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By R. L. Grayson, T. Simonyi, R. A. Andrel

"The purpose or this paper is to disclose analytical, statistical, and observational results relating to mineralogy and trace elements in respirable dust samples collected from two different mines in West Virginia. Samples were taken from longwall panels, and the panels operated in different coal seams, one located in the northern part or the state and the other in the southern region. Mining conditions and equipment arrangements on the panels will be described along with dust control techniques used. Results from sample analyses are summarized with emphasis on relationships between mineralogy, trace elements and mineral particle size to worker locations. Correlations are made between micro x-ray diffraction and energy dispersive x-ray analyses for sample mineralogy.IntroductionThrough the work of many researchers worldwide, the health of coal miners in modern societies is now protected from harmful exposure to respirable coal mine dust. A vast amount of research culminated in the exposure-response model of Jacobsen, et al, (l) which has been used to establish the 2 mg/m3 exposure limit in the United States. According to the model exposure to respirable dust for 35 years at this level or less could prevent the occurrence of a clinically significant case of coal workers' pneumoconiosis (CWP) in a miner. The exposure limit, of course, must be adjusted whenever greather than five percent free silica exists in the respirable dust.The Jacobsen model was built around a mean mass concentration exposure, which generally showed the highest correlation with both incidence and progression of CWP. As Morgan, et al noted, however, the quantity of respirable dust inhaled is not the only significant factor. 2) They noted that although mass of respirable dust correlates highe.st with the incidence of CWP, it is not a causal factor. Admittedly, the insidious processes causing the disease occur at the lund cell-dust particle level."

Mar 1, 1989

By Anish Kumar

Keywords: Ultrasonic velocity, Poisson?s ratio, Elastic constants A new correlation has been established between two independent elastic properties, ultrasonic shear wave velocity and Poisson?s ratio, in a wide variety of isotropic solid materials, such as pure metals, ceramics, polymers and intermetallics. It has been shown for the first time that Poisson?s ratio decreases with increase in elastic moduli, E & G and ultrasonic velocities. This new correlation between two independent elastic constants may lead to the reduction in independent elastic constants for isotropic solid materials from two to one, at least for a given alloy system with different microstructural conditions.

Jan 1, 2005

By C Li, D O’Dea, R Moreno-Atanasio, T Honeyands

The behaviour of iron ore granules in the feeding process of sintering is significantly influenced by the material properties of the granulated mix. Therefore, the measurement of key material properties of the iron ore granulated mix is indispensable prior to the simulation of the sintering process based on the discrete element method (DEM). In this paper, three key property parameters of the iron ore granulated mix, apparent density, elastic modulus and rolling friction coefficient, were measured in laboratory-scale experiments. For different sintering processes, the moisture content of the granulated mix normally varies according to the specific requirements for granule size distribution and operating conditions. Therefore, understanding the effect of moisture content on the property parameters of iron ore granules is very helpful in accurately determining the property parameters for DEM simulation work. In this paper, six groups of iron ore granule samples with six levels of moisture contents were prepared through granulation and the trends in apparent density, elastic modulus and rolling friction coefficient with the increase of moisture content were plotted and analysed based on the measurement results. The results show that as moisture increases from 6.9 per cent to 9.1 per cent, the apparent density decreases from about 3000 to 2800 kg/m3. With moisture increasing within the same range, the elastic modulus first decreases from over 200 MPa to below 100 MPa and then reaches a relative constant value of about 40 MPa at higher moisture contents. Rolling friction coefficients are measured using two methods with both indicating a similar trend, with the rolling friction coefficient first decreasing and then rising as moisture increases from 6.9 per cent to 9.1 per cent. The relationship between µr and µ’r is assumed to be similar to that between static and dynamic friction coefficients.CITATION:Li, C, Moreno-Atanasio, R, O’Dea, D and Honeyands, T, 2017. Variation in property parameters of iron ore granulated mix with moisture content, in Proceedings Iron Ore 2017, pp 79–84 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Hargraves A. J, Smith J. W

Experiments conducted at Tahmoor Colliery, Sydney Basin, have demonstrated the variability in chemical and isotopic composition of seam gases issuing from boreholes in the Bulli seam and desorbing from lump coal from the same source.From this work it appears that an immediate preferential release of methane accompanies the physical disturbance of the coal seam by penetration with development or drilling or by detachment. In addition, both early released methane and carbon dioxide are depleted in 13C relative to later desorbed gases, therefore the analyses of gas samples taken after such events may not reflect the true bulk composition of the undisturbed seam gas in situ. A method for overcoming this problem by taking gas samples at depth in the "steady state" is proposed.

