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By R. M. Smailer

Detailed description of the development of the FIOR process1 and, subsequently, other technical papers relating to the operation and start up of the FIOR plant2,3 are available in the technical literature. The Fluidized Iron Ore Reduction (FIOR) process plant constructed in the Matanzas region of Venezuela represents the first commercial application of this technology. The FIOR process was developed by Exxon Company during the 1950's and 1960's; and the facility in Venezuela was designed and constructed by Davy McKee with the plant start up in 1976. While there is a minority government ownership in the company, FIOR de Venezuela operates as a private sector company with the majority of the ownership being private capital.

Jan 1, 1981

By Albert F. Duzy

Recently there have been some problems associated with hot coal in shipments from the USA to overseas markets. This paper will serve several functions. First, a brief review is presented, together with a selective bibliography. Second, a thorough discussion of coal oxidation is covered. Third, potential effects of storage are presented and, lastly, methods are suggested for the safe storage and bulk transfer of coal. The scope includes coal storage for power plants.

Jan 1, 1983

By D. Zhao

High temperature deformation characteristics of austenitic 304L, and martensitic 410 and 416 stainless steels were investigated by conducting compression tests over a wide range of temperatures and strain rates (950-1250 C and 0.001-20 s-1). Flow behaviors of the three alloys were characterized. Optical metallography was performed to determine the as-deformed microstructures. The flow behaviors were related to microstructural phenomena during high temperature deformation. Dynamic recrystallization was responsible for the flow softening. Both dynamic and static recrystallization were operating, and the recrystallized grain size increased with increasing temperature and decreasing strain rate. Strain rate sensitivity was found to increased with increasing temperature and decreasing strain rate. No defects such as cracking and shear bands were observed at those test conditions. Preferred processing conditions can be selected by considering as-deformed microstructure and strain rate sensitivity.

Jan 1, 1994

By Sijun Li, Bingyu Zhang, Haitao Zhou, Zhendong Zhang, Guofei Si, Xianghua Liu

"Hot compression test of Nb microalloyed coiled tubing steel is performed on Gleeble3500 at 1123K—1373K and strain rate from 0.001 to 5s-1. It is found that flow softening occurs and the flow curves exhibit a peak with a characteristic of dynamic recrystallization (DRX) and change with temperature and strain rate significantly. The peak stress and peak strain are dependent on the Zener-Hollomon relationship with activation energy of 390 KJ/mol. On the basis of Avrami equation and the Zener-Hollomon parameter, it is obtained that the dynamic recrystallization kinetics equation with which the calculated and measured recrystallization fraction is very close. On the results of hot compression test, the Nb microalloyed coiled tubing steel is rolled by Thermo-Mechanical-Control-Processing (TMCP), and it is obtained that the yield strength and tensile strength of Nb microalloyed coiled tubing steel are 565MPa and 685MPa respectively, and the elongation percentage is 30.1%.IntroductionCoiled tubing is widely used in oil field for well logging, well completion, drilling, work over and other operation in various fields to solve a number of conventional operating techniques problem which are difficult resolved, and it plays a more and more important part in exploration and production at oil field. [1] It will improve the efficiency of exploration and exploitation, studying, developing and using coiled tubing technology. Therefore, the development of domestic coiled tubing materials and manufacturing technology are great significance. It is well known that Coiled tubing has relatively poor working conditions and complex force state. So, the coiled tubing needs satisfier a kind of high strength, high plasticity, and corrosion resistant under complex oil gas condition. As the coiled tubing technology developed, the level of the coiled tubing steel is from CT55 originally to CT90 and CT100, and the corresponding tensile strength is 483MPa-758MPa. [2, 3]"

