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By C. H. Mahoney, P. E. LeGrand, A. L. Tarr

MAGNESIUM, it is now generally realized, differs in some important aspects from most other structural metals, not excepting even its close neighbors, the aluminum-base alloys. This is particularly true with respect to the effects of elevated temperatures on the two light metals when in the molten state. Aluminum, on the one hand, should not be raised above its melting point any higher than is absolutely necessary if one is to avoid danger of gas absorption and a tendency toward grain growth in the resultant casting.1 Magnesium alloys, in sharp contrast, actually benefit by being heated to temperatures considerably above their melting point. It is a commonly accepted practice to establish the desired fine grain in the industrial magnesium alloys of the aluminum-bearing group by raising the temperature of the melt after the refining treatment to some 25e C (482°F.) above the melting range. To recall briefly the typical practice for magnesium alloys, the molten metal is refined by fluxing at about 730° C. (1350 F.), and after the melt has been covered with a suitable flux, the temperature is raised to between 870°C. (1600°F.) and 930°C. (I700°F.). It is then cooled as quickly as possible to the casting temperature. This superheating, as it is called, results in a fine-grained cast metal structure which has superior mechanical properties, enhanced amenability to solution heat-treatment, and better machinability than cast metal that has not been superheated. The minimum temperature of superheating varies to some extent with the composition of the alloys to be treated and usually increases with the percentage of magnesium in alloys containing the same constituent metals.2 It should be noted that the grain-refining effect of superheating is markedly apparent only in connection with the alloys containing aluminum as an alloying constituent-the binary alloy containing r.5 per cent manganese, for example, is not refined in grain to any noticeable extent by a superheating effort. While the phenomenon of superheating is well known in the magnesium industry, the mechanism of the process has remained a mystery. During the superheating cycle something occurs that forces a fine grain upon the solidifying metal. The process has been controlled in an empirical manner, and occasionally, especially on large-scale melts, and for no apparent cause, no grain refinement is obtained from a superheating treatment. Only a few papers of importance have been published on the subject. Of these, one of the most helpful is the paper by Achenbach, Nipper and Piwowarski,3 which gives considerable data concerning the effect of superheating on various properties such as fluidity, shrinkage and hot crack formation, as well as grain size, and a discussion without any definite conclusions on the theoretical aspects of superheating. A short article by Murphy, Wells and

Jan 1, 1945

By M. Loan

The Zinifex's Hobart Smelter uses the paragoethite process to remove dissolved Fe(III) from concentrated zinc leach liquors. This produces a residue consisting primarily of 6-line ferrihydrite (a hydrated Fe(III) oxyhydroxide), several insoluble components derived from the calcined zinc concentrate neutralization agent and other precipitated phases, such as jarosite and silica. The precipitation of 6-line ferrihydrite in the paragoethite process was studied using a laboratory-scale continuous crystallizer, and the conditions were selected to limit high levels of dissolved silica and jarosite. This approach allowed the reactor pH and the rate of precipitation to be correlated with residue solid-liquid separation, particle size, morphology, residual zinc and sulfate concentrations, and phase formation (e.g., goethite, jarosite, schwertmannite, and 2- and 6-line ferrihydrite). These studies delineated the mechanism of 6-line ferrihydrite precipitation in the kinetically controlled paragoethite process, and its inter-relationship with goethite and jarosite precipitation under conditions where 6-line ferrihydrite is favoured. Unexpectedly, the generation of a more crystalline goethite precipitate with larger "primary" particle size did not produce a residue of improved properties, as bulk aggregates dictate the physical properties of the residue and not the crystallinity. Furthermore, it is difficult to precipitate 2-line ferrihydrite or schwertmannite under existing paragoethite process conditions.

Jan 1, 2006

By D. A. Salinas G., A. H. Castillejos E.