Jan 1, 1987

By Webber. G. R.

Variation in content of some of the major and minor elements in the Lake Dufault granodiorite near Noranda, Quebec has been studied. The element variation and specific gravity data show a pattern consistent with the concept of a concentrically zoned intrusive on the western side of Lake Dufault with a potassium-rich core and a calcium-rich inner zone. The part of the intrusive on the eastern side of Lake Dufault is of more problematical origin, but the suggestion is made that it has resulted from assimilation of volcanic rock by the intrusive. THE purpose of this investigation was to test the application of x-ray fluorescence analysis to the study of variation in chemical com-position of the Lake Dufault granodiorite. The Lake Dufault granodiorite is an intrusive body approximately six miles long by three miles wide located four miles north of Noranda, Quebec. This intrusive is of particular interest because of its -

Jan 1, 1962

By Paul Hagan

A diverse range of rockbolt designs and resin anchors are available for use in underground mines. Despite their wide spread use, the factors that affect the performance a rockbolt is not fully understood. The laboratory-scale rockbolt test facility at the UNSW Mining Research Centre is being used to gain a better understanding of the behaviour of rockbolts leading to an improvement in ground support. A test program investigated the nature of load transfer between a fully encapsulated rockbolt and the surrounding rock mass. It was found that with all other factors held constant, there were differences in the behaviour of load transfer depending on the method of loading. The typical pull-out arrangement as used in most field test work resulted in a different load transfer function to that observed when the load on the rockbolt was induced through bed separation.

Jan 1, 2004

By Neil J. Mansfield

Tool manufacturers are required to provide declarations of vibration emission values in order to sell their tools within Europe. To ensure that users can compare results obtained from different manufacturers, the declared values must be obtained using a methodology as specified in the relevant test code (such as in the ISO 8662 series of standards). In most cases, the vibration emission values obtained using test codes under-estimate the vibration that an operator will be exposed to when using the tool on a work-site. A further problem with manufacturers’ data is that usually only a single value is provided for a tool. This is despite many factors affecting the vibration emission, including inserted tool type, work piece, operator technique, tool condition. New improved test codes are in the process of being developed. In order to provide guidance to users on how to interpret manufacturers’ data, a Draft CEN Technical Report (Draft CEN/TR 15350 (2005)) was developed. Part of the CEN/TR provides multiplication factors for combinations of task and tool type. For example, data obtained from electrical hammer drills (tested according to EN 60745-2-6:2003) should be multiplied by 2, for hammering applications, in order to obtain an estimate of the vibration emission during work. In response to concerns from industry, the UK trade association OPERC have, in collaboration with hire companies and tool manufacturers, established a freely accessible online database of tool emission values based on independent tests carried out under simulated work-site conditions. This paper reports some of the data obtained from electrical hammer drills, highlighting the range of emission values that can be obtained for a tool. Data from many other tool types are also included in the database. Methods Tri-axial hand-arm vibration was measured at both handles of each of 19 electrical hammer drills, in accordance with ISO 5349-1 (2001). Each tool was measured with three experienced operators and at least 5 runs were completed for each operator. Tools were tested using a range of appropriate new bits from 4 to 40 mm diameter. The minimum number of bits for a tool was 3; the maximum number was 29. 146 tool / bit combinations are reported here, representing about 2200 individual 6-axis measurements. Operators were required to drill vertically into a concrete block with a compressive strength after 28 days of 40 N/mm². Two drills (1 and 15) were battery powered; others were powered using a 110V transformer supply.

