Search Documents

By C. J. Veal, C. I. House, S. R. Bellamy

INTRODUCTION Coal gold agglomeration (CGA) is a new concept in gold processing. It involves the recovery of oleophilic (oil-loving) gold grains by causing them to adhere selectively to the surfaces of coal oil agglomerates. Under optimum conditions very high recoveries of gold. can be achieved. The agglomerates are recycled to build up gold loading to typically 1000 - 5000 g/tonne. Bullion can be produced by burning the loaded agglomerates with subsequent recovery of gold from the highly loaded ash either by dissolution/electrowinning or smelting. A wide-ranging programme of laboratory testwork has been performed to investigate the response of different ore types to the process. This has shown CGA to be most applicable to ores in which the gold is liberated or easily liberatable, relatively coarse (ca 500 µm) and fine (<5 µm) gold grains being recoverable with equal ease. The best opportunities for CGA seem to be: • placers containing fine gold not recoverable by gravity concentration • low grade gravity concentrates to avoid multiple magnetic/gravity separation stages and amalgamation • free milling ores where the gold can be liberated at a reasonable ore particle size eg >d80 50 µm • tailings past or present from gravity concentration plants. CGA testwork ranging in scale from laboratory to pilot plant on tailings produced by gravity concentration in the 19th century Australian gold rush has already been reported (Bonney, C F, 1988; House, C I, Townsend, I C and Veal, C J, 1988). An economic appraisal for a Canadian free milling gold ore has also been published (Buckley, S A, House, C I and Townsend, I G, 1989). This paper describes results of a detailed laboratory programme to assess CGA as a means of recovering gold from a beach sand deposit in New Zealand. The area from which the samples were taken consists of quarternary interglacial marine, lagoonal, fluvial and eolian deposits. The heavy minerals present are predominantly ilmenite and garnet and small concentrations of gold. In certain locations the sands and gravels are consolidated by a limonitic cement. In the 19th Century some parts of the deposit were mined and the ore processed using stamp milling and gravity concentration. Gold recoveries were low, probably below 50%, due primarily to the fine size of the gold grains, the flaky nature of the gold and also imperfect liberation by the stamp mills. Our laboratory testwork was divided into three parts: i) Preliminary studies on an initial sample to assess the feasibility of treating the ore by CGA ii) Extended studies on further samples from various locations in the deposit to confirm predictions from (i) iii) Conventional gold recovery techniques. EXPERIMENTAL PROCEDURES All CGA tests were performed by agitating a slurry of ore in water in a 0.6 dm3 pyrex beaker fitted with four vertical baffles. When required, potassium amyl xanthate collector was added and the slurry conditioned for 5 min. Coal (ex BP Coal Australia&apos;s Tahmoor Colliery) previously ground to a d80 50 µm was added followed by a commercial grade of gas oil (density 840 kg/m3). The agglomeration time was 30 min. The agglomerates were separated from the tailings by screening, both were then dried and analysed for gold by fire assay. This test procedure provides a reasonably accurate estimate of gold recoveries that might be expected from our 1 tph pilot plant. Ore samples were ground either dry in an agate ring disc mill or wet in a steel batch tumbling

Jan 1, 1989

By S. Gregory

Many gold treatment plants have sulphides and coarse particle gangue components that contain gold in their tailings (cyanide leach residues and flotation tailings). Coarse and very fine liberated gold may also be present in some tailings streams. Two issues usually govern the economics of recovering additional gold from gold occluded in sulphide and gangue particles. The liberation characteristics of the gold in the sulphide and coarse gangue (gold liberation versus grind size) is the first and most important of the two. If fine grinding can liberate a reasonable amount of the gold, then the next important issue is how effectively these two constituents can be concentrated. Flotation will achieve high sulphide recovery but is usually costly. Selectivity is also an issue because of entrainment. Continuous centrifugal gravity concentration offers a viable solution to the recovery of both sulphides and coarse gangue however selectivity is also likely to be a problem. The possibility of improving concentrate grade by using a Falcon B separator was investigated. This paper describes a program of test work carried out on a gold leach tailings using a laboratory Falcon &apos;13&apos; separator. The program involved three different bowl angles: 10, 12 and 14 degrees and two bowl speeds (giving 250 and 350G accelerations). A number of tests were also performed on samples that had free gold present to ascertain the size-by-size recovery of gold in these samples.

