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By Mark Van Dyke, Mark Mazzella, Gamal Rashed, Nicole Evanek, Brent Slaker

In the past decade, there have been several incidents of massive ground collapses in underground stone mines in the eastern United States. Fortunately, these events have not resulted in any fatalities. However, three mine workers were injured and many others were at risk due to the hazard from the fall of ground and/or the airblast associated with these massive collapses. The National Institute for Occupational Safety and Health (NIOSH) initiated a project to better understand the causes of these massive ground collapses to help prevent their future occurrence. The main objective of this study is to investigate the main factor(s)that initiated one of these massive ground collapses. The authors relied on several tools including three-dimensional (3-D) LiDAR scans for the surface subsidence feature and the underground mine workings around the collapsed area, borescope data at multiple locations around the collapse, S-Pillar analysis for average and unfavorable conditions, and numerical models. The emphasis has been placed on the impact of the following limestone pillar stability parameters: pillar width-to-height (W/H) ratio, benching, the existence of karst features, weak roof, and geological discontinuities. 3-D LiDAR scans were utilized to show the shape and the extent of karst cavities observed within stable pillars around the perimeter of the collapsed area. Together, this coupling of field measurements and observations and modeled systems suggests the potential causes of the collapse.

Jul 1, 2023

By Fulian He, Jianhang Chen, Shoubao Zhang

"Fully grouted rock bolts have been used in mining industry for many years. Significant research has been conducted to evaluate the load transfer behavior of fully grouted rock bolts with experimental programs. However, compared with that, less work has been conducted with analytical modelling. Therefore, in this paper, the authors used an analytical model to study the load transfer behavior of fully grouted rock bolts. To confirm the credibility of this analytical model, an in-situ pull-out test was used to validate this model. There was a close match between the experimental result and the analytical result. Following this, a parametric study was conducted with this analytical model. The influence of coefficients, Young’s modulus of the rock bolt and the diameter of the rock bolt on the load transfer performance of rock bolts were studied. Furthermore, the load distribution along the fully grouted rock bolt was analytically studied. The results show that the axial load in the rock bolt decayed from the loaded end to the free end independent of the pull-out load. However, the trend of the load distribution curve was influenced by the pull-out load. This paper was beneficial to better understand the load transfer mechanism of fully grouted rock bolts.INTRODUCTIONRock bolts have been used in the mining industry for a long time. They are used as the reinforcement tendons to keep the stability of openings in underground mining and the slope in open-pit mining. Furthermore, rock bolts are commonly used not only in the mining engineering, but also in civil engineering (Thompson, Villaescusa, and Windsor, 2012).The rock bolt is a tendon which can be a rod or a cable inserted into a borehole drilled in rock masses or soils. Traditionally, the material of rock bolts was steel. However, engineering practices showed that the steel rock bolts can be easily corroded by the moist environment in underground mines. Next, Fiber Reinforced Polymer (FRP) was used to manufacture rock bolts, which are termed as FRP rock bolts. Experimental results proved that the FRP rock bolts can effectively reinforce the surrounding rock masses without being corroded (Wang et al., 2018)."

Jan 1, 2019

By H. Ries

INTRODUCTION OF the several interesting physical properties of clay which have claimed the attention of investigators in recent years, none is more important than the behavior of the material when heated to temperatures above those of dehydration. Some of the problems to be solved are: 1. The mineralogical changes that take place in firing. 2. The relation between temperature and change in constitution, shrinkage, porosity, etc. 3. The importance of the time factor, as duration of firing, either in reaching a given temperature, or of exposure to a constant temperature. Mineralogical Changes As a result of fusion, reactions take place between the constituents of a clay, which results in a reorganization of the mass, and the formation of new compounds. Of the new minerals developed, sillimanite is the one usually recorded, and has been referred to by a number of observers.1 There appears to he a difference of opinion, however, regarding the temperature at which it is formed. Thus. Klein2 notes that sillimanite forms only above. 1300° C., while Mellor claims that it can develop below 1200° C., the difference in results being conditioned by the time factor. In Klein's experiments the test pieces were fired in 12 hr., while in Mellor's, the temperature rose from 800° to 1180° in 24 hrs., and occupied the same time in cooling back to 800°.

