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By Andrew Corry

GEOPHYSICAL investigations based on radioactivity have been applied to the earth's crust for the purpose of discovering bodies rich in radioactive substances, or for the location of solutions with high emanation or radioactive-salt content, or for the detection of oil, which, in virtue of colloidal properties, has strong powers of radioactive absorption. RADIOACTIVE SUBSTANCES Radioactive substances are distributed in all rocks, waters, and gases in the earth's crust in small quantities. Granites and similar acidic rocks are richest in uranium and thorium, two chief radioactive substances; yet the quantities present in such rocks are of the order 10-12g., this concentration being expressed in grams per gram of the whole substance per cubic centimeter. In granites the uranium yields, according to Haddock, 3 X 10-12 g. of radium per gram of rock. In basalts the uranium yields 1.19 X 10-12 g. per gram per cubic centimeter. Of thorium the granites yield -2 X 10-5 g. per gram of rock; the basalts, 0.77 X 10-5 g. per gram. Certain series of alkalis of low atomic weight, like potassium and rubidium, show weak radioactivity; this property has no significance so far for geological research. The uranium is esti-mated indirectly from the electrical properties of one of its derivatives as a -gas (emanation) into which it is transformed. The thorium is expressed directly, though it is measured as a derivative, thorium emana-tion. There is a measure for the gaseous radium emanation, the curie, which is that quantity of radium emanation, or radon, which stands in equilibrium with 1 g. of radium. The concentration of the emanation is the Mache unit corresponding to 3.64 X 10-10 curie per liter. When gases become permeated by alpha, beta, and gamma rays, plus and minus ions are produced in them by the decomposition of neutral gas molecules, and under the influence of an electrical field these ions are given opposite motions. The measurement of the alpha rays and the bisection thicknesses of the beta and gamma rays is a means of analyzing unknown radioactive substances. These rays accompany the disintegration of radioactive substances and arise from "spontaneous internal changes

Jan 1, 1929

By R. W. Boyle, W. Dyck

"Scientists throughout the world have observed radioactive disequilibrium in the uranium decay series. Radiometric and fluorometric determinations of U in plants from the Goldfields district and in sediments and rocks from the Beaverlodge district exhibit marked radioactive disequilibrium. The eU/U ratio in plants rooted in mineralized ground shifts from greater than unity to less than unity for those rooted in background soils. A similar shift is observed in the transition from rocks to stream sediments and to lake sediments in the Beaverlodge district.Results of a Rn-Ra-U survey of lake bottoms in the Key Lake district show that anomalous hydromorphic U from U mineralization is parallelled by anomalous Rn, even though there is much less Ra in the lake-bottom sediments than one would expect from the amount of U present. IntroductionDisequilibrium in the U decay series has been studied for many years and is observed in almost all surficial environments. Rosholt (1959) measured U, 234Pa, 23O'fh, 226Ra, 222Rn, and 210Pb in a large number of U ores and outlined six types of situations to explain disequilibrium. Davy (1974) outlines the geological significance of radioactive disequilibrium situations with respect to exploration. Levinson and Coetzee (1978) discuss possible mechanisms by which separations of parent and daughter elements are affected and suggest analytical pitfalls that may be encountered in the use of radiometric techniques when disequilibrium has occurred. Generally, it is the oxyphile and easily complexed parent 238U (with its associated isotopes 235 U and 234U) that is leached from rocks and soils at a faster rate than are the daughters, 230Th, 226Ra, 2loPb, and 206Pb. This mobilized U is adsorbed on sediments in streams and lakes, or enters groundwaters, where it is eventually precipitated under reducing conditions, occasionally in oregrade concentrations. This surface leaching and"

