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By Yvette Heritage

"The risk of fatalities from rib failure is still prevalent in the coal mining industry. This risk has prompted further research to be conducted on rib deformation in order to understand the mechanisms of rib failure, with the long-term objective being to improve rib support design. This paper presents the results of ACARP research project C25057, which investigated the mechanics and drivers of rib failure. The results of rib deformation monitoring at three different mines in Australia provides rib deformation characteristics for overburden depths ranging from 160 m to 530 m. Monitoring includes deformation during development drivage conditions and during the longwall retreat abutment stress environment. The rib deformation monitoring covered three different seams: the Goonyella Middle Seam, Ulan Seam, and Bulli Seam in the Bowen Basin, Western Coalfield, and Southern Coalfield, respectively. The observed mechanisms driving the rib deformation ranged from bedding shear failure along weak claystone bands to vertical shear fractures to kinematic failures driven by shear failure dilation. The variation in mechanisms of rib failure, together with the seemingly consistent method of rib support design, prompts the question: What exactly is the role of rib support?INTRODUCTIONThe current risk of rib fatalities in the coal mining industry has prompted further research into understanding the mechanisms of rib failure. Three Australian mines assisted further research by providing sites for rib deformation studies as part of the Australian Coal Association Research Program (ACARP) project C25057. The mines included in this study were Moranbah North Mine, Ulan West Mine, and Appin Mine. This paper provides key results of the rib deformation monitoring relevant to assessing the mechanisms of rib deformation.The approach of monitoring rib deformation and rib support loads was used to measure and characterise the dynamic rib deformation present in both development and longwall retreat stress environments. The characterisation of rib deformation, together with rock failure modelling, was used to determine the mechanisms for failure within the rib and to assess the interaction of rib support with the failure process. The mechanisms of rock failure are considered an important factor in understanding the drivers for the failure. Consideration of the site-specific failure mechanisms can provide for a more tailored support design."

Jan 1, 2018

By Douglas R. Piteau, Dennis C. Martin

Instability of rock slopes may occur by failure along pre- existing structural discontinuities, by failure through intact material or by failure along a surface formed partly along discontinuities and partly through intact material. Although certain fundamental failure modes are recognized, the mechanisms of slope failure are varied and complex. Such mechanisms are governed by the engineering geology conditions of the rock mass, which are almost always unique to a particular site. An understanding of failure mechanisms requires a knowledge of the physical, mechanical and strength properties of the intact material and discontinuities which make up the rock mass, as well as the structural geology and hydrogeology. These engineering geology parameters also must be evaluated with respect to the slope geometry to determine failures which are kinematically possible. Only after obtaining a reasonable appreciation of the possible failure modes can a rational mechanical stability analysis be carried out. Both two-dimensional and three-dimensional failure mechanisms should be considered in assessing the design of rock slopes. Simple analyses methods are used initially to identify those possible failures which could control slope stability. More complex and detailed analyses usually are required for a few critical failure modes which could control stability, or where a more complex type of failure mechanism is envisaged. Complex failure mechanisms are usually identified when assessing previous slope failures. More detailed information concerning slope geometry and engineering geology parameters must be acquired where analyses must be more rigorous.

Jan 1, 1983

By M Hood, X S. L, W J. T Daniel, H Gurgenci

It is believed that disc cutter shape affects rock fracture and therefore cutter performance and cutter life. However, the current generation of disc cutters is made of hardened steel and these cutters wear rapidly and consequently they are unable to maintain their original shape in strong and abrasive rock. This wear problem could be reduced if the cutter was made from a harder material. Unfortunately as material hardness increases so does the propensity for brittle failure. In this study the optimum cutter shapes were identified by studying the mechanics of rock/tool interaction. The results showed that bevel and wedge cutters are better than cutters with dome and flat edges. A new cutter was designed, based on this result, using a harder material to increase the life by a factor of 20.