Jan 6, 2006

By D. H. Whiting, A. J. Sinclair

"The San Antonio gold mine, in the Archean Rice Lake Greenstone Belt, was in continuous production from 1932 to 1968, during which period the mine yielded 1.35 million ounces (41 985 kg) of gold and 195,000 ounces (6065 kg) of silver from 4.88 million tons (4.44 Mt) of ore for average grades of 0.28 ounces per ton (9.0 g/t) gold and 0.04 ounces per ton (1.3 g/t) silver. After the 1968 closure, several publications appeared implying that gold grade of ore decreased with increasing depth.Recent observations by the authors show that the relatively low grades in the middle levels of the mine are controlled geologically. However, the reduced average are grade in the lower levels of the mine was due to inadequate mining control that led to a high level of dilution. The similarity of geological factors such as vein styles within structural domains, variations in mining control, recent ore muck sampling results and lithogeo chemical profiles all indicate the similarity of ore in both upper and lower levels.Strict mining control should yield improved grades of gold for future production from the lower levels at San Antonio, in contrast with the production grades of the late 19605that represented extensively diluted ore. High-quality production records are an essential component in re-evaluating a past producer, particularly where workings are accessible. Poorly founded conclusions which cannot be checked by access to workings can have a negative impact on the evaluation procedure."

Jan 1, 1990

By Dennis R. Dolinar

In general, the direction of the maximum horizontal stress in the eastern United States is fairly well defined. However, the variation of the magnitudes of the horizontal stresses is not very well understood. Because the horizontal stresses cause severe ground control problems in underground coal and limestone mines throughout the eastern United States a more complete understanding of how the magnitudes vary would be useful for developing mine design strategies to combat horizontal stress related ground control problems. Therefore, in this National Institute for Occupational Safety and Health (NIOSH) study, the variation of the magnitude of the horizon stresses in sedimentary deposits in the eastern and Midwestern United States are examined with respect to two factors, the elastic modulus of the rock and the site depth. Stress measurements from thirty-seven sites are used in the evaluation. Examining the applied excess strains indicates that the eastern United States can be, separated into high and low strain zones. For most of the eastern United States the maximum applied excess or tectonic strain ranges from only 300 to 550 micro strains. However, there is one area, a portion of the Beckley seam in the central Appalachian region where the strains are significantly higher than the other regions. In this higher strain zone, the maximum applied tectonic strains range from 700 to 1,000 micro strains. Regression models for each zone based on the elastic modulus can explain between 83 to 85% of the variation of the maximum horizontal stress. Because one region, the northern Appalachian district, has strains that are about 20% higher than the other regions in the low strain zone, multiple strain models based on geographic regions were developed for the low strain zone that can explain 87 to 91% of the maximum horizontal stress variation with the elastic modulus. Depth was found not to be a significant causal factor in any increase in the horizontal stress even though the site depths ranged from 275 to 2,500 ft. Beyond a theoretical increase, based on Poisson’s effect and gravity, no other increase in the horizontal stress with depth can be justified with this data. The most significant factor controlling the variation of the maximum horizontal stress is the elastic modulus of the rock, not the overburden depth.

By Dennis Dolinar

In general, the direction of the maximum horizontal stress in the eastern United States is fairly well defined. However, the variation of the magnitudes of the horizontal stresses is not very well understood. Because the horizontal stresses cause severe ground control problems in underground coal and limestone mines throughout the eastern United States a more complete understanding of how the magnitudes vary would be useful for developing mine design strategies to combat horizontal stress related ground control problems. Therefore, in this National Institute for Occupational Safety and Health (NIOSH) study, the variation of the magnitude of the horizon stresses in sedimentary deposits in the eastern and Midwestern United States are examined with respect to two factors, the elastic modulus of the rock and the site depth. Stress measurements from thirty-seven sites are used in the evaluation. Examining the applied excess strains indicates that the eastern United States can be, separated into high and low strain zones. For most of the eastern United States the maximum applied excess or tectonic strain ranges from only 300 to 550 micro strains. However, there is one area, a portion of the Beckley seam in the central Appalachian region where the strains are significantly higher than the other regions. In this higher strain zone, the maximum applied tectonic strains range from 700 to 1,000 micro strains. Regression models for each zone based on the elastic modulus can explain between 83 to 85% of the variation of the maximum horizontal stress. Because one region, the northern Appalachian district, has strains that are about 20% higher than the other regions in the low strain zone, multiple strain models based on geographic regions were developed for the low strain zone that can explain 87 to 91% of the maximum horizontal stress variation with the elastic modulus. Depth was found not to be a significant causal factor in any increase in the horizontal stress even though the site depths ranged from 275 to 2,500 ft. Beyond a theoretical increase, based on Poisson's effect and gravity, no other increase in the horizontal stress with depth can be justified with this data. The most significant factor controlling the variation of the maximum horizontal stress is the elastic modulus of the rock, not the overburden depth.

