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By Guy Deschênes

Thiourea solutions can be used as leach liquors to treat gold ores or slimes. It is also efficient to elute resins or strip solvents that were loaded in cyanides solutions. The hydrogen pressure reduction is a practical step to recover gold and silver from leach solutions, and strips and eluates without any destruction of thiourea. It is a critical point because these processes have to consider the recycling of the liquors to be irore economical. The effect of temperature, pressure, acidity, compotation of the solution and the nature of catalysts on pressure reduction by hydrogen were investigated. An electranetallurgical study was? carried out to investigate the mechanism. The composition of the products was studied by different analytical methods. The process shows a good selectivity to precipitate gold and silver in a thiourea solution containing iron and copper. Gold and silver concentrations can be decreased to 0.2 ppm and 0.1 ppm at respectively 70 KPa H2 and 28°C. No decomposition of thiourea was evident during the tests. Metals such as nickel powder or platinum activate the reaction and improve the reduction.

Jan 1, 1989

By Thom Seal, S. J. Jung

This paper will combine three SME annual meeting presentations on reducing gold inventory in cyanide heap leaching. Information on Part I – Side slope leaching (SME 2003), Part II – Determining the dry zones using geophysical resistivity (SME 2004), and Part III - Presents a new technology “Hydro-Jex”, to introduce the required lixiviants to the un-leach or under-leach zones in heaps (SME 2005). This paper will describe how Newmont Mining Corporation continues to improve the economics of the heap leaching process for precious metals recovery.

Jan 1, 2005

By K. Prajapati, P. Hes

Transmission of vibration to the operator from percussive vibrating tools is increasingly of concern in industrial and mining applications. Prolonged exposure to high levels of vibration transmitted via the hand causes disorders known as hand-arm vibration syndrome (HAVS). The vascular component of HAVS is called vibration white finger (VWF) and has a debilitating effect on the hand. Vibration at frequencies below 1250 Hz, a tight hand-grip force and cold environments are reported to increase the likelihood of developing VWF. A vibration damping handle design with patents pending that addresses some of the causes of VWF has been developed and retrofits onto jackleg pneumatic rock drills. The handle is decoupled from the drill while maintaining jackleg twist-grip controls on the hand-grip using a combination of sealed self adjusting hydraulic pistons and compliant materials in series, and a new air control valve. The ergonomics of the hand-grip was also modified by the addition of a polyurethane sleeve with a diameter of 50 mm. The new hand-grip reduces direct cold metal contact and minimizes grip force. Measurement of vibration as the quantity acceleration was made in accordance with international standard ISO 5349. Overall vibration damping in all axes of 50% to 63% was attained at frequencies below 1250 Hz. The dimensions of the damping handle are comparable and its weight is only 100 g heavier than a standard handle.

Jan 1, 2001

By Reid A. F

Since early 1971 Western Titanium N.L. has been operating an ilmenite upgrading plant on a commercial basis at Capel, Western Australia. In their process ilmenite is pre- oxidized, then reduced in a rotary kiln to a mixture of metallic iron and titanium oxides. The iron is leached out by accelerated rusting in aerated water, leaving a product with titanium content, expressed as Ti02, of about 92%. Samples from different stages of the up- grading process, representing operations over the last two years, have been studied in detail by X-ray diffraction methods, and the sequences of phases and reactions occurring have been determined. Quantitative X-ray studies showed the ilmenite feed materials to consist of a mixture of ilmenite and pseudo- rutile. Pre-oxidation of the ilmenite at =1000¦C leads to the formation of rutile plus a Fe2TiO5-FeTi205-Mn2TiO5 solid solution. The final reduction product consisted of a mixture of metallic iron, reduced rutile and a FeTi05-MnTi205-Ti305 solid solution. The relative amounts of these reduction products were very sensitive to the initial concentra- tions of the minor constituents manganese and magnesium. The effects of variation of ilmenite feed rate, reducing atmosphere,- reduction temperature and controlled addition of magnesium were also studied.

