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The work to be described is part of a comprehensive research on the influence of impurities on the properties of lead. The author had previously compared an electrolytic lead containing less than 0.002% total impurities with a commercial lead containing 0.008% impurities (excluding oxygen) and had shown that the former recrystallised more readily than the latter under the same conditions of cold work and annealing. This difference in properties was attributed to the difference in purity. Electrolytic lead containing only 0.0005% total impurities has been prepared and cast in vacuo. Some interesting effects have been obtained by working and annealing this lead, and by adding silver to it. The preparation of this lead, and the effects obtained thereon, are described in this paper. Thepaper is divided into the following sections:(I) Preparation of electrolytic lead.(II) Vacuum Casting.(III) Effect of Cold, Work and Annealing on two Electrolytic Leads, having 0.002% and 0.0005% Total Impurities respectively.1 Research Fellow, Dept. of Metallurgy, University of Melbourne.2 Proc. Aust. lnst. Min. Met., 1932, 87, 145.

Jan 1, 1934

In a previous paper the author showed that silver considerably delayed the recrystallisation of lead after cold work. The effect of antimony on the rate of recrystallisation of distorted lead was studied next, and the experiments performed, and the results obtained, are described in this paper. Electrolytic lead was used as a standard of comparison.It was also used to make the lead antimony alloys.This electrolytic lead contained 0.0005% total impurities.It was prepared from commercial lead by fire refining, followed by electrolysis and finally by vacuum casting. The process was described in the previous paper and the description need not be repeated here. PREPARATION OF LEAD - ANTIMONY ALLOYS.The steps taken to procure pure antimony are outlined in the appendix. To make the lead antimony alloys a mother alloy was prepared thus:-A quantity of the antimony (it was received in the powdered form) was placed in a pyrex glass tube, which was closed at one end. The antimony was washed with hot hydrochloric acid (1: 1), then with more dilute acid, then with distilled water, and finally with absolute alcohol; it was dried by warming and evacu,ating the tube. This should leave the antimony more nearly free from surface oxides.The amount of antimony was determined by weighing quickly; the appropriate amount of vacuum-cast electrolytic *Research Fellow, Dept. of Metallurgy, University of Melbourne.

Jan 1, 1936

This paper contains an account of some creep tests on electrolytic lead and some of its alloys. The stresses used in determining creep were 500, 350, and 200 lb. per sq.' in. The alloys contained silver, bismuth, tellurium, antimony and zinc respectively. All were castin vacuo, and tested "as rolled." Tests were done also on electrolytic lead which had been cast in air.The electrolytic lead contained 0.0005% total impurities.The preparation and vacuum casting of this lead have been described in a previous paper in this series. The preparation of the alloys, and the air casting of the electrolytic lead, are described in the next section.EXPERIMENTAL PROCEDURE.Every effort was made to keep the vacuum-cast specimens from contact with the atmosphere throughout their history.The ingots were stored eIther in a vacuum desiccator or immersed in heavy oil. The creep specimens were coated with vaseline except during rolling, etching and photography, which involved exposure to the atmosphere for about 45 minutes all told.It is not claimed that vaseline is a perfect shield against the intrusion of atmospheric gases. Possibly during the months that some tests were in progress the gases diffused through the vaseline and gained a limited access to the lead.Nevertheless, the use of vaseline gave protection that brought the tests nearer the ideal at which the author aimed, *Research Fellow, Dept. of Metallurgy, University of Melbourne.

