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By P. M. Gruzensky

A survey of the literature has been made covering the extraction of bismuth from raw materials, its separation from lead, and its subsequent refining. The use of aqueous, nonaqueous, and fused electrolytes in electrolytic refining is reviewed. This literature survey has been prepared preliminary to some proposed investigations concerning the electrometallurgy of bismuth, and, although an effort has been made to cover a majority of the applicable references, a critical review was not attempted and no assertion is made that this manuscript is exhaustive in nature. Titles of publications in parenthesis are translations from the language in which the reference was originally published.

Jan 1, 1954

By Leroy E. Schulze

A review of development and a reevaluation of uses of the hydraulic air compressor are suggested by the constant changes in technology, which frequently make an old art valuable in solving current problems. Contacts with research workers in various branches of engineering indicate that this older method of producing compressed air may not be familiar to some or that its salient features might be useful in solving problems involving uses of compressed air. Briefly, a hydraulic air compressor may be described as an inverted siphon, consisting of an intake head where water and air are mingled, followed by a gravity-fall tube in which air is intimately mixed with the water and is compressed as the water pressure increases during the fall down the tube, then a separating, or stilling, chamber in which air bubbles rise to the surface of the water and collect in the upper portion of the chamber at a pressure equal to the weterhead maintained by the height of water in the discharge leg of the circuit. The water, which now contains only the fraction of air that has gone into solution, passes out of the separating chamber and rises up the discharge leg to the surface, which is, of course, at some suitable distance below the level of the intake. Present-day applications include (1) utilizing low hydraulic heads, which otherwise have little commercial values; (2) utilizing low hydraulic heads in reclamation work to supply compressed air, or in some instances to produce a small suction, for air-lift pumping (or for operation of air motors), with minimum attendance and without need for electric power; (3) utilizing medium heads, as at dam and lock installations, to produce compressed air for pneumatic operation of airlifts, gates, valves, and rubber gate seals; (4) utilizing underground waters, as in mines, to produce compressed air for general mine use; (5) using this method of isothermal compression of air in combination with standard compressors wherever hydraulic head is available, thereby securing the advantages of low-temperature intake to the mechanical compressors and reduction of moisture content below that of atmospheric air; (6) development of large air supply at pressures up to 150 p.s.i.g., which, after performing work in reciprocating or centrifugal expansion cylinders, is available at temperatures approximating -50° F. Possibilities in freezing and reheating should be mentioned which may prove economical for obtaining uniformly dry air for process work, wind-tunnel tests, or large air-conditioning installations, such as ventilation of underwater traffic tunnels, and may be economic for supply of supercharged air to gas-turbine plants.

Jan 1, 1954

By A. T. Coumbe

The first survey 3/ covering sales of liquefied petroleum gases was made in 1930 by the Bureau of Mines, which at the time was under the United States Department of Commerce. This original canvass covered national totals for 1922 through 1929, and most of the supply came from natural gasoline plants. The 1930 report showed approximate totals for butane and propane and for butane-propane mixtures and pentane grouped together. No attempt was made to breakdown the national sales by various uses until 1931, when the quantities for domestic or household consumption, gas manufacturing, and industrial requirements, including miscellaneous uses were indicated. As the market for these liquid petroleum gases expanded and as new uses came into importance, their respective quantities were shown separately in the annual survey. Sales for internal-combustion engine fuel and for raw material for chemical plants were first taken out of the industrial total in 1936. During World War II liquefied petroleum gases became important as feed stock diverted to synthetic rubber plants, and consequently the survey was broadened to cover this particular demand, beginning in 1944. Pentane was dropped from the survey after 1943, as, being liquid at atmospheric pressure, it is not considered as one of the liquefied petroleum gases and furthermore, the quantity reported made up less than 1 percent of the total sales. Thirteen producing companies reported to the Bureau in the first survey made in 1930, and in the 1952 canvass about 130 producers--petroleum refiners and natural gasoline companies--and about 1,300 dealers cooperated by filing schedules showing a breakdown of their sales. Their 1952 deliveries of approximately 4.5 billion gallons of liquefied petroleum gases were equivalent to about 3.4 billion gallons of gasoline or 3.1 billion gallons of distillate fuel oil.

