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By Eric J. Grimsey

Nickel smelting and converting can be viewed as processes in which iron is either partitioned or transported between matte and slag. Metal recovery depends on the mass of iron transported to slag, the thermodynamic environment in which the transport is made, and the extent to which the slag, once formed, is left in contact with the matte. The importance of these effects is discussed with reference to a new equation which describes metal recovery in terms of a mass balance and a thermodynamically related parameter which is easily measured in practice.

Jan 1, 1993

By Yoshihiko Maeda

It is said that the 21st century will be an era of the remedy of the global environment. In order to reserve natural resources for the future and to avoid the dispersion of heavy metals after usage and to avoid pollution problems, it is extremely important to recycle heavy metals as much as possible by reasonable recovery procedures. The nonferrous metal industry is expected to play a important role in the recycling of heavy metals that are originally their products. From the depressed metal price experienced in Japan in 1980'h due to the sudden change in current exchange rate between US dollar and Japanese yen, one of major nonferrous metal company, Dowa Mining, has diversified its business area not only to the so-called down stream, but also to the environmental business including metal recycling, industrial waste treatment and soil remediation by utilizing technologis and facilities once used or still used for mining and smelting of copper, zinc, lead and precious metals. In this paper some of these applications will be presented.

Jan 1, 2003

By Yoshihiko Maeda

It is said that the 21 st century will be an era of the remedy of the global environment. In order to reserve natural resources for the future and to avoid the dispersion of heavy metals after usage and to avoid pollution problems, it is extremely important to recycle heavy metals as much as possible by reasonable recovery procedures. The nonferrous metal industry is expected to play a important role in the recycling of heavy metals that are originally their products. From the depressed metal price experienced in Japan in 1980th due to the sudden change in current exchange rate between US dollar and Japanese yen, one of major nonferrous metal company, Dowa Mining, has diversified its business area not only to the so-called down stream, but also to the environmental business including metal recycling, industrial waste treatment and soil remediation by utilizing technologies and facilities once used or still used for mining and smelting of copper, zinc, lead and precious metals. In this paper some of these applications will be presented.

Jan 1, 2003

By R. W. Brigstocke

History The birth of the mining industry of Canada took place about 1670. According to Salone (Salone E., La Colonisation de la Nouvelle France, page 205) the first discovery of ore in the country was made by an iron-master, Monsieur de la Potardiere, near Trois Rivieres, Quebec. Under French rule some prospecting was done; but at this time no one seemed to consider the working of mines practicable. It was not until the time that Begon became Intendant, when the Marquis of Vaudreuil was Governor, that mining was attempted. Begon was a patron of industrial arts and did his best to promote home manufactures. The mining industry was developed under his regime and discoveries of copper and lead ores were made in 1730. About this time the St. Maurice Forges were erected to treat bog-iron ore, and they were in operation for many years. Prior to 1747, iron pans to the value of £21,000 were manufactured, together with bar-iron and plough-shares. About 1769, that is, ten years after the conquest by Wolfe, stoves and other articles, and, later, potash kettles, appeared. What is still more interesting to us-or was, at least, to General Wolfe-is that cannon balls made at the St. Maurice Forges delayed his operations. A map dated 1744, a copy of which appears in the report of the Ontario Bureau of Mines for 1913 (Vol. XIX), indicates the extensiveness of the wanderings of the French and also shows the location of the lead mine on the east shore of Lake Timiskaming. Bog-iron ore was turned into metal, with charcoal for fuel, at Norman-dale, Norfolk county, Ontario, in 1813, and at Clementsport, Nova Scotia, in 1825. In a volume published in 1672, reference is made to the occurrence of coal on the Atlantic seaboard, and in 1677 Monsieur Duchesneau, the Intendant, levied a royalty of twenty sous per ton on all coal taken from Cape Breton.

Jan 1, 1932

By R. L. Pariani, R. R. Moskalyk

Justifying refinery material handling equipment jointly involves economics and indirect benefits. The simple evaluation method is applicable when either retrofitting facilities or costing new metal refineries. The text includes points of interest regarding equipment selection as an additional guide. Although the copper industry was used as a basis, it is recognized that similarities in material handling may exist within the parallel electrolytic refining and winning of metals such as copper, nickel, lead, zinc, tin, and cobalt. The analysis of four major automatic systems, typically implemented in many tank houses, includes tabulated data plus a detailed description of additional benefits. General information regarding auxiliary material handling equipment and an overview are included for subject completeness. It is suggested that the quantitative and qualitative aspects presented may contribute to the basis for justification of automated material handling. The labor-oriented economics plus related intangible benefits described herein should provide incentives to modernize or replace manual operations where practical.