Jan 1, 2012

By Axel Hultgren, B. Herrlander

THE original aim of the present investigation was to study the mechanism of cracking on hot-deforming red-short steels. During the microscopical examination of hot-deformed soft steels attention was directed to various patterns of so-called veining in the ferrite, as related to variations in the deformation procedure and the heat-treatment of the steels. Later, a hot-short steel of higher carbon content was also studied. Historical Storey1 suggested in 1914 that veining developed during the gamma-alpha transformation from the growing together of several alpha nuclei within the same gamma grain. Rawdon and Berglund2 found that in soft steel, forged somewhat below A3, the ferrite showed profuse veining, while usually there was very little veining after forging at very high temperatures. They emphasized the similarity between the pattern of veining formed by deformation about 600°C and that of slip lines formed by deformation at room temperature. They also suggested a relation between the gamma-alpha transformation and veining. They became convinced from etching and from the slip-line pattern in cold-deformed material, that the orientation within any ferrite grain showing veining was uniform. In recrystallized alpha grains veining was absent. Veining did not appear materially to affect the properties of ferrite. Independent of veining, continuous networks, attributed to preexisting delta and gamma grain boundaries were sometimes found, the former only in cast steel. Those networks were usually connected with small inclusions. Ammermann and Kornfeld3 confirmed that recrystallized ferrite grains showed no veining. In soft steel annealed between At and A3 there was veining only in the ferrite grains formed during cooling. Electrolytic iron deformed at 880° was free from veining. Bannister and Jones4 considered veining in ferrite to be a manifestation of microscopical and submicroscopical inclusions. Northcott,5,6 in studies on veining in steel and other metals and alloys, attributed veining to oxide inclusions. It could generally be removed by annealing in hydrogen, a suggestion earlier made by Rawdon and Berglund. Tritton (discussion in ref. 5) emphasized the importance of perfect polishing for bringing out veining by etching, and thought the veins or subboundaries were produced during the gamma-alpha transformation, when it was rapid, as a result of the volume change and contraction during cooling.

Jan 1, 1946

By Steven George Jansto

The hot ductility behavior of different microalloyed steel chemical compositions was examined simulating the thermal and strain conditions through the straightening or unbending section of the continuous casting machine. All samples were obtained from industrial slab casters ranging from 200 to 300 mm in slab thickness from steel mills throughout the world including China, Brazil, North America and Europe. The slabs were crack-free and hot rolled into prime quality products. No laboratory heats were tested. Although these microalloyed steels exhibit inherently lower hot ductility behavior, as measured by percent reduction in area at elevated temperature, these steels still exhibit sufficient ductility to satisfactorily meet the unbending stress and strain gradients existing in the straightening section of most casters. The majority of the published hot ductility data, as measured by % reduction in area (%RA), were based on laboratory heats and hence, are inaccurate in accessing the propensity for slab cracking on an industrial caster. This situation then results in invalid conclusions for different chemistries. This research has determined the minimum required %RA for crack-free casting is significantly lower than results based upon previously published laboratory generated data. For example, the literature quotes 40% RA minimum for Nb-bearing steels when in fact as low as 10% minimum RA is more than sufficient to assure crack-free casting based upon the extensive testing and analysis performed in this study. Instead of %RA, the measurement of strain energy has been introduced to evaluate hot ductility behavior. It is concluded that strain energy is a better measure of hot ductility behaviour than %RA. There is considerable value in the evaluation of the hot stress and strain curves, process metallurgy parameters and their relationship to slab quality instead of just basing hot ductility decisions on simple %RA measurements.

Aug 16, 2017

By Yanhui Sun, Yanan Zeng, Kaike Cai

"Hot ductility of Nb-V-containing steel has been studied by theoretical calculation and thermal simulation experiment. Meanwhile, microsegregation and precipitates were analyzed. The results showed that segregation degree of elements S, P, 0 is greater in mushy zone, while, the hot ductility was deteriorated by inclusions of Fe(S,O), (Fe,Mn,Si,Al)(S,O) in the interdendritic region. At the temperature 1100°C, a few NbN particles, 60-70nm, have little effect on mechanical property. In the temperature range 1000°C to 975°C, R.A declined rapidly from 82.36% to 69.61% with the diameters decreasing from 20 to 10nm and quantity of particles increased 23 to 45inds/µm2, respectively. In the temperature range from 900°C to 850°C, R.A reduced unobviously from 34.27 % to 30.01 % with ferric films thickening gradually. The critical stress, 52.38MPa, was equal to tensile strength at 975°C. Intergranular fracture was easy to occur with higher critical stress below 975° C.IntroductionProductivity and product quality of slab are seriously affected by cracks during continuous casting and the influencing factors of cracks are various[l]. From microcosmic angle, resisting deformation ability of initial solidification shell decreases obviously with solute elements segregation which can urge the low melting point ofliquid film to form at grain boundaries[2, 3]. Meanwhile, with temperature decreasing, particles would precipitate as the practical solubility product is greater than equilibrium solubility product. The carbonitrides would lead to stress concentration at austenite grain boundaries. Therefore, the transverse cracks of microalloyed steel would form during the straightening operation in the continuous casting process. The hot ductility of steels in the temperature of mushy zone was characterized by microalloy elements segregation, zero strength temperature (ZST) and zero ductility temperature (ZDT). The nature, shape, and size of precipitates have been investigated by TEM (JEM2100). Hot tensile test with low strain rate was simulated by Gleeble-1500. The objective of present study is to provide reference for zero defect of microalloyed steel during continuous casting process."

