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By Ernest N. Patty

Placer gold-bearing gravels of interior Alaska and the Yukon are, for the most part, permanently frozen, and are described as permafrost. The first step in preparing these gravels for dredging is to strip by bulldozer the surface layer of tundra, brush, and scrub timber, and to expose the ebony colored surface of the frozen mud at the grass roots. This mud varies from a frozen, muddy ooze to a sandy silt and locally may contain layers of peat. The whole mass is intercalated with ice dikes and lenses. The thickness will vary from a few feet up to 100 ft, depending upon local conditions. A freshly exposed surface will thaw to a depth of 4 in. per day during the summer season. Common practice is to expose a large surface of this mud to the sun and each day's thaw is then swept off by water and carried away in suspension.

Jan 1, 1951

By Lenny Winkel

With the aim to develop a solar-driven process for the extraction of copper from sulfide concentrates research on the decomposition of copper sulfides under inert atmospheres has been initiated. Thermogravimetric measurements on chalcocite (CuzS) revealed that copper is formed already at 1823 K. Chalcopyrite (CuFeS2) also disintegrates at this temperature, although at a lower rate. Copper and iron have been identified in the solid residue. The results confirm the feasibility of copper extraction by direct decomposition of sulfides under atmospheric pressure. The decomposition under inert atmosphere prevents generation of SO2, it also alters the behavior of volatile impurities during decomposition of copper sulfide concentrates. Chemical eqUilibrium calculations for chalcopyrite contaminated with enargite (Cu3AsS4) have shown that the absence of an oxidic slag allows for a complete evaporation of arsenic and subsequent separation from intermediate sulfides. The need to better assess the potential of direct sulfide decomposition has prompted the development of an experimental setup for studying the decomposition reactions. The experiment has been devised such that data on the decomposition kinetics and on impurity removal can be obtained at temperatures up to 2500 K.

Jan 1, 2003

By Lenny Winkel

With the aim to develop a solar-driven process for the extraction of copper from sulfide concentrates research on the decomposition of copper sulfides under inert atmospheres has been initiated. Thermogravimetric measurements on chalcocite,(Cu2S) revealed that copper is formed already at 1823 K. Chalcopyrite (CuFeS2) also disintegrates at this temperature, although at a lower rate. Copper and iron have been identified in the solid residue. The results confirm the feasibility of copper extraction by direct decomposition of sulfides under atmospheric pressure. The decomposition under inert atmosphere prevents generation of SO2, it also alters the behavior of volatile impurities during decomposition of copper sulfide concentrates. Chemical equilibrium calculations for chalcopyrite contaminated with enargite (Cu3AsS4) have shown that the absence of an oxidic slag allows for a complete evaporation of arsenic and subsequent separation from intermediate sulfides. The need to better assess the potential of direct sulfide decomposition has prompted the development of an experimental setup for studying the decomposition reactions. The experiment has been devised such that data on the decomposition kinetics and on impurity removal can be obtained at temperatures up to 2500 K.

Jan 1, 2003

By M. Neises, M. Roeb, C. Sattler, S. Stenger

"A two-step thermo-chemical cycle process has been developed and investigated. It is based on metal oxide redox pair systems, which can split carbon dioxide as well as water molecules by extracting oxygen atoms and reversibly incorporating them into their lattice. If concentrated solar radiation is used as the heat source, a promising method exists to produce synthesis gas from water and CO2. An easy way of operation is gained by the combination of a ceramic substrate as the absorber structure, which can be heated to high temperatures with concentrated solar radiation, and of a metal oxide coating which is capable to carry out the redox reactions. The performance and kinetics of a ferrite based redox material coated on ceramic substrates were investigated in a laboratory set-up. CO2 could be reduced with significant conversions. In addition, several side reactions were observed like the formation of carbon and like the Boudouard reaction.IntroductionThe search for alternative energy carriers and for processes able to reuse carbon dioxide stimulates the research for sustainable routes of alternative fuel production. In the scope of this search thermo-chemical processes combined with sources of concentrated solar energy have become more and more attractive. Ideally, the only raw materials for such processes are water (H2O) and carbon dioxide (CO2) enabling not only a process free of emissions, but also allow to reduce emissions of other processes by reusing CO2 to provide synthesis gas, which itself can be applied to produce chemical commodities or even better synthetic fuels like methanol or petrol.In contrast to the direct splitting of those raw materials, thermochemical cycles split water and CO2 in several steps and enable hydrogen (H2) and carbon monoxide (CO) generation at temperatures controllable by today’s technical equipment. One of the most interesting thermochemical cycles is a two-step process using metal oxide based redox systems. During the first step of this cycle (the regeneration step) the metal oxide is reduced setting some of its lattice oxygen free according to reaction (1). In the next step (the splitting) the reduced and activated material is oxidised by withdrawing oxygen from water and CO2 and at the same time hydrogen and CO is set free according to reactions (2a) and (2b) respectively."

