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By John W. Brown

For seventeen years, I have been involved in surface coal mining in the Mldwest coal fields only to find that once again, I have experienced a problem that was not known to exist in our area. The existence of high sulfur coal seams and pyrite-bearing formations coming In contact with ANFO mixtures has presented yet another potential problem facing the blaster.

Jan 1, 1992

By C Li, K McDonald an, T Nicholson, C Brown

The relative reactivities of chars prepared from different coal samples at temperatures in the range 500 to 1150¦C were determined by measuring the rates of metallisation of a standard ilmenite concentrate. The results have been interpreted in relation to different measured physical and chemical properties of the chars. Char reactivities were found to correlate with the maximum specific surface area (SSA) of the chars, obtained from plots of SSA versus temperature. Weathering of coal samples gave higher reactivities which correlated with higher SSAs. Experiments using recycled chars showed that the high internal SSAs developed during earlier reduction reactions provide no benefit in terms of increased metallisations. The important role of char hydrogen contents in controlling low temperature metallisation rates was demonstrated. Chars prepared from different rank coals had the same hydrogen content when prepared at the same temperature. Ilmenite metallisation rates had a linear dependence on the hydrogen content of the chars. Large differences in the slopes of the metallisation versus H2 content curves for different chars were interpreted in terms of SSA variations and catalysis of the gas reactions by dispersed metallic iron particles in the chars. A simple test based on magnetic separation of the char was shown to give an indication of enhanced reactivity due to contained metallic iron.

Jan 1, 2001

By Misra VN

The carbon-carbon dioxide reaction is the rate determining step in industrial processes such as the rotary kiln direct reduction process for iron ores. The use of brown coal as a reductant in the rotary kiln process has been shown to result in higher throughputs and lower kiln temperatures. No experimental data has been reported on the effect of coal type or the use of brown coal chars. Methods of carbon-carbon dioxide reacti- vity measurement are discussed. None of the methods have been related to direct reduction practice. No standard test has been developed to assess the reactivity of brown coal chars to carbon dioxide. For routine comparative work the gas analysis method of Okstad and Hoy appears to be the most suitable although some modification to the experimental conditions is required. For detailed kinetic studies direct weighing techniques are to be preferred. The factors affecting the reactivity of brown coal char to carbon dioxide are reviewed. Numerous factors such as the origin of the coal, pretreatment and ,physical and chemical differences have been found to affect the reactivity of brown coal chars but no data has been reported on the effect of coal type on reactivity to carbon dioxide.

Jan 1, 1980

By Standish N

The heterogeneous reactions of carbonaceous materials with oxidising gases are basic to all combustion phenomena and to many gasification processes. The carbon- carbon dioxide reaction at elevated temperatures (Reactivity) plays important roles in many metallurgical operations like iron blast furnace and ferro-alloys smeltings, zinc and lead smelting, alumina reduction, cupola operation and direct reduction processes. The stoichiometry but not the mechanism of the reaction between CO2 and carbon is represented by the equation (Boudouard reaction) CO2 + C 2CO (1) This reaction is more complex than that between carbon monoxide and metal oxides, which involves essentially a transfer of oxygen from the oxide to carbon monoxide to generate carbon dioxide without any change in gas volume, whereas the volume of the product gas of Equation (1) is twice that of the reactant gas. In the present paper an attempt has been made to review critically the reactivity measurements of various carbonaceous materials in carbon dioxide atmosphere. Steps in C-CO2 reactions, surface reaction mechanism, role of mass transfer on reaction kinetics, dynamic oxygen exchange reaction and rate equations and rate controlling steps are discussed. Various methods of reactivity measurements with their pros and cons are also presented. Effects of pertinent process variables on the reactivity of carbon are also described in detail.

Jan 1, 1986

By N. Kanarin

A thermodynamic study is reported on the chlorination of Fe(1-x.)O, Fe2O3, Cr2O3, MgO, Mg2SiO4 with chlorine in the presence or the absence of reducing atmospheres. The reactivities of these compounds as well as that of Mg3Si2O5(OH)4 using Cl2+N2, Cl2+air, and Cl2+CO gas mixtures were studied by non isothermal thermogravimetric analysis between 20 and 1000 °C. The same solids were chlorinated in a horizontal experimental set, during two hours between 350 and 1000 °C, in reducing and oxidizing atmospheres: The chlorination products were examined by XRD and SEM, and possible reaction paths were examined. Results indicate that the carbochlorination of these solids was better than their chlorination; Furthermore, the carbochlorination was performed at lower temperatures than those of the chlorination. Finally, the reaction extent was higher in the case of carbo-chlorination of these compounds. Based on these results, a process was suggested for the selective recovery of chromium compounds from the chromite concentrate.