Jan 1, 2005

By B. K. Parekh

Silicon carbide (SiC) can be produced by heating rice hulls to elevated temperature, The product is a mixture of beta crystalline silicon carbide whiskers, particles and unreacted carbon. The silicon carbide whiskers are 0.5 micron in diameter and 50 to 100 micron in length and have been found useful for reinforcing metal and other composite materials. The carbon can be removed by combustion, but this makes separation of the silicon carbide whiskers from particles difficult and a high grade whisker product cannot be made. However, a clean high grade Sic whiskers product can be obtained from the pre-burned converted rice hulls using physical separation processes that are based on differential wetting. Recovery of Sic whiskers from the pre-burned material was found to exceed 90 percent. A modification of the froth flotation process developed during this study is now being used commercially to separate silicon carbide whiskers and particles and to recover a high grade whisker product.

Jan 1, 1985

By John Hanna

Over the years the coal industry in Alabama has generated about 150 million tons of fine waste coal, increasing at a rate of 2 million tons/year, during mining and cleaning operations. Reclamation of the fine-size wastes containing 20-60% by weight clean coal provides, free of charge, mined and crushed feedstocks for coal recovery and eliminates a major source of acid water pollution. Tests were made on the impounded wastes and current plant discharges to recover the coal fraction by sizing, gravity and flotation techniques. Gravity separation of the plus 100 mesh material produced commercial grade coal averaging 8.2% ash, 0.8% sulfur and 13,350 Btu/lb. However, the coal recovery was relatively low at 50-65%. Froth flotation using mechanical and froth column methods gave similar coal products at much higher coal recovery of 87-93%. The coal produced analyzed 10% ash and 1.1% sulfur.

Jan 1, 1991

By Mukesh Jain

The liquor from potroom wet scrubbers is treated with lime to precipitate the soluble fluorides. The solids after filtration, referred to as scrubber mud, contain in addition to calcium fluoride, alumina, carbon, tars including polyaromatic hydrocarbons (PAH), cryolite and pachnolite and are considered hazardous. This communication deals with the pilot plant scale calcination of scrubber mud with a rotary kiln to obtain non-hazardous fluoride raw materials. Air classification was performed to separate the mudinto aluminarich andcalcium fluoride rich fractions which were then calcined. With proper control of calcination parameters and addition of lime, the carbon and tars were destroyed and hydrogen fluoride emissions were controlled. The calcined products could be used in the steel indusny as a fluxing agent or as a substitute for fluorspar in the production of aluminum fluoride.