Jan 1, 1998

By Ray Schmidt

When your committee approached me for a talk on "Mechanics of Secondary Metals Collection," I replied that this subject would probably not be very interesting to a group of engineers and requested permission to dwell on the Westinghouse Salvage Setup. I will attempt to avoid duplicating the points covered by Mr. Bliven. The Westinghouse Electric and Manufacturing Co. has main manufacturing Divisions in 25 cities and 9 different states, scattered throughout the country, as well as Naval Ordnance Plants in two midwest cities, and a Merchant Marine Turbine Plant, and two special War Production Plants in Eastern cities. You can, therefore, see that we must have a well rounded pro- gram with the entire respect and sponsorship of the various Division Managements. That was not so easy to get. Management has been a great deal like the general public in the past. I am sure most of you can remember the not very ancient day when each town had a ragman who had a horse and wagon and went through the streets of the town, from door to door, picking up what scrap he could accumulate. He was known as a junk man, and indeed, with the exception of the very last few years, the attitude of manufacturing management was: "We have a job to do. We have a product to manufacture. We don't have time to bother with the junk business."

Jan 1, 1943

By Jay S. Gunasekera

Metal parts are traditionally processed by either filly-liquid (e.g., casting) or filly-solid (e.g., forging) state. Semi-solid metal forming incorporates elements of both casting and forging. In 1991, Gunasekera(5) developed a model illustrating the influence of flow stress by the liquid fraction. The result fits Kiuchi's (1979)(7) experimental data quite well. This model assumed the liquid part is surrounded by solid as small pockets inside the material, which is opposite to the real practical situation. Since the melting usually first happens at the grain boundary, it is better to treat the semi-solid material as small metal crystal surrounded by liquid.

Jan 1, 1997

By G. F. Flaherty

THE property of Tashota Goldfields, Limited, in the Lake Nipigon area, Ontario, is located about 4 miles west of Onaman lake and 16 miles by winter road south-southeast of Tashota station on the transcontinental line of the Canadian National railways. The mine, formerly developed to a limited extent under the name of Tashota Gold mine, has, since late in 1933, been under the management of Minefinders Limited, who, in 1935, brought it into production on a 60-ton per day basis. During the winter of 1934-35, the writer was geologist at the property. The geological structure in the immediate vicinity of the mine workings lends itself well to analysis on the basis of the mechanical principles of folding. Since structure is of prime importance in the localization of the ore-shoots and of the host shear-zones at the property, the correlation of all structural details and their mechanical interpretation forms a working hypothesis of structural control for the direction of exploration and development work. It is believed that the structural relations here set forth may be found applicable in part, or at least suggestive, in working out the relations of ore-shoots to structure in the Sturgeon River area to the south, and in the Little Long Lac area to the southeast (Figure 1).

Jan 1, 1936

By AIME AIME

AN unusually interesting meeting devoted to the discussion of the ways and means of improving coal mining practice, through the larger use of machinery underground, was held in the Auditorium of the Engineering Societies Building on March 11. The meeting was organized by the Materials Handling Division of the A. S. M. E. and held under the auspices of the Metropolitan Section of that Society and the National Coal Association. The New York Section of the A. I. M. E., which had been invited to participate, found itself unable to do so formally because of a conflicting date for its March meeting but informally did its part to aasure the success of the meeting. As a result of the discussion at and preceding the meeting, the National Coal Association, through Walter Barnum, chairman of its research committee, has asked the A. S. M. E. and A. I. M. E. to join the Association in a study of the present problems of the bituminous coal industry. Messrs. Harry L. Gandy, Calvin W. Rice and H. Foster Bain have been selected to act as a committee which shall develop plans for a joint program.

Jan 1, 1926

By B Taylor

Although the underground mining environment is arguably safer now than at any time in history, as underground mining operations across the globe increase in-depth, magnitude, and complexity, protecting workers from harm becomes increasingly challenging. In deep, stressed, seismic mines the development face is one of the most hazardous work areas. The active face is usually the furthest extent of the underground workings, so ventilation can be difficult to maintain, exposing workers to high temperature and humidity while working on foot and doing manual labour. While mechanisation has made many tasks easier in modern times, the reality of underground mining is that development charge-up workers still spend long periods directly exposed hazards at the face. In 2019, Orica and Epiroc partnered to co-develop the world’s first fully mechanised development charging unit using fully wireless initiation, called Avatel™. Built on Epiroc’s M2 Boomer carrier platform, the system is designed to allow one person to charge a development face from the safety of a fully enclosed cabin, thereby reducing exposure to hazards at the face. The system was prototyped in Europe before entering commercial introduction in 2022. This paper reviews earlier attempts to mechanise underground charge-up and describes the development journey and engineering challenges of building a mechanised development charging machine.