Jan 9, 1917

By C. M. Tucker, Kent R. Van Horn, W. P. Sykes

RECENT investigations of the molybdenum-carbon alloys have been reported by Becker and Ebert1‡, Westgren and Phragmén2, T. Takei3, and H. Tutiya4. Takei3 studied the Mo-C system by employing metallographic and X-ray methods, and the other publications described the determination of the crystal structure of the molybdenum carbides. In exploring this system by a technique previously applied to the tungsten-carbon series5, the results of Takei were confirmed with two definite exceptions; i.e., first the composition of the eutectic, and second the nature of the carbon-fish intermediate phase. Consequently, a more thorough examination of the molybdenum-carbon constitution was initiated in an effort to correlate the data supplied by the microstructures, diffraction patterns and chemical analyses. METALLOGRAPHIC INVESTIGATION A briquette of molybdenum powder when heated in a carburizing atmosphere at 1500° to 1600° C. for several hours develops the carbon-rich layer shown in Fig. 1. The carburization was accomplished by placing the briquette in a carbon tube, which was heated in the hydrogen atmosphere of an alundum muffle wound with tungsten resistor. While the macrostructure indicates two distinct shells, and suggests the possibility of two carbon-rich phases, no evidence of this condition could be detected by the microscope, which revealed but one high-carbon constituent. This carbide forms next to the molybdenum as a relatively

Jan 1, 1935

By Sidney A. Swensrud

MUCH discussion has occurred as to the use or uses which might be made after the war of either or both .of the large diameter (24 inch and 20 inch) War Emergency pipe lines built by y the United States Government during the war, to move crude petroleum and refined products such as gasoline and light distillate fuels. Indeed, the disposition and future use of these lines constitutes, in the minds of many people, one of the most important problems of postwar readjustment in the Oil Industry. The two lines, running from points in Texas to the New York-New Jersey-Philadelphia area, were constructed only because of the inability during the war to continue normal ocean tanker movements from the Gulf Coast to the East Coast. Physically they could continue after the war to move crude or refined products, and it appears that lines of such large diameter as these, if operated at or near capacity, could move these liquids at costs per barrel which might be considered in the same general cost range as for tanker movements.1 If, therefore, we were to look forward at the end of the war to a shortage of tankers, it is probable that the continued use of these pipe lines for petroleum movements to the East Coast would be worth considering, as against building new tankers to take over the movement, provided there were no other economic or national defense reasons for restoring tanker fleets and no other better use for the pipe lines. Because of the extensive tanker construction program which has been and still is in progress, and because of our Navy's marked success in combating the submarine problem, it appears to be quite possible, however, that instead of a shortage of tankers at the end of the war, we may have a surplus instead. If this should turn out to be the case, then there would seem to be considerable doubt that these lines would continue to be used for moving petroleum or products to the East Coast at the expense of tying up tankers. It would hardly seem probable that the owner of any such tankers would ship via one of the large lines at the expense of tying up one of its own tankers, unless the pipe line tariff rate charged was lower than the out-of-pocket cost of operating a tanker as against the out-of-pocket cost of keeping it tied up. And considering that a substantial part of the cost of operating a tanker goes on even when it is tied up, it is very difficult to figure out how any pipeline tariff could be established that would be low enough to compete with individually owned tankers that otherwise would be idle. Certainly a pipe line tariff rate high enough to cover direct costs plus even a low rate of depreciation and return on the investment would be far above the out-of-pocket tanker operating costs. In view of these considerations, it has seemed desirable to examine with some care some of the various alternatives that have been suggested as to other possible uses to which these lines might be put. One of these is for transportation of natural gas to the New York-New Jersey Philadelphia area. This Eastern area, located at the destination of these lines, contains the heaviest concentration of population in the United States, and is not now served with natural gas. At the other end of the lines lie the greatest discovered natural gas reserves in the United States, if not in the world, and many

Jan 1, 1944

By Wright S, Jorgensen F. R A

The reaction between lead sulphate and a number of base metal sulphides (galena, sphal- erite, chalcopyrite and synthetic pyrrhotite was studied as a means of desulphurizing lead sulphate containing fumes and residues to levels acceptable as ISF feed. The reactants were mixed with 50% zinc oxide to act as a "basket" to contain the molten products of the reaction and pressed into small briquettes 20 mm in diam. Factors such as temperature, time and the composition of the atmosphere were investigated. Using the PbS/PbS04 system as an example it was shown that the reaction became rapid above 800¦C and that both sulphur dioxide and oxygen in the atmosphere were detrimental to achieving low sulphur in the product. In an inert atmosphere all the sulphides when roasted for 1 h at 1000¦C gave results corresponding to the elimination of more than 95% of the sulphur in the reactants. Leach plant residues were considered for use as the "basket" material. It was shown that the residual sulphide and sulphate components of the residues underwent similar reactions to those experienced by the pure systems.