Jan 1, 2013

By Laurent Dorel, Sebastien Maillard, Afchine Nasserian, Jean-Paul Faure

Surface quality monitoring is primarily implemented in the last steps of steel manufacturing before shipment to the end user. However, an increasing trend for also addressing this topic in the upstream stages, such as hot rolling plant, is tackled by Primetals Technologies to give steel producers the key to a global optimized yield management, and efficient “lessons learned” processes. After the last developments of SIAS Next Gen platform, including High Resolution and Near Infra-Red, some site results will be exposed on the very specific high constraints lines such as ESP Endless Strip Production and Plate Mills, and highlights the related most interesting aspects for our customers.

Oct 1, 2019

By P. M. Tyroler, W. J. Thoburn, M. R. Alberty

"An initial test of this unique application demonstrated that hot gunned refractory would adhere satisfactorily. Subsequently, it was found that the proportion of material sticking during application increased with increased vessel temperature and when a mix containing pitch was used. About 75 per cent of the latter type adhered when it was applied at 1600°C.TBRC availability increased from an historical average of 62.5 per cent to 64.7 per cent during four campaigns when hot gunning was routinely practiced. Refractory cost was about 20 per cent less than that anticipated without gunning. Average parameters per campaign with gunning ranged as follows: 90 to 108 heats, 10 to 37 applications and 1.4 to 2. 7 hours per application. Prior to gunning, the average number of heats per campaign was 73.IntroductionThe Top Blown Rotary Converter process at Inco's Copper Cliff Nickel Refinery converts copper-nickel-sulphur concentrates to a material suitable for carbonyl refining (1),(2).Operating conditions are particularly hard on refractory. Batch cycles finish at temperatures up to 1650°C, with occasional excursions over 1700°C. New heats are then usually initiated immediately and the refractory is subjected to intense thermal shock from the cold feed. Temperature cycles are also introduced three to four times during a heat when the process is interrupted for scrap charging, temperature measurement or sampling.Abrasion wear results from rotation of the converters at speeds up to 15 RPM and from agitation of the bath with supersonic-velocity oxygen. Mechanical damage also occurs when chunks of scrap or solid matte are processed. Chemical corrosion is also present, as we know from our own laboratory work(2) and reports of operations elsewhere. As a consequence, refractory material and installation form a very large proportion of the converter plant costs. Equally important is the loss of converter availability during rebricking; this significantly reduces plant capacity."

Jan 1, 1981

By Pedro Augusto David Machado

The hot metal produced in small blast furnaces runs with a highly heterogeneous charcoal. The result is a significantly higher hot metal chemical composition variation, especially for the silicon content, which varies from 0.4 to 1.5% in Mini Blast Furnaces - MBFs, designed to feed an EAF and/or a BOF. These MBFs operate with frequent variation in their productivities to feed preferably only one of the steelmaking reactors, that is, EAF or BOF. The hot metal suitable amount, chemical composition and temperature, to be delivered at the steelmaking vessel, become the major concerns in the integrated operation MBF to EAF or BOF. In order to cope with those undesirable frequent variations, a solution has been proposed based on the existing technologies of oxygen jets and ladle refining techniques adapted to a hot metal ladle or to a Torpedo Car. The proposed technique is not only able to adjust hot metal temperature and chemical composition, but it also generates the adequate conditions for refinement from P and S, as well as “cleaning” hot metal ladles and Torpedo Cars by melting pig iron skulls. Therefore, this new technique development results in high hot metal yield, an adequate chemical composition and bigger campaign of hot metal ladle.