Jan 1, 1980

By A. Subbotin

During developing the Ingulska mine at the Mi-churinske uranium deposit in the central part of Ukraine the radioactive rock dumps have been piled. A height of dumps reaches to 15-25m. They occupy a large territory and can be a source of covering with radioactive dust the area around the Ingulska mine. Uranium content exceeds 0,01% in all dump rocks samples while in the dust fraction samples it ranges from 0,01 to 0,06%. Uranium content in road dust at the dump?s foot reaches 0,137%. A new (for Ukraine) method of f-radiography of tree and bush leaves sampled at the territory about 100km2 has been used. It is based on fission of 235U nucleuses due to heat neutron influence in a nuclear reactor and on following study of the Lausan films with tracks drawn by the fractures of these nucleuses. Uranium content of the dif-fusion-disseminated dust type is (0.9-22.2)?10-6% while in the individual particles it can be considered much more because of burned holes in Lavsan above them. The dust content with uranium in Kirovograd reaches to 20-50 part/cm2 while near the dumps it ranges from 100 part/cm2 to 300 part/cm2 in the radius of 1,5-2km from the Ingulska mine.

Jan 1, 2005

By L. M. Lowe, D. G. Feasby, J. R. Goode

"Rare earth resources usually contain minor amounts of radioactive elements. The most widely recognised sources of radioactivity are associated with thorium and uranium. However, also present in the resources are isotopes of rare earth elements (REE) that are themselves radioactive, including lanthanum (La-138), lutetium (Lu-176) and samarium (Sm-147). These radioisotopes, as well as remnants of the natural thorium (Th-232) and uranium (U-238, U-235) decay series, can contribute to significant levels of radioactivity in mixed REE concentrates and in separated products. Levels such as these can present challenges for transport, transboundary movement, product storage, workers’ health and safety, as well as waste management issues at the facilities that separate out the individual REE’s. These are discussed in this paper. A particularly challenging radioactive isotope is Ac-227 (a decay product in the U-235 decay series). Actinium behaves chemically similar to lanthanides and hence normally concentrates with REE multi-element composites. Reliable analysis of Ac-227 is not widely available and the methodology required to deal with this challenge is briefly described. A principle reason for minimization of radioactive content throughout REE processing is restrictive specifications by concentrate purchasers in order to reduce waste management challenges. Approaches to the minimization of radioisotope content in REE concentrates and separated products are outlined in this paper."

Jan 1, 2014

By I. Pordea

The materials used for the construction of buildings contain natural radionuclides of the U238 and Th232 series and are ? 50% due to land radioactivity. Another component of natural radioactivity is K40, with ? 40%. The presence of these radiopollutants in the final products (i.e. bricks, concrete) due to body irradiation is by two pathways: external irradiation and internal irradiation. External irradiation is due to gamma radiations emitted by Pb214 (RaB) + Bi214 (RaC) from the U238 series, by Ra228 (Mezothoriu I) + Ac228 (Mezothoriu II) + Tl208 (ThC??) from the Th232 series and by the K40 radionuclide. Internal irradiation is due to inhalation of radon (Rn222) and Rn220 (Tn) plus short life descendents (Po, Pb, Bi), radionuclides which are present in concrete. A fraction from radon present in concrete enters into a house leading to internal irradiation by inhalation. In Romania, the maximum concentration of radon allowed for new buildings is 200 Bq/m3.

Jan 1, 2008

By Alfred C. Lane

WE recently received from Professor A. C. Lane, Emeritus Professor of Geology and Mineralogy, Tufts College, Mass., and a Corresponding Member of this Institute, a very interesting account of some recent developments in radioactive methods of determining the age of minerals and, therefore, of the rocks in which they occur. It deals in particular with studies of the minerals of certain pegmatite dykes on the Huron claims and Bear claims in southeastern Manitoba, which, the results indicate, are among the oldest rocks of the earth's crust. The following article presents a non-mathematical summary of Professor Lane's paper . . It will be noted that he is anxious to obtain suitable samples of certain minerals and rocks for further age studies. We hope some o our members may be able to supply him with the material he needs. It may be well to explain briefly how the age determinations are made. Uranium is continually breaking down, or disintegrating in successive steps through radium, etc., to a final product which is lead (uranium-lead), and the rate at which this change takes place is known. Minerals containing uranium will therefore contain lead also, and the lead-uranium ratio mul-tiplied by a certain factor (approximately 7 ,600) will give the age of the mineral in millions of years. Thorium also disintegrates at a known rate to give lead (thorium-lead) as a final product, and the age of a mineral containing thorium can thus be calculated from the lead-thorium ratio. Thorium breaks down more slowly than uranium. In unit time, one gram of thorium produces about as much lead as 0.36 grams of uranium.-ED.