Jan 1, 1994

By V. F. Petrov, E. P. Olberg, S. V. Petrov

"The study was carried out using process solutions produced during cyanidation of gold-bearing concentrates from a gold-processing plant. It was found that the water contained a significant portion of thiocyanate (7910.0 mg/L), cyanide was virtually not present. The metals occurred primarily as iron (355.0 mg/L) in the form of ferrocyanide. Cyanide recovery was conducted using an ozone treatment process with reactors developed by the Environmental Department of Irgiredmet. The process design ensured complete utilization (100%) of O3, thus equipment operation safety increased.The recovery of free cyanide from thiocyanate was 76.6%, which corresponded to 5.12 kg of NaCN (100%) per 1 m3 of solution. Recovered NaCN can be used for recycling in hydrometallurgical processes.The operating costs estimation showed that the production cost of a tonne of recovered cyanide was US$1288.7, considering the prices of energy and commercial sodium cyanide in Russia in 2017, i.e. recovered cyanide is cheaper than commercial cyanide by 55.8%.INTRODUCTION Depletion of oxidized gold-bearing ores readily amenable to cyanidation has shifted focus to large-scale processing of primary ores with high sulphide content. Primary ores processing flow sheets involve gravitational and/or flotation concentration with subsequent treatment of produced gold-bearing concentrates. Typically, concentrates reporting to cyanidation contain considerable amounts of sulphur that can interact with CN- and further formation of SCN-. The use of refractory gold liberation methods (bacterial liberation, ultra-fine grinding) provides activation of this side reaction up to complete consumption of free cyanide in a short period. This makes water recycling unviable and impractical.The interaction of the sulphur content in concentrates and cyanide contributes substantially to consumption of NaCN required for efficient gold recovery. Inappropriate consumption of the main reagent achieves dozens of kilogram per tonne of material to cyanidation, and reaches approximately 100% when gold is recovered from activated sulphide-containing products (e.g. by ultra-fine grinding)."

Jan 1, 2018

By E. J. Beckman, R. M. Enick, C. Shi

A novel liquid-liquid separation for the recovery of free or liberated gold from mixtures of fine particles was evaluated. Two inexpensive and environmentally benign fluids were selected for the study, water and carbon dioxide. The separation, which is conducted at 295 K and at the vapor pressure of carbon dioxide (6.0 MPa), is based on differences in wettability between the precious metals and other minerals. Contact-angle results indicated that, in the presence of water and liquid CO2, gold is slightly hydrophobic. The addition of CO2-soluble fluoroalkyl thiols or f uoroetherthiols increased the hydrophobicity of gold exposed to water and CO2 to a greater extent than alkylthiols. Minerals, including quartz, pyrite and magnetite, were hydrophilic. During the separation, an aqueous slurry of fine mineral and gold particles was mixed with liquid carbon dioxide. Pure gold particles (-325 mesh) were found to agglomerate at the H2O-CO2 interface. The minerals tended to remain in the aqueous phase. Despite these promising preliminary results, very poor gold recoveries were obtained when applying the procedure to an Australian gravity concentrate. This was attributed to the native gold particles in the concentrate being either too large, agglomerated in slimes or coated with minerals. Although this particular application was unsuccessful, this water-CO2 biphase technique may be applicable for other separations that require the removal of very fine, hydrophobic particles from an aqueous slurry.

Jan 1, 2000

By J. H. D. Hargrove, A. F. Snowball

Atmospheric pollution control has become increasingly important in re-cent years with laws and public opinion having required the reduction of contaminants from industrial gas effluents. Treatment methods have advanced to make possible, with proper plant design and operation, a satisfactory removal of these contaminants. Gases from Cominco's metallurgical operations at Trail, approximating 900,000 c.f.m., are treated by baghouses, electrostatic precipitators, cyclones, or wet scrubbers. The tabulated data include gas and dust conditions, plant performance, and some details of plant equipment. Discussion emphasizes the special features, scope of application, and basic design principles of the treatment methods, all based on Cominco experience. Recovery of over 99 per cent of the fume and dust is achieved by the major installations from which effluent gases go to atmosphere. Cooling of gases for baghouse recovery and conditioning for electrostatic precipitation are mentioned. Co3ts are tabulated for some of the installations on the basis of a unit of 1,000 cubic feet of gas. Suggestions are made on the procedure for assessing a smoke treatment problem and for selection of suitable equipment.