Jan 1, 1973

By D. J. Zhao

The reduction of ilmenite pellets was investigated at 950°C and 1000°C under a CO-N2 gas mixture with 10 L/min gas flow rate. All the reducing reactions were conducted in a furnace with a thermogravimetric analysis system. The reduction rate is higher at 1000°C than that at 950°C. At the early stage of the reactions, with the CO concentration increasing in the gas mixture, the reduction rate increased at 1000°C. In addition, at the early stage of the reactions, a rapid temperature increment and a rapid conversion of oxygen were observed on the curves of temperature versus time and conversion of oxygen versus time under different experimental conditions. The solid reaction products obtained in these experiments were analyzed by Scanning Electron Microscopy (SEM) and Energy Dispersive Spectrometers (EDS). Metallic Fe with small amount of Ti dissolved in it and oxides of Ti were found in the solid reaction products, but the formation of any nitride phases was not found under the prevailing conditions.

Jan 1, 2014

Reduction of Iron Content from Silica by Gravitational Processes In this research work, it was attempted to reduce the iron contents (Fe2O3) in silica sample which was provided from Shenin silica mine using gravitational processes including jig machine, multi gravity separator (MGS), shaking table and spiral. The silica sample contains 93.75 per cent SiO2, 0.44 per cent Fe2O3, 2.78 per cent Al2O3, and 0.08 per cent TiO2 and the Fe2O3 has to be reduced to about 0.1 per cent or less than 0.02 per cent. Mineralogical studies and XRD analysis indicated the presence of haematite, pyrite and goethite as the major iron impurity phases. Mineralogical studies of polished and thin sections yielded that the degree of freedom of silica is more than 80 per cent in the range of -300 +212 mm. After elimination of fine particles, at first nine tests were carried out on crusher product (in two size fractions), wet rod mil product and scrubber product by means of Jig Machine. The best results were obtained with about 0.15 per cent Fe2O3 on rod mill and scrubber product which was not desirable. Thereafter 7 tests were carried out using shaking table; the best results were obtained with about 0.14 per cent Fe2O3 on rod mill and scrubber product which was not desirable. MGS showed the worst result in order to iron removal from silica which was not desirable. Finally 9 testes were carried out using spiral whish is the best gravitational separator for elimination of iron impurities from silica. The best result of spiral tests were achieved on scrubber product. In this test concentrate weight percent and its Fe2O3 grade were 82.32 per cent and 0.085 per cent respectively. Finally a test was carried out using 2 stages of spiral in order to develop flow sheet. In this test concentrate weight percent and its Fe2O3 grade were 78.8 per cent and 0.1 per cent respectively. This product can be used to produce float (clear flat) glass.

Sep 13, 2010

By Whitehead A. B

INTRODUCTIONDuring the past few years there has been considerable interest in developing the so-called direct reduction processes for treating iron oxides. The various methods proposed were recently reviewed by Scortecci and Palazzi (1960).In particular the application of fluidized bed techniques received considerable attention and, on first examination, this seems to be the ideal method 'of dealing with fine iron oxides. Several difficulties (e.g. product agglomeration) require the method to be investigated further before its potentialities can be fully assessed.PROPOSED FLUIDIZED BED REDUCTION PROCESSESBrassert and De Jahn (1951) were among the earliest to suggest the use of fluidized beds for the reduction of iron ore to metallic iron. Their patent was followed by many others proposing similar concepts, mainly from Lewis (1955), Ogorzaly (19.56), Shipley (1956), Agarwal (1960'), Osborn (1958), Texaco Development Corporation (1956) and Stelling (1957).The H-iron process (Squires and J ohnson, 1957; Lubker and Bruland, 1960) is the only scheme that has been an economic success. This process, mentioned later, manufactures a 'premium quality product in the form of sized iron powder.AIM OF THE PRESENT WORKThe work reported here was performed to assist in the formulation of a comprehensive pl'ogramme of research into fluidized bed reduction processes to be undertaken at the...

Jan 1, 1962

By Marcelo B. Mourão

The reduction of iron ores by solid carbon, when both are agglomerated together in the form of pellets, has important kinetic advantages. Although several studies have been performed on the subject, some points on the controlling mechanisms need clarification. There is a big scatter in the values of the apparent activation energy reported in the literature, and this may be due to factors like heat transfer, flow of gases in the reduction system, pellet size and composition. This work is concerned with the effect of several parameters on the reaction rate. The parameters studied were temperature (in the range 1173 K to 1423 K), carbon type (coke or charcoal), pellet size, gas flow rate, catalyst action of the produced metallic iron and added sodium carbonate. It has been shown that the values of the apparent activation energy can change according to the reduction conditions employed, and hence any modeling effort will have to take account of these parameters. EPD Congress 1994