Jan 1, 1938

By A. M. Gsudin, F. W. Bloecher, C. S. Chan-s, P. L. De Bruyn

M ANY elements can now be obtained in radioactive form. The radioisotopes have the same chemical properties as the corresponding inactive forms, differing from them only by their nuclear instability. This combination of properties permits radioelements to act as atomic tracers, the tracer atoms revealing themselves at the time of their decay with emission of electrons and positrons (beta radiation), helium nuclei (alpha radiation), or electromagnetic radiation (gamma radiation). The tracer technique is particularly attractive for the study of surface chemistry problems in general and flotation problems in particular because of its extreme sensitivity. A large proportion of the ionizing events, initiated by the characteristic decay emissions in a radioactive sample, can be recorded by radiation probes of suitable design and geometry. An idea of this sensitivity can be gathered from the following example: assume that 0.001 mg of pure RaD (radiolead), a beta-ray emitter, is used in a flota¬tion tracer experiment. This is 1210 X 10-1 mole; since the fraction trans¬formed per second (the so-called decay constant), is 9.92 X 10-10, the number of ionizing events per second would be (6.023 X 1023 X y,,, X 10-1) X 9.92 X 10-10 = 2.845 X 106. (The decay constant is expressed in sec-'. Its product with the half life, expressed in seconds, is the pure number, natural logarithm of 2 = 0.693. The half life is the length of time required for decay of one half of the total number of radioactive atoms of one particular type.) (See reference (1) at the end of this article.)

Jan 1, 1948

By A. M. Gaudin

Introduction The discovery of artificial radioactivity, that is, of radioactivity of acorns other than those which are naturally radioactive, has increased vastly the possibility of using radioactivity as an analytical cool. The incomparable value of radioactive atoms, which are commonly termed tracers, arises from the extreme sensitivity of this analytical method. To get an idea of this extreme sensitivity it may be useful co recall that gravimetric analytical methods will not permit the weighing of anything much lighter than one-hundredth of a milligram of material. Under the most favourable circumstances, this represents an uncertainty in the answer of 1016 acorns, or 10,000,000,000,000,000 acorns. Accurate spectrographic methods possibly have a sensitivity 10,000 times greater than this, but the uncertainty is still of the order of 1012 atoms. The tracer permits ascertainment of decay of a single atom so that its sensitivity, without half trying, can be several orders of magnitude greater than that of any other method available co chemists. In addition co the sensitivity of tracers to which reference has just been made, tracers have another property which makes them unique. A radioactive atom is almost exactly like the corresponding non-radioactive acorn m regard to its electronic structure, and therefore in regard to its chemical properties. The nucleus is different, but the nucleus does not participate in chemical reactions. Therefore, a tracer acorn behaves like an ordinary atom until such time as its nucleus undergoes a catastrophic decay. This unique property permits one to use tracer acorns as atomic spies and therefore to follow the behaviour of acorns of a certain kind among their own kind. In other words, the tracer method permits us to study and measure what we call self-diffusion. All of the uses of tracers that have been made depend on the two properties co which reference has been made.

Jan 1, 1949

By G. Carman Ridland

A program of exploration for radioactive deposits, conducted in 1945 in the well-known mineralized areas of the Front Range, Colorado, was rewarded with the discovery of pitchblende in a dump at Caribou Hill. The presence of pitchblende in. the silver veins at depth apparently is not expressed as gamma-ray anomalies at the surface.