Jan 1, 1987

By Robert van Hille, Alison Lewis

The precipitation of a selection of metals from both a synthetic and an actual metal-rich effluent was investigated. The experimental aspects of this study were carried out in a two-stage process consisting of a pre-treatment clarifier and a fluidised bed (pellet) reactor. Each unit operation in the two-stage process was investigated separately. The pre-treatment clarification stage at pH ˜ 5 resulted in a 99.9% removal of iron and 97.3% removal of aluminium. The pellet reactor was used to precipitate nickel as nickel carbonate from a pure stream and a removal efficiency of 99.6% was achieved. The high local supersaturation at the reagent inlet points caused the formation of a large amount of fines, but these agglomerated onto the pellets up the length of the bed. For copper precipitated as copper sulphide from a pure stream, a maximum removal efficiency of 92% was achieved. The high local supersaturation at the reagent inlets also caused the formation of a large amount of fines, but the extremely sparingly soluble nature of copper sulphide meant that the fines were not agglomerated up the length of the bed. For removal of cobalt as cobalt carbonate from an actual stream, a stable cobalt removal of only 60% was achieved. This was found to be due to the presence of magnesium, which reduced the cobalt precipitation efficiency through the formation of the magnesium bicarbonate ion.

Jan 1, 2003

By Carmen M. Neculita

Optimizing the long-term efficiency of passive systems for the treatment of highly contaminated acid mine drainage (AMD) is still a challenging issue. The optimization lies, among others, on improving the understanding and quantification of metal removal mechanisms in order to predict and enhance the stability of neo-formed minerals in secondary phases. Sorption, and precipitation as oxides-hydroxides, carbonates and bio-sulfides are likely the most important metal removal mechanisms involved in passive biotreatment of both slightly and highly contaminated AMD. In the same time, the preferred mechanism is precipitation of metal sulfides that are more stable and less pH dependent than carbonates and oxides-hydroxides. However, results of relatively recent research studies performed at laboratory scale showed that sulfides accounted only for up to 15% of total metals removed in passive bioreactors treating highly contaminated AMD dominated by iron (around 500 mg/L). Several approaches were used in the aforementioned studies to understand and quantify metal removal mechanisms in spent reactive mixtures collected from long-term (12-15 months) operating column bioreactors. These included: thermodynamic equilibrium modeling and various chemical extractions and mineralogical analyses (such as single and sequential extractions, acid volatile sulfides-simultaneously extracted metals determination, scanning electron microscopy, X-ray diffraction, and thermo-gravimetric analysis). The large proportion of metals (85%) removed by sorption and precipitation as oxides-hydroxides and carbonates suggests a relatively high mobility of the neoformed minerals, especially in low pH conditions. However, no data is available on the long-term stability of spent reactive mixtures and, on the implications for the sustainable management of this type of solid waste. Lately there is almost a consensus that the efficiency of highly contaminated AMD treatment is warranted by the use of multi-step passive systems, including both chemical and biological units, installed sequentially. However, very few well-documented studies are available on the design, construction, operation and long-term efficiency of these multi-step systems. A leading example is the tri-unit passive system installed on the abandoned Lorraine mine site (Québec) to treat a highly contaminated AMD dominated by iron (about 2,500 mg/L). This tri-step system (160 m3), consisting in two bioreactors separated by a unit filled with wood ashes, achieves to date a satisfactory removal of iron (up to 99%). Moreover, based on the data collected during laboratory testing, iron was mainly removed in the wood ashes unit (from around 3,200 mg/L to 10 mg/L) by precipitation of oxides-hydroxides as predominant mechanism and only partially by sorption. However, no data is available on the actual metal removal mechanisms in the field. Overall, theses multi-step systems are more complex and their long-term performance is even less predictable than the single unit systems. This paper presents the current knowledge and the research needs on metal removal mechanisms in passive bioreactors and multi-step systems for the long-term treatment of highly contaminated AMD. KEYWORDS