Jan 1, 1936

By Met M, Worner H. K

In pursuance of the investigation into the influence of various elements on the properties of lead during the past year, the effect of several elements on the creep rate of commercially pure lead has been investigated; a standard initial stress of 500 lb. per sq. in. having been adopted for comparison purposes. Other work which has been carried out indicates that the relative results of creep tests may be altered by varying the applied stress, but this aspect of the problem will need to await further investigations for itscomplete elucidation. The results obtained with dilute tellurium alloys are considered sufficiently interesting, and in some respects are so extraordinary, as to warrant publicatiorr at this stage.n must be realised however that, since the results obtained appear to be at variance with those said to have been obtained in practice and those previously published, the present investigation can only be considered as a contribution to our knowledge of the general problem.Consequently it is not considered advisable or necessary to offer detailed explanation of the results given. In fact, some features of the tests about to be described will need further investigation before an adequate explanation is possible.

Jan 1, 1936

The paper, presented at the North of England Institute of Mining and Mechanical Engineers' general meeting held in Newcastle-upon-Tyne, 8th April 1916, presents experimental work undertaken to observe the quenching effect of different substances, to find the most efficient of these substances, and to arrive at a possible explanation of their preventive action. The coal-dusts experimented with were such as passed through a 100-mesh sieve (10,000 holes to the square inch), and were obtained by grinding the coals. The quenching substances, used in as fine a state of division as possible, included gypsum, dried Chance mud, quicklime, magnesia, magnesia alba (levis), anhydrous sodium carbonate, sodium bicarbonate, soda-crystals, Glauber salts, ground shale and boiler-ashes

Dec 1, 1916

Discussion following the presentation at the North of England Institute of Mining and Mechanical Engineers' general meeting held in Newcastle-upon-Tyne, 8th April 1916, included the author's introduction, written contributions by Bedson P.P., Gregory T.W.D. and Morgan J.D., oral contributions by Louis H., Greener T.Y. and Severs W., and the author's reply

Dec 1, 1916

The aim of this investigation was to study the influence that varying production rates have on iron sinter quality. This was done by performing sinter pot tests at different pressure drops over the sinter bed, namely 11 kPa and 15 kPa (for 500 mm total bed depths). During each of the sintering processes temperature-time profiles were recorded of the top, middle and bottom layers of the sinter bed. On completion of the sinter process the sinter cakes were divided into top, middle and bottom layers. The physical properties of each layer were subsequently characterized by performing a tumbler test and a sieve analysis. A comprehensive mineralogical study was also conducted on each layer. This study revealed that sinters of similar cold strength could be produced under the examined production rates. However, a higher production rate was accompanied by an increased amount of fines. The cold strengths of both sinters significantly increased from the top layer to the bottom layer of the sinter bed. This strength variation is not related in any simple way to the phase composition. Keywords: Sinter, sinter bed, production rate, phase composition, cold strength, tumbler index, sieve analysis, temperature-time profile

Jan 1, 2003

By D M. Brady

Underground coal mines in Australia have embraced the use of various inertisation techniques both proactively and reactively. The use of such techniques can have a significant influence on ratios and trends used to monitor the status of the underground environment. Whilst control strategies should never be ignored in favour of preserving the integrity of ratios, the influence and significance of the changes likely to be seen should be anticipated and understood for reliable interpretation of the situation. This paper looks at the influence inertisation techniques can have on results and subsequent interpretation.CITATION:Brady, D M, 2013. The influence of inertisation techniques on gas interpretation, in Proceedings The Australian Mine Ventilation Conference , pp 259-264 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By Henry M. Howe

THE natural effect of large size should be to increase segrega¬tion. I have previously pointed' to the excessive segregation in many large ingots as tending to confirm this, but I have shown that in case of ingots less than 16 in. square this expected effect of ingot-size is liable to masked by that of other variables. Under these conditions we should expect that if large ingot-size really does tend to increase segregation, this effect would be shown by taking the average of large numbers of cases, so that the effects of these other variables might off-set and cancel each other.

