Search Documents

By M. L. Whisman

The Bureau of Mines developed a radiotracer method for detecting the contribution of selected components and additives to thermally induce deposits of turbine aircraft fuels. Fuels were examined before and after 52 weeks of storage at 130° F. Of particular concern was the influence of aromatic hydrocarbon fuel constituents on thermal-stability quality of jet fuels during storage. A microfuel coker test apparatus was used to thermally stress the test fuels and blends, and the resultant contribution to deposits of selected fuel components, labeled with carbon-14, was determined by radioactive-counting techniques. Ninety-one blends of five test fuels with carbon-14-labeled fuel additives or components were prepared, tested, stored for 52 weeks at 130° F, and reanalyzed for deposit-forming tendency. These additives included two anti-oxidants, a metal deactivator, and a corrosion inhibitor. Of the labeled hydrocarbon fuel systems studied, the greatest reaction was observed in blends containing methyl-and ethyl-substituted indenes. Other aromatic types also showed some contribution to the deposits. Three of the additives showed a marked tendency to degrade and react during storage and thermal stress. A cresol antioxidant, however, barely contributed to deposit formation. Oleic acid interacted with cadmium present in aircraft fuel systems and produced deleterious effects upon the thermal-stability quality of the fuel.

Jan 1, 1971

By K. C. Strebig

The effect of some organic additives in diamond drilling of quartzite was investigated in the laboratory with a drill instrumented to measure the rate of penetration, the thrust, and the torque and to record each as a function of the distance drilled. A statistical plan was followed throughout the investigation, and an equation representing the bit performance was derived from the mathematical theory of reliability. The coefficient of friction in drilling increased with the use of additives, although the wear coefficient decreased. The decrease in wear associated with an increase in energy per unit volume consumed and the increase in penetration rate resulted in a net decrease in the cost per foot of drilling. A hypothesis explaining the effects achieved with the additives is given.

Jan 1, 1971

By Richard F. Link

The principal procedures for the statistical analysis of gold assay and other trace-element data depend on applying either the normal frequency distribution or the lognormal frequency distribution. The consequences of applying both methods are examined through reference to example data from United States and South African gold mines. It is concluded that for estimation of average grades, except for certain data with a very high coefficient of variation (ratio of standard deviation to mean), use of the lognormal distribution is ordinarily undesirable because bias may be introduced and little efficiency can be gained. However, if biased average grades can be tolerated, as in the examination of data from surveys in exploration geochemistry, use of the log-normal distribution may be desirable. Various statistical analyses are detailed, and the tables presented to implement the analyses are more complete than those previously published.

Jan 1, 1971

By Robert M. Doerr

The research objective was to determine the effect of aluminum alloy additions on the oxidation behavior of cobalt-nickel alloys. Thirty high-purity alloys were reacted with 02 at 0.5 atm at 1,351°, 1,389°, and 1,429° K in a volumetric apparatus for about 300 min. The alloy compositions consisted of Co-Ni master alloys (0, 22, 50, 70, 91, and 100 wt pct Ni) with aluminum additions of about 0, 1, 2, 4, and 8 wt pet. Large early deviations from, or changes in, the parabolic rate constant were encountered, but in most cases, the reaction rate declined approximately in accordance with the parabolic rate law. A sharp peak in the parabolic oxidation rate constant was observed for specimens containing a to 22 percent nickel and 1 to 2 percent aluminum at 1,351° K, and the rate constants for these compositions were lower at the higher temperatures. Specimens containing 8 percent aluminum reacted far more slowly than did any of the others.

Jan 1, 1971

By E. J. White

Data from oil well logs and core analyses were used to quantitatively evaluate formation porosity and water saturation of heterogeneous carbonates and to study the pore geometry and performance characteristics of cores from these formations. Logs and cores from the Madison limestone from 233 wells in three fields in the Williston basin were used in the investigation. A comparison of log and core analyses shows that log porosities are consistently larger than core porosities, and the differences are correlatable with core porosity ranges. Water saturations from logs are usually smaller than the corresponding core saturations by summation of fluids, but the difference is attributable to mud filtrate invasion into the cores during drilling. Petrophysical studies show that the low permeabilities and high residual water saturations in these reservoir rocks are due to their fine crystalline texture and complex pore geometry (heterogeneity). It is concluded that both log and core analyses must be used for reliable evaluation of these carbonate formations.