Jan 1, 1950

By G. Carman Ridland

Front Range, Colorado: The majority of the rocks comprising the Front Range of Colorado are pre- Cambrian schists, gneisses, and intrusives which have been elevated to form part of the Southern Rocky Mountain physiographic province. The region is noted mainly for its production of gold and silver, but ores of tungsten, fluorspar, uranium, copper, and iron have been worked. Geological literature describes pitchblende and other radioactive minerals occurring at Jamestown, Boulder County; Central City, Gilpin County; and Lawson, Clear Creek County (fig. 1). These three adjoining counties cover most of the highly mineralized section of the Front Range which extends from James- town to Breckenridge. As far as the writer is aware, uranium has been found only in the portion north-east of Lawson.

Jan 1, 1950

By Henry Faul

MEASUREMENT of radioactivity of rocks and ores has developed into a complete method of geophysical exploration. The problem falls into three natural categories: (I) surface radiation measurement in the field and underground; (2) radioactivity logging of drillholes; and (3) laboratory analysis of samples. Portable counters are used in the field for tracing radioactive formations and for quantitative estimates of radioactive content of surface rock. Wartime advances in battery design make it possible to construct small precision counters that can be carried easily. Even the smallest conventional diamond drillholes can be logged, and actual content of the radioactive element can be measured. The exact grade of very thin active layers or veins can be estimated only approximately. Samples may be analyzed for their alpha, beta or gamma activity, and beta assaying is the best suited to rapid routine operation. Simple calibration with standard samples is sufficient for rough work, but a density correction is necessary when greater precision is required. Samples with high emanating power should be fixed and stored for three weeks to reestablish the radium-radon equilibrium prior to precision assaying. Carnotite can be fixed by sintering or molding with plastics. Among the important new developments, a low-voltage Geiger tube has been designed recently, and crystal scintillation counters hold great promise for high-efficiency gamma-ray measurement.

Jan 1, 1947

By Raymond E. Kary, John W. Mcklveen

The four unit Cholla coal fired power station at Joseph City, Arizona, consumes coal from the McKinley mine located in western New Mexico. Since coals may contain relatively high uranium or thorium concentrations and may release quantities of detrimental progeny of these elements to the environs, there is concern that releases may pose an adverse environmental impact or even a health hazard to the workers. Thus, an effort was made to quantify the radionuclide content of the coal and compare the results with radionuclide concentrations already present in the vicinity of the plant. Additionally an attempt was made to assess any potential for significant enhancement of the levels of radioactivity in the environment or to plant personnel. Background gamma radiation measurements at and near the plant ranged from 8 to 12 [µ]R/hr (70 to 105 mR/yr) with a few localized anomolies measuring to 18 [u]R/hr (160 mR/yr). Levels on top of the coal storage piles decreased to ~ 6.5 [u]R/hr (60 mR/yr). Apparently the direct radiation emitted from the coal is less than the background levels in the vicinity of the plant. Measurements performed on top of several coal seams at the mine confirmed low radiation levels emanating from coal, but readings more than doubled when the overburden was monitored. Laboratory gamma spectrometry confirmed the lower amounts of natural radioactivity in the coal when compared against soil and water samples obtained in the vicinity of the plant and the overburden at the mine. In an effort to see if there is biological enhancement, animal feces was sampled. The radiation variations were found to be influenced primarily by naturally occurring potassium-40 which varied from ~ 1 to 18 pCi/gm rather than fluctuations in the uranium and thorium series. The potassium-40 concentrated in the ash were similar to the concentrations in the environs around the disposal ponds while Radium-226 concentrated in the fly ash was ~ 3 times that found in the immediate surroundings. Radon-222 gas concentrations in buildings at or near the plant ranged from 0.5 to 1.8 pCi/l and were generally lower than indoor concentrations measured in the Phoenix area. The burning of coal at the Cholla station does not appear to increase ambient levels of radioactivity found in the surrounding environs or to the workers. However, the use of byproduct fly ash for construction purposes may need to be examined.

