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By William K. Tolley

The U.S. Bureau of Mines (USBM) is investigating hydrometallurgical processing techniques to recycle metals from semiconductors and other advanced materials. Cadmium and tellurium were recovered from mixed CdTe/CdS scrap produced in the manufacture of thin-film photovoltaic devices. Cadmium and tellurium dissolution was achieved using hydrogen peroxide in dilute sulfuric acid. Leaching the scrap in 2.2 N H2SO4 yielded 99% Cd extraction and 98% Te extraction. Sulfur remained in the leach residue primarily in the elemental form. Elemental tellurium was precipitated from the leach liquor by adding Na2S2O5. Cadmium sulfate was recovered by evaporation. A preliminary process evaluation suggests that the process may have economic potential. Alternative recovery schemes are discussed.

Jan 1, 1995

By J. Kim, H. Cho

The objective of the experiment was to investigate the efficiency of hindered-settling column in recovering carbon from anthracite. Two types of Korean anthracites were prepared for feed materials. Each sample was crushed and classified by size, and washability analyses were performed. Separation efficiency was evaluated under various operating conditions using a laboratory scale hindered settling column. Results showed that the carbon recovery was higher for the smaller sizes, but the purity of the product was better for the larger sizes. In, overall, 2-0.21mm particles of 40-45 % ash could be processed into about 20 % ash products.

Jan 1, 2002

By James S. Browning

In 1975 bituminous coal and lignite production in the United States reached an all-time high of 637 million tons, an increase of 6 percent over production in 1974. The output, valued at $11.9 billion f.o.b. mines, was produced at 5,100 mines in 24 states (6). Coal mining is the largest mining industry in Alabama. Production from Alabama's mines in 1975 was over 21 million tons, and present projections forecast a steady increase in production, with tonnages almost doubling by 1985 (5). Of the total quantity of coal produced, about 16 million tons were consumed in electric power generation and the remainder was used for metallurgical coke production, extraction of chemicals and petroleum based products, and power for industry. The fact that 75 percent of Alabama's power is generated by burning coal attests to the importance of this fossil fuel to the State. Approximately 14 million tons of coal were produced by strip-mining methods in Alabama during 1975 and about 7 million tons were produced by underground mining during the same period. Surface mining is expected to continue at about 14 million tons per year, but by 1980 underground coal mining is expected to increase to about 25 million tons (3). About 7 million tons of surface-mined coal in Alabama is subjected to some means of washing or cleaning. The methods used are screening accompanied by heavy media separation, jigging, tabling and flotation. Some of the simpler approaches employ screening and jigging, or tabling. Except where flotation is used, the screen undersize fraction (finer than 0.25 inch) is rejected, with the result that 10 to 15 percent of the coal is lost. Thus, in the State of Alabama an aggregate of about 1 million tons of coal is wasted annually in the fines which are impounded from treatment of surface-mined coal. The use of the Humphreys spiral to concentrate fine coal was practiced as early as 1947. At that time the Hudson Coal Company (1) used Humphreys spirals to concentrate anthracite fines. In 1950, the use of spirals to treat fine-size

Jan 1, 1977

By James S. Browning

The Mineral Resources Institute and State Mine Experiment Station of the University of Alabama conducted Humphreys spiral tests on fine coal waste from nine preparation plants of Alabama strip mining operations to determine the feasibility of recovering low ash and sulfur fuel meeting steam coal specifications. The ash in the samples ranged from 9 - 5l%, and the total sulfur ranged from 0.4J- 2.39%. Continuous laboratory tests using a Humphreys spiral gave good recovery of the coal with excellent rejection of the ash and pyritic sulfur. Coal recoveries of 83.6 - 94.1% were achieved from the different samples. Ash content of the clean coal products fell within a range of 5 - 12.2%, with a total sulfur content of 0.62 and 1.10%. In quality, the products were comparable or superior to those now being shipped from the preparation plants.

Jan 1, 1980

By E. M. Hill, H. K. Lin, J. L. Oleson

When activated carbon is used for recovering gold in gold industry, carbon fine materials are generated in stripping, acid-washing and kiln regeneration circuits. The carbon fines at the Fort Knox mine, Fairbanks Gold Mining, Inc., contain up to 0.68 kg/t (20 oz/st) of gold. In laboratory tests, gold in the carbon fines was effectively transferred to coarse virgin carbon when the carbon fines were mixed with virgin carbon in cyanide solution at a cyanide concentration higher than 0.10%. A plant-scale test conducted at the Fort Knox mine also shows effective gold transfer from the carbon fines to virgin carbon with a 95% gold recovery in a two-stage gold transfer process.

