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By A. Khoshnevisan

Molybdenum resources around the world are mainly associated with porphyry copper ores. Molybdenite (MoS2) is the main Mo mineral that has rhenium in its crystal lattice. This paper investigates the recovery of rhenium and molybdenum from a molybdenite concentrate using a hydrometallurgical treatment method. The molybdenite concentrate is leached with nitric acid and subjected to solvent extraction to recover and separate rhenium and molybdenum from the leached liquor. The effects of pH and the chemicals? concentration on extraction characteristics of Mo and Re are investigated to define the best condition for selective extraction of these metals. The tested leached liquor contained of 8.2 g/L Mo, 1.5 g/L Fe, 0.5 g/L Cu and 60 ppm Re. A good extraction efficiency, up to 94%, was achieved for Re from the leached liquor, where the extraction of other metals, such as Fe and Cu, was negligible. In particular, at very low pH, rhenium is extracted selectively from solution, while the extraction of molybdenum is less than 10%. After removing rhenium, molybdenum was extracted with LIX984N. The selectivity of molybdenum extraction over other metals in solution was significant. Nearly 94% of molybdenum can be extracted from the solution at a pH value of -0.12, without any interference from other metal ions such as copper and iron.

By Xi-Shan Li, Qian Li, Yong-bin Yang, Tao Jiang, Jie Ge

Compared with other pretreatments of sulfur & arsenic-bearing gold, double-layered pellet roasting has an advantage that sulfur dioxide and arsenic trioxide volatilizing from this refractory gold ores can be solidified into the coating without emission during the roasting. However, the separation of coating from roasted double-layered pellet should be focused on in the novel pretreatment. Based on the difference of physicochemical characteristics between roasted solidified coating and pellet core, several separation methods including grinding, drop impact and water quenching method had been systematically studied in this paper. The results showed that magnetic and gravity concentration could not obtain a satisfactory separation effect. The optimum separation rate of grinding was only 38.94% at grind time 12min, but it increased to 85.05% by drop impact under drop height 0.75m, drop times 20 and impact angle 45°, and that of water quenching taking advantage of slaking reaction of lime could approach 75.32%.

Jan 1, 2015

By Hongmin Zhu, Suning Liu, Kai Huang

"Recovery of silicon particles from the cutting slurry for the manufacturing of solar grade silicon is very important to recycle this kind of special resource. The challenge is to separate the silicon particles from the mixed abrasive particles which contain SiC. Various methods such as sedimentation, centrifugation, and flotation have been conducted, while in present work, a simple and effective novel method was proposed to study the separation of Si and coexisting SiC particles in the cutting slurry. The new process is based on the size difference between the two kinds of microparticles. And the membranes with the different pore sizes of 1µm, 2µm, 3µm and 5µm were used to test the pass ratio and separation efficiency of the suspension. Results shows that the effective separation of Si and SiC microparticles was obtained under the optimal conditions, and indicating great potential of practical enrichment of Si from the coexisting abrasive particles.IntroductionWith the development of the world economy, energy shortage and environment problem is becoming more and more seriously. Solar energy, which is regarded as one of the most important new energy in the word, has received much attention and interest from the scientists [1, 2]. More than 80% solar cells are manufactured by the high purity polysilicon as the raw material. The main process of producing silicon wafer is by multi-wire slicing. In this slice processing, large amount of slurry is produced. The slurry contains more than 30% wt silicon powder, silicon carbide powder as the abrasive, scraps of metal chips, as well as cutting abrasive suspension polyethylene glycol (PEG). The high-purified silicon powders are worth recycling and reusing as the materials for preparing solar-grade silicon though it is a big challenge [3].Most of the current studies were focusing on the recycling of the silicon carbide and PEG, while work on the recycling of the high-purified silicon is not so been focused since there is lacking of very effective separation and recovery technologies till up now. Nishijima utilized the method of superconducting magnetic to recycle the abrasive [4]. Wang applied a combinational process of chemical treatment, high-gravity centrifugation, high-temperature precipitation technique and directional solidification to enrich the silicon [5]. And other purification methods, such as centrifugation [6], froth flotation technologies [7], electrical filed separation [8] and phase-transfer process [9] have been employed. The disadvantages such as using poisonous media or complex equipments decrease the feasibility and efficiency of the above mentioned techniques."