Jan 1, 1987

By T. H. Etsell, P. Kerr, Qi Liu

"The objective of this investigation was to study the reaction mechanisms during the reduction of iron oxides in the presence of calcium chloride and carbon black as a simplified iron segregation process. The gas phase was analyzed by mass spectroscopy and the solid reaction products were analyzed by scanning electron microscopy. Mass spectroscopy, combined with thermogravimetric analysis and differential scanning calorimetry, revealed the presence of several gases at elevated temperatures over time, and the scanning electron microscope in combination with energy dispersive X-ray analysis illustrated the growth of a metallic iron phase on or near the carbon substrate. The results correlated well with similar copper and nickel segregation processes, but also introduced new insights that challenge the simplicity of the current models. The formation and transport of gaseous iron species to the carbon substrate in the presence of steam and hydrogen were evident during the reduction process that was studied; however, there is more happening at a mineralogical level, based on evidence of a liquid phase resulting in substantial growth due to an apparent fluxing effect created by the calcium chloride.These results help to better explain the chemical reactions and, in turn, the thermodynamics and kinetics of iron segregation processes related to the beneficiation of low grade complex iron ores. The results are also applicable to the production of metallic iron and concentrated titanium dioxide from ilmenite ores. The benefit of this process is that it allows ores in which the iron minerals are intimately associated with gangue minerals to be processed in circumstances where conventional mineral processing techniques are unsuitable or incapable of upgrading the material."

Jan 1, 2016

By T. M. Korzekwa, R. L. Cavanagh

Following considerable experience with the beneficiation of Wabana iron ore by standard methods, a study was made of the benefits to be obtained by semi-reduction. The basis of the laboratory program was an extensive mineralogical and liberation investigation which guided subsequent work. Partial reduction and beneficiation on a laboratory scale was carried out on lump ore and fines. The reduced ore was magnetically concentrated and the concentrated fines were briquetted. Data are presented on reducibility, sizing vs reduction rate, magnetic cobbing and separation, and the elimination of phosphorus. Past work is reviewed briefly and comments are made on the relation of laboratory to pilot-scale tests.

Jan 1, 1967

By J. Spotts McDowell

J. W. RICHARDS, So. Bethlehem, Pa.-The paper is certainly an exceedingly, valuable one and it gives detailed information which should be utilized in the following way. There are probably twenty different circumstances or conditions under which silica bricks are used. Sometimes they are used under high pressure, at others under low pressure, at times for low temperatures and others for very high temperatures. If the methods of this paper are followed out, and if the precise mechanical and thermal properties are determined and can be reproduced, the industry can furnish the proper brick for any particular purpose. There is at present only an imperfect classification made as to properties and uses, but we need a "much more scientific classification of the uses to which the bricks are to be put and then should manufacture the bricks suited particularly for each of those purposes. There is one property which is not mentioned in the paper and which is of considerable importance, that is, the 'electrical conductivity. There may be other properties besides, which a good research laboratory can determine, and when we have listed all the various properties and noted the way in which they can be reproduced, the maker can then specify his exact requirements and the corresponding quality of brick can he selected or made to meet them. H. D. HIBBARD, Plainfield, N. J.-About a year ago I had some experience in another country, in melting steel, where silica bricks made in that country failed, but in a different way from those in America. Here, when the bricks get too hot, they are partly melted and string down

Jan 4, 1917

By Walter Weeks

LITTLE study has been made of the pressure changes and energy losses that take place when an air current is divided into splits which subse-quently unite. The discussion and the experiments that are described in this paper deal with the division of an air current into square splits of equal size, the area of each of the splits at the downstream junction being one-half the area of the main duct. APPARATUS AND SYMBOLS The duct system shown in Fig. 1 was built of Y4-in. redwood and made as smooth as possible.The section of the top over the splits and the zone of mixing was of plate glass to permit observation of the stream lines. FIG. 1-DUCT SYSTEM. Static pressures were measured by means of pinhole tubes and a precise inclined manometer. Measurements of rates of flow were .made by determining the drop in pressure through concentric square orifices in the splits. The air was supplied by a fan operated by a direct-current motor that received its current from a motor generator set. Delicate rheostats in the armature. of the motor. made possible the perfect control of the fan speed, which was indicated on an electrical tachometer. Vanes to straighten the. flow were placed at the head of the main duct.