Mar 29, 2023

By Yin Wang, Lin Li, Zhongwei Bi, Like Wei, Wen Li, Shaogang Li, Bin Zhang, Hongjie Li

Presently,Many long-wall fully-mechanized faces in shallow depth coal seams are below room and pillar goaf in Shendong mining area. When the working face is advanced out of concentrated coal pillar in upper room and pillar goaf, strong strata behaviors often cause support crushing accident. Aiming at a support crushing accident which happened in Shigetai coal mine of Shenhua group in Shendong mining area, this paper analyses the stress transfer process while mining out of concentrated coal pillar by numerical simulation software FLAC3D. According to the feature, simplifying the roof of upper room and pillar goaf as supporting-beam structure explains mechanism of large area collapse in room and pillar goaf roof. Based on the feature of supporting-beam structure, deep-hole blasting concentrated coal pillar technology is proposed to control the strong strata behaviors in Shigetai coal mine. The blasting control effect is confirmed through characteristics of strata behaviors, growth circumstance of ground crack and multi-point extensometer monitoring results. By using control technology, Shigetai coal mine has been successfully avoided support crushing accident.

Jan 1, 2015

By S Li, Y Lei, X Wu, C Ma, W Q. Zhang

The failure of roof of thin bedrock working face under loose aquifer in a coalmine can lead to water-sand inrush disaster. Based on the accident of water-sand inrush in 30108 working face of a mine in Shaanxi province, China, the mechanism of water-sand inrush is theoretically analysed. The process and critical conditions of water-sand inrush in working face are reproduced by numerical simulation where the bedrock thickness is 20 m, the clay layer thickness is 40 m and the mining height is 6.5 m. The study found that under the condition of thin bedrock and thick clay layer, the characteristics of the clay layer have a significant inhibitory effect on the development of the fractured zone, and the development of the water-conducting fractured zone is incomplete and insufficient. However, in the process of continuous mining of multiple adjacent working faces, the strength of the clay is gradually reduced by the influence of mining and the erosion of water, and the height of the fractured zone is gradually increased. In the subsequent mining process of the working face, the roof is more likely to be cut-off and lead to water-sand inrush. From the initial failure of the clay to the final crack directly through the surface, the shear strength of the clay is reduced by about 52 per cent. Further simulation found that in addition to the characteristics of the clay layer itself, the main factors affecting the water-sand inrush in the working face caused by overburden failure also include the difference in bedrock thickness and strength, and the difference in coal seam mining height. With the increase of bedrock thickness, the development height of the fractured zone increases gradually with increases of bedrock thickness when the cutting failure of overburden rock no longer occurs. With the increase of mining height, the height of water flowing fractured zone also increases, but the cracking ratio gradually decreases. Therefore, it’s of great practical significance to systematically study the mechanism and critical conditions of water and sand inrush in mines and the main influencing factors for preventing similar accidents in mines with similar conditions.