Jan 1, 1971

By Jack C. White

Studies were made to determine the character and distribution of the copper lost in copper mill tailings. Acid soluble (oxide) and acid insoluble (sulfide) copper were determined for heavy-liquid sink and float products of screen-sized fractions from 12 copper mill tailings. In most of the tailings studied, the coarse-size fractions are higher in copper grade than the respective bulk tailings, high in sulfide copper, and low in oxide copper. Oxide copper occurs predominantly in the minus 325-mesh "slimes." Microscopic examination of heavy-liquid sink products indicated that recovery of liberated copper sulfide minerals is complete in most mills, and that copper minerals not being recovered are locked with gangue particles. Additional copper could probably be recovered from most tailings by size classification, scavenger froth flotation of the coarse fraction, and regrinding of the concentrate to achieve liberation of the locked sulfides.

Jan 1, 1971

By A. R. Taylor

Using solution calorimetry, the following heats of reaction were determined: (1) NaCN(c) + 1/Cu20(c) + 129H20(l) ? CuCN(c) + NaOH?128.5H2O ?H = -13.44±0.10 kcal/mole, (2) HCN(2) + NaOH?128.5H20 ? NaCN(c) + 129.5H20(l) ? = -2.52±0.02 kcal/mole. From these reactions, the heats of formation for CuCN(c) and HCN(2) were calculated to be 22.7±0.4 kcal/mole and 24.9±0.4 kcal/mole, respectively. Reaction 2 was made to check the consistency of literature values for heats of formation of HCN and NaCN. Adiabatic calorimetric measurements between 10° and 400° K showed the entropy and heat capacity of CuCN(c) to be 21.51±0.06 eu and 14.58±0.04 cal/mole deg, respectively, at 298° K. A broad anomaly in the heat capacity was found in the temperature range 285°-320° K. The heat of transition associated with this anomaly was less than 1 cal/mole, the sensitivity of the measurements.

Jan 1, 1971

By W. K. Overbey

Knowledge of fracture systems in oil or gas reservoirs is essential to the efficiency of both primary and secondary production operations. A relationship was established between structural features of the surface and both natural and induced fractures in oil and gas reservoirs, thus providing a method of predicting the direction of rock fracture prior to field development and well completion. Correlations between the surface features and under-ground fractures resulted from analysis of joint strike measurements, bottom-hole impression packer surveys, photographs of hydraulically fractured wells, fracture data from oriented cores, in situ strain measurements from formation outcrops, and lineament analyses from aerial photographs. The mean orientation of surface fractures, lineaments, and stress field directions ranged from N 53° E to N 73° E, compared with an average orientation of N 63° E for the hydraulically induced fractures. Tectonic stress field was shown to influence the direction of hydraulically induced fractures. This report presents the details and application of techniques to obtain the orientation of the principal horizontal compressive stress field component and thus the direction of induced fractures.

Jan 1, 1971

By Vance G. Leak

Leaching of manganese from low-grade Minnesota ores was studied over the temperature range 25° to 225° C at atmospheric and elevated pressures to demonstrate that good recoveries of manganese could be achieved from unroasted ores using reagents available nearby. Various combinations of ore, pyrite, lignite derivatives, and sulfuric acid were tested on a small scale. Pyrite alone required the highest temperature to effect a good extraction, but the combination of pyrite, lignite char, and sulfuric acid solubilized 99 percent of the manganese after 30 minutes of reaction at 75° C.

Jan 1, 1971

By H. E. Blake

An evaluation was made to determine the economics of utilizing waste fluosilicic acid for production of (1) calcium fluoride, and (2) anhydrous hydro-gen fluoride. Two versions of each process were considered and compared. The evaluation showed that both products could be produced and marketed competitively. Lowest estimated product sales prices required to yield a 25-percent return on investment before taxes (discounted cash flow basis) was $339.34 per ton of hydrogen fluoride and $48.64 per ton of calcium fluoride.