Jan 1, 1933

By L. Petitnicolas

The experimental study of nitrogen absorption and its removal from a liquid Ni-20%Cr alloy at 1873 K has been undertaken, using an experimental, apparatus based on the Sieverts technique in order to determine the solubility of nitrogen in the alloy. as well as the kinetics of nitrogen transfer across the gas/melt interface. Experiments show that nitrogen solute equilibrium content can be calculated using the Sievens law. Measurements point out the nitrogen absorption reaction rate to be well described by first order kinetics, whereas experiments on nitrogen removal reveal that the rate is better expressed using a second order equation.

Jan 1, 1996

By O. Neves, C. G. González Beca, M. C. Sol Pereira, H. Sousa Vale, R. A. Guedes de Carvalho, M. N. Sampaio

"As sulphide ores are usually concentrated by flotation , the material is very finely ground <37um), wet and impregnated with the chemicals used in flotation. These conditions are favourable to the development ofchemical reactions which are largely influenced by atmospheric conditions (temperature, humidity, wind, etc.) as well as by the geometry of the piles.Physical and chemical properties of a chalcopyrite concentrate were determined by laboratory tests. The knowledge of these properties was considered necessary in order to establish a correct design of the storage and handling operations of the sulphide ore concentrates obtained by flotation.The properties studied in this work were: transportable moisture limit, flowability, effects of vibration, hygroscopicity, ""caking"", chemical alterations by humidity, oxidation and self-heating (auto-ignition, dry and wet oxidation, self-heating by humidification and its prevention).INTRODUCTIONIn order that the handling and the transport of a powdered material may be carried out correctly, it is necessary to know certain physico-chemical characteristics. Transportable moisture limit (TML), apparent density (both aerated and compacted), compressibility, angle of repose, angle of spatula, cohesion and angle of slide(l-4) are characteristics (among the flowability parameters) worth knowing.Moisture content of the powdered material is fundamental, because if this is too low heavy losses will occur when the product&apos;s particle size is very small, if it is too high, separations between solid and liquid phases may occur. In the latter case, the centre of gravity of the system may change suddenly and cause accidents, mainly if transport is by sea or by river."

Jan 1, 1989

By J. R. Schafler, J. L. Brinkman

"The US coal mining industry has suffered a recent decline in profits caused by a combination of decline in commodity demand and more restrictive government regulation, forcing coal mining companies to cease production in numerous mines. A 40% decrease in the total number of coal mines occurred from 1994 to 2000. The number of mines remained relatively constant until 2008 when a change of government sparked a series of new environmental regulations which have contributed to another 15% decrease from 2008 to 2016. In contrast, production has only decreased by 3%, increasing from 1994 to 2008, and then decreasing since 2008. However, this value is skewed by large increases in sub-bituminous coal production and decreases in other coal ranks. Several aspects assist in executive decisions on mine longevity and economic worth. Studies of open source mine data collected by mandated government surveys coupled with commodity history can be used to find relationships between mine closures and these elements, which include statistics on production tonnage, seam height, coal rank, etc. This paper looks at coal mining trends since 1994 by comparing mine, market, and regulation factors that may influence mine closure. INTRODUCTION The US coal mining industry is currently experiencing a decline in both demand and commodity price while facing implementation of more stringent air and water pollution regulations. Company profits have decreased significantly, forcing several major companies to declare bankruptcy. The industry was required to adapt to survive. Many of these companies have adjusted by abandoning mines; the last two decades have seen a drastic decrease in the number of mines. To discover the primary causes of this downturn, three major aspects must be studied: properties of abandoned mines, commodity history, and regulatory impact. TRENDS SINCE 1994 Each year, US coal mines are required to submit data on a wide variety of categories to the Mine Safety and Health Administration (MSHA) and the US Energy Information Administration (EIA). This data includes administrative records, production values, and information regarding the attributes of the mined material and the mine itself. Each year since 1996, EIA has released a report summarizing the data from two years prior. Additionally, MSHA maintains a database containing a collection of all the most current data. These resources are the primary sources for the following figures."