Aug 1, 2013

By J. Gartelmann, B. Zaslavsky, Y. Vojta, D. J. Chaiko, W. Mego, A. N. Rollins

"Aqueous biphasic extraction (ABE) processes offer the potential for low-cost, highly selective separations. This countercurrent extraction technique involves selective partitioning of either dissolved solutes or ultrafine particulates between two immiscible aqueous phases. The extraction systems that we have studied are generated by combining an aqueous salt solution with an aqueous polymer solution.We have examined a wide range of applications for ABE, including the treatment of solid and liquid nuclear wastes, decontamination of soils, and processing of mineral ores. We have also conducted fundamental studies of solution microstructure using small angle neutron scattering (SANS). In this chapter we review the physicochemical fundamentals of aqueous biphase formation and discuss the development and scaleup of ABE processes for environmental remediation.IntroductionAqueous biphasic extraction (ABE) is a highly adaptable separation technique that can be used in a wide range of applications. We have been evaluating various types of ABE systems for possible applications in the treatment of solid radioactive wastes (1,2), liquid nuclear wastes (3,4), and contaminated soils (5-7), and in the removal of organics from aqueous salt solutions (8). We have also conducted fundamental studies of the solution microstructure of ABE systems using small angle neutron scattering (SANS) (9).The extraction systems are generated by combining an aqueous salt solution and an aqueous polymer solution. This produces two distinct liquid layers that are as immiscible as oil and water, yet each liquid layer contains at least 70 to 80 wt % water. The biphasic systems that we have been working with consist of immiscible polyethylene glycol (PEG) and salt solutions. Some inorganic salts that promote biphase formation with PEG solutions include the sodium/potassium salts of sulfate, carbonate, phosphate, and hydroxide (10)."

Jan 1, 1996

By Ramana G. Reddy, M. R. Bogala

Transition metal silicides have good potential for converting waste heat into electrical energy at higher temperatures. Transition metal silicides are used as thermoelectric alloys at higher temperatures because of their low toxicity, high natural abundance, good transport properties, and better thermal stabilities. In this article, thermodynamic, and thermoelectric properties of promising metal silicides are reviewed, calculated, and compared for waste heat recovery application. Higher manganese silicide (Mn4Si7) was produced from easy one-step self-propagating high-temperature synthesis (SHS) procedure of arc-melting technique. Characterization of the alloy phases were done using X-ray diffraction (XRD). In this study, lattice constants, Vickers microindentation hardness, and thermoelectric (TE) properties (Seebeck coefficient, electrical conductivity, thermal conductivity, and figure of merit) of Mn4Si7 alloy were experimentally determined, and compared with the reported literature values.

Mar 1, 2017

Metal Statistics, Published by the American Metal Market, 111 John St , New York, N. Y. While it is not policy to list in this directory commercial publishers of literature on mining and geology, it is felt that reference to a few standard works of wide distribution and general use should be included; particularly when those works are statistical or of a specific informatory nature Metal Statistics is a book issued annually by these publishers. It contains a general assortment of statistical information concerning the ferrous and the nonferrous metals-price quotations of the metals, tables of production, and so on It is a widely used reference The 25th Annual Edition was issued in March, 1932. The price is $2

Jan 1, 1933

By HAROLD A. KNIGHT

The Miami Copper Co., Arizona, is asking Congress to reimpose the import duty of two cents per pound on copper which, by law, has been suspended until June 30, 1950. C. Donald Dallas, chairman of Revere Copper and Brass, champion of a duty-free regime as regards the red metal, has been answering E. H. Westlake, Miami president, now that Mr. Westlake's statement to stock- holders has been salted away for posterity on wire recorders. Even prior to this action and at the instigation of two prominent consumers of pig lead, the House of Representatives has, in the confines of committee, not yet reported out, as of June 16, a bill to suspend the duty on lead for another year from expiration of the present law June 30, 1949. But apparently the bill was started too late. Thus the tariff issue becomes a Rip Van Winkle again after having slept for several years in the mountains of metals scarcity. During the wartime scarcity and the boom days that followed, most metal producers welcomed a considerable influx of foreign metal since it gave them a little surcease from constant teleibhone calls asking why that delivery of 300 tons of lead, 250 tons of zinc, and 1000 tons of copper had been delayed. These were the days when it was such an undisputed sellers' market that the sellers had even thrown away their certificates of ownership. Another development that brings home the tariff situation, small in it- self but perhaps indicating a trend, has been the announced closing of

Jan 1, 1949

By Corale L. Brierley

Bacteria, algae and fungi react to heavy metals in their environment by immobilizing, mobilizing and/or transforming metals. Microorganisms carry out these changes by (1) precipitating metals outside of the microbial cell, (2) binding and complexing metals to the outside of the microbial cell's protective coating, (3) accumulating metals inside of the microbial cell, or (4) transforming metals by oxidation, reduction, methylation or demethylation. Most of these mechanisms are operative in constructed aerobic and anaerobic wetlands for metal's remediation. Several more advanced biotechnologies for metal's removal from aqueous streams have been introduced, but have not been widely accepted commercially.