Nov 29, 2022

By Chuanhong Li, Zuohua Lin, Zhancheng Guo

"Catalytic mechanism of CeO2 in combustion of coals was investigated in this paper. Catalytic combustion of four kinds of coals with different metamorphic grades by CeO2 was examined, suggesting that catalytic function of CeO2 increases with increase of metamorphic grade of the coals. One important reason for CeO2 promoting combustion of the coals is that pyrolysis of anthracite is advanced by CeO2, which not only raises the pyrolysis rate and pyrolysis conversion ratio, but increases contents of light components in pyrolysis gas; and both pore space and specific surface area of the pyrolysis char are enlarged by CeO2, which is another reason. In order to realize in situ catalysis for reducing catalyst consumption, it is crucial to increase catalyst particle number and enhance the bonding force between catalyst and coal. In addition, remarkable energy saving effect was observed when a nanometer calcium-based rare earth catalyst obtained by hydro-thermal synthesis was applied to catalytic combustion of coal injection into blast furnace.Introduction Coal combustion is acknowledged as one of the most important coal applications. Since addition of catalysts could reduce the ignition temperature of pulverized coal and accelerate the coal combustion, catalytic combustion is generally accepted as an effective measure to realize fast combustion of coal. Furthermore, different catalysts added may produce different effects on ignition temperature of coal. It is reported activity of catalysts with the same cation follows this order: OH->CO3 2->Cl->SO4 2-; while that of the catalysts which have the same anion follows: Cs+>Rb+>K+>Na+>Ba2+>Li+>Sr2+>Ca2+>Mg2+>Be2+ [1-4] .Due to the special physical and chemical structure, CeO2 plays an important role in the catalysis field. Many literatures point out that CeO2 not only has great catalytic effect on energy conversion, succeeded in catalyzing combustion of gaseous fuels such as CH4, CO, etc. but also can catalyze combustion of some liquid and solid fuels such as JP-10, black carbon, carbon deposit in the automobile exhausts and so on [5-9].Pyrolysis, the first step of combustion, directly influences ignition temperature and combustion rate of coals. So a great variety of catalysts were applied to catalyze pyrolysis of coals. And plenty of studies suggest that the alkali and alkaline-earth metal compounds inherent in the coals show apparent catalytic effect on coal pyrolysis. Meanwhile, addition of alkali and alkaline-earth metals into coal combustion process also indicates obvious catalysis effect, accelerating coal pyrolysis, improving pyrolysis conversion ratio, increasing contents of pyrolysis gases and changing composition of the pyrolysis gases [10-15].Although alkali and alkaline-earth metal compounds have good catalysis effect on coal combustion, their application in the catalysis field was limited because of their erosive attack to the combustion equipments. In contrast, CeO2, as a substitution of the traditional coal catalysts, presents widely potential application due to its good catalysis ability, non-corrosive and nontoxic. However, investigation on CeO2 catalyzing coal combustion is rarely reported. In this work, catalytic mechanism of CeO2 in coal combustion was studied, in an attempt to provide theoretical foundation for developing new catalysis technologies."

Jan 1, 2009

Pure camsellite samples were prepared through crushing, sorting and grinding the high-grade iron-containing camsellite ores from Fengcheng, Liaoning, China. The flotation behaviour of camsellite was studied via a systematic investigation of camsellite flotation re-covery changes as a function of choices and dosages of collectors and depressants at different slurry pH. The results showed that at pH 8.5 to 9.5, the recovery of camsellite reached the maximum at 90%~93.5% using dodecylamine as the collector, while under the same condition a recovery of 84%~86% could be achieved with sodium oleate. The adsorption of dodecylamine was not affected by the addition of sodium hexametaphosphate, but the adsorption of sodium oleate could be significantly depressed. This implied that sodium metahexaphosphate could be used as an effective depressant for the other associated minerals during the dodecylamine flotation of camsellite. When starch was used as the depressant, the flotation of camsellite by sodium oleate was almost completely depressed in the alkaline conditions. Significant depressions were also observed when calcium chloride was added in the camsellite-sodium oleate system. The higher the slurry pH is, the stronger the depression. Zeta potential measurements indicated that the flotation was mainly initiated by the electrostatic adsorption of the collector on camsellite. X-ray photoelectron spectrometer (XPS) analysis showed that the adsorption was originated from the electrostatic attraction between the N atom in dode-cylamine and B atom in camsellite. Dodecylamine had a higher coverage on the camsellite surface than sodium oleate.

Jan 1, 2014

By I. Ngo, L. Q. Ma, J. S. Guo

Deformation of gob-side entries has always been a critical concern for ensuring stability in longwall coal mines. This paper addresses the significant deformation and support challenges that arise in thick and hard roof longwall faces (THRLF) due to dynamic pressure. The study aims to elucidate the characteristics and mechanisms of deformation during the retreat of the longwall face. The research findings indicated that the primary cause of deformation was the combination of advanced abutment stress resulting from longwall face mining and the movement of the lateral roof over the chain pillar. To mitigate this issue, we propose a deformation control method known as cutting off the lateral roof (COLR) over the chain pillar. Simulation results demonstrate a significant reduction in roof stress and deformation of the gob-side entry after implementing the lateral roof-cutting technique. These findings provide valuable guidance for effectively managing deformation in gob-side entries, particularly when dealing with thick and hard roof strata.