Jan 1, 2003

By Clarence Zener

THEORETICAL considerations by one of the authors have led1 to the prediction that the dynamic internal friction of annealed metals has a broad maximum at a certain grain size. This prediction they have veri-fied2 for alpha brass. In the present paper the theory is extended to include the precise manner in which the internal friction varies with grain size on either side of the maximum. New experimental data are pre¬sented to test this extended theory. The physical basis for the type of internal friction that is being investi-gated lies in the interplay between stress and temperature. Just as local fluctuations in temperature give rise to local fluctuations in stress, so like-wise fluctuations in stress give rise to fluctuations in temperature. But temperature gradients give rise to necessarily irreversible thermal cur-rents, and hence to internal friction. The theory for this type of internal friction has been developed quantitatively,3 and has been experimentally verified,4,5 for the particularly simple case of the transverse thermal cur-rents accompanying transverse vibrations. Of more fundamental impor-tance are the intercrystalline thermal currents accompanying all types of vibration. The variation in stress across grain boundaries arises from the elastic anisotropy and at least partial random orientation of the individual crystallites. An exact quantitative treatment of the internal friction due to these thermal currents is of course out of the question. However, much information can be obtained from general arguments.1,6 Thus when the frequency of vibration f is low, or when the grain size d is small, adja-cent grains remain nearly in thermal equilibrium, and vibration proceeds isothermally with little internal friction. Again, when the frequency is high, or the grain size large, the heat flow per cycle is small, the vibration proceeds adiabatically with little internal friction. The internal friction will become a maximum in the transition region. The degree of adiabatic-

Jan 1, 1940

By Tatsunori Matsumoto

In order to investigate the variation of the load-displacement relations of piles in a site, vertical load tests were carried out on 25 small diameter steel pipe piles. Out of 25 piles, 15 piles were close-ended pipe piles attached with a blade at the pile toe and 10 piles were open-ended pipe piles. To carry out these load tests in a short period, two types of rapid load test methods, Spring hammer load test and Falling mass load test, were employed. The load tests of all piles were completed in two days with 180 blows in total. In order to estimate a static load-displacement of a pile, non-linear damping method was used. It is shown from the test results that the performance of the pipe piles such as the ultimate pile resistance and the initial pile head stiffness is improved by re-driving.

Jan 1, 2006

By Ross W. Smith

In recent years there has been a considerable amount of research work done relative to the effect of pretreatment and aging in water on the surface properties of both simple metal oxides and more complex oxides such as the silicate minerals 1-6. Of particular interest is the work of Somasundaran6 who states that after preparing minerals by size reduction and washing with dilute acids "... it is essential to treat it (the mineral) with water in order to remove any effects of leaching itself." Somasundaran also states, "... it is advisable to use a solution close to the point of zero charge for conditioning purposes." Parksl notes that, "Dehydration, dehydroxylation, and increased crystallinity can be expected to decrease the PZC. The presence of anionic impurities or of pH-independent potential determining ions will decrease the PZC. Cationic species will increase the PZC." Healy and Jellett4 believe that in the Zn0-water system "the surface charge of Zn0 in water and each pH is determined by the concentration and adsorption of each hydrolyzed (charged and uncharged) Zn(II) species." Finally, according to Parks 2, "The PZC of an unaltered com¬plex oxide in a system devoid of specific electrolytes is approximately the average of the PZC's of its component oxides... Equilibration with water results in loss of mono and divalent cations by exchange with H+, thus a loss of influence on the PZC by those cations, i.e., a shift in the PZC with time in the direction of that remaining oxide. The present paper investigates the change of point of zero charge (PZC) of a number of simple oxides and several complex oxides as a function of aging time in water. In some cases acid pretreatment of minerals was performed. However, in most cases the minerals were not acid pretreated. In several systems pH change as a function of aging time in water was monitored.

