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By Ennis P. C

The Mt Keith ultramafic intrusive extends for about 200 kilometres from Agnew in the south to Wiluna in the north. It forms the host for a number of nickel sulphide orebodies including Mt Keith and Honeymoon Well. Long fibre minerals are associated with the orebodies. The presence of these minerals impacts on the issue of tailings disposal from several standpoints, particularly the slurry beaching properties and dust generation from dry beaches. Central thickened discharge (CTD) is an innovative method of tailings disposal that involves stacking tailings in a low conical hill instead of storing them in cells. In appropriate circumstances this leads to savings in capital costs and operating expenditure. The method was introduced to Australia in 1981, and is currently employed at four operating mines, Elura and Peak Gold, both at Cobar in NSW, McArthur River in the Northern Territory, and Union Reefs near Pine Creek, also in the Northern Territory. It is the proposed method for Century Zinc and Ernest Henry, both in Queensland. The paper describes laboratory test work and design parameters for the application of the method to tailings disposal at Honeymoon Well and compares them with comparable data for other CTD systems. Of particular relevance for design purposes are beach slope, density, and water recovery. Wind tunnel tests were conducted on the Honeymoon Well tailings samples to investigate dust generation from the dry beach surface and it was concluded that dust generation from an undisturbed beach would not occur because of crusting.

Jan 1, 1996

By Youngtak Ko

The northeastern Pacific shows the highest nodule abundance among the oceans in the world, and thus has been drawing international attention for deep-sea manganese nodule development. The objectives of this study are to construct database using geostatistics and geographic information system (GIS), to quantify rating value using probability and statistical methods, to suggest suitable sites for manganese nodule development, and to verify results using three statistical approaches. The copper and nickel contents of the nodules were determined by chemical analysis. Factors related to slope, aspect, water depth, and topography were obtained from multi-beam echo sounding data. The transparent layer thickness was determined using a sub-bottom profiler. The probability method was used to calculate each factor's rating, and the layers for different factors were summed to produce the development potential index (DPI). Result maps were constructed for manganese nodules development. The distribution pattern of DPI showed to be controlled of nodule abundance and metal contents. Verification was performed by comparing the results with sampling data in three ways: success and prediction rate, linear regression, and test of independence.

Sep 14, 2011

By Jin-yan TIE, Ke-xin JIAO, Qian Li, Hai-bin ZUO, Jian-Liang Zhang, Meng SHEN

This paper designs three factors such as temperature, pH, conductivity and three levels of orthogonal test. Temperature is a significant factor. However PH and conductivity are not significant through poor analysis. Further research is conducted on the temperature. Temperature stability is 50 . Suitable water velocity is 2.3m/s, which is calculated based on the largest part of the heat flux intensity and the corresponding water temperature should be controlled with 1.5. Meanwhile, water velocity increased has little effect on the heat transfer capabilities.

Jan 1, 2015

By Serge Ouellet

Résumé Six modèles métriques de remblai cimenté en pâte (RCP) ont été suivis durant 120 jours par l?utilisation de deux méthodes géophysiques non-destructives : la résistivité et la micro-sismique. Les RCP étaient constitués de trois résidus miniers et de deux proportions de ciment (3% et 6% en poids). En parallèle, des cylindres de RCP étaient utilisés pour évaluer périodiquement l?UCS. La résistivité augmentait quasi-linéairement de 28 à 120 jours pour tous les RCP investigués. Des variations de résistivité selon le type de résidu et le pourcentage de ciment ont été observées. Une équation empirique a été dégagée entre l?UCS, la résistivité, le temps, la densité relative et le rapport eau/ciment (E/C). La mesure de la vitesse des ondes de cisaillement a permis de dégager une équation mathématique de type exponentielle qui relie la résistance mécanique sans correction préalable par les paramètres de la recette de RCP. La réalisation de ce projet avait pour but de dégager la meilleure approche non-destructive afin d?estimer la résistance mécanique des remblais en chantier minier. Sur la base des résultats obtenus, les deux méthodes utilisées ont donné des résultats probants afin d?estimer la résistance mécanique et les deux méthodes sont donc à même d?être utilisées en chantier souterrain. Abstract Six scale models of cemented paste backfill (CPB) were followed during a 120 days period using two nondestructive geophysical methods: resistivity and micro-seismic. CPB were made up of three mine tailings and two cement proportion (3% and 6% by weight). In parallel, CPB cylinders were used to periodically evaluate uniaxial compressive strength (UCS). Resistivity was increasing nearly in straight line from day 28 to day 120 for all CPB models. According to the tailing type and cement percentage, resistivity variations were observed. An empirical equation emerged from UCS, resistivity, time, specific gravity of tailings and, water/cement ratio. The use of shearwave velocity allowed to identify a mathematical exponential equation related to mechanical strength without prior correction of the CPB?s formula parameters. The purpose of this project was to identify the best non-destructive approach in order to evaluate the mechanical strength of backfill in a mine site. On the basis of those results, both methods gave conclusive results in order to estimate mechanical strength and both methods can be used in underground operations.