Jan 1, 2002

By E. W. Enqelmann

DURING January, 1933, burlap or coco matting was placed in the bottom of launders handling various products of the flotation plant of the Magna mill of the Utah Copper Co., with the hope of increasing the total recovery of gold. This was soon followed by placing various materials, such as coco matting, cotton twill, and common 10-oz. burlap on the bottom of the main tailing launder. The burlap was found to be the most economical material to use. The test was first conducted in an old wooden launder, 40 in. wide and 2000 ft. long, with 10-oz. burlap fastened

Jan 1, 1935

By Durell Denysschen, Rafael Abela

The recovery of gold from old mine dumps has been carried out over the last two decades. The gold value and price together with recovery methods, determine whether it is economical to process a dump. Pre-concentration with cyclones and spiral concentrators may offer a method to process dumps considered currently uneconomical to treat.

Jan 1, 2006

By C. M. Kleeman

All mines have a finite life and the time comes when the ore is depleted, or it has become uneconomical, or for some other reason which may be peculiar to that particular mine, it must be shut down. The operation at that point of time still has some assets such as mining and milling equipment, workshops, and in the case of a gold mine, an unknown quantity of gold which has been trapped in the treatment plant. Recovering this gold can be done at small cost and can be extremely profitable. Recovery of these hidden assets requires a good knowledge of the treatment plant, i. e. , as say values of heads, tails, and of the products produced; and if mercury for amalgamation was used, where? A careful study of available plant records can be extremely valuable in forming a working plan for adequate recovery. In the following paragraphs the various unit operations and equipment where gold can collect are described and suggestions made for its recovery. Subsequently, a case history will be given for dismantling a gold plant which had a complex flowsheet and which had been in operation for many years. Looking for trapped gold in a crushing section would invariably not be worthwhile since crushing is normally a dry process and there would be few areas where free gold could collect. In the milling section, however, many areas can literally become small gold mines in themselves. Material in the bottoms of grinding mill scoop boxes can be high-grade, and even the scale on the sides of the boxes should be scraped off and collected. Mill liners should be removed and all scale, rust, and residue collected. Residue in the bottoms of rake or spiral classifiers, if they have been used, should be removed as should the scale and rust on the sides of pump sumps, launders, etc. The following procedures should be used to extract gold from these collected materials. All steel (ball scats) should be removed, screened out, and reserved. Fine material should be placed in an amalgam barrel, water added and ground with the amalgamation tailings being sampled and assayed. If high-grade, tails should be reserved; if not, discarded. The coarse material that was screened out should be placed in a heap, regularly sprayed with water and allowed to rust. After several months this material should be screened again and the fines amalgamated.

Jan 1, 1981

By Zenon R. Llanos

"The disposal of spent hydroprocessing (HDP) catalysts in the petroleum refining industry has been a concern in the past due to their classification as listed hazardous wastes. However, because these catalysts have higher metal concentrations than regular ores, and the recent surge in prices for molybdenum, vanadium, nickel and cobalt what used to be considered as a liability for generators is now viewed as a valuable renewable source of strategic metals. At the same time the generation of spent catalysts has steadily risen due to new environmental regulations for low sulfur fuels and an increased appetite of gasoline consumers. This paper will examine spent catalyst market and the role played by Gulf Chemical & Metallurgical Corporation in the reclamation of metals over the last sixty years. Introduction Hydroprocessing (HDP) catalysts are used in petroleum refineries for two main applications: desulfurization and cracking. The catalyst support is alumina or mixtures of alumina and silica. Active metals include molybdenum, nickel, cobalt and tungsten. The selection of catalysts depends on the application and sometimes the cost. The life cycle of HDP catalysts is represented in Figure 1. The catalyst cycle in a reactor varies from continuous to one-two years. Catalysts used in various refining processes are deactivated by coke, sulfur, vanadium and other impurities in the refinery feedstocks and become spent. Refineries can optionally send the spent catalysts for regeneration, metals reclamation or landfilling. Catalysts used for refining heavy crudes often can not be regenerated. Catalysts used with light oils can be reused twice or three times after regeneration. When the option for regeneration is not viable, spent catalysts are send metal reclamation facilities or landfills."

Jan 1, 2008

By Reilly L, Worner H. K

The EnvIRONment process has been developed to treat steel works dust and organic wastes simultaneously. A pelletised feed is fed into a special DC electric furnace, the pellets becoming immersed in a molten slag above a carbon saturated bath. The iron oxide in the pellets is reduced and carburised whilst the organics are broken down to carbon monoxide, carbon dioxide, hydrogen and water vapour. Volatile metals are vapourised and collected in the baghouse. Over two years of trials in a 100 kg DC electric are furnace has brought the process to the stage where it is ready for commercialisation.

