between the concentration in the initial sample and in the leached liquor, pH of the medium and concentration of ferrous iron produced. Inductively coupled plasma optical emission spectrometry (1CP-OES) was used to determine the metals concentration. The results showed that Acidithiobacillus ferrooxidans-LR leached 63% copper from printed circuit boards using supplemented medium with Fe+2.IntroductionThe waste of electric and electronic equipment is generated by discarding of equipment such as obsolete computers and cell phones which is stimulated by the technology innovations and it has been growing each year. Because of the amount that has been accumulated it has become a prominent environmental problem but also can be a source of valuable materials, such precious and base metals [1,2] The printed circuit boards are found in almost all electric and electronic equipment being composed of polymers, ceramics and metals and can be an alternative source to recover base and precious metals. The precious metals are used in the printed circuit boards to protect against oxidation and base metals because of its conducting properties [3]. The heterogeneous composition of printed circuit board is a limiting factor in the recycling processes and the metals concentrations also range."

Jan 1, 2011

By Moresby J. F

Segregation roasting was used to recover more than 85 per cent of copper from crushed, minus 14 mesh refractory furnace-lining bricks. A plus 14 mesh fraction: which was high in copper, could be recycled directly to the smelter, giving an overall recovery of approximately 90 per cent. An oxidation roast at about 700°C was necessary, before segregation roasting, to convert copper sulphides and copper metal to sulphates and oxides. Withsegregatron temperatures in the range 600°-650°C the quantities of solid carbon and NaCI required are 2-5 per cent and 1 per cent respectively. P.V.C. coating from scrap copper wire can be used instead of NaCl as asource of hydrogen chloride for the segregation reaction.

Jan 1, 1978

By T. A. Muhlare

"Large quantities of slag are produced every year and dumped on slag heaps around the world, posing a potential environmental threat due to contained heavy metals content. Slags are waste minerals produced during furnace smelting of minerals. The contained values of base metals may be released into the environment under natural weathering conditions polluting ground and underground water. Copper losses into slag are a continuous problem in pyrometallurgical smelting operations. Due to shortage of ore concentrate, various mining operations have initiated the recovery of copper from dumped slag. The typical process uses crushing, milling and flotation. These operations create excessive liner wear rates during crushing and milling because the bond work index of copper slag is 22 kWh/t and this is considered a very hard slag. The process also has reduced flotation recoveries and requires high flotation reagent consumption. The present work shows that digestion of the milled copper slag slurry with concentrated sulphuric acid at a temperature of 250oC forms a solid cake and leaching of the solid cake with water is a possible option. However, the consumption of sulphuric acid can have a considerable cost on the recovery process. This can be limited by producing a leach residue containing gypsum and silicate materials as amorphous silica which are suitable for use as an additive for Portland cement. Laboratory results show that 90% copper recoveries can be achieved. The leaching is conducted to prevent silica gel formation and iron co-extraction. Leaching is optimum if silica gel-free solutions and good filterable residue are obtained. INTRODUCTION Slag is a waste by-product of smelting and converting operations in metallurgical plants. Both smelting and converting operations are aimed at iron separation from base metal sulphides in non-ferrous metallurgy. The iron sulphide component of the ore or concentrate is oxidized to iron oxide at higher temperatures in the molten form, and then fluxed with silica and other oxide rock minerals to produce fayalite (2FeO•SiO2) slag (Schlesinger et al., 2011). Slags are generally deposited on dumps and considered to be unreactive materials. Smelter copper slag contains significant concentrations of several potentially toxic elements, including arsenic, lead, cadmium, barium, zinc and copper. These elements can be released into the environment under natural weathering conditions and cause pollution of soils, surface waters and groundwater (David, 1998)."

Jan 1, 2015