Jan 1, 1981

By G. Wendel

Uranium is a naturally occurring radioactive material in the earth?s crust. Geological processes have resulted in concentration of uranium into ore mined for its gold content in South Africa. This uranium is present in the form of discrete particles of uranium minerals, generally oxides, which are normally insoluble. Chemical and physical processes during gold mining and extraction, particularly when carried out in conjunction with uranium extraction and sulphuric acid manufacture, act on the uranium minerals and the radioactive decay products of uranium. This may result insignificant accumulations of radioactive materials in certain parts of the process. There are a number of naturally occurring radioactive materials in the earth?s crust, such as Uranium-235, Thorium-232, andPotassium-40. This paper focuses on Uranium-238, together with its decay products, and how they affect the gold mines. Water plays a significant role in the redistribution of radionuclides, both as a physical transport medium, and as a solvent in which chemical reactions take place.

Jan 1, 1998

By H. Landsberg

MANY of the sedimentary rocks contain small amounts of radioactive constituents. These vary in quantity in different layers. Some recent deposits show rather high activity as; for example, the deep sea oozes and some lake deposits.1,2. Measurements made in boreholes have also shown considerable changes in activity from horizon to horizon. The first to publish data on this fact was Ambronn,3 and recently Russian geophysicists have shown remarkable variations of activity from one layer to the next in various wells. Spak4 felt even that he was able to line up horizons from data measured in two neighboring wells. ? The measuring of radioactive radiation is fairly difficult. Large errors are possible by the circulation of gaseous emanations in the well and porous strata. It is, therefore, never certain whether the activity of the layer where the instrumental device or collector is located will be measured, or that of some adjacent layer, For this reason it seemed to be advantageous to take samples of rocks into the laboratory and test them therefor their contents of radioactive material, Such a method has been followed in the past to distinguish radioactive ore from other rocks. Radioactivity of rocks, especially of the igneous type, was also deter-mined in the laboratory by numerous authors for absolute age investi-gations.6 Corresponding data from studies of sedimentary formations are scarce. Specimens taken from a core of the Bradford oil sandstone were tested by Landsberg and Ingham,7 with the results illustrated in Fig. 1, which shows that within relatively small vertical distances the differences of relative activity were considerable. If one assumes that the distribution of radioactive material is fairly uniform throughout a layer, measurements of radioactive radiation in various horizons would offer additional information for stratigraphic

Jan 1, 1939

By Jim V. Rouse

Adverse water-quality impacts of uranium mining and milling activities on both surface- and ground-water resources in the Grants Mineral Belt have recently been documented.1 In some cases, the impacts resulted in violation of existing regulations and license conditions and have endangered public health. Unfortunately, industry-sponsored ground-water monitoring programs do not adequately record the actual impacts of mining and milling on ground-water quality.

Jan 1, 1976

By J. Dille

Metallic cobalt exist in two allotropic forms : the hexagonal compact a which is stable at low temperature ( ( 420') and the cubic form 0 stable at higher temperature. This latest form is the only one which is ductile. During the electrode position of Co, in moderate acidic conditions, we noticed a code position of both a and B forms. The influence of several parameters on the B/a ratio in the deposit was investigated. High acidity and the presence of Fe increased its ratio; on the opposite, high temperature promote the a phase. No significant influence on the material were noticed. The differentiation of a and B forms of Co is rather difficult and the method of J. Scoyer was improved quite successfully.