Jan 1, 1971

By David P. Lindroth

The heat content above 25.0° C up to 1,000° C was measured for six rock types: St. Cloud Gray Granodiorite, Holston Limestone, Sioux Quartzite, Rockville Quartz Monzonite, Salem Limestone, and the basalt at Dresser, Wis. The calorimetric data were obtained with an isothermal jacket-copper block calorimeter. The experimental heat content data for each rock type are presented, along with specific heat data obtained from the temperature derivative of the heat content. For the six rock types the maximum deviations of the specific heats at a given temperature were within 10 percent below 575° C and within 34 percent above 5750°C. The increase in the values of specific heat range from a minimum of 13 percent for the basalt at Dresser, Wis. (temperature range, 100° to 1,000° C) to a maximum of 46 percent for Holston Limestone (temperature range, 100° to 870° C).

Jan 1, 1971

By L. M. Adams

Experiments in reclaiming acidic surface-mined coal lands with raw fly ash from bituminous-coal-fired powerplants were conducted by the Bureau of Mines at two sites in northern West Virginia. Plots at both sites were treated with varying tonnages of fly ash from three area powerplants and were planted with a variety of grasses, legumes, trees, and shrubs. Eight grasses and seven legumes were investigated. Greatest promise for growth under harsh soil conditions was shown by Kentucky 31 fescue, rye and red top grasses, and birdsfoot trefoil, a legume. Survival of trees and shrubs was negligible. Addition of fly ash to the spoil increased the pH to a range tolerable to some types of plant growth, improved the texture of the soil, and increased the available water of the resulting mixture.

Jan 1, 1971

By Galen G. Waddell

This report describes a method of measuring and analyzing the initial deformation which occurs in the medium surrounding a mine accessway as the opening is created. Discussed are (1) the hypothesis upon which the research is based; (2) the in situ rock-deformation measuring equipment developed; (3) the field tests, consisting of measuring the deformation of the medium around two 4-foot-diameter raise bores as the boring progressed; and (4) a finite-element technique to correlate theoretical with experimental results, using elastic theory. Described also are the raise-bore operation and performance. The instrumentation developed proved to have the sensitivity and resolution necessary to measure rock deformation around a full-scale raise bore during excavation. Tests show the relationships of rock deformation to progress of the raise boring and to time. The initial deformation of the opening appeared to be elastic. Using the deformation records and an estimated field stress, the modulus of elasticity was determined for the rock mass. In addition, the importance of this type of measurement in assessing support-problem areas is discussed.

Jan 1, 1971

By Murray Jacobson

A method for determining airborne trona dust concentrations using a midget impinger was developed. During sampling, the trona dust, composed of sodium carbonate and bicarbonate, dissolves in the collecting medium (water). Resulting solutions are then titrated using 0.1 [N] hydrochloric acid solution. The mass concentration of the trona sample is determined from a calibration curve relating the volume of acid required for neutralizing a collected sample to the mass of the dust. Test results obtained using this method are equivalent to those obtained using a gravimetric sampling method.

Jan 1, 1971

By John Nagy

Data from experiments and literature on gas and dust explosions in closed vessels are presented to show the effects of the vessel size and shape; the initial pressure, temperature, and turbulence; and the fuel-air ratio and the strength of ignition source on pressure and rate of pressure rise. An attempt is made to correlate some of these parameters with an elementary mathematical model. Analyses of data on 17 vessels--spherical, cubical, cylindrical, and rectilinear in shape--ranging from 0,018 to 905 cubic feet in volume were made. Although the study was initiated to provide information primarily on dust-explosion phenomena, some data were obtained for gas explosions so that the factor of initial turbulence caused by the pneumatic blast used to disperse dust could be evaluated. The mathematical interpretation of the explosion phenomena was in general accord with the experimental data, and correlation was obtained for several factors affecting explosion development. Neither vessel size nor shape affected maximum pressure (when heat loss was neglected). The rate of pres-sure rise decreased as vessel size increased, and the rate was proportional to the ratio of the surface area of the vessel to its volume. Induced initial turbulence markedly increased the rate of pressure rise and slightly increased the maximum pressure. Changes in initial pressure produced proportional changes in maximum pressure and rate of pressure rise. Initial temperature and maximum pressure were inversely related, but initial temperature had little effect on the maximum rate of pressure rise. Comparative experiments showed no appreciable difference in explosion development of gas and dust fuels. The vessels and experimental work are described, and all data are given in tables. The mathematical model will facilitate extrapolation from laboratory to industrial conditions and will allow comparison of results obtained in different laboratories.