Jan 1, 2014

By Hao Deng, Hongmin Zhu, Jichao Li, Kai Huang

"Silicon and silicon carbide mixing micropowders obtained from the saw cutting industry of polycrystalline silicon ingot is separated by a simple sequential sedimentation. The Zeta potentials of the powders in the aqueous suspension are adjusted by varying the pHs with dilute acid or alkaline reagents. The dispersion and aggregation content of the microparticles is significantly influenced by pHs, and so their settlement velocity in the same hydraulic conditions are quite different, and silicon powders tend to suspend in the upper section of the suspension for its finer size and smaller density under the stronger Zeta potential repulsion force. The original content of the cutting powders with 30%wt silicon are separated into the Si-rich and SiC-rich powder respectively, and 62%wt Si-rich powder can be obtained after 4 times of sedimentation under pH = 8.0, showing the great potential for Si and SiC powder separation and recovery in a cost-effective way.IntroductionWith the fast development of photovoltaic (PV) technology these years, the market demand for the solar-grade high pure silicon material significantly increased, making the silicon recycling and recovery from the wire sawing slurry profitable and attractive[1]. Waste silicon slurry was produced in the multi-wire sawing process of a silicon ingot by using an ethylene glycol-based solution and silicon carbide abrasives as the slicing system. During this slicing process, about 30% of the silicon ingot will become the waste as the fine particles suspended in the slurry, which mainly consists of silicon kerf-loss particles, SiC fragmental particles, tiny iron fragments from the worn sawing wire and ethylene glycol-based solution [2]. The separation of above individual component is usually easy except for Si and SiC fine particles for their quite similar properties. So the biggest challenge for the effective recovery and recycling of silicon particles from the wire sawing slurry actually lies in the mutual separation of silicon and silicon carbide particles."

Jan 1, 2012

By J. A. Bartnik

Flocculation, the process of coagulation or coalescence of finely divided particles, is commonly used in separating fine solids from fluids. Forces disposing of the particles to flocculate include: ionic forces of attraction, secondary entropic forces, and magnetism. Magnetic flocculation is due to a physical magnetizing process which affects suspended ferromagnetic particles. Such particles, after exposure to magnetic fields strong enough to cause reorientation of the particles and alignment of the induced magnetic poles, tend strongly to retain this induced magnetism, as the magnetic retentivity of ferromagnetic particles is a linear function of its specific surface.1 Thus, because they become small magnets with high residual magnetism, the particles become and remain attracted to one another, forming large agglomerates. Fine magnetic particles close to domain size can exhibit energies of the magnetization of the order of 105 ergs/cm3,2 which is many times greater than the energy affected by chemical flocculents. Therefore magnetic flocculation can be used to agglomerate particles having surfaces ionized with like charges and only a minute quantity of ferromagnetic material will be necessary to develop sufficient force to overcome the repulsive ionic forces and hold together relatively large masses of fine solid agglomerates suspended in fluids. Since flocculation occurs after the fine suspension passes through a magnetic field generated by magnets surrounding a pipe section, the simplicity of the process and economic advantage makes magnetic flocculation very attractive.

Jan 1, 1971

By C. Wen

In Huoqiu region of Anhui Province, Fe2O3 occurs mainly in the form of specularite. Besides quartz, the gangue minerals include iron-bearing silicates such as chlorite and sericite which account for about 10% of the total gangue. The separation effect of conventional collectors is poor in the flotation of the minerals, that is, the average grade of iron concentrates is only 60-62%. Using the developed amphoteric collector can successfully realize not only the separation of specularite from various gangue minerals with results of iron concentrate grade above 65% and iron recovery of above 80% but also low temperature flotation at 15°C.

Jan 1, 2012

By A. Hasbi Hassan

Stibiotantalite is a relatively rare mineral not commonly found in the major tin districts of the world, and its separation characteristics have not been documented adequately in the literature. The investigation described here has been carried out on a sample taken from a commercial tin concentrate containing a significant amount of stibiotantalite which would have to be substantially removed before the tin concentrate was smelted. The sample originated from Greenbushes, Western Australia. A mineralogical analysis was performed on the sample with the aid of the Frantz Isodynamic separator 1 and the results presented in Table 1. A screen analysis was also performed, and the results presented in Table 2. The minerals were found to be substantially liberated.

