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By B. Grinbaum, A. Mazuelos, F. Carranza, N. Iglesias, M. Avila, J. L. Lozano, G. Perez, R. Romero, M. \/aliente

Following a failure of a tailings pond darn at a mine in Andalusia, Spain, a huge effluent stream, that contained about 1 g/1 Zn and significant amounts of ferrous, ferric, calcium, copper, aluminium and manganese cations has to be treated, to prevent pollution of a nature reserve. EGMASA, as the regional government environmental agency, suggested to improve the current depuration process by recovery of the Zn from the effluent. A solvent extraction (SX) followed by electrowinning (EW) was proposed and developed to remove zinc.. A pre-treatment stage consisting in bio-oxidation of ferrous iron by using a bacterial process followed by an alkaline precipitation was employed because iron in the effluent is incompatible with both the SX and the EW processes. The SX process was developed successfully at the laboratory scale and verified in a pilot plant on-site, using two Bateman Pulsed Columns for extraction and stripping of zinc. The results were satisfactory obtaining a recovery of 90% of Zn. The process was suitable for industrial application.

Jan 1, 2008

By D. Pearson

About 15,000 tonnes of zinc per year is present in the dusts and fumes produced in electric arc and BOS steelmaking, secondary copper refining and brass ingot making. Apart from the use of some copper-smelter fumes for zinc chemicals manufacture, zinc is not recovered and their disposal by landfill entails some risk of pollution by leach-out. The paper describes processes for recovering the zinc based on leaching and electrowinning. It was shown that the procedures normally employed for purifying zinc-electrolytes derived from primary sources are sometimes ineffective for secondary materials. Alternative process routes are proposed. Source materials were leached with acidic or alkaline reagents and solvent extraction was employed for electrolyte purification in addition to the usual techniques involving precipitation. Examples of integrated flow sheets for specific source materials are presented.

Jan 1, 1980

By M. S. Moats

The treatment of oxidized residues of zinc with high iron content continues to present a technical challenge in both the steel and zinc industries. Two main problems are commonly identified and include high treatment costs and environmental concerns about contaminated, iron-bearing residuals. A new approach to this problem is described in which selective separation of the iron and zinc into salable products may be potentially feasible. The waste material is first leached to give a solution having an approximate concentration of 110 g/l Zn, 15 g/1 Fe and 40 g/1 H2SO4 and other impurities such as Pb, Cd, Cu and Sb. A suitable organic, such as D2EHPA, is used to load the majority of the iron. The aqueous phase is then acceptable for zinc electrowinning after standard solution purification. The novel step in the flow sheet is the efficient recovery of the ferric iron from the organic solvent using a solid metal to reduce the iron to the ferrous state. The Fe+2 is easily stripped into an aqueous phase in a relatively pure form, suitable for use in water treatment. Process parameters and possible flow sheet designs are described and discussed.

Jan 1, 1995

By M. A. Barakat

Large amounts of zinc ash and flue dust containing more than 80 % zinc are accumulated during galvanization processes at the surface of molten zinc bath and in the chimney respectively. Pyrometallurgical recovery of zinc from both of the ash and dust samples has been carried out. The ash was sieved with the help of an industrial sieve shaker provided with mesh sieve having a pore size 0.9 mm. The oversize fraction cut (+ 0.9 mm) was melted at 550 °C under ambient conditions. The produced ingot (1) was analyzed whereas the coarse fraction of the produced slag (+ 0.9 mm) was treated as the coarse ash or added to it. The dust was enriched with suitable fluxing salt prior to heat treatment at 600 °C for 1 h. The produced ingot (2) was analyzed whereas the resulting slag was mixed with the fines of the ash and treated by hydrometallurgical processing to prepare valuable salts of zinc. Parameters affecting recovery processes such as time, temperature and flux percentage were studied. Results obtained revealed that the two prepared ingots (1&2) were successfully recovered with recovery efficiency amounts to =85 %. The obtained samples meet the standard specifications with relatively low price. Also in the light of the strict environmental regulations of pollution control, reuse of these wastes materials will help in keeping the environment clean.

Jan 1, 2000

By B. Garcia-Egocheaga, J. Rutten, N. Goicoechea, U. Meurer, Mager K., W. Saage, Simonettim F.