Jan 1, 1995

By N. Kanari

Reactivity of MgO towards C12+air, C12+N2 and C12+CO gas mixtures was studied up to 1000 °C. Carbochlorination of MgO occurs at temperatures lower than that of its oxychlorination. Effects of gas flow rate, temperature and partial pressure of the carbochlorinating gas mixture on the reaction rate were investigated. The apparent activation energy of MgO carbochlorination is 49 kJ1 mol between 425°C and 600°C. At 550 °C, the apparent reaction orders with respect to C12+CO, C12 and CO, are 2.37, 1.47 and 0.89, respectively. At this temperature, the maximum reaction rate was obtained using a C12+CO gas mixture having a Cl2lCO molar ratio equal to about 0.6.

Jan 1, 1998

By D K, S Freij, A Rossiter, X Han, B Feng

In mining operations, the removal of overburden to expose the ores is achieved by rock blasting using ammonium nitrate based explosives, eg ammonium nitrate-fuel oil mixtures, commonly known as ANFO. However, ammonium nitrate can react with pyritic shales that are often found in many mines, leading to premature detonation or spontaneous explosion. In order to minimise the occurrence of spontaneous explosion, the reactivity of the shale in a mine must be assessed. This will provide a better understanding of blasting risks and thus will improve the safety and the cost efficiency of blasting through the selection of appropriate explosives. In this study, shale samples were collected from different locations in Western AustraliaÆs Mt Whaleback iron ore mine and geochemically characterised. The reactivity of the shale samples towards ammonium nitrate and ANFO was investigated using a combination of large-scale firing range tests and laboratory isothermal reactor tests. Results of the firing range tests show that the reactive ingredients of the shale are the limiting factor for the reactions between shale and ANFO. Based on the firing range test results, further isothermal reactor tests were conducted to investigate the reactivity of shale samples towards ammonium nitrate under controlled conditions. Analysis of the results from the firing range tests and the isothermal reactor tests shows that there are correlations between the reactivity of shale samples and several geochemical characteristics such as sulfate, sulfur, ferrous and zinc content.

Jan 1, 2005

By Juliana G. Gutierrez-Paredes, Gabriel Plascencia-Barrera, Fidel Reyes-Carmona

In Mexico, many tonnes of nickel from waste petrochemical catalysts are dumped every year. In order to recover all that nickel, a hydrometallurgical reactor was designed. This design was performed in a systematical fashion, which included the chemistry of the system under study, both a kinetic and mass transfer study, and finally the use of the RID function, to optimize the reactor size. It was found that the NiO leaching with sulfuric acid is well represented by a first order reaction. The mass transfer results are in good agreement with the experimental results, obtaining over 95% nickel extraction in both cases. A marketing study was also completed that determined that it is possible to make a good profit by processing this residue provided the capital cost was low.

Jan 1, 2000

By J. B. Moritz

From the beginning, man has concerned himself with the task of controlling the elements and forces about him so as to provide a better and easier life. In the accomplishment of this task, he is required to utilize in the best way possible the resources which are available to him. In many cases, the available resources must bee refined before they are in a useable form. Many products in the mining industry fall into this category, as some form of refinement is generally needed to produce a saleable product. Over the years man developed more efficient ways of extracting the resources from earth through the use of electrical and mechanical devices. A reduction in manual labor, which is a by-product of increased efficiency through machines, has also been enjoyed. The combination of man's senses and new devices has also enabled man to reach a high level of control in the refinement process. Control of a process through machinery and man's senses has been termed an "art." Until recently man's senses (sight, feel) were the only method available for making measurements simply because suitable measurement devices (instruments) were not available. Even today some items cannot be measured and man's senses must be used. However, the development in our instrument laboratories tends to indicate that time will eliminate this. In recent years, control of many processes has been reduced to a science and part or all of the art eliminated. This does not imply that process art should be degraded; however, when a process is reduced to a science, uniformity of the product from day to day is attained. Decreased processing time and more efficient use of additives and raw materials are other benefits that result from control of a process when it is reduced to a science.