Aug 3, 2023

By Weidong Pan, Yinchao Yang, Baodong Zuo

Fully mechanized mining technology, with a large cutting height in thick coal seam, has been developed to be large-scale, mechanized, and intelligent. Furthermore, it is also superior to other mining methods because it operates more efficiently and has higher recovery rates of coal resources. Dongpang coal mine (located in north China) is one of the largest coal mining productions in Hebei province. It is significant because it is the first set of coal mines in China to adopt fully mechanized mining technology that has large cutting height potential. When looking at the coal seams of deep mining, specifically in the mine No. 2612 where the working face is 4.5–6.5 m cutting height, the coal walls have low stability due to the way the coal seam fluctuates in a large working face. This paper adopts mechanical analysis, numerical simulation, and field observation research methods to control the rib fall of coal walls in a coal mine. By adopting research methods that analyze the mechanical characteristics of face roof, we are able to conclude the main roof structure of the masonry seam stability criterion in overhead mining with large cutting height. This is done through employing the numerical simulation method, which helped to determine the main factors that influence the rib fall of a coal wall and weighting factor. Through field observations, we discovered the technology method to relieve, control, and mitigate rib falls of coal seam in a coal mine. We also discovered methods that would ensure the smooth mining of the working face of the mine by strengthening the bolting and grouting reinforcement methods used to improve the working face of stope surrounding rock conditions. This paper discusses research results that enrich the stope wall rock control method by expressing how fully mechanized mining technology, with a large cutting height, is meaningful to solve the complex conditions of rock fall caused by thick coal seam.

Jan 1, 2017

By I. D. Reznik

Results of thermodynamic computations have been presented for reactions occurring in the process of segregation roasting of oxide nickel ores to describe more accurately the mechanism of the process. Under conditions of laboratory-scale roasting in combination with close-circuit flotation flow-sheets and magnetic separation, a recovery of 80-82% of nickel into 8 to 10% Ni concentrate and a recovery of up to 66% of cobalt was achieved. Process conditions have been selected for processing of both high-iron and high-magnesium ores. The feasibility of conversion of 94-98% of nickel and cobalt into solution by oxidizing pressure leaching with sulfuric acid has been demonstrated. It has been substantiated that it is reasonable to introduce double-stage segregation roasting.

Jan 1, 2003

By M. Misra

The interaction of xanthate with SO2 in the flotation of sphalerite and chalcopy.ite is discussed. 'The SO depression of sphaledte is due to the decomposition reaction of xanthate by SO2 The decomposition reaction is dependent on the cole ratios of xanthate/SO2, oxygen concentration and pH. Xanthate adsorbs at a faster rate by chalcopyrite than sphalerite. The faster rate of xanthate adsorption by chalcopyrite and the specific action of S02 on the surface of chalcopy.ite facilitate the selective separation of chalcopyrite from sphaledte.

Jan 1, 1989

By Courtney A. Young

All cyanide species are considered toxic and can be found predominantly in industrial effluents generated by metallurgical operations. For example, cyanide's strong affinity for metals makes it favorable as an agent for metal finishing and treatment and as a lixivant for metal leaching, particularly gold. These technologies are environmentally sound but require safeguards to prevent water contamination. Various methods of cyanide remediation by separation and destruction are available, but certain methods are more effective than others depending on the cyanide species being remediated. Photolytic destruction is regarded as the one technique that is independent of the cyanide species involved. The destruction of various cyanide species by several photolytic techniques has been investigated for the past few years. A literature survey suggests heterogeneous photocatalysis with anatase (TiO,) should behave similarly to homogeneous photolysis with hydrogen peroxide (H,O,) since proposed reaction mechanisms for both processes involve hydroxyl radicals. However, experimental evidence on a suite of cyanide species suggests otherwise. A new mechanism for the photocatalytic destruction of cyanides, especially SAD species, is therefore proposed.