Aug 17, 2017

By G. S. Headley

At the Sullivan Mine, recent experience with sulphide fires, locally referred to as " hot muck", has necessitated extensive modifications to pillar mining design and operating procedures. Potentially hot pillars are now being designed and mined to prevent fires. Unusual safety hazards and difficulties are encountered in working with, and adjacent. to, existing pillar fires. Operating procedures developed for these conditions have proved successful for safe and continuing production. These changes have minimized the impact of hot ore on current operations and have promise for an improved future.

Jan 1, 1977

By Jin-Hwa Song

Rolling temperatures and cross rolling ratios were varied to investigate the effect of crystallographic texture of alpha-phase on the anisotropy of mechanical properties in modified Ti-6A1-4V alloy. Hot rolling method was unidirectional and cross rolling, during which the rolling temperature was in the range of 830°C and 920°C. Cross rolling ratios were varied from 0.3 to 1.0 at 875°C. For unidirectional rolling, as the rolling temperature increased texture changed from the mixed basal and transverse texture to the simple transverse texture. Contrary to other work, it was observed that the maximum intensity of transverse components increased with the increase in rolling temperature. For cross rolling, on the other hand, the transverse texture component was almost suppressed at 830°C, giving rise to a symmetrical basal texture. With increasing cross rolling temperature, the transverse texture components developed again. A simple transverse texture, which showed two maxima appearing circularly 90° apart, was observed at 920°C. It was found that unidirectional rolling could not eliminate the transverse texture, which resulted in the anisotropy of mechanical properties. The anisotropy of mechanical properties obtained from tensile and V-notch Charpy test was closely related to the crystallographic texture and its intensity at each rolling condition. To obtain the isotropy of mechanical properties by cross rolling, it is suggested that cross-rolling ratios should be controlled above 0.5. The variation of rolling temperatures and directions has great influence on the anisotropy of impact value rather than tensile strength.

Jan 1, 2004

By Marcelo Rebellato, Beatriz Pereda, Beatriz Lopez, Pello Uranga

The classical application of Nb microalloying in the development of thermomechanical processes for flat products has been related to its suitability to enhance strain-induced precipitation and get a pancaked austenite prior to transformation. As new steel grades or new lay-outs are being developed, more complex metallurgical conditions need to be evaluated. In this context, Nb microalloying, alone or combined with other microadditions, needs to intervene in a more controlled way in additional steps of the thermomechanical process, besides its conventional strain-induced precipitation role. For example, the hardenability enhancement associated with Nb to properly achieve lower temperature transformation products, demands a proper balance of the Nb amount precipitated during rolling and the one remaining in solid solution. Similar effects are also sought when the final available Nb is used to increase strength through precipitation hardening. This manuscript evaluates how changes in the rolling strategies affect the interaction between Nb(C,N) precipitation and austenite recrystallization at different steps of the rolling process. As the possible interactions between parameters intervening simultaneously are quite complex, the application of microstructural models helps to properly define the best austenite conditioning combined with the convenient amount of Nb in solution, as a function of the final property requirements. Along the manuscript, several strategies will be discussed for the case of hot rolling of flat products comparing both normal and coarse initial austenite grain sizes.