Jan 1, 1954

By James Westfield

This report covers the calendar year 1953 and has been prepared and submitted in accordance with the provisions of Sec. 106(a) and Sec. 212(c) of the Federal Coal Mine Safety Act (66 Stat. 692; 30 U.S.C. Secs. 451-483). During this first full calendar year of operations under the Federal Coal Mine Safety Act, the coal-mining industry of the United States attained the best injury records in its history - improving the former best records (made in 1952) by 91 fatal and 10,020 nonfatal injuries. Whereas, the mandatory provisions of the act were intended and designed to prevent major mine disasters, apparently the effects have reached beyond the scope thereof in reducing mine accidents generally.

Jan 1, 1954

By J. H. McClain

In the last 3 years' operation of the zirconium-production plant, zirconium metal has been employed to good advantage in many applications. The most frequent use has been in situations requiring resistance to attack by hydrochloric acid. In this service, it has been shown to be a serious competitor to Hastelloy. Zirconium also has excellent resistance to most other corrosives end could be considered for use as an all purpose metal. For example, this report cites 18 applications in hydrochloric acid, 4 applications in sulfuric acid, 5 applications in phthalic-hydrochloric acid, 3 applications in wet hydrogen chloride-chlorine atmospheres, and 2 applications in fused caustic.

Jan 1, 1954

The Black Hills Mineral Atlas briefly summarizes all pertinent date available on the mines and mineral deposits in the Black Hills that have been explored, developed, mined, or located. The purpose of the atlas is threefold: First, from available date the general potentialities of the Black Hills region can be determined, although it is not possible to calculate actual ore reserves; second, it will provide the necessary basic information regarding a given property or commodity for further detailed study; and third, the compilation is a comprehensive directory of Black Hills deposits.

Jan 1, 1954

By L. C. IlsLey

The theory and practice followed by the Bureau of Mines in investigating electrical equipment4/ made for service in gassy mines are of particular interest not only to manufacturers but also to those organizations that deal with safety anal inspection at the mines. This publication purposes to discuss the theory upon which tests of equipment in explosive atmospheres are based and to consider inspection and other matters pertaining to investigations made by the Bureau in ascertaining whether a machine merits approval. The material in this report is taken from an earlier bulletin,5/ which is row out of print, and has been revised and brought up to date to make the information again available to manufacturers, inspectors, and others interested in the development of safe equipment.

Jan 1, 1954

As a part of its overall wealth in fuel resources, the United States possesses large reserves of coal of ignite rank. According to recent estimates of the Federal Geological Survey (3, 5),l/ the assured lignite reserves of this country amount in total to over 463 billion tons, equivalent to 24 percent of our total national coal reserve on a tonnage basis and 15 percent on a heating-value basis. Distribution and relative amounts of United States coal and lignite reserves are indicated in figure 1. By far the largest proportion of our lignite reserves, over 95 percent is found in North Central States, principally in North Dakota, South Dakota, and Montana, in the vast coal-bearing structural grouping designated as the Fort Union formation. Of the remaining United States reserves, all but a fraction of 1 percent are found in a series of relatively scattered deposits in Texas.

Jan 1, 1954

The lignite deposits of the United States represent a huge potential source of fuel for power generation. It has been estimated that lignite constitutes about 24 percent of the remaining National reserves of solid fuel on a tonnage basis and about 15 percent of the reserves on a B.t.u. basis. (See sec. 3, part 1.) The major portion of these reserves is in North Dakota. Lignite has been used locally for domestic heating since the first settlers burned it at forts and fur-trading posts as early as 1855. Some of the first studies of the use of lignite in steam boilers were conducted by the Federal Bureau of Mines from 1910 to 1920 (15, 19) 1/ However, the commercial utilization of lignite as fuel for producing power developed slowly. Not until about 1925 was any really successful lignite industrial fuel-blaming equipment developed. Since then the commercial use of lignite as a fuel for producing power has been increasing steadily.

