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By Patrick Browne

Drilling programs and the study of active geothermal systems have shown that the reservoir rocks in many fields contain minor quantities of base and precious metals. Commonly, base-metal sulfides occur in the subsurface but, where present, Au, Ag, Hg, As, T1 and Sb rich precipitates deposit near, or at, the surface. Although in some fields (Geysers, Larderello, Tongonan) some of the ore minerals (and others) are relict, there is evidence that they are now depositing in a few systems. Recent work on active hydrothermal systems in New Zealand shows that: (1) Sphalerite, galena, chalcopyrite (forming veins and disseminated discrete crystals) plus rare pentlandite, cobaltite and arsenopyrite, occur at Broadlands, NZ. Rare quantities of base-metal sulfides also occur in cores and cuttings from the geothermal fields of Waiotapu, Kawerau, Tauhara, and Ngawha. Further, Kakimoto (1983) has identified cassiterite, native silver, and trace gold in cores from Tauhara, in the south-eastern part of the Wairakei field. Bore temperatures at the depths from which these minerals were recovered are mostly between 220° and 300°C, but at Broadlands are locally as low as 120°C. The host rocks are Quaternary talc-alkali, silicic lavas and pyroclastic rocks, andesites, dacite and deep Mesozoic greywackes and argillites; however, there is no obvious relationship between mineralization and stratigraphy, permeability or well output. (2) The deposition of amorphous precious metal precipitates (Au, Ag, Hg, As, Sb, T1) from hot springs and well discharges has taken place at Broadlands, Waiotapu and Rotokawa; it also occurs at Kawerau. (3) Water discharging from Frying Pan Lake, Waimangu, is presently depositing siliceous sinter containing up to 4.1% tungsten. A characteristic of mineral-depositing fluids in the New Zealand geothermal fields is their very low salinity (total dissolved salts of 3000 ppm or less but with high CO2); they are of near- neutral alkali chloride composition, although water discharging from Frying Pan Lake has a pH of 4.5, and very low metal contents. Very effective concentration processes (10 times for gold at Broadlands) must occur: in the subsurface these include boiling and rapid cooling but near, and at, the surface, mixing of waters of different pH seems to dominate. In particular, descending acid condensate, derived from separated steam and oxidation of H2S mixes with its parent alkali chloride water, resulting in precipitation of amorphous ore metals. Base-metal sulfides also occur in veins and as disseminated grains in geothermal fields at Tongonan, Leyte and Southern Negros, Philippines. These fields have a porphyry-type setting with host rocks of Miocene andesitic lavas and pyroclastics intruded by diorites so that the fields have undergone complicated thermal histories before cooling to their present base temperatures of about 325°C. Precious metals have precipitated from waters from some wells (Leach, pers. comm.) but they do not, as yet, form ore-grade deposits.

Jan 1, 1984

By R. C. Corey

GERMANIUM is an element that has come into widespread use in the electronics industry in recent, years. So far this increasing demand has been, met by ample supply: however, the future balance is uncertain, and the need has been recognized to discover additional domestic sources of germanium. This investigation was conducted to study the possibility of obtaining a potential supply of germanium from coal or coal ash. It has been known for some time that coal contains germanium; the discovery that By ash from coal-fired boilers often contains appreciably more germanium than the original coal suggested the possibility that coal ash might be an abundant and economical source of this element. In this study the concentration of germanium was determined in numerous samples of coal and ash. A number of miscellaneous waste materials also were examined in the course of the investigation; the results are reported as a matter of general interest. The methods and equipment employed are discussed in detail. Sample-preparation and analytical techniques are described in the appendix. Spectrographic analyses were made on a total of 639 samples, including coal, coal ash, slap ash from lignite and peat, wood ash, and various inorganic materials. Qualitative analyses were run on all samples, and quantitative determinations were made on those samples that contained enough germanium to be measured by this method The lower limit at which germanium can be determined quantitatively by spectrographic analysis is 50 parts per million (p. p. m.), but concentrations of less than 20 p. p. m. can be detected qualitatively.