Jan 1, 2011

By Greg Joachims

Composition of salt in the Permian Flowerpot Shale in northwest Oklahoma suggests that the salt in this formation was deposited in the early phase of solar evaporation. Brine produced through natural dissolution of the subsurface salt has netted very pure brines, with relatively low concentrations of magnesium salts that should result from late-stage precipitation of salt deposits from sea water. Over the last 100 years, extensive studies of sea- water evaporites, in relation to brine density, have been a topic of discussion. The development of evaporation models has facilitated the increased production and purity of solar salt (salt produced through evaporation of brine by the sun's energy). Conversely, this information can be utilized to gain an understanding of how rock-salt formations were precipitated from sea water by analyzing the elemental constituents of the rock salt and of the resulting brine. By evaluation of well-documented, phase-curve tables of sea-water evaporation, a basic theory can be formulated on how the Flowerpot salt unit was formed.

Jan 1, 1999

By Leonardo de Oliveira Turani

A energia eólica, fonte de energia renovável e de baixo impacto ambiental, vem crescendo rapidamente na última década, em especial no Brasil. A conversão da energia cinética dos ventos em energia elétrica é realizada por aerogeradores, que são acopladas em torres, que na sua maioria são constituídas de anéis sobrepostos de aço, os quais são fabricados e montados com o emprego de várias etapas de soldagem. Em função disso, o conhecimento da soldabilidade dos aços estruturais é um fator importante para indústria eólica, dando subsídios para a elaboração de procedimentos que permitam a redução dos custos de soldagem e a seleção adequada dos aços empregados. Este trabalho objetivou a avaliação da soldabilidade do aço estrutural EN 10025-4 S355M através de ensaios mecânicos e metalográficos de juntas soldadas pelo processo de arco submerso (SAW) em duas diferentes técnicas: Single Arc e Tandem Arc. Os resultados mostraram que o aço S355M apresentou excelente soldabilidade, com destaque para o processo SAW Tandem Arc, o que possibilita a maior exploração desta técnica como uma excelente alternativa para a redução do tempo de soldagem durante a fabricação de torres eólicas.

Aug 8, 2018

By Milton Sergio Fernandes de Lima

A soldagem a laser do Ti-6Al-4V necessita de cuidados especiais quanto à reatividade do cordão com o ar. A fragilidade da solda é apontada como um dos entraves para o uso da liga em algumas aplicações de engenharia. Neste estudo, foram realizadas soldas em chapas de Ti-6Al-4V em diferentes condições experimentais. Verificou-se que a dureza aumenta com o inverso do logaritmo da velocidade de soldagem. A dureza, embora heterogênea na largura do cordão, é resultado da contaminação com oxigênio da estrutura hexagonal da fase a-Ti e da formação de óxido de titânio. Um sistema otimizado de proteção gasosa, protegendo ambas as superfícies e em particular a região do plasma, foi eficaz para melhorar o comportamento mecânico das juntas. Os resultados obtidos em tração uniaxial mostraram que houve um ganho expressivo nas medidas de tensão e deformação. Portanto, o sistema é indicado e recomendado para materiais com sensibilidade à contaminação atmosférica.

Aug 16, 2017

By Matheus Soares Siman

A soldagem GTAW tem importância fundamental para a indústria não só pelo excelente controle do aporte térmico, como também ao fato de proporcionar, repetitividade e reprodutibilidade. No entanto, este apresenta uma série de desafios, principalmente em relação à determinação de algumas variáveis e como essas podem afetar a resistência das juntas soldadas. Neste trabalho, investigou-se a influência de diferentes procedimentos de soldagem em tubos de aço SAE 4130 sem costura com e sem a deposição e com a aplicação ou não de pré-aquecimento. Após procedimentos de soldagem, as propriedades mecânicas e a microestrutura da junta soldada, zona fundida, zona termicamente afetada e metal base, foram avaliadas por meio de ensaios de microdureza, de dobramento e análise metalográfica. Foi possível avaliar a influência da aplicação do pré-aquecimento e analisar as propriedades mecânicas e microestrutura das juntas soldadas. Os perfis de microdureza revelaram a importância do pré-aquecimento. O ensaio de dobramento possibilitou a avaliação das juntas de maneira qualitativa. Porém, um ensaio quantitativo, como o de tração, possibilitaria mais informações.