Jan 1, 1995

By Versiane A. Leão

The hydrochloric leaching of chrysotile tailings and soapstone powders) is discussed. This two materials are magnesium compounds associated with carbonates and iron oxides. In this work the chemical and physical characterization of formers is presented and the thermodynamic analyses of leaching is carried out. Magnesium extraction is almost complete for chrysotile tailings while, for soapstone powders, one can be reached 60%. The behavior of iron and calcium impurities is discussed.

Jan 1, 1997

By Elaine R. Goetz

The eastern and southeastern regions of Ohio are part of Appalachian coal country, with a documented 1,300 miles of streams impacted by acid mine drainage. Since 1995, partnerships of local watershed groups, government agencies, private industries and universities have focused on the remediation of the affected waterways. The partnerships have spent $2.4 million annually in constructing and operating treatment systems such as wetlands, anoxic limestone drains, successive alkalinity production systems, steel slag leach beds, and lime dosers. These systems have been partially successful, and water quality has improved in the region, but no treatment has yet met the ultimate objectives of low cost, continual remediation. Our research group has investigated an alternative system for acid mine drainage treatment: electrolysis combined with pH adjustment to selectively precipitate recoverable, saleable metal products to offset the cost of treatment. We utilized a $0.2 million pilot facility constructed by the Wayne National Forest, in Nelsonville, Ohio, to process approximately 40 L/min of mine drainage from surrounding seeps. The pilot facility has multipurpose tanks that can be adapted to process acid mine drainage with different characteristics, such as high or low aluminum content or high or low carbonate concentrations. Sodium hydroxide was used for pH adjustment. Results indicate that saleable product can be generated with this treatment technology. In an initial, not optimized trial, one seep yielded 4.7 kg of dried 69 % iron oxide product from 10 hours of pilot facility operation, treating 23,000 L with electricity costs of $4.68. Dissolved iron concentrations in the water were reduced from 242 ± 18 mg/L to 2.8 ± 2.0 mg/L (99.0 % removal) while the initial acidity of 443 mg/L as CaCO3 was neutralized to an alkalinity of 160 mg/L as CaCO3. Iron oxide can be sold as pigment for an average of $1.47 per kg in the United States. Currently, approximately 80 % of all pigment used in the United States is imported, and there is incentive to purchase domestically recovered pigment. If the iron oxide from the pilot facility could be sold as pigment for $1.47 per kg, 43 % of the operating cost (raw materials, electricity and construction costs) of treatment could be offset by the sale of the product. Considering the cost offset, the electrolysis process shows potential as a sustainable low cost alternative for treating acid mine drainage.

Aug 1, 2013

By Hideaki Tokuyarna

Recovery of metal such as V, Ni and Fe from oil fly ash is important for efficient use of natural resources and protection of environment. Leaching of metals from fly ash followed by ion exchange of leached metals has been examined to develop a process which can selectively recover V and Ni from the fly ash. Experiment of leaching with water, HCI, H2S04 and NaOH leads us to propose a two-step leaching process as an effective and mild operation. The first step is leaching with water for removal of Ni, Mg, A1 and Zn and the second step is leaching with acidic solution for the recovery of V. The metals V and Ni are then separated from other metals in each leached liquor by ion exchange. Advantage of this separation process is that acidic leachant can be reused, which contribute to save separation energy.

Jan 1, 2002

By R. Conor, O&apos

Wastewater treatment systems, both industrial and municipal, produce large quantities of sludge which require disposal. Sludge disposal poses significant environmental liabilities, logistical problems, and economic burdens. Minergy Corporation has developed and implemented several new technologies for the recycling of such high volume wastes as sludge, ash, and foundry sand. These technologies perform mineral recovery from the waste material, converting them into construction material and industrial feed stocks which are inert, marketable products. With a continuously operating processing system installed at the waste source, these technologies reduce handling, eliminate downstream liabilities, and reduce disposal costs.

Jan 1, 1999

By Bin Xu, Qian Li, Qiang Zou, Yongbin Yang, Long Hu, Tao Jiang, Xuefei Rao

The recovery of palladium from the chloridizing leaching solution of spent Pd/Al2O3 catalyst was studied mainly by sulfide precipitation tests and chemical composition analysis. The effects of key parameters including sodium sulfide concentration, pH, addition rate, temperature, and stirring speed on palladium precipitation efficiency are systematically investigated and optimized.

Mar 1, 2017

By Michael R. Grubbs

The Bureau of Mines is currently developing methods for reclaiming the metal and mineral values contained in unburned urban refuse. One important phase of this research deals with recovering Mastic from shredded refuse using in electrodynamic separation process. The results of this study have indicated that mixed plastic concentrates analyzing 99.4 percent plastic can be consistently recovered from the light material fraction of shredded refuse, leaving a mixed paper traction analyzing 99.9 percent paper. Recovery of the plastic exceeds 99 percent.