Jan 10, 1909

By Simon H. Prassetyo

Violent failures of coal pillars, known in practice as coal mine bumps, have long been a subject of investigation. Many field investigations have considered geological conditions that create high stress in the pillar to be the main causative factor leading to bumps. In recent years, constraint at interfaces has been observed to be associated with the occurrence of coal bursts. This paper shows how interface friction and width-to-height (W/H) ratio affect the degree of violence of coal specimen failure. A series of UCS tests on 178 coal samples from bump-prone (Utah, called UT coal) and non-bump-prone (West Virginia, called WV coal) mines were conducted. Three violent failure parameters? peak sound pressure level, core zone failure, and ultimate stress? were used to assess the violence of failure. The degree of violence were investigated at varying interface frictions (high: µ = 0.40, medium: µ = 0.22, and low: µ = 0.13) and W/H ratios (W/H = 2, 3, 4, 5, 6, 7, 8, 10, and 12). A simulation series of modeled coal specimen under uniaxial loading was also conducted using the finite element method to observe the equivalent plastic strain distribution experienced by the modeled coal specimens. It was found that the violence of coal specimen failure depends on W/H ratio and interface friction. Interface friction has more significant influence on the violence of failure at high W/H ratios than it does at low W/H ratios.

Jan 1, 2011

By Mohammad Ali Rowshanzamir, Mehdi Aghayarzadeh

"This article is an effort to improve our understanding of the performance of geogrid retaining structures (GRS) through numerical analyses. The numerical modeling utilized a commercially available finite difference program, FLAC3D. In this context an extensive parametric study has been carried out on two different GRS walls (vertical reinforced block and inclined reinforced block) to investigate the influence of internal design factors such as soil strength properties and reinforcement stiffness on the performance of these walls. The main purposes of the parametric study were to (1) investigate the sensitivity of the modeling results to the input material properties, (2) examine the influence of the internal design factors on the performance of GRS retaining structures, and (3) improve the internal design of GRS walls on the basis of the working stress information obtained from the parametric study. Based on the analyses results, it was revealed that GRS walls with oblique reinforcement and reinforced block (rotated against natural backfill) have much better performance in terms of reduction in the stresses and strains of reinforcing elements as well as decrease in the wall lateral and vertical displacements in comparison with vertical reinforced block (conventional wall). For example, with 12° inclination of the wall reinforced block there was 50% reduction in the backfill settlement. Also increasing the reinforcement stiffness amount from 10MPa to 50MPa decreases the wall face displacement more than 50% in both GRS walls.INTRODUCTIONOver the past few decades, Geosynthetic- Reinforced Soil (GRS), a soil mass reinforced by geosynthetic layers to restrain the soil lateral deformations, has been employed in the construction of many types of earth structures, including retaining walls, embankments, slopes and bridge abutments. In fact GRS structures are typically more flexible (hence more tolerant to differential settlement), more adaptable to low quality backfill, easier to construct, require less over-excavation, and more economical. Nevertheless, there is a need for an accurate design tool that can predict the performance of GRS structures under working stress conditions and can predict their failure loads as well.Many studies have been published on the performance of the soil reinforced walls such as Isabel et al., 1996; Bathurst et al., 2000; Kazimierowicz-Frankowska, 2005; Nernheim and Bathurst, 2008; Chen and Chiu, 2008 Correia et al., 2012; Erlich et al. 2012. Several numerical studies have also been made throgh finite elements and finite difference techniques on reinforced soil retaining walls to analyze the wall deformations (e.g. Hatami et al. 2001& 2006, Liu and Won 2009, and Abdelouhab et al. 2011). A limited laboratory research has been reported indicating of improving effect of tilting face on GRW performance (Chen and Chiu, 2008). However no major numerical study was found on the effects of face or reinforcement tilting."

Jan 1, 2017

Investigation of standard tests used to establish the decrepitation rating of Western Australian iron ore showed scatter in results which could be reduced by textural type sampling. Testing of individual textural types resulted in separation.of a range of decrepitation behaviour patterns. No unique correlation was established between water content in goethite, or between any single mechanism and breakage in shock heating. The latter depends rather on several mechan- isms whose operation is controlled by the texture of the ore. Texture studies were used successfully to predict decrepitation behaviour which could be related to orebody structure for mine planning, and blending for sales or processing requirements.