Jan 1, 1959

By Dachun Liu, Wenlong Jiang, Guozheng Zha, Liang Hu

In this paper, a novel technique for recovery of gallium and arsenic by thermal decomposition under vacuum is presented. The effects of distillation tem- perature on the volatilization behavior of each component were investigated. Theoretical calculations and experimental studies have shown that the method is feasible. The results show that under optimum conditions, highly pure Ga can be extractedwithadvantagesoverconventionaltechniques,includingsimpleoperation andenvironmentalfriendliness.Forexample,metallicgallium(purity > 99.99%)is obtained at 1273 K after 3 h under 3–8 Pa. Arsenic is obtained in the form of a elementary substance which could be preserved with relative ease. (cid:1) (cid:1)

Mar 1, 2018

By Z. S. Abisheva

Results of the study targeted to development of universal acidic-extraction-precipitation technology for gallium recovery from the sublimates are presented in the paper. This will let to utilize a new non-traditional source for gallium production. Phase composition of gallium containing dust was studied. Forms of gallium in the sublimates were determined. The main form is Ga2O3, however, GaP form is also present in the cottrel dust and Na5Ga3F14 form is present in the dust of aluminum electrolysis. The possibility of gallium concentration was established via secondary pyro-selection of the dust. Kinetics of interaction of dust components with sulfuric acid was studied. The products of the interaction subsequently were leached with water. Optimum conditions for direct leaching with HCl and H2SO4 were determined providing gallium recovery from the cottrel dust and the ash carry outs up to 95 %. Gallium recovery from the primary dust and the secondary dust of aluminum electrolysis was at 52; 64 % and 63; 83 % respectively. Effect of Fe, P, K, Na and Al admixtures for gallium extraction from hydrochloric acid solutions was studied. It was shown that gallium chloride complex (GaCl4-) is extracted into the organic phase from the following acid mixtures: HCl + H2SO4, HCl + H3PO4, HCl + H2SO4 + H3PO4, HCl + HF. Kinetic regularities of gallium extraction in the system (tri butyl phosphate) TBP ? HCl - Ga were studied using diffusion cell method with agitation. Optimum conditions for gallium extraction from complex hydrochloric acid solutions with TBP were found providing 99.9 % recovery and separation coefficient for gallium and iron (III) of more than 25 in one stage. Sodium hydroxide and water were selected as reagents for re-extraction of gallium from the organic phase. Different options for disposal of by-products that are formed in the processing of cottrel dust, ash sublimates and dust of aluminum electrolysis were proposed and tested. Keywords: gallium, kinetic, sulfatization, leaching, extraction, technology

Sep 1, 2012

By Gui-fang ZHANG, Zhe SHI, Lei GAO

Secondary V-recycling slag, an industrial waste containing high gallium is being dumped continuously, which causes the loss of gallium. Thus, the alkali fusion process was employed to recover gallium from this slag. The effects factors on extraction of gallium such as roasting temperature, roasting time, alkali fusion agent concentration and CaO concentration were investigated in the paper. The experimental results indicated that excessive roasting temperature and roasting time is unfavorable to the recovery rate of gallium. The appropriate roasting temperature and duration are 1000 and 2 hours, respectively; The appropriate proportioning of Na2CO3: NaOH is 2:1 when the concentration of alkali fusion agent weighs 0.4 times the mass of the slag; In order to remove SiO2 from the leaching liquor, CaO should be used as an additive in the roasting process. The appropriate concentration of CaO should weigh 0.2 times the mass of the slag. Employing these optimal alkali fusion conditions in the roasting process, gallium recovery is above 90%