Pachuca tanks are commonly used in the hydrometallurgical industry to carry out leaching operations. The fluidynamic characteristics of the liquid phase, resulting from the injection of gas into the draft tube, are important to achieve the complete suspension of the mineral particles and has a decisive influence in the mass transfer processes occurring in this reactor. This study investigated the effect of different design and operating characteristics on the liquid velocity field. using a laboratory-scale Pachuca tank. The transparent model was filled with water, and air was injected through the bottom in the absence of mineral particles. The liquid velocities over the whole reactor were measured under several experimental conditions using particle image velocimetry (PIV). This technique allowed to obtain a very detailed picture of the liquid motion even in the draft tube, as long as bubbles were absent from the measured field of view. The experiments have shown that the liquid velocities increase with increasing the draft tube to tank diameters ratio, the distance from the conical bottom to the draft tube entrance, or the gas superficial velocity. On the other hand, an increase in the water level with respect to the draft tube outlet caused a decrease. A mathematical model, which used the no-slip model, to calculate the variation of axial effective density along the two-phase region, was found to predict liquid velocity fields which agree very satisfactory with the experimental results obtained under all the conditions studied.

Jan 1, 1999

By Ross W. Smith

Many studies have been made of the microflotation of quartz (1,2,3,4,5,6) and alumina (3,5,6, 7,8) using various anionic and cationic hetero- polar hydrocarbon surfactants as collectors. A few studies have been made on these minerals using amphoteric hydrocarbon collectors ( 9,10, 11,12) and only a few studies have been made on the use of fluorocarbon surfactants as flotation collectors (13,14). The present investigation compares microflotation response of the two minerals in hydocarbon and fluorocarbon collector systems of the anionic, cationic and amphoteric types. An attempt is made to relate flotation response of the minerals to their electrokinetic behavior and the pKa values of the collectors.

Jan 1, 1979

By Qingming Feng, Dongbo An, Jinhong Zhang

The application of the geopolymerization of mine tailings as construction materials is hindered by the fact that conventional geopolymerization of mine tailings usually involves a large consumption of alkali, i.e., sodium hydroxide (NaOH), and a long curing time, because of the relatively low reactivity and the high Si/Al ratio of mine tailings when compared to other active resources such as fly ash and clay minerals. The present study is focused on efficiently activating mine tailings, reducing alkali consumption, decreasing curing time and improving compressive strength. We firstly investigate the temperature effect on the alkali activation of mine tailings during geopolymerization. Secondly, the impact of additives, i.e., calcium hydroxide and aluminium oxide, on the compressive strength of samples is studied. Thirdly, different forming pressures have been applied to remove excessive alkali and its impact on samples' strength has been investigated. The results show that a 40 MPa unconfined compressive strength (UCS) can be achieved with the geopolymerization samples after mine tailings are activated by sodium hydroxide at 170°C for 1 hour with the addition of calcium hydroxide and alkali dissolved aluminium oxide, further compressed with a 10 MPa forming pressure and finally cured at 90°C for 3 days. The findings of the present work provide a novel method for the geopolymerization of mine tailings as construction materials.

Jan 1, 2014

By H Kim, M J. Sun

Global steel companies are actively combating climate change by reducing carbon emissions. Traditional steel production, using the blast furnace (BF) – basic oxygen furnace (BOF) process, heavily depends on coal and emits substantial CO2. To mitigate this, companies are transitioning to the more eco-friendly DRP (direct reduction plant) – EAF (electric arc furnace) process, which lowers CO2 emissions. This study quantitatively evaluates the impact of increased hydrogen consumption on the carbon footprint of product (CFP) through an analysis of direct reduction process heat and mass balances. The study prioritises a comprehensive material balance based on mass conservation principles. The heat balance is calculated using differences in enthalpy through state energy properties, avoiding heat consumption. Validation using operational data from Hyundai Steel Dangjin works’ blast furnaces shows close alignment between calculated results and actual data, with less than 1 per cent error. This methodology facilitates a detailed analysis of the direct reduction process, offering insights into its feasibility and efficiency. Analysis of the operational impact by increasing the hydrogen ratio demonstrates reduced CO2 emissions and increased heat requirements due to the endothermic nature of hydrogen reduction, in contrast to the exothermic CO reduction. Possible solutions include raising reducing gas temperature or enhancing flow rate. The study effectively utilises designed heat and mass balances to assess material quantities and thermal balance under different operational conditions. It lays the foundation for the initial direct reduction process design, aiding in deriving and optimising operational parameters. Additionally, it provides valuable insights into the challenges of increased hydrogen, contributing to the production of greener steel by addressing these issues.