Feb 1, 2008

By Lucas Sanches Magalhães

A utilização de resíduos industriais é dificultada, na maioria das vezes, pela presença de determinados elementos, como por exemplo, o ferro, justificando assim a sua remoção. Dentro deste contexto, o objetivo deste trabalho foi estudar a sulfatação de um resíduo proveniente da flotação de um minério de ferro e subsequente lixiviação deste resíduo sulfatado. A composição mineralógica da amostra inicial foi obtida por DRX e MEV sendo possível identificar quartzo (SiO2), hematita (Fe2O3) e muscovita (KAl2Si3AlO10(OH,F)2). De acordo com a análise química, os teores dos elementos principais foram: Fe (12,65%), S (4,02%), e Al (0,62%). Na sulfatação, realizada à 250ºC durante 4 horas, foi estudada a influência da relação ácido sulfúrico/amostra (0,1:1; 0,2:1; 0,7:1; 0,8:1; 0,9:1 e 1:1) na extração do ferro. A lixiviação foi conduzida com 5% de sólidos do material sulfatado, sendo avaliada a interferência da temperatura de lixiviação (25°C e 90°C) e do tempo de duração dos ensaios (15min, 30min, 60min, 120min, 180min e 240min). Pelos resultados obtidos observou-se que o tempo de lixiviação foi um parâmetro insignificante. A máxima extração de ferro foi encontrada sulfatando o resíduo na relação ácido/amostra 1:1 e posteriormente realizando a lixiviação deste resíduo sulfatado a 90°C por 30 minutos, alcançando 85,64% de extração do Fe.

Aug 17, 2017

By D. Belin

Treatment of dilute acid mine drainage and similarly polluted water is becoming increasingly complicated. The pressure of economics is now exacerbated by legislation which classifies as hazardous waste the precipitates from conventional lime treatment plants. Since acid mine drainage invariably contains sulfate ions, one solution is to use anaerobic Desulfovibrio type bacteria to reduce the sulfate into sulphide ions which could then be used to precipitate out the heavy metals. Results are presented for both batch flask cultures and continuous column tests. Compost was used as the bacterial substrate in the column test which simulated heaps. Conditions changed from aerobic to the required anaerobic deep in the columns. Polluted feeds (up to 700 mg/l zinc) gave effluent containing well below I mg/l zinc over extended periods. Direct transfer of sulphide ions through a stream from an isolated container of bacteria is a good alternative.