Jan 1, 1959

By Thomas L. Kesler

Essentially all of the barite produced in Georgia has come from the Cartersville district in the northwest part of the state. The earliest recorded shipment of ore, 60 tons, was made in 1894.1 With the exception of the four-year period 1931 to 1934, the separate yearly output has been recorded and published since 1915, whereas the total yearly output of the United States has been published since 1880. The separately recorded production of Georgia (Cartersville) through 1947 is 2,232,544 short tons valued at $14,900,746,2 but unpublished data on the period 1931 to 1934, plus the estimated unrecorded output prior to 1915, make the actual total about 2,400,000 short tons. This is about 21 pct of the total production of the United States, which, through 1947, is 11,328,440 short tons valued at $71,683,386.2

Jan 1, 1949

By Thomas L. Kesler

IF all of the 14 million tons of kaolin produced in Georgia through 1949 had been mined from a single deposit 20 ft thick, it would represent a mined-out area of less than 1 sq mile. This measure of depletion is in such strong contrast with the large size of the area shown in Fig. 1, from which most of the output has come, that there has developed an optimistic outlook concerning future supplies of kaolin equal in grade to that already mined. Dozens of mines are widely but not evenly distributed within this area, which consists mostly of parts of Twiggs, Wilkinson, and Washington counties. There are scarcely half a dozen kaolin mines elsewhere in the state that have been appreciably productive, although the areas in which they occur may have good possibilities. Most of the efforts to find new deposits, therefore, will be confined to the area shown in Fig. 1, for it is here that the industry has established its facilities, and prospecting is encouraged by relatively numerous outcrops and opened deposits of kaolin.

Jan 10, 1951

By R. O. Y. Breese

Perlite is a hydrated acid volcanic glass that has been derived from the alteration of obsidians through incorporation of water into the silica structure. It is distinguished from other members of the water-bearing natural glass family by total water content, characteristic fracture and luster. The distribution of major occurrences worldwide is associated with silicic Tertiary through early-mid Quaternary volcanics related to plate movement. The No Agua dome and flow complex is one of the most highly studied perlite occurrences in the world. It clearly exhibits lithologic and textural zonations that reflect simple cooling history. Similar features are commonly observed within other perlitized, extrusive glass selvages. This paper briefly discusses current thought regarding geologic occurrence, the hydration process and the modes of origin with special emphasis on No Agua.

Jan 1, 1985

By Henrique Kahn, Daniel Uliana, Carina Ulsen, Guilherme Nery

"Gold has been a material in high demand since the dawn of humanity. After hundreds of years of exploitation, the increasingly search for gold occurs in lower grade deposits with greater extraction difficulty. Therefore, for maximum efficiency, deep knowledge of the characteristics of these minerals and their associations is crucial, which is acquired through an accurate and rigorous routine of process mineralogy and batch extraction tests. The industrial gold process extraction occurs by gravity concentration, sulphides flotation and cyanidation. For gravity concentration, it is fundamental to establish the proportion of free or coarse gold grains and its association to heavy minerals; regarding flotation, the most relevant data are the proportion of gold associated to sulphides and their liberation by the surface area; for cyanidation, it is crucial to evaluate gold accessibility and the kinetics of leaching. Thus, the characterization of gold associations and liberation is vital to establish the plant design, to optimize operating plants and to reduce gold losses. Our aim is the characterization of gold occurrence in low-grade Brazilian deposits with complex mineralogical assemblages to support processing flowchart definition and to predict metallurgical recoveries. Gold distribution in light and heavy minerals was evaluated by heavy liquid separation and the occurrence of gold in free or locked particles was carried out on heavy products by SEM-based automated image analysis using the MLA system. All the products of heavy liquid separation were cyanidated in head samples with different milling conditions to evaluate the reaction kinetics and maximum recovery."

Jan 1, 2014

By William Petruk

Volcanogenic base metal ores contain about 0.5 to 7 g/T Au, commonly as an intermetallic compound with Ag and/or Hg, and to a small extent • "invisible gold" in pyrite and arsenopyrite. The Au-bearing phase (electrum, Au-Ag-Hg alloy, etc.) generally occurs as fracture fillings in pyrite, arsenopyrite and chalcopyrite, and rarely • minute inclusions in pyrite and arsenopyrite. The Au-bearing phase in fractures generally occurs • small grains, and is frequently associated with galena, tetrahedrite and other late minerals. The gold is readily liberated from fractures and recovered by flotation in Ca concentrates. Copper concentrates usually recover around 60% of the gold when the ore grade is around 3 g/t. Higher recoveries are obtained for higher ore grades, and lower recoveries for lower grade ores. Lead and zinc circuits act as scavengers for gold, and recover all the exposed gold attached to small particles. Only unliberated gold, "invisible gold" and very minute gold grains attached to large particles are lost to tailings.