Jan 1, 1965

Reading Anthracite, like AIME, is celebrating its 100th anniversary. While Reading marks a century in the mining, preparation and marketing of domestic anthracite, AIME commemorates 100 years of parallel endeavor in promoting the economical production of minerals and metals and the welfare of those employed in the industries dedicated to this pursuit. Both Reading and AIME possess another common denominator, in that both were conceived in the eastern anthracite fields of Pennsylvania, where coal reigned supreme in the early days of mining.

Jan 1, 1971

By T. H. Watkins

COAL is the basis upon which the activities of the industrial nations of the world rest today. In order that the coal industry may bee restored to a reasonably healthy condition, it is essential that both the operator and the miner should understand that they are directly concerned and that their selfish interests demand that they take an active, intelligent, self-sacrificing view of the entire situation and do their part in restoring and repairing the economic structure. Foreign credits, foreign debts, unstable exchanges, destroyed markets, and inability through lack of credit to carry on as before, all require our attention and cooperation. DEEP CONCERN AS TO FUTURE There is deep concern as to the future and a realiza-tion on the part of some of these leaders of industry that they will have to sacrifice their personal time, away from their desks and the details of business, in order to cooperate with other groups in studying the situation and endeavoring to find the best method of utilizing their knowledge in improving conditions and averting further disaster. It is most unfortunate for the country and for labor itself that the labor chiefs are blind to these necessities, and hostile to every effort to secure their cooperation in rebuilding prosperity.

Jan 2, 1922

By Stephen Hammond

?Our own prejudices form the greatest barrier to creating an inclusive working environment.? Have you witnessed? Racism or Negative Comments about an Aboriginal Person? ?You are free to compete with all the others?, and still justly believe that you have been completely fair.? Lyndon B. Johnson

May 1, 2008

By D. W. Loucks

There is plenty of evidence to indicate that at least one of man's chief interests in life is to make himself as comfortable as possible. If you doubt this, just watch the fellow next to you for the next half hour trying to find the most comfortable position that a hard chair has to offer. Comfort, however, does not always mean an easy chair. To some, it may mean a wealth of money: to another, freedom from worry. But to most of us, it means first of all a comfortable atmosphere in which to live, and to a great many of us it probably also means freedom from that annoying task of firing the furnace. Today more than ever before, automatic heat is one improvement that is placed high on everyone's list. Perhaps this is because automatic heating is becoming relatively cheaper. Perhaps it is because of a good publicity campaign on the part of the oil and gas men or maybe it is just that we are getting lazier day by day. At any rate, almost every issue of Better Homes and Gardens, House Beautiful, or your other favorite home magazine carries an article extolling the virtues of this or that automatic heating system.

Jan 1, 1949

By L. B. Phelps

The nation is confronted with thousands of acres of abandoned coal lands. In Pennsylvania alone, these lands have been estimated to cost $15 billion to reclaim (Pennsylvania Bulletin, 1985). One way to deal with this problem is to provide a mechanism by which the active mining industry can undertake to remine certain of these abandoned mine areas. Remining is classified as reaffecting previously mined areas in order td extract the remaining coal reserves while improving the environmental quality of these lands through land restogation and abatement of pollutional discharges. However, there currently is a disincentive for operators to plan to extract reserves on these abandoned mine lands which have preexisting pollutional discharges. Therefore, they presently avoid them. This is because of the "potentially unlimited liability of post- mining treatment for any discharges that would remain after mining? (Pennsylvania Bulletin, 1985).

Jan 1, 1987

By M. R. Peterson

The U.S. Bureau of Mines has investigated new methods for increasing the selectivity in flotation by creating and regulating reagent concentration gradients within flotation columns at steady-state operation. Gradients were generated and traced in a water-only system with the use of fluorescent dyes, and the effects of various operating parameters on these gradients were investigated. From this investigation, it was found that both gradual and steep gradients could be generated in the froth cleaning zone, and that these gradients could be changed through the manipulation of both physical and chemical operating parameters. The application of reagent-gradient control to mineral systems could improve both flotation grade and recovery in commercial flotation operations without the use of additional flotation circuitry.