Jan 1, 1954

By D. S. Kingery

This study describes five fatal accidents so unusual in occurrence that the chain of circumstances bringing them about may never be duplicated. The intent of this publication is to illustrate that everyone working underground is subjected, at all times, to definite inherent mining hazards and that safety devices, though provided, often are ineffective or not used. It is hoped that a study of these fatal accidents in bituminous-coal mines will show workers and safety engineers that nothing can be taken for granted. Safety planning with continuous study can prevent these unusual accidents as well as the routine recurring types, which cause the majority of coal-mining injuries. The treacherous, fatalistic philosophy that "it can't happen to me" or that "when my time's up I'll get it regardless of what I do," still prevails among individuals and even safety engineers. The individual or safety man who believes in luck as applied to safety should not read any further, since this study was written for the sincere, safety-minded individual who accepts the prevention of all accidents as a challenge to his knowledge, initiative, persuasiveness, and salesmanship.

Jan 1, 1954

By R. W. Stahl

One of the broad purposes of the Bureau of' Mines since its establishment has been conservation of mineral resources. As some of the coal beds approach depletion, especially those coals suitable for making metallurgical coke, more and more attention is being given to means of recovering a larger percentage of coal in place. The customary system of mining in the United States is by room and pillar, or some variation thereof, which leaves pillars of coal to support, the roof. In many operations, where the pillars are not systematically recovered, the loss of coal often amounts to 50 percent or more of the original deposit. In many instances in developing new mines, It is planned to recover chain and barrier pillars on retreat when the mine has reached established boundaries. Too often, however, mines are abandoned for some unforeseen reason before completion of mining without recovering any pillars. Usually, these pillars are lost forever. With this in mind, the Mining Division, Region VIII, of the Bureau; of Mines is encouraging mining by longwall methods. It is a generally known fact that almost all of the European coal is mined by longwall methods, which are conducive to a high percentage recovery of coal. A comparison between mining systems usually is on the basis of tons per man per shift. Unless all operating conditions are similar, such a comparison could be misleading. Generally, the output per man shift in European longwall mines is less than that obtained in room-and-pillar mining in the United States. In European mining, maximum recovery of coal is not only mandatory but it must be accomplished without major damage to surface by subsidence. These restrictions necessitate packing or stowing with consequential increases In manpower and decreases in output per man shift.

Jan 1, 1954

By D. S. Kingery

Efficient transportation is necessary to complement modern mechanized mining methods. The increasing trend toward high-capacity face loading equipment has demanded equally efficient haulage methods; this has been met by increasing mine-car sizes, using larger locomotives, and increasing haulage speeds, all requiring properly installed and maintained haulage roads specifically designed for this type of traffic. The recommendations and specifications included in this circular were made to point out salient factors important to the proper construction and maintenance of track haulage roads and to serve as recommended standards for track installation and maintenance. GLOSSARY OF TERMS USED Haulageway. - The track, walkway, trolley wire, feeder lines signal end telephone lines, signals, telephones, support, and drainage of the entry referred to. Subgrede. - The base upon which the ballast is laid.