Jan 1, 1990

By William E. Lamont

As a part of the Department of the Interior's rutile and titaniferous materials development program conducted under the Defense Production Act, the Bureau of Mines investigated the potential for producing national stockpile grade rutile from plant products of phosphate beneficiation plants operating in the central Florida pebble phosphate district. The potential for producing ilmenite, zircon, and monazite concentrates from the plant products was also investigated. Results of these studies indicated that 3,000 to 6,000 tons of rutile, 28,000 to 55,000 tons of ilmenite, 9,000 to 19,000 tons of zircon, and 400 to 800 tons of monazite passed through the plant circuits annually. All of these minerals are presently being sent to waste ponds. Beneficiation of a bulk heavy mineral concentrate separated from the amine flotation tailing (froth product) of numerous plants in the district showed that it was possible to produce a rutile concentrate containing over 94 percent Ti02. Additional studies showed that over 70 percent of the Ti02 in the rutile concentrate could be isolated in a product containing 98.0 percent Ti02. The studies also showed that it was possible to produce ilmenite concentrates containing 63 percent Ti02, zircon concen¬trates containing 65 percent Zr02, monazite concentrates containing over 85 percent monazite [(Ce,La,Y,Th) (P04)], and xenotime concentrates containing over 35 percent xenotime (YPO4).

Jan 1, 1969

By G. V. Sullivan

The Federal Bureau of Mines examined tailings samples from 13 western copper operations to determine the potential for recovering rutile. Results showed that six of the samples contained sufficient liberated titania to be considered potential sources. One sample contained 0.75 percent Ti02 or 0.40 percent liberated rutile. Batch flotation studies developed a procedure that recovered 70 percent of the liberated rutile at a grade of 34.7 percent TiO2. Sulfuric acid leaching studies on 12 of the samples dissolved 100 to 2,200 grams Cu per ton of tailings; leaching of the slimes showed slightly more copper was dissolved, 1,800 to 3,300 grams Cu per ton of minus lo-micrometer material. Bulk sulfide flotation of nine of the samples resulted in concentrates that contained 0.38 to 2.0 percent Cu and 0.7 to 2.1 and 6.9 to 42.9 grams per ton Au and Ag, respectively.

Jan 1, 1981

By Joseph C. Zelanko, Anthony T. Iannacchione

One of the most difficult, longstanding engineering problems associated with coal mining is the catastrophic failure of cog mine structures known as bumps. For more than 70 years, researchers and practitioners have assembled a wealth of technical information on coal bumps in an attempt to understand and control them. However, many technical issues raised long ago are still being debated today. This paper examines past experiences and recognizes achievements in the realm of coal bumps. U.S. Bureau of Mines (USBM) researchers collected and analyzed 172 coal bump incident reports and compiled the pertinent statistics into a database. Actual field studied are also discussed. Examination of past experience has shown that there is no one set of defining characteristics that is responsible for coal bumps. In all cases, bumps occur when complex arrangements of geology, stress, and mining conditions interact to interfere with the orderly dissipation of stress. However, it is evident from the database that a tremendous reservoir of knowledge has been established from past experience that has unquestionably limited the severity of coal mine bumps in the United States.

By Wei Yingchun

Based on the deep burial depth of coal deposits in Huainan-Huaibei coalfields, Anhui Province, China, this paper puts forward the concept of partitioning of coal deposits according to occurrence conditions. This process is controlled by tectonic forces. The classification scheme of coal deposits exploration types is presented according to occurrence and mining conditions of coal deposits as viewed from the perspective of deep coal exploration properties. The principles underlying geological exploration services for the resources development are incorporated. There are six exploration types of coal deposits in the Huainan and Huaibei coalfields. Exploration models tailored to different types of exploration have been established and exploration strategies corresponding to different exploration models have been proposed. Steady-state temperature must be measured for the deep heat-harm type of coal deposit. The sealing coring of mine gas samples should be performed for the high mine gas type of coal deposit. For coal deposits with complex structures, such as those located beneath nappes, coal-controlling structural styles must be performed. Existing data on shallow districts are very important to the research of folds and fault-block types of coal deposits beneath and peripheral to old and existing coal mine areas. For the types of fault-block coal deposits hidden by thick Cenozoic cover, particular attention must be paid to comprehensive use of research on regional coal occurrence law and geophysical methods. The present work promotes the exploration level of coal deposits in Huainan-Huaibei coalfields to best meet the need for sustainable development of the coal industry.