Jan 1, 1972

By L. Paulino, C. E. Zangiacomi, J. Yamamoto

"This paper presents the learning from Alcoa Po9os de Caldas Smelter in Brazil, after several energy restrictions resulting from the failures of three rectifier units at its power switchyard. Starting on December 27th, fuses and diodes failed in three rectifier units of Potline #1, causing a long and dangerous power interruption. Even after current was reestablished, amperage was only 70% of the line target leading to a bath freezing process that lasted for around 48 hours. The process engineering team played with several potroom parameters as pot resistance, bath and metal levels, alumina feeding and bath chemistry in an attempt to minimize impact on the potline metal output and energy consumption. As it will be illustrated, the first battle was to keep the pots running on a ""survival"" approach. After that, several changes took place on the procedures used to run at reduced current which were considered rather successful. Finally, some recommendations will be given to foresee and prevent transformers and rectifiers from undesirable failures."

Jan 1, 2006

Provide a means of recovering precious metal values from finely ground tailing materials. Approach Determine the procedures needed for agglomerating the finely ground material for subsequent heap-leach cyanidation of the precious-metal-bearing tailings. Applying Agglomeration/Heap-Leaching to Fine Tailings Agglomeration technology was developed by the Bureau of Mines to provide cost-effective recovery of precious metal values though better heap leaching of clayey or low-grade ores. While many precious metal producers have adopted this technology to reclaim precious metals from crushed ores and wastes, other operations have experienced problems in using the heap leaching technique effectively on piles of fine tailings. In contrast to the coarser ore and waste material, most tailings piles contain more than 50 percent minus 200 mesh materials with no coarse material. Fine particles and clays present in the pile can impede 8 uniform flow of the leaching solution through the heap, thus preventing efficient and cost-effective precious metals recovery.

Jan 1, 1986

By G. Mei

"This study explores froth flotation and selective flocculation methods to recycle waste phosphors containing several rare earth elements, namely, yttrium (Y), europium (Eu), cerium (Ce) and terbium (Tb). The effects of the presence or absence of collector and of flocculant and their dosages, as well as the pH, were investigated. Reverse flotation resulted in concentrates with grade of 27.03 percent and recovery rate of 71.36 percent, while flocculation resulted in concentrates with grade of 31.43 percent and recovery rate of 91.28 percent. The flotation and flocculation behaviors were further analyzed by X-ray diffraction analysis, zeta potential measurements, particle size distribution and other methods. The successful separation of rare earth minerals by flotation was attributed to the selective adsorption of the collector onto quartz, making it particularly recoverable by reverse flotation so as to be separated from the valuable materials. The analysis of the particle aggregation process indicated that its better flocculation performance was due to the selective adsorption of flocculants onto the unwanted materials, enlarging the flocculant sizes by forming aggregations and facilitating the separation of rare earth minerals from waste materials based on different settling rates. IntroductionBecause waste phosphors pose the problems of heavy environmental burden and high risk to human health (Hu and Cheng, 2012) as a result of containing heavy metals such as mercury and manganese (He et al., 2006; Lucas and Emery, 2006), they have received added attention as urban mining resources for extracting rare earth elements (REEs) like yttrium (Y), europium (Eu), cerium (Ce) and terbium (Tb).At present, chemical processes such as acid leaching, alkali fusion, roasting and extraction are the primary methods for recovering REEs from waste phosphors (De Michelis et al., 2011; Li et al., 2012; Li, 2010). With these strategies, phosphors can be effectively decomposed and their REEs extracted. After the removal of impurities, the REEs can be efficiently precipitated by adding an H2C2O4 solution (Porob et al., 2012). Although relatively high recovery rates are achieved, those processes entail high energy consumption and can cause severe environmental pollution."

Jan 1, 2017

By Q Xin, X Shengming, C RuÆan, Z Zhigeng a

The optimum defluorinating conditions for Sichuan bastnasite crude ore were determined by orthogonal experiments. Over 95 per cent fluorine in the crude ore was stripped by roasting 30 minutes of the crude ore with Na2CO3/ore =0.25 at 650oC. The stripped fluorine crude ore was further treated by NH4 Cl to recover rare earth. Above 95 per cent rare earth can be leached by water after the stripped fluorine crude ore mixed NH4Cl(NH4Cl/ore =1:1) roasted 1 h at 325oC. At the same time, the rare earth leaching solution contains little Fe, Si and Al. Therefore it is propitious to further purify the solution and recover rare earth.

Jan 1, 2000