Oct 1, 2019

By Michael W. Roper

McDermitt Mine is located in northern Humboldt County, Nevada, approximately 5 miles south of the Orgeon-Nevada line (Figure I), within the Opalite Mining District. The operation is a joint venture between Placer Amex Inc., San Francisco, and Mineral Exploration Company Ltd., a limited partnership. The McDermitt orebody possesses a discontinuous, gently dipping blanket-like form within 150 feet of the surface over an area 2200 by 2500 feet. The ore zone averages 20 feet in thickness. The ore minerals consist of cinnabar (HgS) and corderoite (Hg3S2C12) deposited parallel to bedding within argillized, Miocene age, tuffaceous lacustrine sediments. Exploration indicates reserves of approximately 3,000,000 tons ore at a grade of 10 pounds mercury per ton (0.5%) An open pit mining operation utilizing scrapers and bulldozers supplies a concentrator with 700 tons of ore per day. The milling operation consists of autogenous grinding, flotation concentration, concentrate dewatering, and tailing disposal, with a design capacity of 100 tons per hour. The furnace section consists of a concentrate filter, vertical six hearth furnace, mercury condensing system, and exhaust gas scrubbing systems. It has a design capacity of 1000 pounds of dry concentrate per hour. The McDermitt orebody is situated about 2000 feet north of the Cordero Mine which, with adjacent properties, produced over 115,000 flasks (76 pounds per flask) mercury from 1941 to 1972' Two other major mercury producers in the district have been the Bretz and Opalite Mines, located in southern Malheur County, Oregon, within 5 miles of the Oregon-Nevada line. Bretz and Opalite have produced about 14,800 and 12,370 flasks mercury respectively, from 1926 to 1965.1/

Jan 1, 1976

By Liming Yuan, Wei Tang, RICHARD THOMAS, JOHN SOLES, DAVOOD BAHRAMI

The abstract discusses the issue of mine equipment fires caused by hot surface ignition of flammable liquids. The research investigates the ignition probability of liquid fuels (diesel, engine oil, hydraulic fluid) on different metal surfaces (stainless steel, cast iron, carbon steel) under various ventilation speeds. The results show that the type of metal and ventilation speed influence the ignition temperature, with diesel being the most easily ignited fuel and carbon steel requiring a higher ignition temperature. The study provides data for understanding equipment mine fires and developing mitigation strategies.

May 4, 2022

By L. Yuan, J. Soles, D. Bahrami, W. Tang, R. Thomas

Mine equipment fires remain as one of the most concerning safety issues in the mining industry, and most equipment fires were caused by hot surface ignitions. Detailed experimental investigations were conducted at the NIOSH Pittsburgh Mining Research Division on hot surface ignition of liquid fuels under ventilation in a mining environment. Three types of metal surface materials (stainless steel, cast iron, carbon steel), three types of liquids (diesel fuel, hydraulic fluid, engine oil), four air ventilation speeds (0, 0.5, 1.5, 3 m/s) were used to study the hot surface ignition probability under these conditions. Visual observation and thermocouples attached on the metal surface were used to indicate the hot surface ignition from the measured temperatures. Results show that the type of metal has a noticeable effect on the hot surface ignition, while ventilation speed has a mixed influence on ignition. Different types of liquid fuels also show different ranges of ignition temperature. Results from this work can be used to help understand equipment mine fires and develop mitigation strategies.

Mar 2, 2022

By J Isles, S King, A Valenza, R Lawolo, J Evert

PT Nusa Halmahera Minerals (PT NHM) is an Indonesian joint venture company owned by a subsidiary of Newcrest Mining Limited (75 per cent) and PT Aneka Tambang (Persero) (25 per cent). PT NHM operates two underground gold mines, Kencana and Toguraci at the Gosowong mine site in North Halmahera District, North Maluku Province, Indonesia.The Toguraci underground mine development commenced in 2011 with ore production commencing in 2012. Water temperatures ranging from 50°C to 80°C were encountered in the Toguraci open pit associated with the structures containing the gold bearing veins and are believed to be fed from a relic volcanic system one to two kilometres below the mine. Underground development and production has continued to intersect these structures with the result that an integrated programme of geological, hydrogeological modelling and operational project work has been required to dewater the mine ahead of the descending stoping fronts.This paper will detail these programmes.CITATION:Lawolo, R, Isles, J, Evert, J, Valenza, A and King, S, 2017. Hot water management at PT Nusa Halmahera Minerals’ Toguraci Mine, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 191–198 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