Jan 1, 1988

By P. Davey Wheeler

San Francisco meeting, September, 1915) IN an article in the General Electric Review, January, 1915, reference was made to the X-ray examination of a steel casting 9/16 in. thick. Fig. 1 shows one of the radiographs thus obtained. All these radiographs showed plainly the tool marks on the surface of the casting. All but one showed peculiar markings the shape of which strongly suggested that they were indeed the pictures of holes in the interior. A circular piece, 1 in. in diameter, was punched from the casting at a point where the radiograph shown in Fig. 1 indicated that a blow-hole should be found. (Location of sample shown by circle in Fig. 1.) Fig. 2 is a photograph of the end of the punching, showing the .hole that was found. Since that article was written it has seemed desirable: (1) to obtain data from which the exposure necessary for any thickness of steel could be at once calculated; (2) to find the thickness of the smallest air inclusion which could be radiographed in a given thickness of steel; (3) to determine in what direction to hope for further progress; and (4) to develop the technique of, radiographing metals. In order to gain some preliminary data, several pieces of ½ -in(12.5mm.) boiler plate were obtained, 5 by 7 in. (12.5 by 17.5 cm.) in size. In one of these, holes were drilled in such a way that the axis of each hole was midway between the faces of the steel and parallel to those faces. The diameters of these holes were as follows: Hole number Diameter 1 1/4 in. = 6.3 mm 2 1/8 in. = 3.1 mm. 3 1/16 in. = 1.6 mm. 4 1/32 in. = 0.8 mm. 5 1/64 in. = 0.4 mm.

Jan 8, 1915

By George W. Sheary

Situated 45 miles west of Philadelphia and 50 miles southwest of Bethlehem Steel Company's Bethlehem plant, the integrated Grace mine facilities produce 4000 tpd of high-quality iron ore pellets. Startup of the Grace mill was in November 1958, and iron concentrates were shipped until March 1960, when the pellet plant went into operation. The underground mine, when fully developed, will hoist about 9000 tpd, including development rock. The crude ore, which has an iron content of approximately 42%, is magnetically cobbed and crushed in closed circuit with 3/4-in. slotted vibrating screens. The ore is washed and screened in the mill and the plus 1/4 in. screen product is again cobbed prior to feeding to the rod mills. Grinding is done in rod mills, and in ball mills that are in closed circuit with 30 in, cyclones, to 1% on 100 mesh and 65% minus 325 mesh. The ground ore is magnetically concentrated by three-drum permanent type finisher magnets to 67% Fe. The magnetite concentrate is pumped from the mill to a 50 ft thickener in the pellet plant. The thickened magnetite concentrate is relayed to the filters through a two-stage pump arrangement. The filter cake is fed by belt from filter concentrate bins to mixer-muller belts where it is intimately mixed with bentonite and a slight amount of water for moisture control. The fluffed concentrate then drops into balling cones. The green pellets from the balling cones are fed in a prescribed feed pattern to shaft furnaces through the use of shuttle car mechanisms. The green pellets are dried, heated to 2500°F and cooled to 1200°F as they descend through the furnace and into pellet coolers where the pellets are further reduced in temperature to 250°F. Heat is recovered in the cooling process through the use of air-to-air heat exchangers. The cooled pellets discharge on a rubber conveyor belt and are transferred to 6000-ton pellet railroad loading bin. The final pellet product consists of 90% plus 1/4 in. material (after tumble testing1) and contains 66% Fe plus 3% silica.

Jan 5, 1962

By Bruce W. Smith

Non-contacting, radioisotope density and level gauges are discussed. The characteristics of the more commonly used isotopes, the techniques of detection and the methods of presenting information are reviewed. The gauge parameters of accuracy, response time and long-term stability are tabulated with reference to calibration techniques and operating requirements. Automatic control systems, both pneumatic and electrical, are used in conjunction with density gauges on filter feeds, and in thickener underflow and heavy media processes. These systems are described. Procedures for installation, start-up and operator training are outlined, along with considerations of preventative maintenance and service requirements. Typical gauge system costs, including capital expenditure, installation, start-up and service, are presented, wherever possible, in order to provide a basis of comparison with more conventional systems.

Jan 1, 1964

By L. R. Wilkinson, W. J. Howarth, G. J. Wenk

Over a period of three years, a cooperative program in Australia has resulted in the development of radioisotope immersion probes for the on-stream analysis of mineral slurries. Two basic probe types are now available on a commercial basis - fluorescence and absorption probes - and within each type there are a number of variations so that optimum sensitivities can be obtained for elements with atomic number greater than titanium (22), thus covering most metals of interest to modern metallurgy.

Jan 1, 1973