Aug 1, 2013

By YONGQIONG YANG, Ning Wang, CHONGGUANG LUO, LI ZHU, Hanjie Wen, SHENGJIANG DU, Hannian Gu

Kaolin clay from Late Permian sequences has been considered a potential resource for niobium (Nb) due to high concentrations reported at several hundred micrograms per gram and large areal distribution. A previous case study identified titanium (Ti)-bearing minerals associated with kaolin clay as the main host phases for niobium. Correlation between the Nb and Ti concentrations was poor, however, and the types of Ti-bearing minerals and modes of Nb occurrence were unclear. To investigate this, typical kaolin clay samples from Late Permian sequences in southwest China were characterized, and final products derived from them were investigated using X-ray fluorescence (XRF), inductively coupled plasma-mass spectrometry (ICP-MS), X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM) and energy-dispersive X-ray spectroscopy (EDS). The results revealed three types of titanium dioxide (TiO2) mineral phases in the clay samples: (1) massive TiO2 minerals, (2) aggregates of nano TiO2 minerals and (3) granular TiO2 minerals. The first two did not contain niobium. From the EDS analysis, the granular TiO2 minerals, including anatase and rutile, were the source of Nb in the kaolin clay samples. 

By YONGQIONG YANG, Ning Wang, CHONGGUANG LUO, LI ZHU, Hanjie Wen, SHENGJIANG DU, Hannian Gu

Niobium in kaolin clay from the Late Permian sequences was reported in the range of several hundreds of micrograms per gram and was considered as a potential resource for its high concentrations and large areal distribution. Ti-bearing minerals associated with kaolin clay were identified as the main host phase for niobium in some case studies. However, the correlation between the concentration of niobium and titanium is poor, and the types of Ti-bearing minerals and modes of occurrence of niobium are not clear. Typical kaolin clay samples from the Late Permian sequences from southwest China were characterized, and the final products derived from kaolin clay sample were investigated using XRF, ICP-MS, XRD, SEM, and TEM (EDS). The results reveal that there were three types of TiO2 mineral phases in the clay samples: (a) massive TiO2 minerals and (b) aggregates of nano TiO2 minerals did not contain niobium while (c) granular TiO2 minerals were the source of niobium from the EDS analysis. The granular TiO2 minerals included anatase and rutile, both of which were the sources of niobium in kaolin clay in the current study. The findings are of great theoretical implication for source and origin study of Ti-bearing minerals and guidance for separation and recovery of niobium from kaolin clay.

Nov 30, 2020

By J. Smuts

The mixed-valence iron silicate ISCORITE (Fe7Si010) was identified recently in a number of ironmakingmater1als, some of which were first produced more than a century ago. Although the existence of iscorite was not reported before 1967 and published phase diagrams do not make provision for it, the morphology of the phase in all the materials that were examined suggests that it is stable under a variety of conditions. It is shown that is-corite can accommodate various foreign cations in its lattice where they can replace Fe and/or Si. The morphology of is-corite in a number of materials of different origin is shown in relation to iron oxides and silicates in optical and SEM/BSE images.