By P. Leo

The Al-Zn-Mg alloys (e.g. 7004, 7020) are employed for land transport and architectural applications whereas the Al-Zn-Mg-Cu alloys (e.g. 7075, 7050) provide the high strength aircraft alloys. The Cu gives rise to suitably sized and distributed precipitation but causes high quench sensitivity. Their hot work processing also has marked differences; the Cu-free alloys have good extrudability whereas the Cu-bearing alloys have low extrudability and are difficult in rolling as well. The behaviors of the two classes are described in terms of flow stresses and ductility over 300 - 500°C, along with constitutive contrasts. The ductility of the alloys with Cu is much reduced above 400°C by precipitation of a phase at the grain boundaries that can be avoided by suitable heating schedules. The high strength alloys are subject to de-lamination corrosion of sheared edges due to severely pancaked grains; this can be alleviated by holding between passes, in mid-rolling schedule. In torsion tests at 10-1 to 10 s-1/ 250 - 500°C, the stresses (ductilities) at 300°C/ 1s-1 and activation energy Q for 7004 were 118 MPa (2) and 262 kJ/mol. The 7075 was tested after several pretreatments: completely over-aged (softened): 107 MPa (5), Q=150 kJ/mol; whereas, solution and quick cooling to testing caused extraordinarily high peaks related to dynamic precipitation resulting in 160 MPa (1.2), Q=300 kJ/mol.

Jan 1, 2011

By G. Kugler, M. Tercelj

"The 1.2690 high alloyed tool steel is usually applied for cold working and is alloyed with carbide-forming elements Cr, V, W and Mo. It exhibits very poor hot deformability. Since there is no enough available data in literature for elucidation of this problem, hot workability and development of microstructure during hot deformation was studied. Hot compression tests were carried out in temperature range 850-1150 °C and strain rates range 0.001-6 s-1. SEM and OM were used for observation of microstructure. Results revealed very complex precipitation of carbides that depends on deformation temperature as well as on strain rate. It was found that especially at lower temperatures of hot working range the precipitation of carbides strongly depends on strain rate. Three different hot deformation behaviors’ were observed depending on temperature and strain rate range.IntroductionThe hot workability of highly alloyed high speed steels is usually described as relatively poor in comparison to other steels due to their tendency of cracking during hot working especially when inappropriate hot working conditions are applied. Alloying elements such as Cr, W, Mo and V in ledeburitic tool steels form carbides that improve hardenability, strength, hardness, wear resistance, etc., but they decrease hot workability and narrow hot working temperature range in comparison to conventional steels. The size, distribution, type and fraction of carbides, as well as the thermomechanical history of material and hot working parameters have major influence on the hot workability. The microstructure of ledeburitic tool steels during hot deformation can be characterized as a two-phase system consisting of an austenite matrix and a combination of ledeburitic carbides [1-4]. In the soft-annealed condition the total volume fraction of carbides is in the range 19-30% and in the quenched condition in the range 9-25%, depending on the chemical composition. During heating before deformation a large quantity of carbides dissolve, but non-dissolved carbides can have an extremely diverse influence on the hot workability due to variations in their composition, size, distribution, hardness and shape, and their different behavior during the deformation phase [5-7]."

Jan 1, 2011

By Lztok Peruš, Goran Kugler, Matevz Fazarinc, Milan Tercel

"Hot deformability of M42 tool steel additionally alloyed with cobalt and molybdenum was investigated. Hot-compression tests were carried out in the temperature range 850 °C -1200 °C, at strain rates range 0.001--6s-l up to strain of0.9. Field-emission scanning electron microscope and optical microscopy were used for characterization of microstructure of deformed samples, which revealed a very complex precipitation of carbides that strongly depends on the soaking temperature, the soaking time, the stress state, the deformation temperature as well as on the strain rate. Gathered data was used to calculate the processing parameters such as process maps, apparent activation energies and strain hardening exponents. For better understanding of thermodynamical properties of the studied steel a simultaneous thermal analysis was conducted. Furthermore the analysis of phase equilibrium was calculated using Thermo-Cale software. On the basis of these studies the optimal soaking temperature and process windows were determined.IntroductionHot workability ofledeburitic tool steels is important economic factor. This means that for each tool steel individuallysafe range of hot working parameters should be revealed. Publications in the literature with regard to the hot workability of tool steels are rare and therefore more information from this research area is desired.The relatively low hot workability of ledeburitic tool steels, i.e. steels in which the solidification is completed by a eutectic transformation of the residual interdendritic liquid to austenite and various alloy carbides (ledeburitic carbides), is usually characterized by the production of surface and internal cracks during the hot deformation."

Jan 1, 2013