Jan 1, 1991

By A. Miura, G. Granata, C. Tokoro, A. Fuwa

"The high copper demand as well as the lack of new high-grade deposits, are pushing the copper industry to process low-grade and refractory ores containing chalcopyrite. However, for a quantitative dissolution of copper from the chalcopyrite, the leaching performances still need to be improved. In the present research, we studied and optimized the iodide-assisted leaching of chalcopyrite in H2SO4-Fe2(SO4)3 media. The evolution of surface species during leaching was determined by x-ray photoelectron spectroscopy (XPS) and mineral liberation analysis (MLA). Inductively-coupled plasma spectrometry (ICP-MS) was used to determine the dissolved copper. Significance of experimental results was assessed by statistical analysis while a kinetic analysis of the leaching process was performed by fitting the experimental data with the Shrinking-core model. Results showed the significant positive effect of iodide on copper extraction rate. In the presence of KI, the dissolution rate of copper was almost double than in the parallel experiments without KI. Whether using KI or not, elemental sulfur was generated on the surface of the leached chalcopyrite. Nevertheless, in the presence of KI, the passivation layer did not arrest the leaching. Analysis revealed that the leaching rate was limited by the chemical reaction control step.INTRODUCTION Due to the large demand of copper, processing low-grade ores containing copper sulfides such as chalcopyrite (CuFeS2) has become unavoidable (Watling, 2013). Since ores with CuFeS2 may also contain appreciable amounts of arsenic that cannot be smelted, and because low-grade ores are uneconomic to smelt, the hydrometallurgical technologies are crucial for recovering the copper (Dutrizac, 1978). Sulfate-based processes are attractive because of the lower operating costs and because the sulfate ion is more suitable in case copper would be recovered via electrowinning. In ferric sulfate solution, chalcopyrite undergoes oxidation due to the large amount of Fe(III) and dissolution due to the presence of the sulfate ion (Majima, et al., 1985). The leaching reaction in ferric sulfate medium can be represented as in (1):"

Jan 1, 2017

By R. L. Eppley

The Blacklick Creek Watershed Association was awarded a $158,000 Growing Greener grant from the Pennsylvania Department of Environmental Protection in 2002 for the design and construction of a sulfate reducing bioreactor (SRBR) cell to treat acidic discharge from the Judy 14 abandoned underground coal mine near Indiana, PA. The vertical flow SRBR was designed to treat 38 liters per minute of MIW containing elevated concentrations of aluminum and iron. Other treatment systems at this site plugged due to aluminum precipitates; this problem did not occur in the SRBR. The bioreactor has been periodically overloaded with flows up to six times the design rate. To date, the only maintenance performed on the unit has been the addition of hay to the surface of the unit in response to less than expected performance. The periodic hay additions appear to have restored the SRBR to nearly post-construction levels. Since construction, the SRBR has treated about 136,000 cubic meters (36 million US gallons) of MIW.

Jan 1, 2010

By J. Wagner, P. Eger

Although lifetime estimates for sulfate reduction based on total substrate carbon typically range from 20 to 30 years, field and laboratory experiments showed that rates of sulfate reduction decreased over time as readily available organic material was consumed. When the rate of acid input exceeded the rate of sulfate reduction, alkalinity was removed from the substrate, pH decreased and metals increased. Output pH increased from 4 to over 6 after the system was shut down for several weeks and the rate of acid input was reduced. Successful long term treatment requires a design based on the input pH and the long-term organic decomposition rate.

Jan 1, 2001

By J. Wagner, P. Eger

Although lifetime estimates for sulfate reduction based on total substrate carbon typically range from 20 to 30 years, field and laboratory experiments showed that rates of sulfate reduction decreased over time as readily available organic material was consumed. When the rate of acid input exceeded the rate of sulfate reduction, alkalinity was removed from the substrate, the pH decreased and metals increased. Output pH increased from 4 to more than 6 after the system was shut down for several weeks and the rate of acid input was reduced. Successful long-term treatment requires a design based on the input pH and the long-term organic decomposition rate.

Jan 1, 2002

By Tracey Bodnarchuk, Philipp Mirzoev

Sulfate balance control is a common problem for zinc plants. Roast-leach-electrowin plants are mostly concerned with the over-generation of sulfates while for the HudBay direct leach plant both extremes are possible including potential necessity to buy sulfuric acid to replenish a sulfate-depleted circuit, which makes the problem doubly important. Quantitative methods were applied at the HudBay plant to analyze sulfate generation/depletion based on a local sulfur balance and sulfate extraction calculation in the leach circuit, using a Pb-tie method. Main factors were established influencing sulfate generation/depletion, including the critical role of Pb and pyrite. Regression analysis proved to be effective and allowed the quantitative prediction of Pb concentrations necessary to reach the equilibrium for the sulfate balance. This in turn provided a firm basis for a sulfate-control strategy realized through concentrate blend correction, which allowed the plant to fine-tune sulfate generation/depletion effectively reducing economic consequences of excessive/deficient sulfate generation.