Jan 1, 1998

By A. Kurkov

Flotation process is based on the formation of primary collector-based supramolecular associates at the mineral surface and within the pulp. Supra molecular chemistry allows studying within a common framework, all kinds of molecular associates, from dimers to large assemblies, resulting from spontaneous association of a large number of interacting components of the flotation system, where the collective action of non covalent bonds can have an important role. Self-organization of supra molecular assemblies in the flotation process can be controlled by modifying the chemical structure of the collector, the nature and arrangement of functional group in it, by introducing secondary agents (SA) into the process, to adjust the interaction between the collector and the surface and to control the hydrophobicity of the adsorption bed. This offers broad opportunities to build supramolecular assemblies to improve the efficiency of flotation. Besides, the more complex is the system, the weaker are the interactions, that determine its behavior. This powerful factor still is not employed deliberately to control the flotation process. Organophosphorus compounds (OPC) - dialkyl phosphoric acids whose radicals contain ethoxylated groups ? are considered as nanocompounds, that can be used in building supramolecular assemblies. The presence in an OPC molecule of functional groups (P=O, P (O) O-, P (O) OH), ethoxylated groups, and aromatic rings is the basis for the formation of stable supramolecular associates. Gross formula: C54H94KO16P. Molecular weight is 1069.39. Phosphoryl anion has a regular tetrahedral structure with the angle of 109.5°. Lengths of -P-O- bonds in a PN molecule are 1.7345Å; length of the hydrocarbonic radical C42-C72 = 33.942Å. In an alkaline environment, PN is in the form of the anion, in an acidic environment ? in the form of the polycation due to protonation of the oxygen in the EO group. Chem Office software suite was used to generate three-dimensional images of an OPC molecule in acidic and alkaline environments, to reveal the OPC geometry (bond lengths, valence angles, aliphatic radical length), to identify the collector's binding sites with the mineral surface, to find the most stable and energy-efficient molecular conformations of an OPC molecule and its complexes with minerals under various conditions. Mechanisms of interaction between OPCs and the mineral surfaces are different. In ores whose minerals are dominated by ionic bonds (fluorite), the interaction mainly involves the anionic form of the collector; in ores, whose minerals are dominated by covalent bonds - the oxygen of the phosphoryl group (donor-acceptor interaction) and the oxygen of the ethoxylated groups. This difference is responsible for the formation of spatial associates with different surface layer structures. Introduction of supramolecular chemistry concepts into the analysis of flotation phenomena and mechanisms can become an effective tool for better understanding the flotation process and offers new means of consistently improving its effectiveness.

Sep 1, 2012

By Sadatoshi Ohmori, Karen Shinoda, Nobuharu Isago

Method of tunnel excavation is generally classified such as full-face excavation, bench-cut excavation, diaphragm with center pillar excavation, center drift advancing excavation and so on. These excavation methods should be selected properly in terms of ground condition, the area of tunnel section, the arrangement of construction. Center drift advancing excavation method in mountain tunnel construction, is often applied under quite weak ground condition, prior to the main tunnel widening excavation. Recently, the advancing drift is for the excavation of extreme larger section in main tunnel to confirm the stability of face. In addition, we make advancing deformation occur in drift when the construction was done in poor ground like squeezing and swelling ground, and the force occurred in main tunnel was expected to reduce by the effect of ‘dodging’ for support structure. Mechanical relation between drift and main tunnel has been mainly grasped on past experiences in Japan. However, the characteristic of tunnel enlargement was partially discussed by using the three dimensional analysis and the result was grasped by past experiences on the basis of each tunnel construction. It is considered that the natural ground stress is normally released as the advance displacement, but it was released after the main tunnel widening, causing a displacement and deformation increase. Up to now, the construction practice has shown the reduced displacement during the main tunnel widening excavation by the drift, and the numerical analysis agreed with above observation. However, there is no report found that the displacement and deformation at the time of widening excavation of the main tunnel become larger in case of a drift application. In Kyusyu area, western part of Japan, the northern part of Yoshinomoto tunnel was applied an advancing bench-cutting method for a center drift for the purpose of obtaining the geological information for support selection of the main tunnel in widening excavation. The shape of center drift was a perfect circle with a diameter of 4.0 m or 6.0 m and the same temporary support regardless of the geological situation. As a result, the displacement and deformation of the main tunnel after widening excavation were larger than the section where the center drift was not applied. Furthermore, the displacement and deformation of the main tunnel after its widening excavation was considered larger in the section where the cross-section of the center drift with 4.0 m diameter was applied than one with 6.0 m. Therefore, the center drift with a high rigidity support structure had the effect of suppressing the advancing deformation prior to the main tunnel widening excavation.

Jun 13, 2021

By J. A. Finch, M. Mimezami, M. S. Hashemi A.

The adsorption of magnesium and calcium ions on sphalerite and pyrite is discussed. These ions are common in process water and often considered be detrimental in sulphide flotation. The study attempts to characterize the adsorption mechanism, which has been less studied than the oxide system. Generally for oxides metal ion uptake occurs when cations are hydrolyzed. Our findings reveal that magnesium and calcium adsorb on sulphides at pH below hydrolysis, but adsorption is not chemical. At higher pH, charge reversal occurs that does correspond to presence of hydrolysis products. Advances

Jan 1, 2009