Jan 1, 1973

By Mei-Yan Yang, Qiu-Ying Wang, Ltd. Yunnan Yuntong Zinc Co., Guo-Mu Chen, Meng-Yang Huang, Peng Zeng, Guo-Feng Li

"Historically, alot of jarosite was found in the leaching residue when leaching indium from secondary zinc oxide materials. The reasons for the formation of indium bearing jarosite were theoretically analyzed. The influence of controlling the acidity and the addition of reagents on the indium leaching yield during secondary zinc oxide processing was investigated. In order to increase the leaching yield of indium, a measure of controlling the creation and destruction of jarosite was proposed. The production data shows that the leaching yield of indium was increased from 60 to 96%, and the content of indium in leaching residue simultaneously decreased from 900g/t to 100–200g/t when implementing such controlling measures.INTRODUCTIONIndium does not occur as independent minerals in the earth’s crust and is mainly associated with complex sulphide minerals. Specifically some sphalerites can contain as much as 900g/t of indium. Most indium is recovered from by-products of copper, lead or zinc metallurgy. Therefore, the research on the recovery of by-products in non-ferrous metallurgy is important(Sinclair et al, 2006). The main technologies used for this objective in China include: •,pre-neutralization-reduction-precipitation indium process(Yu et al, 2008), •,countercurrent oxidizing acid leaching process and sulphation roasting-water leaching process(Cao, 2005), •,oxygen pressure acid leaching of zinc concentrate-P204 extraction process(Yang et al, 2006), •,doubleacid leaching-solvent extraction process on lead dross from a reverbatory furnace flue dust(Liu, 2003),•,an acid leaching-solvent extraction process on smelting ash(Zhouet al, 2005). Although high pressure and extreme conditions can be used to improve extraction from high iron bearing indium residues(autoclave processing), mild extraction with lower cost and lower environmental impact are preferred.This paper describes both how the indium extraction using mild conditions in a secondary zinc circuit was quite low and, how through XRD and chemical analysis jarosite formation was found as the main cause. The paper then proceeds to discuss a method for improving the leaching yield and the application of this method in industrial practice."

Jan 1, 2016

By A. G. Spencer, A. D. Taylor

This paper discusses some of the advantages and problems associated with the selection of large unit equipment for a metallurgical plant. A given flowsheet and material balance for an iron ore concentrator is assumed. Then two plant designs are developed, one utilizing a number of smaller-size equipment units and one utilizing the largest available equipment units. The mechanical and electrical problems are discussed and a comparison of capital costs is made. Finally, brief consideration is given to a plant de-sign using units larger than those which are currently available.

Jan 1, 1968

By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

In the leaching of gold in aqueous cyanide solutions the rate of gold leaching may be decreased by the passivation of the gold, that may however be prevented or reversed in the presence of lead species in solution. In the present study potentiostatic, potentiodyanamic and XPS (X-ray photoelectron spectroscopy) analysis were used to further clarify the action of lead ions on the anodic activity of gold in alkaline cyanide solutions. It was found that lead increased the gold dissolution rate as it deposited on the gold surface at potentials more positive than its reversible Nernst potential for bulk metal deposition, i.e. by underpotential deposition mechanism, but that it decreased gold activity if present as bulk plated lead on the gold.