Jan 1, 1995

By T. R. A. Davey

A simple model for metal solution behaviour may be derived, on the basis of dilute solution solubilities (where? log concentration of solute varies linearly with reciprocal temperature) and not-so-dilute region solubilities (where the log of the alpha-function at saturation frequently varies linearly with reciprocal temperature) and assuming activity to vary according to the quadratic formalism in between. Matte binary systems usually exhibit regular .solution behaviour when the constituent species are chosen appropriately. In many recent papers, metal solubilities in .slags are expressed as the sum of several different and supposedly independant molecular species (e.g. oxides, sulfides, chlorides), Such a view is untenable because of the now proven ionic nature of slags. Some possible reasons for the great effect of sulfur on copper solubilities in slags are discussed.

Jan 1, 1985

By W. W. Adams

Two important facts stand out as features of the metal- and nonmetal-mining4 industry of the United States in 1941 as compared with 1940: First, the number of employees and man-days of employment increased; second, accident-frequency rates, both fatal and nonfatal, decreased. Reports from mining companies to the Bureau of Mines covering underground, open-pit, and surface operations for 1941 re¬vealed the largest number of men employed since 1926 and the largest number of man-days worked since 1929. The combined fatal and non¬fatal accident-frequency rate for 1941, calculated on a basis of one mil¬lion man-hours of exposure to hazard, was (except for 1931 and 1932) the lowest since 1911, the earliest year for which figures are available. During this 31-year period, only 1938 and 1939 showed lower fatality rates, and only 1931 and 1932 had lower nonfatal-injury rates. Operating companies reported that 9,620 mines were active during all or some part of the year. These employed 125,290 men, an increase of more than 4 percent over 1940. The total volume of work performed at all mines, measured in terms of man-shifts, increased to nearly 32 million, a gain of 10 percent; man-hours of employment rose to almost 254 million, an increase of 10 percent over the 231 million man-hours worked in the previous year. The year's operations resulted in an average work-year of 255 days per man, an increase of 13 days per employee over the average working time in 1940. Although the 8-hour day prevails generally at most mines, the industry as a whole averaged 7.94 hours per shift, as in 1940.

Jan 1, 1944

By W. W. Adams

The first full year of the second World War for the United States presented a picture of the metal-and nonmetal-mining 4 industry which, without proper analysis and explanation, would convey a distorted view of achievements during 1942, especially because employment at gold and silver (lode and placer) mines-the largest group-declined to such an extent that the over-all totals for the country were reduced even though increases were made at mines producing copper, lead-zinc, iron, miscellaneous metals, and non-metals. A complete panorama of the metal-and nonmetal-mining industry, exclusive of coal mining, reveals a decrease in the number of men employed, the man-hours of employment, and the accident-frequency rates. Were the gold and silver (lode and placer) mines to be considered as a separate category; it would be seen that the number of men employed at all the other groups of mines increased appreciably over 1941. These other increases must be considered important, since these mines produced the vital war minerals that made valuable contributions to the military successes of the United States and its Allies during the year. A separate analysis of each of the various groups of mines may be found elsewhere in this bulletin. For the purpose of maintaining continuity in this series of bulletins, however, the discussion in this introduction will be confined to the entire metal-and nonmetal-mining industry (excluding coal mining, for which a separate bulletin, No. 462, has been published).

Jan 1, 1945

By J. PARKCEH CHANNING

Discussion of the paper of Lewis T. Wright, presented at the New Haven meeting, February, 1909 (Trans., xl., 492 to 495). J. PARKE CHANNING, New York, N. Y. (communication to the Secretary*):-Mr. Wright, in his introductory paragraph, says: " It is commonly believed by metallurgists that in copper-smelting, the copper in the slags, which is irreducible by continued smelting, is retained in the form of 'prills' of matte." On a recent visit to Greenwood, B. C., I was discussing with J. E. McAllister, the general manager of the British Columbia Copper Co., and the former metallurgist of the Tennessee Copper Co., this very question; and he held strongly to the idea that the copper in slag was in two forms-one portion contained in occluded matte and the other as an oxide. He believed that this same rule would apply to the silver in the slag. From my experience I am strongly inclined to agree with Mr. McAllister; and it appears quite reasonable that in furnaces treating oxidized copper-ores, and to a less degree in furnaces treating sulphide ores, there is always bound to be present a certain amount of copper oxide and silver oxide, which will behave like any base and get into the slag as such. We all know that in Arizona, in the early days, when it was customary to produce black copper, because the ores were nearly all oxidized or carbonates, and sulphur was scarce, the slags as a rule carried 2.5 per cent. of copper and seldom ran less than 1.5 per cent. of copper. The economic point was determined by the extra coke necessary to produce the reducing action. In connection with the extra saving in copper, Arthur L. Walker, now professor of metallurgy at Columbia University, and formerly general manager of the Old Dominion Copper Mining Co., at Globe, told me that with coke at $60 per ton it never paid him to make slags containing less than 2.5 per cent. of copper. *Received Oct. 8, 1909.