Oct 30, 2017

By Felipe Lacerda Giro

Atualmente, a soldagem por extrusão de peças semi-acabadas (chapas) em PEAD tem se mostrado como uma solução atraente para a fabricação de pequenas embarcações de serviço. Neste sentido, a qualidade da soldagem torna-se um elemento fundamental para a garantia da integridade estrutural da embarcação. Neste trabalho são apresentados os resultados da análise da influência de diferentes fatores na qualidade da soldagem por extrusão de chapas de polietileno de alta densidade. Os fatores analisados envolveram o aporte de calor, a preparação do chanfro, a velocidade de soldagem e a pigmentação do fio de solda. A influência de tais fatores na qualidade da solda foi avaliada tendo como referência os resultados de ensaios de flexão em corpos de prova.

Aug 17, 2017

By Milton Lissberger

MILTON L. LISSBERGER, ? New York, N. Y.-Solder is a mechanical mixture of tin and lead, a fact which is susceptible of very simple demonstration. A bar of solder of a grade even as low as 30 per cent. tin and 70 per cent. lead, passed through a buffing machine, will show a surface practically identical with that of a bar of second-quality or reclaimed tin. The buffings, on chemical analysis, will prove to be almost pure lead. According to the best practice, solder is made in the following manner. Virgin pig lead is first melted, and when it is thoroughly liquefied, virgin pig tin is added, together with a small amount of flux; the latter is for the purpose of bringing to the surface the so-called "liver," consisting of impurities that may have remained in either the lead or the tin as a result of incomplete refining. The combined material, when completely liquid, is thoroughly stirred for some hours, and is then cast into small pigs. Just before casting, and continuously during this operation, the molten metal yields dross, consisting largely of the oxides of lead and tin; this should be carefully skimmed off. After the pigs have cooled, they are taken to a smaller kettle, remelted, and cast into the desired shape for use; or if wires, ribbons, etc., are to be made, the solder is cast into slugs suitable for extrusion and rolling. During this second operation, the skimming of dross should be even more carefully done than at first. Hand mixing has proved to be the only reliable method for the production of the best quality of solder, irrespective of its percentages of lead and tin. The best quality of solder is not necessarily that which contains the highest percentage of tin, but rather is that composition which performs best on the required piece of work. In order to produce

Jan 12, 1918

By Daniel J. Rider

In 1980 the Niagara Frontier Transportation Authority contracted for three miles of cut and cover box structure and station construction in Main Street, Buffalo, New York. Project depths ranged from 30 feet to 60 feet below street grade. Soils, Figure No. 1, consisted of loose to very compact sands and gravels. Ground water level was generally 20 feet below grade. Specifications required a soldier pile and timber lagging support system with external dewatering. Soldier piles were to be installed in prebored holes with bentonite slurry and lean concrete backfill. Conventional pile driving was not allowed due to concerns over excessive noise and vibrations and its effect on nearby historic structures and the surrounding population

Jan 1, 1987

One of the engineering proposals in the last Congress which was of interest to engineers was the soldiers' land settlement plan proposed by Secretary Lane, under which returned soldiers, sailors and marines would be employed on construction work in the reclamation of swamp and arid lands and would thereafter be given preference in the selection and settlement of those lands. This bill failed in the fillibuster at the end of the session. It is likely that some sort of a plan for soldiers' settlement will come before the next Congress. A new bill has been written up for introduction at the next session which proposes an "infiltration method" of buying improved farms in established communities for' the soldiers' settlement purpose, under the authority and direction of the Farm Loan Board. The contrast of this bill to the one recommended by Secretary Lane is of vital importance to engineers at this time; first, because of the broad engineering improvement program that the latter bill proposes as against no engineering improvement under the infiltration plan; secondly, the community settlement plan of Secretary Lane means improvement of waste lands requiring much engineering work.