Jan 1, 1972

By Ross W. Smith, Nikhil Trivedi

The variation of point of zero charge (PZC) of both simple and complex oxide minerals was studied as a function of aging time in water. In most cases the PZC's of the simple oxides moved toward more basic pH values with aging time. Evidence to date suggests that this phenomenon relates to dissolution of disturbed layers on the mineral's surface accompanied by later readsorption of metal hydroxy species back onto these surfaces. The readsorption takes place after the solution becomes supersaturated with respect to some crystalline phase. The variation of PZC's of complex oxides as a function of aging time in water is apparently related to several different mechanisms. In a few cases PZC shifted toward more basic values with time. This shift could be attributed to much the same mechanism as for simple oxides. In most cases, however, PZC of complex oxides shifted toward more acid values with aging time, probably because of loss to solution of soluble cations whose oxides possess basic PZC's.

Jan 1, 1975

By R. R. Klimpel

Introduction The grinding of coal-water slurries has received increasing industrial attention during the last decade. In particular, there is long-term interest in the use of pulverized coal-water slurries to replace oil in combustion equipment and in the development of coal gasification/liquefaction processes that require coal-water slurries as feed. More specifically, the use of coal-water slurries in gasification requires grinding a high-density slurry containing the smallest amount of water consistent with slurry pumping and spraying. As part of a fundamental engineering research support program aimed at the industrial implementation of dense coal-water slurry grinding, this author has published several papers on how specific rates of breakage vary as a function of slurry rheology (Klimpel, 1982,1982/83). These papers demonstrated that there is a consistent pattern of change in specific rates of breakage of coal in dense slurries with controlled variation in slurry rheology. By matching rheological data with laboratory grinding results, it was possible to identify directly slurry conditions that correspond to: 1) slowing down of breakage rates, 2) the occasional acceleration of breakage of some sizes, and 3) conditions where chemical additives will increase rates of breakage. In brief, these conditions were analyzed using two different criteria: a) the net production rate of material less than some specified size (e.g. kg/min of minus 325 mesh) in a standard batch laboratory mill test as a function of controlled changes in grinding conditions, and b) the use of the one-size-fraction feed method, which consists of following the disappearance of this largest size over grinding time in a batch laboratory mill to arrive at well-known specific rates of breakage (Austin et al., 1984). Detailed references to the methodology used as well as the conclusions are available (Klimpel, 1982, 1982/83) and will not be repeated here. The purpose of this paper is to further demonstrate several additional characteristics of dense coal-water slurry grinding that were shown in a simplified sense in the earlier publications of the author but which have clearly demonstrated themselves as being very important in the industrial simulation and scale-up of such coal-water grinding systems. In particular, this includes the clear and unambiguous demonstration of how the simultaneous acceleration of breakage of some size fractions and slowing down of the breakage of other size fractions is occurring as a function of changes in coal-water slurry density. In the earlier publications (e.g. Klimpel, 1982), it was shown by specially designed experiments that the addition of fine material and/or the use of a chemical thickening agent accelerated the specific rates of breakage of coals of coarser size fractions using the one-size-fraction method. There were also numerous examples given of non first-order breakage (the slowing down of coal breakage rates) using also the one-size-fraction method due to the presence of excessive amounts of fines which corresponded to the development of a rheological yield value. The problem with the simulation and scale-up of any laboratory and/or pilot-scale mill data to an industrial scale using the mechanistic modelling approach involving specific rates of breakage and breakage distribution parameters (e.g. Austin et al., 1984) is the number of assumptions involved in translating the smaller mill breakage parameters to the predicted larger mill breakage parameters. It is apparent, at least to this author, that to accurately simulate and predict larger scale equipment performance from smaller scale data (given that the larger scale data performance is known and hence predictions can be thoroughly checked) requires a better knowledge of breakage parameters than is currently available. More specifically, it was felt that one of the chief problems was the inability of the one-size-fraction method of determining breakage parameters to sufficiently represent the actual magnitude and sometimes even the directions of. the complicated interactions involved with slurry density changes in coal-water slurry grinding. Thus, a special set of experiments was conducted in a somewhat larger batch ball mill (0.457 m diam x 0.610 m length) than the 0.203-m-diam mill used in the original rheology characterization paper (Klimpel, 1982) so as to minimize any unusual effects due to wall-ball interactions (2.54-cm-diam balls used in both mills). More importantly, the measurements of specific rates of breakage were done using a proprietary tracer method on a portion of a given size fraction, which was then remixed into a natural feed size distribution before grinding. The experimental procedure and analysis of subsequent data was done in exactly the same manner as the radioactive tracer technique on coals as originally developed by Gardner (1962). The advantage of such an approach is that it makes no assumptions such as the independence of the specific rate of breakage of any size on the absolute sizes and amounts of other sizes present (both larger and smaller) in the mix of natural feed material. It will be shown that the measured rates of breakage using the direct tracer technique and the one-size fraction method on the same coal are indeed different. In fact, an accurate assessment of what is happening to the rates of breakage as a function of changing slurry density can only he made by measuring particle breakage under grinding conditions approximating the size distributions actually being produced in practice. Experiment procedures and results The pilot mill used was 44 cm diam x 60 cm long with a volume of 91,250 cm3 and was fitted with six 0.5-in. lifter bars.