Jan 1, 1991

By H. F. Mills

THE Iron King mine is 12 miles east of Prescott Arizona, in low foothills of the Agua Fria mining district. It was operated in 1906 and 1907, using gravity methods of concentration, mostly on oxide ores. In 1923 and 1924 shipments of sulphide ores were made to the Humboldt smelter. It remained inactive and stripped until 1936, when it was unwatered and sampled to the 400-ft level, the bottom at that time. In 1937 the Iron King Mining Co. purchased the mine and shipped oxide ores. During 1938 a bulk flotation plant of 140 tons daily capacity was erected. The mill has been enlarged and operations have been continuous since the mill first started. In July 1942, the Shattuck Denn Mining Corporation purchased the physical assets from the Iron King Mining Co., and since that time it has operated as the Iron King Branch of the Shattuck Denn Mining Corporation. Economic metals recovered are gold, zinc, silver, lead, a little copper, and fluxing pyrite. The ore occurs as a series of northward-dipping shoots arranged in echelon pattern, the series extending over a length of 3500 ft. Strike lengths of shoots vary from 60 to 600 ft, and widths from 3 ft to as much as 14 ft. The ore occurs in a sheared zone in pre-Cambrian chloritic schist. This schist belt is about 6 miles wide, and the ore zone is about 4 miles from the pre-Cambrian granites to the west. No intrusive rocks have been found in the mine, nor is there evidence of any on surface that might indicate a genetic connection with the ore occurrence (Fig I). The schists strike N23°E and dip 75° to the northwest, which might indicate an overturned thrusting from the granites. In the upper levels, the echelon pattern in which the ore occurs was quite regular, no disturbance of the enclosing schist, or of any faulting that might contribute to the formation of the ore pattern was noted. There is a possibility that the ore zone may be on the axis of an isoclinal fold. Another interesting feature is the more or less typical zoning of minerals along the strike in each of the ore shoots (Fig 2). The north end of each shoot is enclosed by schist, while the south ends usually extend out at full width beyond the economic mining limits in a pyrite-quartz low-grade material. The plane of demarcation between ore and schist is very sharp, with little or no impregnation of sulphide in the schist, especially on the footwall side. The footwall schists are usually firm and strong, and vary from dioritic phases to fine-grained, lighter colored bands, almost silky in texture. The hanging wall for a width of 50 to 8o ft consists of alternating sheetings of chloritic and pyritic schists. The mine is now partly developed to the 92o-ft level, with some diamond drilling from the 1150-ft station of No. 6 shaft. Economically there has been little change in nature or grade of ore from the top of the sulphides, about 200 ft below surface, to the bottom levels. There have been a few echelons in depth, just as there are in plan, and while a few shoots have had

Jan 1, 1947

By Deborah A. Kopsick

Several minerals were observed and collected in a small gully originating from a weathered coal processing waste (gob) pile in Barton County, Missouri. The rapid alteration of these various minerals after collection suggested that they might represent a dehydration sequence. X-ray diffraction of the dehydrated and rehydrated minerals deposited on the gob pile indicated the presence of the monohydrate and heptahydrate forms of ferrous sulfate, szomolnokite and melanterite respectively. The occurrence of melanterite (FeSO4.7H2O), was limited to isolated areas of ponded water while szomolnokite (FeSO4.H2O), was associated with the outwash areas of the pile. Laboratory dehydration of melanterite collected at the gob pile revealed the formation of rozenite (FeSO4.4H2O), an intermediate form of ferrous sulfate. Szomolnokite was shown to be the stable form of these ferrous sulfates during these experiments while melanterite and rozenite were shown to alter readily. Chemical analysis of szomolnokite revealed enrichment in Fe, Mg, Zn, Cd, Cu and Mn relative to the chemical composition of the gob ad the lechate generated from the gob wastes. Although this gob pile had been weathering for more than 35 years, significant concentrations of trace metals were still being released from the pile through the generation of leachate and the formation of various soluble metal enriched ferrous sulfate minerals.

Jan 1, 1982

By A. G. Pentland

PROSPECTING is popularly supposed to be surrounded with an air of romance and adventure. The word 'prospecting' brings to mind high mountains, northern lakes, and aeroplanes. A note of urgency has been added to this by the war, particularly in the case of strategic, minerals. Prospecting for strategic minerals in a modern mine in full production, although it may Jack the romance of travel in little-known places, has the advantage of having all the necessary machinery at hand and ready to go into action at a moment's notice. HISTORY Tin was discovered in the Sullivan ore in 1925, when a white streak was noticed on a pilot table which was being used to check the amount of galena in the tailing. The mineral which made up this streak was identified as cassiterite. The amount of tin in the ore is so small that, while of scientific interest, it was considered to be of very little economic importance. Nevertheless, several attempts were made to learn something of the occurrence during times when other work was nor pressing. These studies were dropped when anything came up that seemed more important.