Because of the increasing use of zinc as an active and passive anticorrosion agent for steel, leading to constantly growing return rates of galvanized steel components, especially through the automotive industry, major Electric Arc Furnace (EAF) flue dust amounts with higher zinc contents will accumulate in future. Landfilling of steel plant flue dusts is no longer allowable for ecological reasons. These dusts are classified as hazardous by law. Waelz technology is safe and reliable. The range .of treatable feed materials has been extended by process modifications and state-of-the-art offgas technology. Waelz oxide, the product, is delivered to metal smelters for zinc production and the byproduct, Waelz slag, can be used in road construction. Despite the fact that Waelz technology is among the best available techniques (BAT), it is continuously being optimized further with respect to energy input, product and offgas quality in order to comply with the ever more stringent environmental regulations. However, if these flue-dusts are treated, the loops between the steel and the zinc industry can be closed by reusing recovered zinc which in tum leads to savings in natural resources and a more reasonable use of landfills.

Jan 1, 2000

By P. Aguirre

Recovery of zinc, copper and nickel from electroplating waste solutions was achieved 'by using a Pulsated Percolated Porous Electrode "3PE" reactor on a pilot plant scale. Intensity - potential curves were used to study the possibility of metal removal and to define the working potential range. The present study describes the use of the 3PE reactors in several electroplating industrial units for the decontamination of their effluents. These effluents were issued from different industrial solutions such as cyanide, sulfate, chloride and Watts baths. Using the stripping curves, deposition rates and electrical efficiencies were determined as function of the metal concentrations in these effluents. Their decontamination could be achieved to the level of few ppm of metals with reasonable current efficiencies. The recovery rates of zinc and copper were about 93 and 99 %, respectively. The. treated effluents contained less than 7 and 1 % of the initial contents of Zn and Cu, respec¬tively. This process allows the recycling of the recovered metals and leads to water saving.

Feb 13, 2014

By Kim McKnight

Dupont has successfully incorporated a Floatex Density Separator into its wet-gravity operations for the recovery of zircon from titanium tailings. Results indicate that the Floatex achieved a zircon recovery of approximately 95% while rejecting similar amounts of quartz and other gangue minerals. Additionally, a unit capacity approaching 16 tonnes/hr/m2 was achieved. Results also show that the alumino-silicates can be separated into other product streams that will further improve process economics and minimize waste material. The improved plant feed grade provided by the Floatex has allowed for either an increase in overall plant capacity and/or final product grade. This paper will present the findings from the in-plant study.

Jan 1, 1996

By Marcel Magnusson, Guozhu Ye, Pekka Vaananen, Yang Tian

The most used technology for recycling of spent alkaline batteries consists of crushing, magnetic separation and processing of the nonmagnetic fraction, black mass, using a rotary kiln. In the process only zinc is recovered and all manganese in the black mass is lost. According to the EU regulation for recycling of batteries, more than 50% of batteries should be recovered. To meet the demand, Swerea MEFOS has together with a major battery recycler IsoLogistics in Finland and Sweden developed technologies for efficient recovery of zinc and manganese aiming for >50% recovery. This paper will focus on a treatment process using a DC furnace to produce a ZnO- and a MnO-product. The process has been demonstrated in pilot scale, 1 ton/h. The major outcomes will be highlighted. Another approach by using thermal vacuum technology for distillation of zinc metal has also been demonstrated in laboratory scale which is also reported in this paper.

Mar 1, 2018

By P. Blonde

Recent analysis has suggested that a balanced recovery profile can improve flotation bank performance. Test work was conducted to test the balanced profile concept at the Penhorwood talc mine near Timmins, Ontario, Canada. Plant trials were devised to determine how to control the recovery profile and the resultant impact on grade and recovery in a rougher bank of four cells. Accompanying gas dispersion measurements revealed a maintenance issue with one cell that was corrected. By manipulating air and frother addition it was possible to bring the bank closer to a balanced recovery profile and the down-the-bank grade/recovery improved. Plant production showed an increased talc grade at similar yield with the balanced profile. The results provide justification for a long term plant trial.

