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By Y Peng, D Wannas

In the fine particle flotation technologies being developed today the fine hydrophilic (gangue) particles are usually well dispersed. These highly dispersed fine particles can be recovered into the flotation froth product by mechanical entrainment. Flocculation of hydrophilic particles caused by polymer depressants could potentially reduce the mechanical entrainment of these particles. This paper reports testwork completed on fine particles of several solids, iron oxide, hydroxylapatite, galena and sphalerite, as well as on a relatively coarse quartz sample (-75+38 ¦m). Dodecylamine was used as a collector for the quartz, and several dispersants and polymer depressants, including sodium silicate, sodium metaphosphate, zinc sulfate, potassium dichromate, corn starch, corn dextrin and carboxymethyl celluloses (with molecular weights of both 700 000 and 80 000) were used as flotation modifiers. The major part of the testwork involved flotation tests in a 200 ml flotation column. Both water and solid recoveries were recorded. The degree of flocculation and dispersion was determined by settling tests in 250 ml graduated cylinders. It was observed that flocculation of the fine hydrophilic particles significantly reduced their mechanical entrainment, while dispersion severely aggravated it. Thus, in the flotation separation of artificial mixtures of the -75+38 ¦m quartz and fine iron oxide or hydroxylapatite, polymer depressants that caused flocculation were found to perform better than the ones that did not cause flocculation.

Jan 1, 2005

By S. N. Sahu

Attempt was taken in this study to explore the misplacement phenomena in binary mixture in solid-liquid fluidisation system. The binary mixtures of hematite and quartz particles at different sizes were taken. The closed size range particles were taken to minimize the size and shape effect in fluidization. As both the minerals have appreciable density difference, the separation of both minerals with closed size range has an advantage. The experiments were conducted in different permutation and combination of different sizes of binary mixture to observe the fluidization phenomena. The samples were taken at different heights in fluidized zones and analyzed the distribution of particles of both minerals. The fluidization characteristics were evaluated with respect to operating and design parameters. It has been observed that when the terminal velocity of quartz and hematite particles is same or near to each other, then misplacement is significant. In general, the segregation index value is near to one, complete segregation takes place whereas this value is near to zero, complete mixing takes place. The experimental data were used to find out the segregation index for different size ratios of quartz and hematite particles and the values are within 0-1. When the size ratio is 1 or less, complete segregation takes place whereas this ratio is within 1.0-1.4, partial mixing takes place. Similarly, when the size ratio is within 1.4-2.0, complete mixing takes place whereas this ratio is within 2.0-4.6, then it moves towards complete segregation in inversion manner. Keywords: particulate fluidization, misplacement zone, bed expansion, terminal velocity, mixing characteristics, segregation index

Sep 1, 2012

By Kai Tang, Casper van der Eijk

Natural gas has been used as reductant in the production of iron for several decades. Recently, the use of natural gas as reductant for other metals has been drawing attention because of the low price of natural gas, as well as the reduction of CO2 emissions compared to the use of coke and coal. In this work, the reduction of a mixture of Ti- and Ni-oxides by natural gas has been studied. Within the Ni-Ti system, the intermetallic compound Ni3Ti is thermodynamically the most stable one. Therefore, powders of Ni-oxide and Ti-oxides were mixed in an atomic ratio of three to one and subsequently pelletized. Reduction was performed in a TGA furnace at constant temperature with varying reducing gas atmospheres. In a natural gas containing atmosphere, the Ni-oxide was easily reduced to metallic nickel while the Ti was reduced to Ti-oxycarbides or Ti-oxynitride when nitrogen was present. Depending on the process parameters, several percent of Ti was dissolved in the nickel-based solid phase.