Jan 1, 1954

By Rov G. Stott

In recent years there has been no loss of life from fires in the underground mines of the Lake Superior district, but numerous minor fires and several serious ones involving loss of property and production have occurred. The iron-ore-producing companies recognize that well-equipped mine rescue stations are a valuable asset against the ever-present ranger of mine fires or the possibility of hazardous atmospheric conditions underground. Prompt action by trained and properly equipped rescue teams is recognized as the prime essential in saving lives, property, and production when fires occur. To achieve this purpose, the mining companies have provided themselves with mine rescue equipment and maintain trained mine rescue crews. This circular describes how one progressive company has provided, maintained, and improved upon such protection for its underground iron-ore mines on the Marquette and Menominee iron ranges of Michigan's upper peninsula. SUMMARY The central mine rescue station of The Cleveland-Cliffs Iron Co. at Negaunee, Mich., has provided the company's mines with competent and well-equipped mine rescue teams. The new central mine rescue station at the Mather mine "B" shaft has the distinction of having underground training facilities provided as a part of the station. The company maintains the largest trained force in mine rescue in the Lake Superior district, and mine rescue training is employed as a part of the accident-and fire-prevention program. One of the most important results has been the promotion of closer cooperation and understanding between the management and the workmen. In addition to the service rendered to company mines, the station and its personnel have given assistance to others. The station and its equipment have also been used for training several nearby community volunteer fire departments. This mine rescue station and its personnel have been a dependable and valuable asset to the community in which it is located.

Jan 1, 1954

By M. L. Davis

The principal causes of many methane-gas explosions that have occurred in anthracite mines, especially in thick pitching veins, during recent years can be traced to lack of a satisfactory method of testing for such gas in areas adjacent to those in which blasting is to be done or other sources of ignition introduced. As coal-mine officials and inspectors are required to make examinations for methane in all accessible open workings, including high places, and permissible flame safety lamps have been used almost universally for making these examinations, considerable difficulty has been experienced in proper testing of atmospheres at elevations beyond the normal reach of the examiner, and resultant explosions have often indicated perfunctory tests. The accepted practice of testing for gas in voids or high places generally consists of raising a flame safety lamp, suspended from the end of a long drill, stick, or pipe, into the atmosphere to be tested. Disadvantages noted are: Action of the flame within the lamp cannot be seen readily when the lamp is more then 18 inches overhead, the flame will not be extinguished when less than about 4-1/2 percent of methane is present, and indications of small percentages of methane within the lamp may disappear entirely while the lamp is being lowered slowly to view; the examiner must usually be exposed unnecessarily to falling material; and the lamp may fall and be broken. Thus, the need for a more reliable, safe method of testing for gas in out-of-reach places is apparent. Several electrical methane detectors, tested and approved by the Bureau of Mines, have been used satisfactorily, though infrequently, for making the aforementioned gas tests. Some of these detectors employ a rubber aspirator bulb and rubber tubing of suitable length to draw the atmosphere from high places through and over energized parts of the detector. However, the original expense, susceptibility to damage, and awkwardness of tarrying these instruments in steep-pitch workings has precluded their general use in everyday examinations. Although not as efficient as the electrical detector for determining small percentages of methane or as reliable because of the limitations imposed by oxygen-deficient atmospheres, the modern per¬missible flame safety lamp can, it is believed, be used safely with the rubber aspirator bulb and tubing to greater advantage and with comparative reliability in testing for gas in out-of-reach places. Slight reference to this method of introducing air into a safety lamp is made in a Bureau of Mines publication of l921,2/ and it is quite possible that the method has been utilized in some manner by individuals in American mines during the intervening years. A similar method was used in connection with a nonpermissible Wolf flame safety lamp in at least one coal mine in Japan before World War II. A major change in the construction of this lamp would bar its approval by the Bureau of Mines. An American adaptation of the Wolf lamp, developed