Jan 1, 2015

By A. Demirag, F. Burat

"The most important metals in the jewelry sector are undoubtedly gold and silver. As a result of workmanship work done in the jewelry industry, the tiny metal and jewel fragments and metallic powders are scattered. Given the prices of gold and silver on the market, the dust that emanates from these workshops is of great importance. Gold recycling has become as important as raw material production within the mass market and gold production industry. In 2016, 29% of the world gold supply has been obtained through recycled gold production. Waste derived from jewelry activity is included in this category, and represents an essential component of this percentage. In the scope of this study, the recovery possibilities of Au and Ag from jewelry sweeps floor sample was investigated using flotation method. In the experiments, optimum pH value, particle size, the effect of dispersant, type and amount of reagent were investigated. As a result of these studies, it was determined that the optimum pH value was 6.5 and the particle size was -212 microns. It was observed that the most suitable reactive combination was Aero 242 and Aerophine 3418A and Na2SiO3 has no positive effect on recovery of Au and Ag as a dispersant agent. As a result of tests, a final concentrate containing 268 ppm Au and 2122 ppm Ag was obtained with 81.4% and 74.5% recovery respectively. INTRODUCTION Because of the softness of pure gold, it is usually alloyed with base metals for use in jewelry, altering its hardness and ductility, melting point, color and other properties. On the other hand, gold has some special chemical properties which in normal conditions, don’t react with water, dry or humid air, oxygen, ozone, nitrogen, hydrogen, fluorine, iodine, sulfur and hydrogen. In these days, gold is used in different sectors like jewelry, electronics, finances and investing, dentistry, medicine, aerospace, awards & status symbols. According to Deutsche Bank Research, the primary usage of gold is jewelry. It has been used to make ornament and jewelry for thousands of years. In this sector craftsmen learned that alloying gold with other metals like copper, platinum and silver to increase gold’s durability. Alloying gold with other metals changes the color of the products. Another significant sector of gold is electronics. Modern electronics want the use of noble metals, like gold, especially in the areas of information processing, telecommunications, and military and space electronics (Habashi, 1997). Electronic devices use very low voltages and currents which are easily interrupted by corrosion or tarnish at the contact points. Gold is the highly efficient conductor that can carry these tiny currents and remain free of corrosion. Electronic components made with gold are highly reliable. Gold is used in connectors, switch and relay contacts, soldered joints and connecting wires. Every sophisticated electronic device have a considerable amount of gold. This includes cell phones, calculators, personal digital assistants, GPS units, and other small electronic devices. Most large electronic appliances such as television sets also contain gold. Humankind has known silver since prehistoric times like gold because silver occurs in native form. The metal is found in the Earth's crust in the pure, free elemental form native, as an alloy with gold and other metals, and in mineral such as argentite. Most silver is produced as a byproduct of copper, gold, lead, and zinc refining. Silver is very soft metal like gold also, it is the highest electrical conductivity, thermal conductivity, and the lowest electrical contact resistance of all metals (Habashi, 1997). Silver is used in different sectors like industry, jewelry, electronics, photography silver good, and coins. The main usage of silver is supplied by electronics. Silver's unsurpassed thermal and electrical conductivity among metals means it cannot easily be replaced by cheaper materials. In addition to silver is using in ener"

Jan 1, 2018

By G. B. Harris, C. W. White

Cyanide has been used for the recovery of gold since the mid 1800s, but several jurisdictions have already banned its use, and environmental pressures are increasing to finding an alternative. Gold also forms chloride complexes similar to those of cyanide, but the use of chloride has never achieved widespread acceptance. This paper describes a chloride-based flowsheet, wherein the key unit process is the recovery and recycle of chloride ion. It is shown that the chloride-based flowsheet is competitive economically with the conventional cyanide-based flowsheets, and that it has a number of other advantages, particularly environmentally.

Jan 1, 2011

By James L. Hendrix, R. Y. Wan, David W. Kappes, Jinrong Zhang, M. C. Fuerstenau, Terence E. Albert

A sulfidic flotation tailings ore, containing 1.14 gpt Au and 242.53 gpt Ag, was treated by low temperature chlorination roasting followed by cyanide or chloride leaching. Eighty per cent of Ag was recovered by cyanide leach when the ore was roasted at 350°C with 50 kg/ton calcium chloride. About seventy per cent of Au was made cyanide amenable by chlorination roasting at 400°C. A better Ag recovery, ninety per cent or over, was achieved by chloride (NaCl+HCl) leach. However, Au recovery was very poor by chloride leach. Ferric chloride, calcium chloride, and cupric chloride were compared as chlorinating agents for their effect on Au and Ag recovery. The study found that low temperature chlorination roasting is very effective for recovering Ag associated with stibnite and stannite. The best chlorinating agent for the test ore was found to be calcium chloride. Parallel roasting-leaching tests indicated that chlorination roasting was far superior over oxidation roasting for both gold and silver recovery.