Jan 1, 2017

By D. F. Malan, T. E. Oates

A recent experimental pillar extraction project at a UG2 bord-and-pillar mine presented a unique opportunity to compile a new pillar database. Currently, the South African hard rock bordand- pillar mines are designed using the Hedley and Grant formula with a modified K-value. This empirically derived formula was developed for uranium mines in the Elliot Lake district of Canada. The use of this formula for the design of pillars in South Africa is questionable. Very few pillar failures have nevertheless been observed and its current calibrations for the various reef types are possibly too conservative. A new UG2 pillar database of 66 pillars, of which seven are classified as failed, was compiled by the authors. This enabled a revised ‘first-order’ calibration of the K-value for the Hedley and Grant formula. The new estimated value for the UG2 is K = 75 MPa. This gives a pillar strength that is more conservative than the PlatMine formula. This work should nevertheless be considered as only a preliminary calibration as the database was small. Further work is also required to determine whether the exponents in the formula for the width and height parameters are appropriate for UG2 pillars.

May 3, 2023

By Jay R. Schafler, Jacob L. Brinkman, Catherine E. Johnson

"The United States coal mining industry is currently experiencing a decline in both demand and commodity price while facing implementation of more stringent air and water pollution regulations. Company profits have decreased significantly, forcing several major companies to declare bankruptcy. The industry was required to adapt to survive. Many of these companies have adjusted by abandoning mines; the last two decades have seen a drastic decrease in the number of mines. To discover the primary causes of this downturn, three major aspects must be studied: properties of abandoned mines, commodity history and regulatory impact. Trends since 1994Each year, U.S. coal mines are required to submit data on a variety of categories to the U.S. Mine Safety and Health Administration (MSHA) and the U.S. Energy Information Administration (EIA). This data include administrative records, production values and information regarding the attributes of the mined material and the mine itself. Each year since 1996, EIA has released a report summarizing the data from two years prior. Additionally, MSHA maintains a database containing a collection of all the most current data. These resources are the primary sources for the figures included in this article. There are several items to note regarding this data:1. The EIA reports from 2016 and 2017 were not released at the time of writing this report.2. The MSHA data set is actively maintained as information is provided. This means the data for 2016 is from June 27, 2016 and data for 2017 is from Aug 24, 2017. All other points represent the end of-year values.3. Each of the figures only includes data pertaining to active mines. EIA defines active mines as both active and temporarily idled mines, and inactive mines as nonproducing and abandoned mines. MSHA separates all four into separate categories, though this paper combines the MSHA values according to the EIA definition for the purpose of comparison."

Jan 10, 2017

By Carlos Torres, Albert Cabrejo

For the last 20 years mine slopes have been monitored with slope stability radars. Since 2015 a group of dedicated geotechnical engineers dedicated to remotely monitor radars around the world have detected 2000+ slope failures of different characteristics. A statistical analysis of the information gathered of these failures have been made and the summarized results are presented with some degree of analysis appropriate for the vastness of the database. The analysis considers different types of commodities, countries, mining processes, rock types, and weather conditions.

Sep 29, 2023

By Chengcan Wang, Jin-Tae Han, Young-Eun Jang

"The waveform micropile is a newly developed foundation type for increasing the bearing capacity with the created shear keys on the pile’s shaft. Analyzing the increment of resistance at the shear key zone is a crucial factor in the design of the waveform micropile. Hence, centrifuge tests were carried out employing six different models, including a waveform micropile in the axial loading condition. The analysis results of the load-settlement curves showed that the waveform micropile achieved a higher bearing capacity compared to the micropile without shear keys. In addition, the test results revealed that the load-settlement relationship was affected not only by the pile shape but also by the locations of the shear keysINTRODUCTIONA micropile is a small-diameter pile, typically constructed with a less than 300 mm diameter. Generally, the micropile’s construction involves drilling, grouting, and insertion of a reinforcement material, such as a thread bar. The micopile can be utilized in a variety of fields for reinforcing the foundations of existing structures. It also has advantages for accessing challenging areas like limited-access construction sites, including those with a low headroom space and adjacent structures, due to the small size of the construction equipment. Thus, since it was introduced in 1950 in Italy, the micropile has become one of the preferred solutions when other deep-foundation methods are not applicable to the site.Federal Highway Administration (FHWA) gives the micropile design implementation guideline of neglecting the end bearing due to its small diameter but considering the frictional resistance if the bond zone of the pile is in the soil or on a weak rock. The bearing capacity is considered primarily only if the micropile is founded on a high-quality sound rock (FHWA, 2005). Micropile design in South Korea is currently being performed based on the FHWA manual and taking into consideration the frictional resistance for the design as the pile generally sockets into a weak rock or soft rock. Moreover, the frictional resistance within the soil layer has usually been ignored, considering only the shaft resistance of the rocksocketed length in the conservative design. The design concept excluding the frictional resistance in the soil layer, however, may lead to an extension of the pile socket length, which will increase the construction cost. Hence, many researches have attempted to provide better design and construction methods to increase the bearing capacity in a cost-effective way (Juran et al. 2001; Sadek and Isam 2004; Tsukada et al. 2006; Finno 2002; Gomez et al. 2003; Seo et al. 2013)."