Jan 1, 2003

By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

Although the cyanidation process for gold leaching has been applied for more than a hundred years, some aspects of it, such as the passivation of the gold and the depassivating action of heavy metals, are still not well understood. In this work the anodic behaviour and surface composition of gold in alkaline aqueous cyanide with lead additions were investigated using polarization experiments and XPS. It was found that lead in the solution activated the gold at low concentrations, somewhat more positive than the reversible potential for gold, but that the activity again decreased at higher concentrations of lead. The potential range for the activation of the gold coincides with that where underpotential deposition of lead occurs, i.e. –200 to –600 mV(SCE), as indicated by the surface composition of the gold, shown in figure 1. Note that the concentration of lead on the surface of the gold only increased with time in the bulk plating potential range for lead, where gold is not activated by the presence of lead. It is also shown that up to 20 mg/L of lead added to the solution will activate the gold, provided that bulk plating of the lead is avoided. It is also important to avoid reducing conditions during leaching, where bulk plating of lead may occur, if the gold is to be activated by lead to achieve a high leaching rate, as the bulk plated lead screens the surface rather than activating it.

Jan 1, 2003

By J. Y. Kim

Lead ions originating from galena during processing of complex sulphide ores migrate to "cover" the surface of sphalerite and iron sulphide mineral particles, and cause poor selectivity in differential flotation. Generally in sulphide ore processing, the lead-activated minerals float in the Cu/Pb rougher circuit. Subsequently, surface lead complicates the zinc flotation circuit by lowering the concentrate grade due to the co-flotation of lead-activated iron sulphide minerals. The effect of lead in the differential flotation of sphalerite from Cu-Pb-Zn and Pb-Zn ores is discussed. Plant and laboratory test data are interpreted by determining the surface composition of individual grains of sphalerite and iron sulphide particles using two surface analytical techniques, Laser Ionization Mass Spectrometer (LIMS) and Time of Flight-Secondary Ion Mass Spectrometer (TOF-SIMS). Cationic and anionic species on the surface were analyzed to elucidate the phenomena.

Jan 1, 1995

By Suzanne Young

The effect of LiF additions on liqt.1id1.:1s temperature and electrical conductivity over a wide range of cryolite bath ratios (1.0 to 1.5 weight ratio) was investigated. Results did not agree with multi-regression equations reported by Dewing and Choudhary over the entire region. New regression equations were developed. Reasons? are given for the differences. The models are used to discuss the economic implications of LiF additions to Hali cell electrolytes.

Jan 1, 1985

By Karl-Heinz Obst, Juergen Stradtman

The importance of the chemical and physical properties of lime has been overlooked for years although the quality of lime plays an important role in the production of steel. With the introduction of the oxygen injection process these properties have been re-evaluated. The CaO, MgO, S, and P2O5 contents of lime are important, but so are the physical properties such as granulation, reactivity with respect to slag formation, and the degree of burning. Soft burnt lime enhances de-phosphorisation and de-sulphurisation, and facilitates the smelting process in general, mainly due to its large specific surface. Special lime, prepared as briquettes from quicklime and fluxes or as pellets from limestone and various fluxes with or without binding agents, clearly accelerates lime dissolution during the slag formation process, lowers the melting point, and enhances de-phosphorisation, de-sulphurisatlon, and de-carburisation even more than soft burnt lime. The introduction of special limes in the oxygen injection process for steel production has opened up new fields for commercial exploitation of slags as well as improved operational techniques.

By P Toor

Due to the high energy consumption of milling, it is desirable to improve the efficiency of this process. One alternative to reduce energy and material consumption while optimising production yield in mill operation is through balanced design and selection of liners. Over-design of liners leads to increased life but at a cost to grinding performance, a relationship which to date has not been studied closely. This paper provides a description of this process of liner life cycle optimization and presents initial results from the first of two life cycles being studied for a 32 foot (ft) SAG mill. The use of commercially proven high resolution laser scanning based liner shape information provided by the MillMapper® software correlated with well controlled site surveys at various points in the liner life was used as the basis for comparison. The survey data was modelled in JKSimMet to provide direct comparisons of mill performance. This potentially provides a methodology for the design of liners that maintain a favourable shape for the majority of liner life, yielding desirable production parameters such as lower specific energy consumption and higher throughput, while at the same time maintaining practical liner life cycles.

Aug 8, 2011