Aug 1, 2013

By J. R. Parga

Bacís mining is a young enterprise in Mexico that produces a pyrite concentrate rich in gold and silver. When gold and silver are associated to sulfide minerals, pre-treament such as: roasting, pressure oxidation and bioleching, is required to decompose the sulphides and thereby expose the gold and silver particles to the cyanide solution. A novel method demonstrates that the oxidation and dissolution of gold and silver in alka-line cyanide solution can be conducted simultaneously in the same autoclave in less than 90 minutes with a recovery that exceeds 96%. Factors affecting recovery efficiency such as pH, leaching time in the reactor, temperature, particle diameter, pressure, % of NaCN and pulp density were investigated.

Jan 1, 2007

By C J. Greet, S Jacques

In most instances, the application of high-chrome grinding media results in an increase in the recovery of the valuable mineral(s). The authors have published data from a number of plant-based case studies, which indicate that it is not unreasonable to expect a recovery increase in the vicinity of 1.5 to 2.0 per cent for a copper ore. It is of interest to understand where the increase in recovery is coming from. That is, is the additional copper recovery the result of improved fine particle flotation or is it due to an improvement across all size fractions?This paper aims to answer this question. Laboratory flotation tests were completed using forged steel and a high-chrome alloy on a volcanogenic massive sulfide copper ore. The unsized data indicated that the application of high-chrome grinding media to this ore resulted in an improvement in both copper recovery and copper concentrate grade. A detailed kinetic analysis of both the copper sulfide and gangue minerals was completed that clearly shows that the change to a more inert grinding media produced significant increases in the flotation rate constants (both fast and slow) across all size fractions. It is also possible to observe that the change in pulp chemistry has resulted in a decrease in the flotation kinetics of the -20 micron pyrite, while the coarse pyrite recoveries have increased, presumably because of an increase in the flotation of the chalcopyrite/pyrite composite particles.CITATION:Greet, C J, Jacques, S and Kinal, J, 2014. Recovery-by-size kinetic analysis to determine where metallurgical improvements occur when converting to high-chrome grinding media, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 217–224 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By A. Fleming

The exploration process, like any other commercial activity, can only succeed if the objective of the exercise is clearly defined and persistently pursued. Successful exploration requires properties, funding, personnel and persistence. Many of us have years of experience in conducting exploration in our countries of residence. Conducting exploration in a foreign country, however, requires a number of significant other criteria.

Jan 1, 1997

By A G. L Pratt, M S. Kemp

BHP has used many innovative techniques when recruiting its workforce for the Cannington Project. Looking for a balance of experience and enthusiasm it was necessary to develop pre-selection tests to reduce the initial number of applicants to a manageable number for first interviews in Townsville. Success at this stage led to an applicant, and their spouse, to go through a second interview at the mine site. The full process from application to job offer took up to six months, but the results were felt to be worth the effort. The approach taken has resulted in a highly motivated and flexible workforce. This paper outlines the philosophies behind CanningtonÆs recruitment process, highlights some of the issues associated with the approach, and offers some measures of the outcomes.

Jan 1, 1998

By P. Conrad, S. Rosenthal

"Engineers remain in demand. Job opportunities in the United States still exceed the number of students graduating from college with degrees in Mining Engineering. Although enrollment is up for freshman studying Mining Engineering, many of those students will either change majors or not complete their degree, maintaining that deficit of available Mining Engineers. What can be done to ensure that enough Mining Engineers will graduate to fill the needs of the mining industry over the next ten to 20 years? The authors believe that this need can be met by recruiting students to Mining Engineering programs who are genuinely interested in working in the mining industry. With this in mind, Montana Tech conducted its first Mining Engineering camp in July 2014 to get junior and senior high school students interested in careers in the mining industry by showing them that Mining Engineering is both an exciting and rewarding career. This paper discusses What a Blast! The 2014 Montana Tech Mining Camp. INTRODUCTION The concept of summer camps for high school students is not new. For example, Missouri University of Science and Technology has offered their “Explosives Camp” for several years. A large percentage of attendees to these camps discover or confirm an interest in Mining Engineering and enroll in the school’s program. The Dean of the Montana Tech School of Mines and Engineering challenged department heads to develop and offer summer camps for prospective high school students to get a taste of engineering with the goal being to improve recruitment for each discipline. Mining Engineering embarked on the concept of a summer camp in 2013 with a concept to provide a week’s experience in Mining Engineering during the summer of 2014. What it takes to progress from concept to reality, with some of the learnings to be shared, follows."