Jan 1, 1992

By R. R. Klimpel

The grinding of coal-water slurries has received increasing industrial attention during the last decade. In particular, there is long-term interest in the use of pulverized coal-water slurries to replace oil in combustion equipment and the development of coal gasification/liquefaction processes which require coal-water slurries as feed. More specifically, the use of coal-water slurries in gasification requires grinding a high density slurry containing the smallest amount of water consistent with slurry pumping and spraying. As part of a fundamental engineering research support program aimed at the industrial implementation of dense coal-water slurry grinding, this author has published several papers on how specific rates of breakage vary as a function of slurry rheology, Klimpel (1982, 1982/83). These papers demonstrated that there is a consistent pattern of change in specific rates of breakage of coal in dense slurries with controlled variations in slurry rheology. By matching rheological data with laboratory grinding results, it was possible to identify directly slurry conditions that correspond to: (1) slowing down of breakage rates, (2) the occasional acceleration of breakage of some sizes, and (3) conditions where chemical additives will increase rates of breakage.

Jan 1, 1990

A slag-metal equilibrium study of the system SnO-FeO-(Si02+Al2O3)/Sn-Fe was carried out at 1250°C. The distribution coefficient, k =(Sn/Fe)metal X (Fe/Sn)slag was found to range from 246 for an iron contentof 0·53 per cenrt in the metal to 82 for an iron content of 6·4 per cent. The value of the ratio ?SnO/?FeO was calculated and found to be approximately a function of per cent SnO in slag alone in the region (Si02+Al2O3)/ FeO = 0·4 to 1·2. Comparison with other published work suggests that the addition of CaO to slags having (SiO2+Al203)/FeO ratios of about 1·1 raises the value of ?SnO/?FeO...

Jan 1, 1974

By R. J. Good

It is well known that the elimination of impurities such as iron pyrite, shale, clay, silica, etc., from coal, by floatation [Sun, 1954; Aplan, 1983] and selective oil agglomeration [Keller and Burry; 1990] depends on the fact that coal is hydrophobic, and the impurities are hydrophilic. The water contact angle has long been used to evaluate the hydrophobic nature of coal, first by Brady and Gauger (1940), who demonstrated that the contact angle of water on coals increases with rank, and passes through a maximum at about 88% carbon. Brown (1962) found that the contact angle of coal decreased with increasing ash content. Sun, and also Aplan, have reported a direct relationship between values of the contact angle and rank, and have related the contact angle to coal floatability. Horsley and Smith (1951) first demonstrated that the captive bubble contact angle may be used to characterize the hydrophobicity of a coal containing more than 80% carbon DAF, while Parekh and Aplan (1978) have shown that the sessile-drop technique may be used to evaluate the hydrophobicity of coal of any rank.