Jan 8, 1979

By A. H. Hassan

Stibiotantalite is a relatively rare mineral not commonly found in the major tin districts of the world, and its separation characteristics have not been documented adequately in the literature.

Aug 1, 1979

By P. Sen

Frequently during the processing of minerals very fine particles are generated which are difficult to recover by conventional separation techniques and are rejected with waste water from mills. A method has been evolved for the continuous recovery of such fines by allowing the suspensions to flow through a rotating cylinder. Theoretical analysis of the trajectory of particles have shown that the efficiency of separation increases with R.P.M., tube diameter, particle diameter and density. Experiments carried out with the overflow from a hydrocyclone containing particles in the size range of 2-10 microns gave a separation efficiency of 60-70% with an R.P.M. of 3500 of the rotating tube.

Jan 1, 1980

By S. K. Kawatra, T. C. Eisele

To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of. Currently, the major markets for scrubber sludge are for manufacture of gypsum products, such as wallboard and plaster, and for cement. However, the quality of the raw sludge is often not high enough or consistent enough to satisfy manufacturers, and so the material is difficult to sell. Other markets, such as paper manufacture and plastics fillers, have even more stringent quality requirements and will not accept raw sludge at all. In the work described in this paper, several reagents have been examined to determine their ability to selectively improve the flotation of the unreacted limestone contaminant away from the desirable products (calcium sulfite and gypsum). The most success has been achieved using a cationic collector, which shows a higher selectivity between calcium sulfite and calcium carbonate than do the anionic collectors that were studied.

Jan 1, 1995

By Bingchen Chen, Zhitong Sui, Junwei Ma

"In the blast furnace slag, titanium disseminated in various mineral phases Titanium could be concentrated mainly in perovskite, which could be selectively precipitated and grown by optimizing the operation factors like the slag composition, temperature of heat treatment and additive agents. This study aims at establishing the titanium slag mineralogy and its distribution in the treated slag and the as-received slag, as well as the methods of perovskite separation. After heat treatment, the grain size was grown from 5 - 20µm to 80 - 200µm, the distribution of Ti02 in perovskite was increased from 48% to 81 %, the morphology was changed from snow-shaped grain to coarsening dendrites or equiaxed crystals. A concentrate were produced by gravity separation analyzing 35.25% Ti02 with a recovery of 68.28% and a tailing analyzing 9.53% Ti02 , and a possibility of flotation upgrading was discussed. I INTRODUCTION CHINA is rich in mineral resources of titanium, 92.4% of which is vanadium-titanium bearing magnetite. About 53% titanium were in iron concentrate after mineral processing, by which the blast furnace slag containing about 25% TiO2 were produced[11 • The content of TiO2 in such slag is too low to separate titanium dioxide, and it is also too high to produce slag cement[21. It has been accumulated to 50 million tons so far, which is still increasing at a rate of 3 million tons per year, and results in a waste of titanium resources and pollution of environment. Due to the dispersed distribution of titanium component in various mineral phases, very fine grain(<10µm) and complex interfacial combination, it is very difficult to recovery titanium component from the slag by traditional separating technique. In this paper, a novel technique to recovery titanium from the waste slags was proposed [3H4l, on which three continuous processes were involved: selective concentrating, selective growing and selective separating. Perovskite was designed as a titanium-rich phase, in which the most titanium was concentrated promptly, then perovskite could be selectively grown and coarsened by optimizing the heat treatment and the appropriate additives [ 5l[6l. The grain size of perovskite phase was larger than 80 µm, and the crystals appeared as coarsening dendrites or equiaxial grains like lump."