Aug 21, 2024

By F. Varley

Researchers from the National Institute for Occupational Safety and Health (NIOSH), in cooperation with mine operators, conducted a study of heat stress exposures among mine rescue workers in underground mines. Mine rescue workers face extreme heat loads as they enter hot and poorly ventilated environments, particularly when they are wearing breathing apparatuses. The burden of wearing a closed-circuit breathing apparatus (CCBA), the inability to drink fluids for extended periods of time, and the potential for ventilation disruptions and fires combine to increase the risk of heat illness during a response to an emergency. In this research, ambient environmental conditions and heat strain indicators were measured using conventional ventilation monitoring tools during mine rescue training exercises. Heat strain was measured with an ingestible temperature-sensing pill that measured core temperature continuously. In addition, a heart-rate monitoring chest strap was used to indicate physical strain resulting from physical activity and heat. Both core temperature and heart rate data were transmitted to a remote recorder worn by a rescuer and time-stamped. Team activities were also observed to determine the contribution of work rate to a person’s total heat load. The effectiveness of several engineering controls, such as cooling the air inhaled by rescuers through an apparatus, wearing cooling vests, and supplying water through the CCBA masks, were investigated. Administrative controls, such as limiting the duration of exposure and controlling the work rate through forced-rest regimens, were also evaluated. Results to date are discussed, and tools for evaluating team condition and estimating the length of time it would be safe for rescuers to work are proposed.

By F. Varley

Researchers from the National Institute for Occupational Safety and Health (NIOSH), in cooperation with mine operators, conducted a study of heat stress exposures among mine rescue workers in underground mines. Mine rescue workers face extreme heat loads as they enter hot and poorly ventilated environments, particularly when they are wearing breathing apparatuses. The burden of wearing a closed-circuit breathing apparatus (CCBA), the inability to drink fluids for extended periods of time, and the potential for ventilation disruptions and fires combine to increase the risk of heat illness during a response to an emergency. In this research, ambient environmental conditions and heat strain indicators were measured using conventional ventilation monitoring tools during mine rescue training exercises. Heat strain was measured with an ingestible temperature-sensing pill that measured core temperature continuously. In addition, a heart-rate monitoring chest strap was used to indicate physical strain resulting from physical activity and heat. Both core temperature and heart rate data were trans-mitted to a remote recorder worn by a rescuer and time-stamped. Team activities were also observed to determine the contribution of work rate to a person’s total heat load. The effectiveness of several engineering controls, such as cooling the air inhaled by rescuers through an apparatus, wearing cooling vests, and supplying water through the CCBA masks, were investigated. Administrative controls, such as limiting the duration of exposure and controlling the work rate through forced-rest regimens, were also evaluated. Results to date are discussed, and tools for evaluating team condition and estimating the length of time it would be safe for rescuers to work are proposed.

Jan 1, 2004

Blasting in Norwegian mines is often carried out by contractors who tend to look for the cheapest solution, without concern about fragment quality. The requirementsfor a contractor are usually only related to the maximum size of boulders and the quantity per month. Even when the owners of the mine are responsible for blasting, very little effort is made to optimise the blasting process. This paper presents test methods which were used and results from small-scale and full-scale blasting tests. In the small-scale tests, cubes 500 x 500 x 500 mm of four different rock types were blasted in a chamber, using two types of dynamite explosive. The velocity of detonation (VOD) for the dynamite explosives was 3000 m/s and 6000 m/s respectively. Three cubes of each rock type were blasted with each type of explosive, and a total of six cubes of each rock type was used. The entire muckpile (approximately 350 kg) was- sieved and weighed after each blast and fragments between 8-16 mm were tested for impact values and flakiness. The results of these tests clearly showed improvement in fragmentation the closer the acoustic impedance ratio of the explosive (VOD x density) over the rock (Cp density) was equal to one. The results also showed that the quality of the fragments (in terms of impact values) tends to be better when the cubes are blasted with the high velocity dynamite.