Jan 1, 1994

By R. L. Bleifuss, S. Zhong, H. E. Geotzman

Microwave heating of iron ore was investigated as an alternative to conventional reduction processes to solve the problem of slow heat transfer. Microwave heating and reduction tests were run on composite green balls made from coal and magnetite concentrate. Benchscale tests were run on both powdered and pelletized feeds using a 15 kW microwave generator. A significant increase in the reduction rate was obtained. With 20% excess stoichiometric carbon in the mix, more than 90% reduction of the iron ore can be achieved in about 10 min at temperatures of around 1,000°C. The reduction of iron ore with coal by microwave heating produces a pure, dust free, high-Btu flue gas that can be used in related thermal operations. Depending on the purity, the reduced iron product could be fed directly to an electric arc furnace for melting. In some cases, the removal of a slag phase may be required to eliminate excess silica and alumina.

Jan 1, 1997

By Heihachi Kamura

In this research, the proper temperature for the reduction of iron ores by carbon monoxide was determined. Also, the difference of the rate of reduction on the sizes of ore under four mesh per linear inch was estimated, but no evidence could be found. Rates of reduction on the seven kinds of ore were compared with the results of the experiment, showing a close relation between reducibility and density of ore. Finally, the maximum size of ore that can be reduced in applicable length of time was determined. The author thinks that the process of production of steel may be replaced by low-temperature reduction of iron ores some time in the future. THE reduction of iron oxide, such as Fe203, to iron in the blast furnace is performed principally by carbon monoxide, but partly by solid carbon by the two following reactions: Fe203 + 3CO = 2Fe + 3CO2 2Fe203 + 3C = 4Fe + 3CO2 It is known that reduction by carbon monoxide takes place at a much lower temperature than reduction by carbon and that the reducing action of carbon monoxide progresses to the inside of the ore in lump form by gaseous diffusion. In the reduction by carbon, however, the reducing action takes place only at the contact surface of the ore and carbon, so that the more complete the reduction by carbon monoxide, the more efficient is the operation. However, the reduction does not progress as shown in the foregoing formula, because carbon dioxide acts oxidizingly on the metallic iron to such a degree that when the gaseous composition reaches a certain proportion of carbon dioxide to carbon monoxide, the reduction practically stops, even though the gases are moving slowly through the heated ore. The proportions of carbon monoxide and carbon dioxide in the gas depend on the kind of iron oxide and the temperature of reduction, also the duration of time in the reaction. The longer the time of the reaction, the higher the proportion of carbon dioxide obtained in the gas, but finally it will attain to a condition of equilibrium.

Jan 1, 1925

By Michael Tenebaum

IN a previous investigation1 the authors studied the effect of pressure on the reduction of iron ores by hydrogen. With hydrogen as a reducing agent, the rate of reduction was increased substantially by increasing the pressure from 1 to 2 atmospheres. The results with hydrogen prompted the present study of the effect of pressure on reduction with carbon monox-ide and with mixtures of carbon monoxide and nitrogen. FEATURES OF REDUCTION PROCESS The gas stream in the lower part of the blast furnace always contains sufficient concentrations of reducing gases to complete reduction provided sufficient time is allowed for the reaction to proceed. Reducing gases react immediately with the iron oxide on the surface of lumps of ore. However, as the unreduced surface recedes from the easily accessible exterior of the lump, the reaction proceeds by virtue of the diffusion of the gases into and out of individual pieces. The rate of diffusion of gases, which undoubtedly plays an important role in the reduction of iron ores, depends on several factors, most impor-tant of which are: (1) molecular weight or density, (2) pressure, (3) tem-perature, (4) concentration gradient. Thus, the rate of reduction of a lump of iron ore at any temperature will depend not only on the specific reaction rate but also upon: (1) available surface of unreduced iron oxide, (2) rate of diffusion of the reducing gas to the reacting surface, (3) rate of effusion of the gaseous products of the reaction from the reacting surface, (4) adsorption of the gases on the reacting surface.