Jan 1, 1943

By Stephen C. Tadolini, Anthony T. Iannacchione

"Coal burst represented a major hazard for some U.S. mining operations. This paper provides an historical review of the coal burst hazards, identifies the fundamental geological factors associated with these events, and discusses mechanisms that can be used to avoid their occurrences. Coal burst are not common in most underground mines. Their occurrence almost always has such dramatic consequences to a mining operation that changes in practice are required. Fundamental factors influencing coal burst events include strong strata, abnormal strata caving, elevated stresses, critical size pillars and the lack of sufficiently sized barrier pillars during extraction. These factors interact to produce excessive stress, seismic shock and loss of confinement mechanisms. Over the 90 years of dealing with these hazards, many novel prevention controls have been developed including novel mine designs and extraction sequences, most of which are site specific in their application. Without an accurate assessment of the fundamental factors that influence coal burst and knowledge of their mechanisms of occurrence, control techniques may be misapplied and risk inadequately mitigated. INTRODUCTIONCoal burst1are violent failures of ribs, roof or floor in underground mines. They are known to occur in complex ways and often under unique sets of conditions. This has made them extremely difficult to anticipate and control. Assessing coal burst risk requires engineers, managers, and safety professionals to recognize the fundamental factors responsible for these events. This helps practitioners recognize the hazard potential and understand the context in which various controls and barriers should be used. Only then can coal burst events be anticipated andappropriate mitigation techniques deployed.Over the last 90 years, a few coal burst events have been anticipated but most have eluded prediction. The authors examined the historical record (Appendix A) and determined that an inadequate understanding of the initiating geologic factors and their associated mechanisms of occurrence have contributed to the poor predictive capability. The historic record also indicates that control techniques have typically been site specific in their application."

Jan 1, 2015

By Hewitt Wilson

Until recent years the term "whiting" was applied exclusively to the water-ground chalks of certain north European countries. In many industries these are still considered superior to the whiting made from domestic limestone and marble. However, the latter material has replaced much of the European whiting in the American market, largely due to improvements in grinding and classification by American manufacturers.4 To encourage the domestic industry, the Bureau of Mines in 1931 undertook a study of the preparation of whiting from American raw materials and a comparison of the finished products with European whitings.

Jan 1, 1937

By F. N. Siddiquie, Mohd Shaif, Rajiullah Khan, Juned Alam

Manganese ore bodies of Banswara Mn belt were classified into stratiform and stratabound types, based on their mode of occurrence, distribution, and their chemical characters. These ore bodies generally composed of braunite, pyrolusite, cryptomelane/ psilomelane, wad, etc. The stratiform-type Mn ore bodies are conformable with the associated host rocks (Mn phyllite, etc.) and occurred in the form of layers, bands, etc., which are variable in their shape and size. These ore bodies are also strongly folded with the enclosing host rocks. The others, which are stratabound-type Mn ore bodies, also showed an intimate association with the associated host rocks. These types of ore bodies occurred in thin layers, pockets, lenses, stringers, etc. The classified ore bodies are confined with Kalinjara formation of Aravalli Supergroup of Paleoproterozoic age. The ore bodies are structurally controlled and well associated with phyllite, schist, limestone, quartzite, etc. The stratiform-type ore bodies constitute a marginal to low Mn grade and are also characterized by lower Mn content (26.19–39.24%) along with the Mn/Fe ratio of 7.16–12.23, while the stratabound-type Mn ore bodies are rich in Mn (35.92–49.64%) along with the higher Mn/Fe ratio of 14.15–23.97. However, the poor Mn grade along with high siliceous impurities of Banswara Mn deposits is subjected to them for intermittent mining activities in the past and, consequently, did not attract the scientific and industrial community for the evaluation of these resources. Therefore, the authors attempted this study in a scientific and systematic manner (mode of occurrence/distribution and possible methods for evaluation/exploration) to evaluate the potential of existed and newer Mn deposit resources in the Banswara Mn belt. The whole findings would be very much helpful for exploration/ mining geologist along with other concerned, to completely evaluate these Mn deposits in the future.

Aug 16, 2021