Jan 1, 2015

By J. O. Marsden

Over the past eight years, Phelps Dodge (a division of Freeport-McMoRan Copper and Gold, Inc.) has developed a suite of proprietary hydrometallurgical processes for the treatment of copper concentrates as an alternative to conventional smelting and refining technology. The technical viability of two processes has been commercially demonstrated in a large scale plant at Bagdad, Arizona, designed to process approximately 52,500 metric tons per year of concentrate containing 30.5% copper. The first process utilizes high temperature (225°C) pressure leaching, followed by countercurrent solid-liquid separation, and then blending of the copper-bearing solution with low grade stockpile leach solution for subsequent treatment by SXlEW for copper recovery. The second process uses super-fine grinding, medium temperature (l60°C) pressure leaching, followed by solid-liquid separation, and treatment of high grade copper-bearing solution by direct electrowinning to recover the bulk of the copper values. The latter process will be utilized at Morenci in a commercial facility designed to treat mixed chalcopyrite-chalcocite-covellite concentrates. This facility is scheduled to start up in 2007. Other flowsheet options have been developed by Phelps Dodge for application to a variety of concentrate materials in specific situations. Examples of various flow sheet options are presented in this paper, and the advantages and disadvantages associated with each are discussed in detail.

Jan 1, 2007

By I. E. Zevgolis

A comprehensive critical review on the subject of sulfates-induced swelling behavior of lime-treated soils is presented in this study. Starting with the description of a well documented case study, the mechanisms behind the swelling behavior and the factors that affect this behavior are discussed. Then, the major experimental methods of sulfates content determination are briefly presented. Finally, an attempt is made to categorize sulfates level and equivalent risk for civil infrastructure. The paper indicates that limited work has been done, not only on identifying safe conditions for use of chemical stabilizers in presence of sulfate rich soils, but also on developing materials and methods to avoid, or at least mitigate, the problem.

Jan 1, 2008

By A. H. Kaksonen

Numerous reactor designs for biological sulfate reduction have been reported. Fluidized-bed bioreactors (FBR) can efficiently retain biomass and allow high mass transfer and reaction rates. This work reviews the development of various sulfate-reducing FBR processes for treating acidic metal- and sulfate-containing waters and recovering metals from bioleaching liquors. The FBR process performance was evaluated with continuous flow experiments under various operational conditions: fluidization rates, influent pH values, metal, sulfate and salt concentrations, hydraulic retention times, electron and carbon sources, and temperatures. Substrate utilization and sulfide inhibition kinetics were determined with batch FBR-kinetic experiments. An artificial neural network (ANN) model was used to predict the performance of the FBR. Sulfate-reducing bacteria (SRB) were characterized in FBRs with molecular and culture-based approaches with the aim to gain a better understating of the bioprocesses. Based on the studies, FBRs are well suited for the combined removal of metals, acidity and sulfate from water.

Jan 1, 2010

By Steve Lloyd, Ryan J. Foy, Brandon Steinborn, Jerome P. Downey

Research was performed to evaluate copper and silver extraction from samples of bornite flotation concentrate. Sulfation roasting experiments were performed in a rotary tube furnace, a fluidized bed reactor, and a static bed muffle furnace. Roasting was plagued with rapid, lowtemperature calcine sintering, apparently related to the presence of organic matter in the concentrate. Calcine entered a weak acid leaching process to remove copper, and silver was extracted from the weak acid leach residue in a ferric chloride and hydrochloric acid solution. Copper extraction efficiencies in excess of 90% were attained in the weak acid leach while 90% silver extraction was achieved in the ferric chloride leach, along with copper and lead extractions as high as 93% and 99% respectively. The two-stage leaching process resulted in overall extraction efficiencies of 99% copper and 90% silver.

Jan 1, 2015

By F. H. A. Abdalla

A process is described for the recovery of valuable nonferrous metals from steelmaking dust by suiphatizing roasting using ammonium sulphate. Maximum recoveries of soluble metal sulphates achieved at optimum conditions were> 99.0 %. Selective metal separation of the soluble sulphates in the leached liquors were performed either by controlling the roasting temperature or by adjustment the pH values of the leached liquor ranging from 3.6-6.2. Either pure zinc oxide orland tin oxide could be obtained at optimum conditions, and the products were evaluated chemically and by X-ray analyses. The residues rich in iron oxide can be removed and recycled. The mechanism of sulphatizing roasting process was considered. A general flow-sheet for the overall process of treatment the steel making dust to recover its valuable nonferrous metals was suggested, which ca be applied for other nonferrous bearing materials.