Jan 1, 1954

By G. E. McElroy

Economic solutions of problems of mine-ventilation improvement can be found by mathematical analyses of alternative methods of procedure, but, in the case of our older bituminous-coal mines, the airway network is usually so complex that mathematical solutions are too tedious to be practical. Recourse usually is made to extremely costly and uncertain trial-and-error procedures with the existing layout and equipment. The resulting errors often prove costly and sometimes create hazardous conditions. Both the economic and safely aspects of alternative methods of ventilation improvement may be rapidly and cheaply investigation with analogue computers. An electrical analogue computer, designed and built especially for analyzing mine-ventilation-distribution problems, has been placed in service by the Bureau of Mines at its Pittsburgh, Pa., Experiment Station. It is a nonlinear, low-voltage, fluid network analyzer of a type developed by Malcolm S. Mcllroy, professor of electrical engineering at Cornell University. It was designed in close coopera¬tion with Professor Mcllroy and built by the Standard Electric Time Co., Springfield, Mass. It is the seventh unit of this type to be placed in service and the first designed for mine airflow problems. The other six were designed for either water- or gas-distribution analyses. Three are much larger and more expensive units. The largest unit has a capacity of 20 sources, 576 mains, and 180 loads, or regulated-flow paths. The Bureau unit has a capacity of 5 sources, 128 mains, and 48 loads.

Jan 1, 1954

By E. E. Harton

Bureau of Mines Information Circular 16, Bibliography of Investment and Operating Costs for Chemical and Petroleum Plants, was published in October 1949 as an aid in making estimates of investment and operating costs of processes for manufacturing synthetic liquid fuels. Development of such processes by the Bureau of Mines was authorized by Public Law 290, 78th Congress. This bibliography included refer¬ences to and abstracts of publications appearing from 1930 to September 1948 on all processes in general use in the petroleum refining and chemical industries. Publications in this field have been numerous since compilation of the above bibliography, and the present report was prepared to cover the field from September 1948 through June 1952.3/

Jan 1, 1955

The Black Hills Mineral Atlas briefly summarizes all important data available on the mines and mineral deposits in the Black Hills that have been explored, developed, mined, or located. The purpose of the atlas is threefold; First, from available data the general potentialities of the Black Hills region can be determined, although it is not possible to calculate actual ore reserves; second, it will provide the necessary basic information regarding a given property or commodity for further detailed study; and third, the compilation is a comprehensive directory of Black Hills deposits.

Jan 1, 1955

By W. D. Walker

All pipelines used to transport liquid fuels over coal mines are potentially hazardous; however, this publication deals only with dangers in transporting gasoline. Since transporting gasoline by this method is an established practice, the hazards connected therewith should he recognized by coal-mine operators and pipeline companies so that every known precaution may be used to reduce and keep the hazards to a minimum. The purpose of this paper is to direct the attention of coal-mine operators and employees, pipeline-company officials, and other interested persons to the explosion and fire hazards that arise from seepage of gasoline into underground mines. A hazard is not only presented in an individual mine when gasoline enters underground workings; but, in cases where mines are interconnected, a hazard exists in mach such mine.

Jan 1, 1954

By G. C. Branner

The bauxite diagram presented as figure 1 was developed to clarify, by graphic means, the theoretical chemical constituents of gibbsite-kaolinite-type bauxite for all possible proportions of these two minerals from pure gibbsite to pure kaolinite. The tables in the report reflect the same date. The diagram provides (1) a graphic representation of the relations of constituents with respect to a ill possible percentages of alumina and silica, (2) a basis for verifying the accuracy of analyses of gibbsite-kaolinite bauxite, and (3) a basis for estimating the type and proportion of alumina hydrate and/or silicate minerals that may be present in gibbsite-kaolinite-type bauxite. The diagram, with accompanying interpretations and use formulas, will be useful to those connected with the mining and processing of bauxite.

Jan 1, 1955

By R. G. Warncke

In the 1953 National First-Aid and Mine Rescue Contest, 58 teams from 9 States participated, 14 teams from 6 States in mine rescue and 47 teams from 9 States in first aid. Three of the teams were combination teams in that the same team participated in both the mine rescue and first-aid contests. The States represented and the number of teams from each State are shown in table 1. [ ] The contest was conducted in accordance with the general rules prepared by the Rules Committee and approved by the General Committee of the National First-Aid and Mine Rescue Committee.

Jan 1, 1955