Jan 1, 1992

By C. E. Jordan

The Bureau of Mines has investigated the fundamentals of fatty acid/fuel oil conditioning for improved flotation selectivity. Both conditioning time and intensity can provide optimum flotation selectivity as well as good recovery. Traditional conditioning seeks to optimize conditioning parameters with subsequent recovery of the hydrophobic mineral. In the fatty acid/fuel oil system many silica gangue particles are also rendered hydrophobic by the flotation collector. Fundamental studies have shown that particle-particle collisions transfer the collector reagents selectively to the mineral surfaces with the highest affinity for the reagent. This mechanism deactivates the gangue particles while increasing the collector reagent loading on the selected mineral. The degree of this transformation is directly related to the number of particle-particle collisions which can be controlled through conditioning time or conditioning mixing intensity.

Jan 1, 1995

By C. H. G. Bushell, M. Malnarich

Reagent control in flotation is more an art than a science. Operators vary the amount of re- agents used according to the metallurgy obtained. The amount of collector may be increased, for example, if tailings losses are high and decreased if concentrate grades are low. Often control decisions are based on only one assay, such as the tailings analysis by microscopic or quick assaying techniques. This method of control has given reasonably satisfactory results but is clearly far from perfect. No adjustment in reagent addition can be made until information is received that metallurgy has deteriorated, that is, until the optimum time for adjustment has already passed. The first adjustment probably will be an overcorrection or an undercorrection, and time will be required to establish the best new addition rates. The seriousness of the problem depends on variability of the ore. In ore of continually shifting composition and complexity, mill results will shift back and forth from excessively high concentrate grades and high tailings losses to excessively low concentrate grades and low tailings losses. Economic incentive for improved control also increases with increasing size of mill. Even a small improvement in percentage recovery in a large mill pays for expensive control equipment.

Jul 1, 1956

By M. J. Virnig, G. A. Kordosky

Throughout time, the mining industry has been very successful in meeting the world's requirements for metals and materials while meeting the challenges of decreasing ore grades and increased emphasis on protection of the environment. This success has been due to the development and implementation of new technologies. A clear example of such a development over the past 25 years is the increasing use of leaching/solvent extraction/electrowinning for the recovery of copper from oxide and sulfide ores. The key to the successful introduction of this technology was the discovery and development of the hydroxyoxime liquid ion exchange reagents by General Mills Chemicals (now Henkel Corporation). An important role was also played by the close working relationships between General Mills Chemicals and Ranchers Exploration which resulted in startup of the first plant in 1968 and between General Mills Chemicals and Bagdad Copper which resulted in the startup of the second copper SX-EW plant in August of 1970. Following on the heels of the hydroxyoxime development came the commercialization of other new chelating reagents based on different chemical functionalities, i.e., beta-diketones, alkylated 8- hydroxyquinolines and sulfonamidoquinolines. This initial spurt of activity was then followed by a slowing of development in terms of new reagent functionalities. Activity has continued in terms of further optimization/improvement of existing reagent functionalities but the commercialization of new reagent functionalities has slackened. This observation reflects the fact that the development of new reagent functionalities for metal recovery has become increasingly more expensive such that the right combination of price and sales volume must exist in order to justify the investment required to bring a new reagent to the market place. Given the dependence of the mining industry on innovation to meet the needs of the future, one can ask how these new developments, particularly in new reagents, will occur. To arrive at an estimate of the costs involved in commercializing a new metal extractant functionality, particularly a chelating type functionality, a case study of the development of LIX ®* 34

Jan 1, 1994

By Deepak Malhotra

Following a severe recession in the early 1980's, mining companies have taken significant steps to improve metallurgy and reduce operating costs. They do not view chemical reagents and the long-term relationship with reagent producers the same way they did two decades ago. This paper discusses the general perspective of changes that have taken place over the years, especially with respect to cost of production, selling price and environmental constraints. A cooperative program between the consumers and producers of chemical reagents is recommended to understand each other's problems and identify the present and future needs of the mining industry. This approach will be beneficial to the long-term survival of both parties.

Jan 1, 1994

By William F. Riggs

In the fresh application of a frother, collector, or the change of any particular reagent, the interaction caused by this change is often overlooked since we attempt to solve a problem or improve a situation with use of a particular reagent without regard for the Interactions or side effects. When a particular reagent is added to a flotation circuit or substituted for another reagent, a series of chemical reactions occurs which. In turn, will create different physical responses. This discussion will provide a series of examples which have actually been experienced by the author.

Jan 1, 1994