Jan 1, 1939

By Michael Tenenbaum

RECENT researches on the reduction of iron ores have stimulated interest in the effect of increased pressures within the iron blast furnace. From a physicochemical viewpoint, it seems logical to suppose that the increased pressure would increase the rate of reduction of the iron ore within the furnace. This increased reaction velocity would in turn be reflected in an increase in the output of the blast furnace. Any sub-stantial effect of elevated blast-furnace pressures should accordingly be of both technical and economic interest to the operator. It is doubtful whether it is possible to increase the pressure in the stack of the blast furnace beyond two or three atmospheres without incurring severe mechanical difficulties. The benefits to be procured by elevations in pressure must therefore be restricted to pressures below two, or at the most, three atmospheres. Within this range it would seem both economically and mechanically feasible to modify the present design of the upper portion of the blast furnace to accommodate these more stringent operating conditions. This investigation was undertaken to study the effect of moderate pressures on the rate of reduction of iron ore with hydrogen. The use of carbon monoxide is contemplated for later work. Although any results that are obtained in the laboratory cannot be interpreted directly in terms of large-scale commercial operations, it is possible, through such an investigation, to ascertain the order of magnitude of the effects of higher pressure. A more quantitative conception of the effects that would result from the use of increased pressures in the modern blast furnace is needed.

Jan 1, 1939

By George Kazonich

The high costs and environmental problems associated with making iron and steel in the United States is driving the development of new technologies to replace the blast furnace. A prototype reactor incorporating rocket technology was designed and built. This rapid rate reactor was operated successfully and consistently made iron metal. Minus 325-mesh magnetite particles could be reduced to iron metal in less than 50 ms in a high temperature flow through reactor. Iron product was recovered inside the reactor and in a downstream cyclonic separator. The results of typical operation and how parametric changes affected the reduction of iron ore concentrates are discussed.

Jan 1, 1993

By O. E. Etheridge Jr., R. A. Lowe, C. I. Basilio, J. M. Randolph, S. W. Sheppard

The low-shear viscosity of kaolin slurries is one of the principal characteristics that determine whether a clay can be utilized for paper and ceramic applications. In this work, the causes of high low-shear viscosity and methods for improving the rheological behavior of the slurries were investigated. The presence of fine-grained smectite impurities within the kaolin was shown to detrimentally affect the low-shear rheology of the slurries produced from these clays. It was also shown that mechanically working (i.e., pugging) a crude kaolin followed by desliming to remove these impurities can reduce the low-shear viscosity.

Jan 1, 2000

By U. Kammer

The reduction of the lead content in the separator fraction produced during the mechanical processing of spent lead-acid batteries is an important environmental and economical issues. The reduction of lead down to less than 1 percent is very difficult using hydroseparators that are common in battery recycling facilities. Very promising results were achieved performing experiments on a test rig using a new technology in battery treatment: a discharge-type jigging unit. The materials is fed onto the jigging bed and transported through the machine. Due to the intensive movement of the feed, an additional washing effect is also obtained in addition to separation of the lead and plastic fractions. The knowledge gained from this development work at UVR-FIA GmbH in Freiberg, Germany, led to a patent application. This paper focuses on the results of the development work and the start-up and one year's operation of the industrial-scale application at Harz-Metall GmbH in Goslar, Gennany.

Jan 1, 2000

By H. B. Menardi

THE history, geology, ore deposits and current mining operations of the Huitzuco district have been described by C. W. Vaupell1 and the current mill operations by David Segura.2 This paper completes the story of Huitzuco with a description of the reduction of the flotation concentrates. The predominant ore mineral in the Huitzuco deposit is livingstonite, a rare, mercury-antimony sulphide (HgS.2Sb2S3). Other associated minerals include cinnabar, stibnite and elemental sulphur. The gangue is largely limestone and gypsum. Former operators mined a selected grade of ore, from which the mercury was recovered by an expensive, inefficient operation. A consid-erable tonnage of rejects and fills, carrying mercury and antimony, was left in the mine. In order to recover both mercury and antimony from these fills and also from newly developed ore, a combination method has been developed, by means of which the livingstonite is concentrated by flotation and the flotation concentrates subsequently reduced to metallic mercury and antimony. An essential part of the flotation treatment, as developed by Segura, is the use of copper sulphate as an activating agent. A typical analysis of concentrates now being produced at the property is as follows: Hg, 7.73 per cent; Sb, 26.40; Fe, 1.20; S, 29.68; CaO, 11.50; MgO, 7.25; Si02, 1.63; A1203, 0.65.