Jan 1, 1996

By Eiichi Kuzuno, Atsushi Shibayama, Toyohisa Fujita, Kazuo Koike, Toshio Miyazaki, Hitoshi Masuda

"A solid sulfur is more useful to recover and store than a sulfuric acid as a by-product in the zinc hydrometallurgy. In this experiment a zin concentrate (sphalerite) was leached with ferric sulfate at about 373 K for 3 to 6 hours. Zinc was leached more than 95%. After a solid-liquid separation, the leached residue contained solid sulfur was obtained. The particles in the residue were dispersed by lignin and the solid sulfur of approximately 85% was recovered as float product by a flotation with frother in the pH 4. The dried float product was heated at 413K for 2 hours. The pure solid sulfur was recovered. On the other hand in the leached liquid a zinc oxide was ·added and ferrous .iron was oxidized to ferric iron by blowing oxygen. This ferric iron was returned to the zinc leached process after solid-liquid separation.IntroductionZinc concentrate is usually roasted as pretreatment in zinc hydrometallurgy and the produced S02 is changed to sulfuric acid. However, recently in Japan the utilization of sulfuric acid has been limited and it is more costly to store. Instead of producing sulfutic acid the solid sulfur recovery has been examined by direct leaching of zinc_ concentrate in this experiment.In the direct leaching, several kinds of effects have been studied for leaching of sphalerite in ferric sulfate solution. The addition of lignine siilfonate1 • 2) and fine· grinding3) increases the · speed arid leaching fraction of sphalerite. The leaching ratio depends on impurities in sphalerite ores4 • 5). Here, the zinc concentrate is leached ferric sulfate solution under atmospheric pressure at 373K. The solid sulfur in leached residue is separated as float products from other solids by sink-float separation and flotation. The sulfur in float products is purified by evaporation at 413K and recovered."

Jan 1, 2000

By R. Padilla

The reaction of chalcopyrite with gaseous sulfur has been investigated in the range 350-450 °C in order to transform this mineral into a more acid soluble copper sulfide and insoluble iron sulfide. The results of thermodynamic analysis of this system as well as the X-ray diffraction analysis of the reaction products showed that in the temperature range 350 400°C the sulfidation reaction proceeded without formation of intermediate copper-iron sulfides according to: The effects of temperature and time on the conversion of chalcopyrite were studied. Conversion of chalcopyrite reached about 80% very rapidly with increase in temperature up to about 400°C. The recovery of copper from the sulfidized samples was determined by leaching in oxygenated 1.2M H2S04, 2M NaCI solution. Copper recoveries over 90 % were obtained from samples sulfidized for 30 min at temperatures lower than 400°C.

Jan 1, 2001

Because of the different types of reagents used for the flotation of sulfide and nonsulfide minerals, it is convenient to consider these two groups of ores separately. The metal sulfides and native metals are substantially all floatable with xanthate and similar collectors.

Jan 4, 1982

By Omar A. Muhtadi

Brohm Mining Corporation, in conjunction with Geobiotics, Inc. has nearly completed a pilot heap biooxidation test on sulfidic ore from the Gilt Edge Mine near Rapid City, South Dakota. Some results from the pilot testing have shown the correlation between the extent of biooxidation and the increase in cyanide gold recovery seen in the laboratory. Bench scale testing showed approximately a 1: 1 correspondence between percent biooxidation and percentage increase in gold recovery. The economics of large scale biooxidation were also evaluated in terms of increased gold recovery versus the time and cost of biooxidation. In the pilot test, the rate of biooxidation became limited by the acid water neutralization system. Later in the test, measures were taken to overcome this problem. Results from bench scale column bioleach testing showed that the Gilt Edge sulfide ore is quite amenable to biooxidation with a substantial increase in gold recovery with just partial biooxidation. Direct cyanide gold recovery of 51 % on ore crushed to -3/8" was enhanced to 82-85% after oxidation of37% of the sulfide as measured by iron. Laboratory experiments also showed that the slow rate of biooxidation of this ore could be accelerated by removal of metal sulfate build up from the leach liquor. The combination of these normally non-toxic metals became inhibitory to biooxidation if not removed by the neutralization circuit.

Jan 1, 1995