Jan 1, 1995

By S. Torno

The elimination of ultrafine (<10 µm) clay particles is essential to the treatment of abandoned coal-washing plant tailings for the recovery of the remaining coal fraction by enhanced gravity processing. Effective hydrocyclone classification is required to remove this fraction. The highly variable composition and particle size distribution of such wastes creates significant difficulties in the operation of hydrocyclones for such classifications. Hydrocyclone laboratory investigations and their plant setup require lengthy or time-consuming tests. The use of empirical models of such classifications frequently requires modification to correspond to actual operating conditions. Results of the evaluation of computational fluid dynamics (CFD) modeling to predict hydrocyclone classification of coal-washing plant tailings are presented. Results of the standard k-epsilon turbulence, SSG turbulence and large eddy simulation CFD models are compared with the results obtained from analyzed hydrocyclone classifications. The CFD models tested are shown to be very effective in the simulation of hydrocyclone classifications for the determination of the classification particle size and adequate for determining the efficiency index values for many applications. The large eddy simulation model was identified as the most precise, but it is recommended that all three models be improved simulations of classifications above and below the classification particle size.

Jan 1, 2011

By D. R. Nagaraj

There are few organic ligands that can adsorb effectively on noble metals, especially gold, in aqueous media. Ligands containing sulfur and nitrogen donors are known to be the most effective. Dithiophosphorous acids, for example, are known to adsorb on gold under certain conditions and these, along with xanthates, are used traditionally to recover gold values by flotation from ores. These compounds, however, are not necessarily selective for gold since most of the associated sulfide minerals are also floated. Monothiophosphorous acids, on the other hand, were recently discovered to float gold values selectively from sulfide-containing ores in a mildly alkaline medium; thus the dicresyl monothiophosphate is now used commercially in a gold flotation operation in the U.S.

Jan 1, 1991

By Ali Kahriman, D. Adiguzel, R. Ulger, U. Akkaya

The environmental problems arising from ground vibration has been faced and discussed frequently in various industries such as quarry, mining, civil works, shaft, tunneling, pipe line and dam construction etc. where the blasting operations are unavoidable. This paper presents the results of ground vibration analysis induced by blasting during the construction of the Istanbul Kadiköy-Kartal metro tunnel. Different rock formations in this tunnel route which is 21.6 km in length were encountered during the excavation process by blasting. As a first stage, Hoek’s Geological Strength Index (GSI) values of rock units were determined by using inverse distance weighting method. The GSI values which were obtained from boring data were used when evaluate the data. GSI values were estimated by inverse distance method (figure 3) along with the tunnel route. Afterwards, ground vibration parameters induced by 21 shots which were made in different locations was monitored and passing routes of vibration waves determined. Weighted averages of GSI values were calculated according to distance of the regions where vibration waves passed. Multi regression analyze were made with using frequency, charge per delay, GSI and the distance between the shot point and monitor station. The main goal of this study is to investigate the relationship between ground vibration frequency induced by blasting and GSI.

Jan 1, 2011

By J. M. Mutmansky

"This study analyzed laboratory comminution techniques for respirable mine dust generation and the properties of the resulting dusts. It was the objective of the study to determine the suitability of the resulting dusts in reflecting the properties of natural airborne dust. This paper deals specifically with the amount of contamination introduced into the generated dust as a result of abrasion when using nine different grinding methods. The analysis was made by comparing the content of 25 chemical elements in the lab-generated dusts with the same elements in the airborne coal mine dusts. It was found that all the lab-generated dusts possessed contamination but that several methods produced smaller percentages of contamination and that the residence time in the grinding device was an important factor in the contamination levels. INTRODUCTIONDust in the atmosphere is a health hazard and a major source of occupational diseases in the coal mining industry (Anon., 1980; Merchant, Boehlecke, and Picket-Hamer, 1986). It has been shown that coal workers' pneumoconiosis (CWP) is directly related to the inhalation and accumulation of respirable coal dust in coal miners' lungs. In order to effectively protect coal workers from coal dusts, we must have a clear understanding of dust properties including dust generation and dust-lung reaction mechanisms. This requires extensive biomedical research. Dust related research often requires large samples of respirable coal dusts to be collected, either for repeated experiments or stored for future reference. Unfortunately, current sampling instruments are not able to meet this demand. Ali a result, laboratory-generated coal dust ls frequently used as a substitute for coal mine dust in biomedical and other research applications. Now, the questions are how close the characteristics of laboratory-generated dusts are to those of mining-generated dusts and which equipment is moat appropriate for research dust production in the laboratory . These are some of the interests of this research project. The primary objective of this project was to find a laboratory technique which can generate coal dusts possessing properties similar to coal mine dust with respect to particle size distribution, chemical composition, and particle shape and morphology. However, this paper will focus only on the chemical compositions of the prepared dust samples and try to identify the sources of chemical contamination from various size reduction processes."