Jan 1, 2014

By G. Castillo, J. Mortensen

"INTRODUCTION Molybdenite is typically produced as a co-product in the copper ore flotation process. At the Rio Tinto Kennecott Concentrator (RTKC) in Copperton, Utah, the molybdenite is initially floated with copper sulfides and other value minerals producing a Cu-Mo concentrate. This is then separated in the molybdenum plant by depressing copper sulfides and pyrite and floating only molybdenite. The molybdenum plant in RTKC comprises the rougher circuit and several stages of cleaning to achieve a certain grade requirement of Mo. The rougher circuit is where the first stage of separation occurs. Cu sulfides and pyrite are depressed in the rougher circuit by adding NaSH under nitrogen and in the cleaner circuit by adding NaSH under air. The depression of Cu sulfides (and pyrite) by NaSH is related to the redox activity1. It is important therefore to maintain a reducing potential in the circuit in order to achieve effective Cu-Mo separation. If the rougher circuit is under air, like RTKC’s molybdenum cleaner circuits, it is harder to maintain the target redox potential because NaSH oxidizes rapidly in the presence of air thereby increasing NaSH consumption significantly. CU-MO SEPARATION AND ROLE OF PULP POTENTIAL The collector adsorption on copper sulfide minerals is through an electrochemical mechanism2. The collector changes the surface chemistry of the Cu mineral allowing it to float. Molybdenite, or MoS2, on the other hand, floats readily in the presence of a frother as it is naturally hydrophobic. Usually, hydrocarbon oil extenders such as diesel or burner oil are added to enhance Mo recovery. In order to effectively separate Cu from Mo, the collector complex on the copper surface needs to be destabilized or desorbed using a reducing agent such as NaSH or Nokes. As long as the circuit is under highly reducing conditions, the collector remains detached from the sulfide mineral surface allowing Cu sulfide depression. Therefore, it is important to measure the oxidation-reduction potential (ORP) continually and maintain the reducing condition with addition of NaSH. For a given collector each mineral will have a characteristic potential or electrochemical window for flotation to occur3, therefore, it is necessary to reduce the potential outside of this window in order to effectively separate Cu and Fe sulfides from MoS2 minerals2. In RTKC plant, the target reducing condition is between -450 to -550 mV to effectively destabilize the collector and depress Cu and Fe minerals. Typically the dosage of NaSH used in the molybdenum plant could range from 6 to 30 gallons/min (gpm). The high dosage of NaSH could pose risk of H2S exposure. RTKC wanted to evaluate alternatives to NaSH in order to reduce its consumption and minimize risk of H2S gas generation."

Jan 1, 2016

By N. A. Ziegler

THE chief difficulty in determining oxygen in steels is its tendency to form a variety of compounds. Almost every element, found as an ingredient in steels, maybe expected to be present as an oxide. Some of these oxides have widely differing properties, and consequently behave differently when attempts are made to reduce them by the vacuum fusion method. As I pointed out in a paper published in the Transactions of the A.S.S.T., Vol. 20, No. 1, many experimenters are spending considerable time and effort in attempting to deter¬mine the degree of completeness of the above reactions, and hold different opinions on the matter. In studying this subject the following table, taken from Hodgman and Lange's "Handbook of Chemistry and Physics" may be used as a guide.

Jan 1, 1933

By Girley Ferreira Rodrigues, Crocce Denise Romano Espinosa, Victor Bridi Telles, Eduardo Junca, Jorge Alberto Soares Tenorio

"Steel sector is responsible for the generation of solid waste, liquid and gaseous effluents. The Solid waste are mainly composed of slag, dust, sludge and scrap. The industry generates approximately 650kg of solid waste per tonne of steel. Approximately 10% of this waste is in the form of dust and mud. The basic oxygen furnace dust is a waste generate by steel sector. Each tonne of produced steel generates 10 to 20 kg dust. Thus, the aim of this paper is study the reduction of pellets made with BOF dust using hydrogen and study kinetic during the reduction. The tests were performed in a netzsch thermobalance to obtain the data of lost mass. This loss mass is coming from iron oxides present in the BOF dust.IntroductionThe generation of solid waste is a problem for many companies in the steel sector. The main solid wastes generated are slag, dust, sludge and scrap [1]. Beyond solid waste liquid and gaseous effluents are also generated.The basic oxygen furnace is responsible for 60% of all steel produced. This sector is the second largest generator of solid waste from an integrated steel mill, contributing with 27% of solid waste generated in a plant ( 5-7 million tons of waste generated annually worldwide) [2,3,4]."

Jan 1, 2013

By Alain Denis, Marcelo Curtes Martins, Jeferson Rocio de Oliveira

In this work we present a study of optimization of a new inhibitor for turbulence pickling line. The efficiency of inhibition was measured and the weight of loss was evaluated in four different materials to optimize the dosage of the inhibitor. In seven months we had 8.7% of reduction in pickling losses.