Jan 1, 2000

By M. M. Kulkarni1

Kaolin clay is used as a filler and pigment in various applications such as paper, paint, rubber, plastics, adhesives, ink and ceramics etc. Major mineral content in crude kaolin clay is kaolinite along with some accessory minerals as quartz, hematite, mica, feldspar, anatase, rutile, illemnite etc. The Fe and Ti bearing minerals play very important role in determining quality of the kaolin, as these minerals impart yellow, pink or darker color to the white kaolin. Conventional beneficiation methods used in kaolin processing are de-gritting, classification and sodium dithionite bleaching, which improves the optical properties of kaolin, wherein reduction of color imparting constituents such as Fe2O3 and TiO2 is marginal. In the present study, these coloring impurities are separated using selective adsorption of water-soluble polymers. Degritted kaolin samples after passing through 45 micron sieve is used in the study for selective flocculation by polyacrylamide based polymers. The effect of pH, zeta potential, and polymer dose on the reduction of impurities is studied. Analytical tools such as XRF, XRD, SEM, and TEM techniques are utilized and results are discussed in detail.

Sep 1, 2012

By J L. Carpenter, S M. Iveson, K P. Galvin

Wet beneficiation of iron ore fines less than 1 mm typically involves a desliming stage ahead of the fine gravity separation such as spirals. The desliming is achieved using a bank of cyclones. The reject ultra-fines emerge in the overflow stream at relatively low pulp density, contain high proportions of low-value slimes, but also well-liberated iron ore ultra-fines below 0.045 mm in size; however, recovering the valuable iron ore ultra-fines from this overflow stream presents a significant challenge due to the need to remove such a large amount of water and slimes.The REFLUX™ Graviton consists of distinct 3D-printed modular units, based on REFLUX™ Classifiers, which are rotated at high speed in a large centrifuge. This system has previously been investigated under semi-batch conditions, demonstrating the potential for precision separations with significant capacity. It has been shown that the throughput advantage of the inclined channels and G forces multiply. This is the first paper presented showing the performance of this system under continuous steady-state conditions. Ultra-fine silica in the size range of 0 to 0.045 mm was fed to the Graviton at different volumetric rates, fluidisation rates and pulp densities ranging from 2 wt per cent to 30 wt per cent, in order to develop a fundamental understanding of the system’s performance. Experiments were then repeated using ultra-fine iron ore.CITATION:Carpenter, J L, Iveson, S M and Galvin, K P, 2017. Separation of ultra-fine particles using the REFLUX™ Graviton, in Proceedings Iron Ore 2017, pp 141–148 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Tom Leistner, Urs A. Peuker, Martin Rudolph

"It is well known, that for conventional froth flotation techniques the processing of ultrafine mineral particles is generally inefficient and results in rather low-grade concentrates and relatively high losses of valuable minerals. Therefore, the investigation of other possible methods, which can selectively separate such fine particle systems effectively, is of considerable interest. In this study, the application of two-liquid flotation, a flotation-related process using oil droplets instead of air bubbles, is investigated as a possible processing strategy for the separation of ultrafine particle systems. The investigation involves the testing of the two-liquid flotation technique as simple laboratory-scale batch trials and moreover, the up-scaling to a semi-continuous process by using a modified lab scale flotation column. Magnetite and quartz particles, with particle sizes below 10 µm respectively, as academic mineral mixture and iso-octane and water as the two immiscible liquid phases are chosen for the experiments. To manipulate the wettability of the magnetite particles as well as the interfacial tension of the oil/water interfaces, surface active reagents of fatty acid basis are introduced in the system. The selectivity of the process is characterized by determining the removal of magnetite particles from the aqueous suspension through selective accumulation at the oil/water interface or extraction into the oil phase, respectively. Operational parameters including pH of the aqueous suspension, additional electrolyte addition and surfactant type as well as dosage are varied in order to maximize the efficiency and stability of the process."