Mar 1, 1992

By Jianliang Li, Jan M. Mutmansky

This study analyzed laboratory comminution techniques for respirable mine dust generation and the properties of the resulting dusts. It was the objective of the study to determine the suitability of the resulting dusts in reflecting the properties of natural airborne dust. This paper deals specifically with the amount of contamination introduced into the generated dust as a result of abrasion when using nine different grinding methods. The analysis was made by comparing the content of 25 chemical elements in the lab-generated dusts with the same elements in the airborne coal mine dusts. It was found that all the lab-generated dusts possessed contamination but that several methods produced smaller percentages of contamination and that the residence time in the grinding device was an important factor in the contamination levels.

Jan 1, 1992

By K. S. Coley, G. A. Irons, T. Kaneyasu

"It is very important to reveal the lime dissolution mechanism in steelmaking slag, to promote its dissolution without calcium fluoride, which is now almost forbidden for use in most industrialized countries. In this research, the purpose was focused on the development of an experimental method to measure the mutual diffusivity of Ca2+ under the condition of lime dissolution into slag. By forming diffusion couples using a ""vacuum slag aspirating technique"", the method was established. The following mutual diffusivities of Ca2+, in CaO-SiO2-FeO slag systems, imitating oxygen steelmaking slag, were determined using this method:4.1*10-10 m2/s at 1400°C for 27wt.%CaO-53wt.%SiO2-20wt.%FeO slag,4.3* 10-10 m2/s and at 1400°C for 20wt.%CaO-40wt.%SiO2-40wt.%FeO slag, and 1.3*10-10 m2/s at 1250°C for 20wt.%CaO-40wt.%SiO2-40wt.%FeO slag.It was also verified that, if the basicity and ferrite content of the bulk slag are low, then a calcium silicate film forms on the lime surface, and drastically deters the lime dissolution."

Jan 1, 2004

By Larry R. Fletcher

A misfire results when explosives fail to detonate as planned during a mine blast. Accidental detonation of misfires is a frequent cause of personal injury, equipment damage, and lost production. In an effort to minimize these problems, the Bureau of Mines investigated the causes of misfires, methods for detecting misfires, and procedures for their disposal. During this investigation, input was obtained from explosives suppliers, mining companies, blasting contractors, blasting consultants, and governmental agencies. Additional data were obtained through detailed analysis of blasting accidents involving misfires.

Jan 1, 1983

By E. E. McGinley, L. D. Woodworth

DURING the past several years has occurred what, in the light of future events, may aptly be called the rebirth of the acid Bessemer process. The increased attention given to the technical and metallurgical details involved in the production of Bessemer steels has been exceedingly fruitful, and indicates the value of further research and plant development. In times like these, when the steelmaking capacity of the country is operating at a maximum rate to supply materials for the national defense program, it behooves the Bessemer operator not only to strive to increase production but also to maintain a high standard of quality. The opportunity is ripe, it seems, to recapture fields of application once considered the birthright of Bessemer steels, but supplanted in recent years by open-hearth grades. This involves cooperation all along the line, from the blast-furnace operator to the metallurgical contact man and salesman. The metallurgist&apos;s part in this program involves the study of the many steelmaking variables and the measures necessary to ensure constancy in the finished product. It is equally important that the knowledge gained be disseminated widely to ensure the wise application of Bessemer steels in new fields. The merits of Bessemer steels for certain work are well understood. The combined properties of good weldability, machinability and stiffness are unique and fully explain the strong entrenchment of Bessemer steels in certain fields; e.g., skelp for small butt-weld conduit, screw steels machined in automatics, and certain tinplate applications. It is the purpose of this paper to review briefly the physical properties of Bessemer steels as contrasted with those of open-hearth steels, to discuss control measures now employed in the making of Bessemer steel, and to consider the advantages derived from the use of these control measures. PHYSICAL PROPERTIES OF BESSEMER VS. OPEN-HEARTH STEELS A number of Bessemer blows and open-hearth heats were tested for tensile strength, ductility and impact strength. The steels selected were confined to sections from ¾ to 1 ¼ -in. diameter, inclusive, and the carbon content covered was sufficient to yield parallel ranges in ultimate strength for the comparison. Other factors, such as the extent of deoxidation of the steel and variations in chemistry, were kept as comparable as possible. Machined test pieces of 0.505-in. diameter with an 8-in. gauge length were pulled. The data obtained are shown in Fig. 1, ultimate strength being plotted against carbon content. This graph shows that for equivalent carbon content Bessemer steel has on the average 15,000 lb. per sq. in. greater tensile strength and, conversely, for the same tensile strength Bessemer steel requires on the average 0.14 per cent less carbon. The average phosphorus content for the Bessemer steel was 0.090 per cent,