Jan 1, 1971

By George S. Koch

Several methods of calculating ore grades by diamond-drill sampling in the Homestake mine, Lead, S. Dak., have been evaluated by statistical analyses of assay data. The natural distribution of gold particles, partly masked through sampling and assaying procedures, is probably lognormal. As a consequence of the gold particles being clustered rather than randomly distributed within the ore bodies, (1) more mine samples are needed to obtain a specified precision of mean grade than the number predicted by the standard-error-of-the-mean law; (2) the variance of gold values is not inversely proportional to sample volume, and, therefore, small-diameter drill core yields samples nearly as good as larger diameter core; and (3) sampling at 5-foot intervals provides nearly as good results as sampling at shorter intervals.

Jan 1, 1971

By Foster Fraas

Calculations based on data related to the electrostatic precipitator illustrate the variation in the electric forces on a particle with change in position in the ionized field. The feeble forces in some separators are explained by the low field intensity at midpoint locations between the electrodes. When the particles are in contact with the exterior surface of a rotating cylindrical electrode, a high field intensity at the electrode surface combined with the image charge results in large electric forces. The permissible feed velocity increases as the square root of the electrode diameter, providing high values in efficiency and feed rate capacity, particularly in surface-to-mass ratio separations such as are encountered in secondary materials recycling operations.

Jan 1, 1971

By F. E. Armstrong

Tritiated water has been used as a tracer to follow the path of leach liquids as they flow through a copper-mine dump. Semipermeable layers, produced within the dump by compaction and "stratification" of deposized dump material, restrict the vertical movement of water. Knowledge of this restriction would aid in the optimization of the leaching process. The portion of the dump of particular interest was approximately 2,000 feet long, 800 feet wide, and 200 feet high. A total of 94 curies of tritiated water was injected into the dump at the rate of 650 gpm over a period of 39 hours. The leach liquid was sampled at natural surface outflows and through a series of wells, some drilled to the bottom of the dump and others to intermediate levels. More than 3,300 samples were analyzed, most by liquid scintillation counting, but a few hundred by gas counting. Data obtained permitted calculation of flow paths, recycle times, total fluid volume, and estimates of retention times in various portions of the dump.

Jan 1, 1971

By C. Q. Cupps

Rate of gas diffusion in reservoir oil has been investigated in an effort to explain the variation in oil characteristics observed in the Weber Sandstone reservoir, Rangely field, Colorado. Coefficients of gas diffusion were determined experimentally for the Rangely oil system and used in a mathematical simulation of gas diffusion during the probable life of the Rangely reservoir, estimated at 65 million years. The simulator involved solution of Fick's law for diffusion in two dimensions by the method of finite difference and successive over-relaxation. The results show that continuing gas diffusion is a logical explanation for the variation in oil characteristics at Rangely and that the pattern of gas distribution by diffusion in an asymmetrical reservoir will not conform to structural contours as originally proposed.

Jan 1, 1971

By Richard N. Spencer

This report describes investigations of the economic merits of multiple zone mining and beneficiation versus selective mining of altered Western phosphate rock. The same deposit was considered in both instances and it was assumed that the grade of selectively mined ore was comparable to the grade of the concentrate from beneficiation. The beneficiating scheme used for the investigation was one proved by small continuous circuit operation. All economic factors were found to favor multiple zone mining plus beneficiation. Capital requirements and production costs were lower, and production life of the deposit was extended 4.5 times. The concentrate from beneficiation would be a uniform high-quality feed for acidulation and would be low in stable metallic oxide (R203) content. Such a feed would permit improved plant operating control, and the low R203 would promote more rapid filtration and minimize sludge formation in the phosphoric acid. With the proposed treatment, the concentrate produced by flotation from this deposit would cost about 1.5 times as much per ton as the concentrate produced by classification sizing. Therefore, inclusion of a flotation step in treatment schemes requires an economic analysis for each ore deposit.

Jan 1, 1971