Jan 7, 1919

By G. E. Bandelis

In this paper, solid bed erosion processes and the mechanisms involved when a two-phase liquid-solid mixture flows over a bed of solids in a horizontal annulus are analyzed. There are few such studies available with some authors arguing that the flow rate for erosion is always less than the flow rate for the suspension of solid particles thus necessitating further study and analysis of such phenomena. Tests were run to determine the mechanism of erosion and the erosion velocities of the solid bed formed in a concentric annulus for three flu-ids, water, a low concentration water solution of Carboxyl-methyl-cellulose (CMC), which behaved as a Newtonian fluid and a higher concentration CMC water solution which behaved as a power law fluid. Glass spheres of 2 mm nominal diameter were used as solids. The flow rate at which erosion occurred together with the mechanism of bed erosion were determined visually, while the whole process was video recorded. Our tests indicated different erosion mechanisms and different erosion velocities for the three tested liquids, with the liquid viscosity playing a major role. The first mechanism, observed for water flow, gives erosion from the front of the bed while the second mechanism, observed for the flow of the two viscous fluids, gives erosion from the top of the bed. The role of each of the parameters to erosion is investigated, whether it is turbulent flow with the turbulent fluctuations being more capable to remove the solids from the formed bed or whether it is liquid viscosity, which results in the hydrodynamic shearing force. The results demonstrate that liquid viscosity plays a role in the erosion mechanism and yields different erosion velocities of the solid bed hence, it should be taken into account when modeling flow pattern transitions for solid-liquid flows. Prior studies have not identified this and it could be the reason of the disagreement between theoretical models and experimental and field data.

Jan 1, 2006

By James A. Bloom

To operate the Morris Fork Preparation Plant with a closed water circuit has been an elusive goal for Union Carbide. The benefits of a closed circuit have never been questioned. The removal of fine solids from washery water makes possible the recirculation and reuse of the water. Heavy media drag tanks and other separating machines perform better and more consistently with washery essentially free of fine solids. Finally, the production of a clarified effluent makes unnecessary the sludge ponds usually associated with a coal preparation plant. Why then do I say elusive? Because, since plant design was completed in 1970 we have been in hot pursuit of an ever-growing fine solids problem. In four years the minus 28 mesh material in the plant feed has nearly doubled. The replacement of conventional sections with continuous mining machines has led to a lowering in size and quality of product from the mine. In addition, increasing emphasis underground on roadway clean-up has contributed to the fines problem.

Jan 1, 1975

By M Player, R Klug, N Schwarz

There are several technologies available for thickening and dewatering of mining process slurries. The most commonly used are thickeners and filters, but technological developments have made solid bowl decanter centrifuges a viable option and their use, as a modern and alternative technology, is being considered more and more. In terms of tailings, the main goal for all mine operations is to minimize operating costs and the environmental impact of the disposed material. The high potential risk of wet tailings storage in tailings dams is causing this technology to become unpopular, and there is a strong drive in many parts of the world, by governments, communities and environmental agencies to limit any further construction and use of such facilities. For the alternative disposal method of dry disposal of tailings, two aspects of the process have to be evaluated, namely the maximum dryness of the separated solids and the maximum liquid recovery. For most mining operations dry disposal is a new concept. Presenting these companies with examples of operations where this processing option has been successfully applied and proven, will help them to adapt to the changing requirements in the future. Focus has been placed on adapting decanter centrifuges to the mining environment. Modern decanters stand out in terms of their small footprint, low water demand, high availability and their high degree of automation, combined with the excellent cost / performance ratio. Decanter centrifuges have started to play a key role in applications such as tailing dewatering, drilling and tunnelling muds processing, hydrometallurgical processes of gold, nickel or zinc and separating crud in solvent extraction plants. This paper will present advantages of decanter centrifuges compared to the traditional technology and corroborate these advantages by case studies.

Jul 1, 2021

By Richard A. Cubeta

Precast concrete segments have been used in sanitary sewer tunnel design for decades. Federal mandates (reduction in heavy metals and I & I), and system design changes (increased retention times) and other factors have exacerbated corrosion problems. In an effort to combat the ever-growing effect of microbiologically induced corrosion, owners, engineers, and designers have been specifying thin-film lining systems to protect precast concrete segments. These systems have compatibility and installation issues. Chemical additives or calcareous aggregates have been utilized in precast concrete, but have only proven to retard the rate of corrosion and do not eradicate the problem. Solid cast polymer segments are stronger than precast concrete, do not require linings or coatings, are impervious to ground water infiltration, and, above all, are inherently corrosion resistant through and through.