Jan 1, 1993

By Clement K. Chase

Although flotation is the generally accepted process employed to recover gold and silver as well as copper, lead, and zinc from primary sulfide ores, the metallurgical requirements for the treatment of massive sulfide ore deposits differ markedly in many respects from those employed for the more common disseminated porphyry deposits. In Arizona, some properties classified as other then massive sulfide deposits because of mining and geological characteristics have produced mill-feeds similar to those from massive deposits. Several such occurrences are noted. The process requirements for massive sulfide deposits and unique mill-design implications are discussed in the perspective of world-wide economic considerations and the individual regional metallurgical and economic constraints in the United States.

Jan 1, 1986

By R. M. G. S. Berezowsky

An atmospheric ammoniacal thiosulphate leach system was developed to recover gold and silver from residues of the ammoniacal oxidation leaching of sulphidic copper concentrates. Extractions of 88 - 95% Au and 83 - 98% Ag were attained within 2 to 4 hours at 40 - 60°C in thiosulphate leaching of the oxidation leach residues of Manitoba chalcopyrite concentrates analyzing 24.6% Cu, 0.18 oz/ton Au and 4.26 oz/ton Ag and a complex British Columbia chalcopyrite/tetrahedrite concentrate analyzing 18.5% Cu, 0.27 oz/ton Au and 276 oz/ton Ag. Parameters affecting the Au and Ag solubilization included thiosulphate, ammonia, and cupric ion concentrations, temperature, retention time and the degree of Cu extraction and sulphide oxidation in the primary oxidation leach. The precious metals were recovered from the thiosulphate liquors by zinc dust cementation.

Jan 1, 1979

By V. I. Lakshmanan

The growing concerns on process efficiency, escalating operating and capital costs along with environmental and social concerns of using conventional technology for extracting gold and titanium dioxide demand an in-depth understanding of the fundamentals and a broader understanding of the various process steps involved. This will allow development of efficient process flowsheet for product recovery and compliance with regulatory guidelines. This paper will discuss our recent developments in mineral processing and hydrometallurgical technologies to recover gold and titanium dioxide from a wide range of feed materials including ores, concentrates and tailings.

Sep 1, 2012

By R. J. Sawyer

The Greens Creek underground polymetallic mine restarted production in 1996 from a newly discovered high grade ore zone. Efforts to improve payable gold recovery have focused on gravity separation. The paper compares testwork and plant results for a newly installed gravity circuit.

Jan 1, 1997

Two pilot-plant investigations were conducted in which strong-base resins were compared with activated carbon for the extraction of gold cyanide from leached pulp from the Golden Jubilee Mine. The results show that gold can be recovered with carbon, but that the extraction efficiency is poor, probably because high concentrations of humic and fulvic acids are. present m the pulp. .However the extraction of gold cyamde from this material with strong-base resins JS very effo:1ent, and the overall efficiency of extraction is better with resin than with carbon, even when the concentration of resin is one-third that of carbon, and the flowrate of resin is one-third that of carbon. The results of the pilot-plant campaign reported in this paper led to the conversion of the Golden Jubilee plant from carbon-in-pulp to resin-in-pulp in February 1988.

Jan 1, 1989

By D. M. Muir, C. Cao

Many gold ores have copper mineralisation which presents problems in a carbon-in-pulp operation. Various types of copper-gold ores and ways of tackling the problem are discussed. In some cases copper and gold can be upgraded to a concentrate by flotation; otherwise, copper or gold can be selectively leached. When both copper and gold cyanide are present in solution, it is possible to minimise copper loading onto carbon or to selectively strip the copper from the carbon. Alternative leach solutions like thiourea and bromine are discussed and results obtained with the ammonia/cyanide system are presented in the light of our present understanding of the chemistry involved.

Jan 1, 1989