Jan 1, 1992

By A. Demirci, A. Keçeciler, Y. S. Durutürk

"This paper deals with the results of the variation of thermal conductivity of rocks with pressure on a laboratory scale. For this purpose, the authors have added a pressure-supplying unit to the apparatus developed by Mousset-Jones and McPherson (1986), Önder (1995), Ashworth and Ashworth (1979), and Innaurato and Occella (1989) in order to measure the thermal conductivity under pressure. The values obtained from the tests performed by this new apparatus have been stated using a regression analysis and the related graphs have been drawn. Results have shown that the thermal conductivity of rock varies digressively with pressure. The same results have been obtained in different rocks types. IntroductionOne of the most important tasks of mining engineers is that of establishing, maintaining and sustaining safe and healthy working conditions in underground mines.Heat can have a profound effect on safe and healthy working conditions and is one of the main problems in deep underground mines. In this regard, the temperature of the air passing through the mine openings increases steadily and causes a decrease in the efficiency of workers due to the unwanted physical effects to human bodies in the working area. At the same time, the hot and humid environment resulting from heat and temperature rise causes some important occupational diseases and increases the accident risks in the related openings."

Jan 1, 2002

By A. D. Mutch

IT has long been known that there are wide variations in the thermo-electric potential of pyrite. In the last few years a study of this variation and other properties of pyrite was carried out at the University of Toronto by F. G. Smith on specimens of pyrite from many localities.1-3 As a result of these studies the pyrite geothermometer was developed by Professor Smith. The calibration of the pyrite geothermometer is based on the assumption that "crystals of any one electronically conducting mineral species deposited at a high temperature have a more positive thermo-electric potential than crystals deposited at a low temperature, and the thermo-electric potential varies continuously between any given limits of the temperature of deposition." The cause of the variation was postulated to be crystal discontinuities, such as lineage boundaries. As yet this postulated relationship has not been established as fact. On theoretical grounds it is indicated that the thermo-electric potential of pyrite or any other partial conductor is dependent upon a number of factors as well as the temperature of formation. For this and other reasons there is ground for doubt as to the validity of the relationship postulated above. To date a large number of readings have been made with the pyrite geothermometer which have been recorded in terms of the calibration of the instrument in degrees centigrade. So far most of the pyrite tested by this technique has been in association with gold ore. The values for the temperature of formation obtained in these tests appear to be reasonable and, in relation to geological problems, to vary in the right sense. Determinations on some specimens not in association with gold ore have given readings that appear to be much too high, taking into account the probable maximum temperature of the host rock. To sum up, although many determinations made with the. pyrite geothermometer appear to give reasonable values for the temperature of formation of the pyrite, there are at the same time other readings which seem anomalous. On the basis of an examination of available results of work with the pyrite geothermometer, two problems must be considered: 1-the validity of the calibration of the pyrite geothermometer; and 2-the nature of the distribution of the thermo-electric potentials of pyrite in relation to the specific problems that have been examined. In this paper the academic problem relating to the validity of the calibration of the pyrite geothermometer will not be discussed. Instead, the variations of thermo-electric potential of pyrite in association with gold veins will be discussed with regard to specific examinations. The first of these two examinations deals with the distribution of thermo-electric potentials of pyrite in association with a gold vein and was carried out in the McIntyre Porcupine Mine, Schumacher, Ont., in the summer of 1949 as part of a study with this technique. The second problem deals with variations of thermo-electric potential of pyrite in gold ore specimens from all over the world. The specimens used in this study were part of the private collection of Frank Ebbutt, geologist for Howe Sound Exploration Co. Results of Detailed and Reconnaissance Studies In discussion of the results of determinations made in these two studies the values of thermo-electric potential in millivolts will be used. It will be noted that in some of the diagrams the determinations are recorded in terms of pyrite geothermometer temperatures. Fig. 1 is a calibration chart relating, pyrite geothermometer temperatures and thermo-electric potentials. A full discussion of the technique is given in the original paper by F. G. Smith.' Briefly, the determinations are made by placing two stainless steel probes, one hot and the other cold, against the surface of the pyrite crystal being tested. The thermo-electric potential that is developed is read with a null-point potentiometer that is calibrated in what

Jan 1, 1952