Jan 1, 2014

By Meifeng Zhi

Separation of uranium and molybdenum in the alkaline leach solution of a U–Mo ore was studied. A process of acidification-solvent extraction-precipitation uranium and molybdenum was determined. The influences of solution acidity and phase ratio of acidic scrubbing on separation of uranium and molybdenum were examined. The molybdenum extraction equilibrium isotherm was drawn. The results show that the separation of molybdenum and uranium can be achieved by acidifying the alkaline leach solution, solvent extracting molybdenum using trialkylamine at equilibrium pH 2.5, and scrubbing the loaded organic phase using sulfuric acid solution. The strip solution can directly precipitate ammonium molybdate. Uranium can be directly precipitated from the raffinat

By Dai Yongnian

"The feasibility to vacuum distillation of a crude metal or an alloy was discussed. The equilibrium relationship between vapor phase and liquid phase in A-B system - - - - - PA/PB =BAa*/b has been derived. The separation coefficient, BA = rAPA/(rBPB) is a judgment criterion. By calculation PA/PB, the equilibrium composition diagram of vapor phase and liquid phase was drawn. By use of the equation derived by M. Olette, the relationship among the volatilization amounts of various impurities in a crude metal (yi) was further solved. 1-(X/100)= C =(1-Y1/100)1/02i . From yi value obtained in practice, 2i, Pi and then can be calcu-lated. The correct volatilization order of various impurities was obtained. These results can be applied to determine the practical conditions (temperture, vacuum degree, type of distilla¬tion furnace, times of distillation and control of product composition) in distillation of a crude metal or an alloy.INTRODUCTIONRefining and separation of various impurities from nonferrous crude metals by vacuum distillation have many the advantages of high metal recovery, impurities recovered in metallic state, flowsheet simplified, good enviromental protection, low operation costs and in complex equipment. So in recent years this method has been adopted widely.Vacuum distillation has also been studied and used in separation of various elements from non-ferrous alloys and the area of its application is being extended rapidly.At this situation, some problems have been put up: What kind of impurities can be removed from crude metals? What kind of alloys can be separated by vacuum distillation? In present paper, attemps have been made to answer these problems and combine with practical results to analyse some valuable data obtained from testwork on vacuum distillation of crude tin and Pb-Sn alloy."

Jan 1, 1988

By G. Czupryna, S. Natansohn

Electrowinning is the prevalent technique for recovering silver from wastes generated in silver-tungsten electrical contact fabrication. Such scrap is placed in a permeable plastic basket, which constitutes the anode compartment, and is suspended in a larger cell where the cathode is mounted. A silver nitrate solution is used as the electrolyte and, upon application of an electric field, the silver migrates to the cathode where it deposits. At times, there is tungsten migration to the cathode compartment and consequent co-deposition with the silver. This W contamination, which may amount to several thousand mg/L (oz per gal), necessitates additional purification of the deposited Ag and its removal would, therefore, be advantageous. Eliminating the W impurity also extends the operating period of the cell with corresponding increases in the Ag output and savings in labor costs. The solution to this problem lies in the selective removal of the W from the AgNO3 electrolyte either by liquid-liquid or liquid-solid extraction. Although W extraction in the liquid-liquid mode with a quaternary amine or other reagents as extractants appears feasible, particularly in view of the low pH (about 1.5) of the system, this approach was not considered because it is essentially a batch-type process. It is a more elaborate industrial operation than extraction by ion exchange resins. Implementing the latter process consists of passing the electrolyte from the electrowinning cell through an ion exchange column which would extract the tungsten selectively and returning the tungsten-free stream to the cathode compartment. This process continues until the W extraction efficiency decreases (as a result of resin loading) below an acceptable value. The electrolyte is then directed through another, similar column while the W values are eluted off the first one and the resin is regenerated for another cycle. Thus, two columns in a parallel flow pattern provide the means for continuous processing of the electrolyte feedstock.