Jan 1, 2016

There are some problems in the beneficiation of fine-grained oxidized iron mineral such as high cost, severe sliming, poor results and low recovery due to the fine disseminated size of the mineral. Taking several representative types of finely-disseminated oxidized iron minerals as examples, the author analyzed the main difficulties in the beneficiation of such kind of ores and discussed the existing problems in grinding-classification, technological process, flotation reagents and separation equipments and the resolvents of these problems.

Jan 1, 2014

By Shilpa S. Haramkar, Bhaskar N. Thorat, Sachin V. Jadhav

The filtration of phosphogypsum is a ubiquitous step in the manufacturing of phosphoric acid. It is highly desired to achieve the minimum concentration of P2O5 in the phosphogypsum cake. This work is aimed at addressing P2O5 losses in phosphogypsum (PG) along with the recovery of P2O5 from slurry by using constant pressure filtration at 1 bar pressure. Laboratory tests were carried out in the phosphoric acid production plant situated in Paradeep, India. Recycled water source near acid plant (i.e., pond water) was used for cake washing to reduce the burden on fresh water stock. The findings indicated that pressure filtration offered the most effective P2O5 recovery (nearly 93.48%). The moisture was reduced to 14–16%, and watersoluble P2O5 in the gypsum cake was found to be negligible. A narrow particle size distribution was observed, which offered effective filterability with average cake resistance of 2.38 × 1010 m/kg, indicating a moderately separable cake.

Aug 23, 2023

By W. Griffith

"While oxalic acid precipitation practices are commonly applied on purified rare earth elements (REEs) pregnant leaching solutions (PLS), few efforts have been reported using oxalic acid (OXA) to recover REEs directly from untreated PLS. High oxalic acid demand is the most significant issue in all these direct oxalic precipitation (DOP) practices. Preliminary research on DOP of REE from a dilute PLS originating from an acid bake followed by water leaching was conducted. At 75°C, the oxalic acid demand was between 12 and 18 times the stoichiometric requirement for complete REE precipitation. Conducting DOP at 25°C had superior REE recovery but the product purity and filterability declined. Between 75°C and 100°C, REE recovery increased with increasing temperature. When sodium hydroxide was used to adjust the pH during DOP, in the range of 0.5 to 1.5, higher pH benefited REE recovery. Using ammonium hydroxide in place of sodium hydroxide, the REE recovery was reduced by close to 5%. Sodium chloride addition to the PLS was also investigated and the results showed that at both 75°C and 25°C, the REE recovery was enhanced substantially. At 25°C, when the oxalic acid addition was controlled at 4.7 times the stoichiometric requirement, the overall REE recovery reached 95% with the addition of 240 g/L NaCl. Other reagents such as KCl, NH4Cl also showed significant enhanced REE recovery at the same oxalic acid addition. The addition of sodium sulphate appeared to largely enhance the precipitation of LREE but inhibited the formation of HREE oxalate. All results indicate the formation of rare earth double salts may play an important role in REE DOP sulphate media.INTRODUCTIONThe conventional routes for recovering rare earth elements (REEs) from a sulphuric acid pregnant leaching solution (PLS) involves an initial purification step for removal of iron, aluminium for example by precipitation through neutralization, followed by precipitation of REEs as hydroxide, oxalate or carbonate salts, or by bulk solvent extraction for REE recovery (Xia, 2013). Another route was used by Bayan Obo in their historical flowsheet, where the PLS was first subjected to double sulphate precipitation, then the remaining REEs, mostly heavy rare earth elements (HREE), were recovered by oxalate precipitation (Li, 2011)."

Jan 1, 2016