Jan 1, 2008

By D E. Langberg, J S. J va, D R. Swinbourne

Specifications on the types and levels of impurities tolerable in metals are becoming increasingly stringent, and are pushing the limits achievable with conventional refining technologies. Particularly difficult is the removal of electrochemically noble elements with low volatilities, such as copper, from more active host metals such as lead, iron and aluminium. Electrochemical refining, utilising the ability of certain solid electrolytes to selectively transport copper or other impurity cations away from the molten host metal into a separate refining phase, may provide an answer to this problem. Numerous studies on solid electrolytes used in concentration sensors have been reported, as well as a limited number on metal refining. Oxygen anion conducting solid electrolytes have been applied to the deoxidation of copper and steel while cation conductors, eg ¯ -alumina and Nasicon materials, have been used to remove lithium and sodium from aluminium. However, solid electrolytes have yet to be applied to the removal of noble elements. The behaviour of solid electrolytes under the extreme conditions of molten metal refining is not well understood. This paper will examine the potential use of solid electrolytes to remove noble metals such as copper from active host metals such as iron. The suitability, and selection criteria of available solid electrolytes for implementation in the metal refining industry in the future will be discussed. In particular, the stability of Cusicon, a copper superionic conductor potentially suitable for use in metal refining, has been assessed and the results of the experiments are presented.

Jan 1, 2000

During the 1998/99 Asian crisis Solid Energy's export revenues collapsed from over US$70M to under US$40M. Simultaneously, domestic market uncertainty led to decreases in volumes and prices. A major new underground mine was not technically viable, and was closed, and several other mines were marginal. Less than two years later, Solid Energy and its JV partner closed a second new underground mine. The company was in financial crisis, and reported an $86M loss for 1998/99. After refinancing with stringent workout conditions it still had minimal returns due to low prices, unaffordable transportation costs and huge unrealised FX losses as the NZ dollar fell 40 per cent in value. The obvious scenario was to æcash upÆ û complete extraction at remaining mines, sell off any viable parts of the business, pay off debt and wind the company down.In 2002 Solid Energy has completed its recovery. Although margins remain slim and volatile in both export and domestic markets, it is achieving record volumes and revenues. It has paid off its shareholder loan, has minimal remaining FX losses, and cashflow is allowing further mine and infrastructure development. The key to the turnaround has been implementation of rigorous planning, analysis and decision-making in all aspects of the business. The company has a comprehensive, rolling 20-year plan used annually to update rolling five year and annual business plans. Solid Energy augments strong line management operations with rigorous standards and processes for mine planning and development, operational decision-making, and functional support. Detailed, quantitative risk analysis is used in all aspects of the business and allows comprehensive integration of opportunity and risk management across all activities in the company.Coal mining is widely perceived as an æold-economyÆ industry. But, like other successful æold economyÆ companies, the information systems and management processes used by Solid Energy are as leading edge as any in the high-tech sector. They are the key to managing to add and sustain maximum value for a company that has access to coal resources sufficient for hundreds of years.

Jan 1, 2002

By Harold E. Rowen

Sintering is accomplished at a temperature of more than 2000°F. For the purpose of this discussion it will be defined as the art of burning a solid fuel with 90 to 95 pct ash content. Think of the problems of combustion involved in keeping a home furnace burning properly with 12 to 20 pct ash in the fuel and remember that the amount of fuel involved in the 5 to 10 pct combustion loss represented by the definition has to be just about right or nothing is going to happen. Our forefathers discovered that many ores containing metals csscntial to the steadily rising standards of living were associated with other minerals, sulfur and arsenic, for example, which had to be removed before ultimate refining. They did this by utilizing the solid fuels they had available-the sulfur or other readily combustible components- to create roasting heat.

Apr 1, 1956

By H. EI-shall

In this paper, the results of a fundamental study involving zeta potential and turbidity determinations of solid suspensions are discussed. Illustrations of how these results are utilized to design field applications of solid grade polymers to clarify mine drainage water are presented. Other applications in different industries are also reported. The operational and economical advantages are examined.

Jan 1, 1994