Jan 1, 1941

By L. E. Djingheuzian

IN 1953, Lewis (1) published an article which brought forth a great amount of discussion by grinding engineers. In his contribution to discussion the present writer (2) suggested that, for the most efficient performance of a ball mill, there must be a .definite relationship between Cn, per cent critical speed, and V p, per cent mill volume occupied by the ball charge. Later, he ( 3) was able to publish some grinding data from Wright-Hargreaves milly which appeared to bear out this contention. It is with this view to establishing a fundamental relationship between Cn and Vp that the idea of this Forum was conceived. Accordingly, a questionnaire was prepared and copies of it were mailed to over eighty Canadian mill operators. This questionnaire did not include a question on dilution on the assumption that each mill operator was using the most efficient dilution for his operation, nor was a question on efficiency of classification included since it was thought that the inclusion of efficiency of dassification in the questionnaire at this preliminary stage might render the forum discussion,. while everybody was trying to find his bearings, too unwieldy. However, it is evident that, as discussions develop, this forum will have to define a uniform method for establishing most efficient classification in grinding circuits

Jan 1, 1957

By D. C. McLean

Early studies in the carbonate leaching of uranium ores led to the investigation of pressure leaching as a method to enhance the dissolution of the metal values in this system. The initial investigations conducted at the University of British Columbia supplemented by the work done by the group at the A.E.C. Grand Junction pilot plant, all established the higher efficiency and better economics of the alkaline pressure leaching system. This work was conducted either in laboratory autoclaves using oxygen overpressures, or in pilot plant sized horizontal autoclaves with air as an oxidant. Both of these testing vehicles utilized agitation provided by relatively high speed impellers (300 to 700 rpm), which apparently enhanced the oxidation of the uranium to the hexavalent state. The installation of vertical autoclaves on a production scale, which through design considerations require relatively slow agitator speeds (68 rpm), led to the studies of the utilization efficiency of the air addition and the use of catalytic type oxidants to effect a greater usage of the oxygen added through the aeration system. In addition to investigating the effects of the chemical additives, studies were also conducted on the effect of different impeller configurations on the extraction of uranium, which in itself is a measure of oxidation efficiency. The material presented in this paper was compiled in the Ambrosia Lake district of New Mexico, and the majority of the data was obtained in the Homestake- Sapin Partners mill, located at Grants, New Mexico.

Jan 1, 1960

By B. P. Faulkner

In 1974, Allis-Chalmers, in corporation with several iron ore operating companies, began to evaluate direct firing of coal in the GRATE-KILN System. Several coals were ground at the Allis-Chalmers Process Research and Test Center and shipped to Cleveland Cliff&apos;s pilot plant near Negaunee, Michigan, where they were used as fuel to pelletize Empire magnetite concentrates in the CCI pilot-scale grate kiln. Pilot plant tests were sufficiently favorable to warrant testing in a commercial-scale pelletizing plant. These tests were conducted at the Empire Mine in the late summer and fall of 1974 and again in the summer and early fall of 1975. In the fall of 1975, Allis-Chalmers Mining Systems Division started a program, in the Advanced Technology Center, designed to develop a laboratory test procedure for the evaluation and study of various parameters associated with the direct firing of coals in a GRATE-KILN System. The initial results of this program were presented at the 50th Annual Meeting Minnesota Section, AIME, January, 1977. This paper will briefly review the initial laboratory work and discuss the latest results obtained.

Jan 1, 1977