Feb 1, 1911

By W. W. Adams

The metal and nonmetallic mineral mines (excluding coal mines) of the United States had a more favorable safety record in 1935 than in any year except 1931 and 1932 since annual statistics of accidents first became available in 1911. The accident rate was even lower than that for 1911, when the recorded rate probably did not reflect all of the accidents that actually occurred because many companies had not yet begun to keep complete records of accidents, especially those causing only minor injuries, and when, therefore, the number of accidents revealed by the companies' reports to the Bureau of Mines was probably not as complete as that reported for later years. Compared. with 1911, the accident rate covering fatal and nonfatal injuries in. 1935 decreased 13 percent. Compared with 1925, when the rate was the highest ever reported, the rate for 1935 decreased 47 percent and compared with 1934, 7 percent. The progress in safety which the mines of the country made in 1935 was not confined to any section or mining region; it was shared by a majority of the mining States and applied to underground mining operations, to open-pit mining, and to work at surface shops and yards. The rate for underground mining declined 8 percent from 1934; the rate for open-pit mining declined 14 percent, and that for surface shops and yards 12 percent.

Jan 1, 1938

By W. W. Adams

This bulletin covers all mines in the United States that were operated in 1936 to produce metallic ores and all mines that were operated to produce nonmetallic minerals other than coal, stone, sand, gravel, or their products. Reports from mine operators revealed a better safety record for fatal accidents in 1936 than in any other year except 1934 during the 26 years for which annual surveys of accidents in the mineral industries of the United States have been conducted by the Bureau of Mines. On the other hand, the record for nonfatal injuries, although better in 1936 than in any year prior to 1930, was not as good as it was from 1930 to 1935, inclusive.

Jan 1, 1939

By W. W. Adams

The year 1937 was signalized by increased employment in the metal-and nonmetal-mining 4 industry of the United States. Measured by the number of men working, there was a 17-percent gain in employment compared with 1936. In total number of man-hours worked at all mines, the gain was slightly over 18 percent. Hazards connected with mining resulted in more accidents to the workers than in 1936, but the increase in number of accidents caused only a slight rise in the accident rate because of the much larger increase in the number of man-hours worked. In fact, the fatality rate per million man-hours of exposure was lower in 1937 than in 1936, but the rate for nonfatal injuries increased slightly.

Jan 1, 1940

By William W. Adams

A new record in accident prevention was made by the metal-mining a industry of the United States in 1938, as signalized by a lower fatality rate than in any previous year. The rate was less than half as high as in 1911, the earliest year for which figures are available. A good safety record was also established in the prevention of nonfatal injuries, as the injury rate was lower than in any other years except 1931 to 1935, a 5-year period notable for its unusually low injury rates. Employment was more limited in 1938 than in 1937, both in number of men employed and total number of man-hours worked. The number of workdays per man also was smaller than in 1937. Operating companies reported that 7,233 mines were active in 1938 or some part of the year and that the total number of men employed was 103,027. This figure represents the summation of the average number of men employed as reported by the companies, the average for each mine being that for the period during which the mine was active. The number of employees at all mines in 1938 was 15,402 less than in 1937. Reports covering all mines indicated a total of 188 million man-hours worked during the year, or 21 percent less than the nearly 240 million man-hours worked in 1937. In the performance of this work accidents occurred that resulted in the death of 156 employees and the injury of 1.2,722, each injured employee being disabled for more than the remainder of the clay on which he was hurt.. The fatality rate for 1938 was 0.83 per million man-hours worked, which was 9 percent more favorable than the rate of 0.91 for 1937. Nonfatal injuries occurred at the rate of 67.61 per million man-hours worked, an improvement of 10 percent compared with the injury rate of 75.37 for 1937.

Jan 1, 1941