Jan 1, 2015

By Joshua Hoffman

The recruitment and retention of future talent into the explosives industry is becoming increasingly important. Student chapters help with this effort but what are they doing and are there things they could learn from each other? This paper discusses the University of Kentucky Student Chapter's efforts to grow membership, retain its recruits, and integrate them into the explosives industry. Several social and professional events during which the students are able to meet and network with members of their future industry are introduced. The special relationship that has been fostered between the University of Kentucky and Missouri University of Science and Technology is discussed. Professional development initiatives which are critical for a student to become vested in the industry are shared in this paper. These opportunities which range from internships to research positions allow a person to get a better understanding of the explosives industry and find the niche that best suits them. Many of the student chapters are closely connected with engineering programs. While this makes sense and both entities benefit from these arrangements there is a trend of job placement primarily in the engineering industry. By providing these students with the chance to learn more about the explosives industry and get hands on experience more of these future engineers and professionals can be retained after their graduation.

Jan 1, 2013

By Henry Howe

W. E. RUDER, Schenectady, N. Y.-In 1913 I presented a paper before this society on Grain Growth, and at that time it seemed to me that the only explanation for grain growth was that of critical strain. I do not think I published the photographs at the time, but I made some experiments on the effect of stretching sheets of metal. This allowed for fairly accurate determinations of the amount of cold deformation, At the time I worked-with silicon steel because one could see the change in grain growth with the naked eye. I stretched about 10-samples from 0.5 per cent. to 10 per cent., and, after heating to 1,050° C., I found that the maximum grain growth occurred at about 2 ½ per cent. cold deformation. This I designated "the critical strain" for maximum grain growth. About a year ago I talked with Prof. Jeffries, who explained to me his ideas of grain growth. It occurred to me that it would be a very easy thing to check the strain hypothesis against the strain and temperature hypothesis, if we took a certain number of these strips, strained exactly alike and heated to different temperatures; in that case the maximum grain growth ought to appear at a different percentage of deformation for each temperature. These experiments showed that there was, as Mr. Jeffries shows in his present paper, a decrease in germinative temperature with increased cold deformation. The samples were stretched from ½ to 8 per cent. and heated for 10 hr. in hydrogen. Samples were introduced into a furnace previously heated to temperature. A maximum grain growth was obtained at 5 per cent. deformation, when heated to 750° C.; at 2 ½ per cent. when heated to 800' C.; at 1 1/4 per cent., if heated at 950°C.; and at 5/8 per cent.. when heated at 1,100° C. This shows very clearly that the germinative temperature decreases with the increase in cold deformation. The growth was very much more marked, however, at the high temperature, i.e., the grain grew more rapidly and attained a much larger size than at lower temperature. In considering the photographs (Fig. A) those along the lateral edges should be ignored because.

Jan 4, 1917

By George Langford

Introduction The manufacture of ductile beryllium is one of the most interesting problems confronting the metallurgist today, and one which becomes more acutely in need of resolution as the uses for beryllium increase. Beryllium belongs to the hexagonal group of metals along with zinc, magnesium, and cadmium. The melting point of the metal is about l,280°C. ± 5°C. Due to its brittleness, the metal's chief use is as an alloying agent in copper and iron. The very low absorption coefficient of beryllium for x-rays makes the metal ideal for x-ray windows, and, similarly, because of its low capture cross-section for neutrons, the metal holds a preferred position in the field of nuclear physics. Modern x-ray diffraction methods were responsible for explaining the mechanism whereby zinc metal, although brittle when cast, could be made ductile at room temperature. The diffraction patterns of zinc and magnesium indicated the importance of the parts played by recrystallization and preferred orientation in this mechanism. It was with this in mind that an Investigation into the recrystallization and preferred orientation of beryllium was undertaken. The investigation, after a series of experiments were conducted involving cold-working and annealing, yielded the recrystallization temperature curve for beryllium. Both the texture of preferred orientation and the effect of recrystallization on this texture when subjected to compressive stresses were also determined. W. A. Alexander, J. K. Swinton and L. M. Pidgeon, in their investigation on The Recrystallization Temperature of Beryllium (C.I.M., Trans., Vol. L, 1947, pp. 657-664), utilized the Brinell ball as a means of cold straining the metal. Sufficient strain was developed to estimate the recrystallization curve for the metal. However, in order to determine the lowest recrystallization curve, as well as to develop a preferred orientation structure, larger deformation than that possible with a Brinell ball was required. The plastic deformation of beryllium can be carried out at an elevated temperature above 700°C. Above 850°C., the metal is quite ductile and can be readily compressed or extruded.