Jan 1, 1984

By Davood Moradkhani, Maryam Rasouli

"The present study reports solvent extraction and separation of zinc from concentrated nickel sulfate solution. In our previous study, Zn and Cd in cold filter cake (CFC, 45-55% Zn, 11-16% Cd, and 2.5-4% Ni) were extracted by alkaline leaching followed by electrowinning processes respectively. The strip solution from electrowinning process, was a pregnant liquor solution (PLS) containing 16.8 g/l Ni and 4.2 g/l Zn. In this work, PLS is subjected to the solvent extraction process for separation of traces of Zn from high grade nickel. The zinc free raffinate containing 16.6 g/l Ni sulfate solution will flow to nickel electrowinning plant for cathode production. Di-(2-ethylhexyl) phosphoric acid (D2EHPA) is the organic phase used in this study. The effects of various parameters such as organic phase concentration (10- 40 % v/v), pH (1.5-3), and temperature (25 and 45°) are investigated. Zinc over nickel separation factor increases by increasing pH from1.5 to 3. The results show that 98.7% of Zn was loaded at25°C O/A ratio of 1, pH 3, and 10% vol. D2EHPA. A 10 M NaOH is used for pH control. However, replacement of pH controlling agent with ammonia solution (25%. v/v) results in interesting observations. Ammonia addition, reduces the solubility of Ni2+ cations in solution. Nickel starts to precipitate from raffinate in a crystalline bluish-green form. The obtained crystals are characterized by XRF and identified to be nickel-bearing analog of boussingaultite, a rare sulfate mineral of nickel with chemical formula of Ni (NH4)2(SO4)2.6H2O. The crystallization rate of crystals is studied. It is a slow precipitation process with 75% in 4 days.INTRODUCTION Annually, many hydrometallurgical processes such as electrowinning, solvent extraction and leaching are applied to waste filter cakes in Zanjan, Iran. These additional processes on filter cakes are critical from both environmental and economic points of view. CFC (cold filter cake) is a toxic but valuable filter cake (45-55% Zn, 11-16% Cd, 2.5-4% Ni, and 0.2-1.5% Cu) produced in many zinc production plants. Our research group at Research and Engineering Company for Non-ferrous Metals (ReCo.), developed a series of hydrometallurgical methods for extraction of zinc, cadmium and nickel from CFC (Moradkhani, & Rasouli 2012). The recovery of zinc and cadmium with alkaline leaching and electrowinning was successfully studied. The strip sulfate solution from cadmium electrowinning unit, contains high concentration of nickel with some traces of zinc impurity. This pregnant liquor solution (PLS) was analyzed and reported to contain 16.8 g/l Ni and 4.2 g/l Zn. In this work, PLS is subjected to the solvent extraction process to separate Zn from nickel (Fig. 1). The organic phase stripping solution containing 4.2 g/l zinc and 200 ppm nickel can be circulated and used in the acidic leaching step. This generates nickel solution with high purity suitable for nickel cathode production."

Jan 1, 2017

By M. J. Collins

A hydrometallurgical process has been tested at the Sherritt Research Centre for separation of zinc, lead, copper and precious metal values from the zinc oxide fume leach residue stockpiled at the HBM&S operations in Flin Flon, Manitoba. Zinc is found primarily as zinc femte and sphalerite in the residue, lead as lead sulphate and jarosite, and copper as sulphide and jarositic compounds. Gypsum and siliceous gangue are significant diluents. The separation process includes hot acid, atmospheric and reducing (sulphur dioxide) leaching; zinc, copper and lead flotation; and atmospheric iron removal steps. Zinc is recovered to a high strength zinc sulphate solution and to a zinc sulphide concentrate suitable for feed to a roaster or to a zinc pressure leach plant; lead to a high grade lead sulphate concentrate suitable for feed to a lead smelter, and copper to a high grade copper sulphide concentrate suitable for feed to a copper smelter. Precious metals are divided between the zinc, lead and copper concentrates.

Jan 1, 1993

By E. A. Brocchi

This work is dedicated to the chemical treatment of a typical EAF dust by chlorine content agents. The residue contains 48% Fe2O3 and 28% ZnO mainly in the franklinite structural form. The others less compounds are: 4.00% CaO, 2.60% MnO, 2.20% MgO, 1.08% PbO, 0.36% Cr2O3, 0.21% B2O3, 0.03% CdO and 0.01% NiO. The experiments purpose is selectively to remove zinc from the residue leaving the iron behind. Thermodynamics studies have indicated some roasting possibilities. The experimental results have shown that both HCl leaching and carbochlorination will remove iron and zinc without any selectivity. However, either the chlorine or the calcium chloride roasting seems to form, preferentially, the zinc chloride. So, it will be presented how the EAF Dust can be treated by the using of chlorine roastings process such as carbochlorination in order to separate the zinc and iron present in the frankilinite, main EAF dust content.

Jan 1, 2014