Jan 1, 1939

By A. K. Bhattacharya

Cylindrical bridge piers are widely used and equations exist that can predict the maximum depth of local scour around such piers. Scour around piers is an undesirable phenomenon, as it requires the foundation to be placed to a greater depth resulting in increased cost, making it worthwhile to investigate scour-reducing measures. A number of scour-reducing measures have been tried out for cylindrical bridge piers including placing a concrete collar around the pier, having a delta-wing projecting upstream in front of the pier, placing riprap around the pier, using a group of piers instead of a single pier, having a slot in the pier aligned in the longitudinal direction. The objective of this study is to investigate the effect of upstream protective piles on reduction of maximum local scour depth around a cylindrical bridge pier. The upstream piles are placed at different radial distances in front of the pier and the scour depths are observed. The proposed equation of Dey (1997) for determining the maximum depth of scour around a cylindrical bridge pier is used. The reduction of local scour around the pier is compared with local scour around an unprotected pier.

Jan 1, 2009

By A. Warczok, T. A. Utigard

"Slags from smelting of copper concentrates contains from 1 to 15% of copper. Copper is present in the form of copper or copper matte inclusions of size from 2 to 1000 micro, and as dissolved cuprous oxide. Removal of the copper requires the slag reduction, primarily reduction of magnetite and co-reduction of cuprous oxide. Thus, the kinetics of the slag reduction play an important role in copper recovery. Instantaneously, at the contact of carbon and a slag the gaseous film is formed. The magnetite and cuprous oxide reduction is going through a gaseous film, separating the slag and carbon of a coke or electrodes. The thickness of a gaseous film grows to a critical value and gas bubbles, containing CO and CO2, are created and rise up in the slag. Results of measurements of kinetic of the slag reduction with graphite showed high value of activation energy, close to the value of activation energy of Boudouard reaction. Strong temperature dependence of the reaction rate points out the thermal instability of the reacting system. It was found that the slowest process in the reduction stages determines the loop of CO and CO2 transfer and magnetite diffusion to the slag/gas film boundary. Strongly endothermic Boudouard reaction seems to cause thermal instability on the reaction surface. So, heat transfer to the reaction surface is very important. Due to low thermal conductivity of a slag the convection dominates in the heat transfer. So, any slag stirring accelerates the rate of reduction and coalescence of metallic copper or copper matte inclusions."

Jan 1, 2015

By Richard Elliott

Current methods for producing low-carbon manganese alloying materials for the steel industry are energy intensive and costly. To enable wider implementation of high Mn steel alloys, a novel solid-state Mn ore reduction strategy is therefore being investigated. This solid-state process, modelled on existing Direct Reduced Iron technology, employs a methane-containing atmosphere to reduce Mn ore pellets to a metal carbide. These pellets may then be smelted, yielding a Mn-rich master alloy. It is well established that CH4 is a suitable reductant for Mn ore powders; however, the reduction behaviour of industrially relevant Mn ore pellets by CH4 is poorly understood. The present work reports the results of an investigation undertaken to address this knowledge gap. The results of this study highlight the significantly different reduction behaviour exhibited by the Mn ore pellets relative to the ore powder under similar conditions and suggest that the diffusion of CH4 into the pellet interior is the limiting factor in achieving complete reduction.

By N. Anacleto, S. Ganguly

Reduction of Groote Eylandt (Australia) and Wessels (South Africa) manganese ores using CH4-H2-Ar gas mixture was investigated in a fixed bed laboratory reactor in the temperature range 1000?1200oC. The extent and kinetics of manganese ore reduction as a function of gas composition and temperature were determined by on-line off-gas analysis using mass-spectrometer and dew point sensor. Morphology of ores and its change in the course of reduction was examined by optical and scanning electron microscopy. Phases of raw materials and reduced samples were analysed by XRD and EPMA. Manganese oxides were reduced to carbide Mn7C3. High extent and rate of reduction by methane-containing gas in comparison with carbothermal reduction were attributed to high carbon activity in the reducing gas, which was in the range 15 - 50 (relative to graphite). The reduction rate of Wessels manganese ore increased with increasing temperature. Reduction rate and extent of Groote Eylandt manganese ore achieved maximum at 1050oC. The decrease in rate and extent of reduction of Groote Eylandt ore at higher temperatures, particularly at 1150-1200oC, was due to sintering and formation of semi-liquid silicate slag. The optimum conditions for the reduction of manganese ores were established as follows: a) temperature: 1150-1200oC for Wessels and 1050-1100oC for Groote Eylandt ores, b) methane concentration: 10-15 vol%, c) hydrogen concentration: above 30 vol%, (d) size: 1-3 mm. An addition of lime (10-15 wt% CaO) to the Groote Eylandt manganese ore increased melting temperature of slag and significantly increased the rate and extent of reduction at elevated temperatures.

Jan 1, 2004