Jan 1, 1948

By Douglas Glenn Stalheim

The uniformity of the final cross sectional microstructure and subsequent final mechanical properties and shape of structural steels is dependent on the type or types of recrystallization behaviors that are created. There are three main recrystallization behaviors that are the foundation of the metallurgy created during production. Alloy design and subsequent processing design strategy drive how much of each recrystallization behavior is created through the cross section of the product. Carbon manganese steels create only one basic behavior while the addition of microalloys, in particular niobium, can add two additional behaviors. The behaviors are intertwined with each other and build upon each other. The three behaviors are Type I, static recrystallization, Type II, no-recrystallization, and Type III, metadynamic/dynamic recrystallization. How much of each behavior is generated through the cross section through the production influences the final transformed microstructure and corresponding mechanical properties and shape performance. This paper will discuss the three behaviors, how they are generated, how to identify which behavior is occurring through modeling or actual mill data. Actual examples from production will be discussed.

Aug 16, 2017

By W. A. Anderson, R. F. Mehl

RECRYSTALLIZATION of cold-worked metals has long been known to proceed by a process of nucleation and growth.1 When a cold-worked metal is heated to a temperature at which recrystallization will ensue, nuclei of new grains, essentially strain-free, appear and grow. As the process proceeds, nuclei continue to appear and to grow, until the cold-worked matrix has been entirely consumed and recrystallization has been completed (Fig. I). Conducted isothermally, a measurement of the fraction of the matrix recrystallized plotted against time, yields an isothermal recrystallization curve, showing the time course of the recrystallization process (Fig. 2).2 Evidently, then, the rate of recrystallization is determined by the rate at which nuclei form and the rate at which they grow. The rate of nucleation N is the number of nuclei that form in unit time in unit volume of the unrecrystallized matrix, and the rate of growth G is the increase in radius of the recrystallized grain per unit time. In recent years attempts have been made to determine N and G as these vary with the well-recognized variables affecting recrystallization: time, temperature, degree of deformation, etc.' Such studies yield information that is more fundamental than that conveyed by the conventional recrystallization diagram,' since the rate of recrystallization is thus analyzed into its two component rates.2 Methods are now available by which N and G can be measured, and analytical expressions have been developed for the interrelationships among N, G, the isothermal recrystallization curve, and the final grain size, which greatly facilitate analysis.2-4 The application of these methods has been demonstrated recently for the recrystallization of silicon ferrite.2 Data on N and G in dependence upon the recognized recrystallization variables are, however, very fragmentary;* values of N and G have been determined for some metals, but the effect of temperature, which would yield the fundamentally important activation energies, has been too little studied. Thus far there has been no detailed study of the recrystallization of any one metal in terms of N and G over appreciable ranges of the variables time, temperature, degree of deformation, and original grain size. It is the purpose of the present paper to provide such a study, employing aluminum.

Jan 1, 1945

By Abu Syed H. Kabir, Mehdi Sanjari, Steve Yue, Jing Su, In-ho Jung

AZ31 magnesium alloy sheets were produced by high speed rolling (HSR) at 1000 m/min at a low temperature of 100 ?. A high reduction of 72% can be achieved in single pass. At the reduction of 30%, the microstructure was covered by shear bands and twins. When the reduction was increased to 49%, dynamic recrystallization (DRX) was clearly observed in the vicinity of shear bands and twins and the full recrystallization was seen at a reduction of 72%. In order to study the static recrystallization (SRX) behavior on the heavily twinned structure, annealing was then carried out at 200 ? on the as-rolled specimens at the reduction of 30% for different times. Static recrystallized grains were also firstly observed on shear bands and twins after 45 s and the microstructure was mostly fully recrystallized after 1 h annealing with a few retained large elongated un-recrystallized grains. Texture weakening was found during annealing on the heavily twinned specimens by SRX, but not during high speed rolling by DRX. In the present study, effect of DRX and SRX on microstructure and texture evolutions during rolling and annealing were compared.

Jan 1, 2015