Oct 1, 2019

By R. G. Reddy

Solid state reduction of roast movat chromite ore with carbon was carried out as a function of C/FeO ratio and temperature in the range 800°C to 900°C by thermogravimetry analysis (TGA). A two stage mechanism, (1) the reduction of FeO present in Roast Movat with carbon monoxide; and (2) the regeneration of CO by the oxidation of carbon with CO2 was proposed. The rate controlling step is the carbon oxidation reaction. A kinetic equation, that of random nucleation, was proposed. The activation energy for the reduction was determined to be 55800 J/mole and is compared to those activation energies determined for other chromite ores.

Jan 1, 1998

By Paulo Rodrigues dos Santos Junior, Luciano Passos de Jesus, Vagno Dordenoni Beltrame, Vinicius Antonio Ramos Pin

Faced with an increasingly demanding and selective market, a thorough analysis of each step of the processes is required in order to achieve high levels of performance. In addition to a major factor of importance in the rolling process, due to its high price, the rolls represent one of the main items in the cost of hot coils production. Using the 6 sigma methodology, there were opportunities for improvement in the grinding process, fatigue analysis, improvement in NDT in rolls, as well as means to guarantee operational stability, which allowed the reduction of roll’s consumption and consequently the cost of production.

Oct 11, 2019

By James T. Skoch

With the ongoing pressure on the secondary aluminum business to limit the amount of waste generated from processing aluminum dross, it becomes very advantageous to preprocess the dross to reduce waste. The advantage of preprocessing is that it significantly reduces the oxides and salt cake generated when melted. Various products can be produced from the oxides for the steel industry. The following paper will demonstrate that removal of oxide fines before melting will result in large volumes of material not being landfilled. We will show that the end result of this technology is to significantly reduce the amount of salt cake sent to a landfill while maximizing the recyclability of the aluminum dross.

Jan 1, 1995

By Nitin Bhavsar, Kaushik Vakil, Lakshmikanth Reddy, Sanjay Sarkar, Tathavadkar. Vilas, Bhavin Desai, Raghavendra Adiga

Gold and platinum group metals (PGM) do not dissolve in sulfate electrolyte from anode during electro-refining of primary copper. The PGM form solid ‘slimes’ which accumulates at bottom of the electrolytic cell. Typically, 8 to 10 ppm silver is present in copper cathodes, which is equivalent to almost 2% of silver loss during electro-refining. The silver can be cemented with cathode copper as soon as it is dissolved into the electrolyte from anode or during entrapment of slime particles in cathode. Over a period of time, the concentrates grade has deteriorated and change in type & amount of impurities in concentrate has resulted in higher silver loss during refining process. Therefore, an in-depth investigation was carried out in both fire- and electro-refining processes to understand the root causes of higher silver loss in copper cathodes. The detailed characterization and the plant data analysis were carried out. The results of study revealed that higher silver loss in 3rd crop cathodes as compared to 1st and 2nd crop cathodes from same anode. In anode silver was present in two forms, dissolved in copper (solid solution) and in slime phases such as Cu2-xAgxSeTe. SEM-EDX study of anode cross section confirmed higher silver and oxygen content in central region (core) of anode as compared that in both air and mold sides. This is due to non-uniform cooling of anode which was confirmed by the solidification modeling. Higher concentration of oxygen & silver at core of anode rised Ag+ concentration in electrolyte and slime particles during 3rd crop. The results of study were used to optimize the anode cooling process and also electrolyte chemistry to reduce the silver loss. The details of study carried out are discussed in this paper using the results of modeling, characterization and experimental studies. INTRODUCTION In the electrolytic refining of copper, fire refined copper anodes are used as raw material. Anodes contains copper of the range 99.5 to 99.6%, rest being the impurities. Hence, the purpose of the refining is (1) to remove the impurities so that final cathode conforms to the LME specifications and also (2) to recover the precious metal from the anode copper. When anode is dissolved, most of the impurities reports to the anode slime settled at the bottom of the cell, and rest dissolves in the electrolyte. Dissolved impurities remains in electrolyte and are removed during electrolyte recycling. However, sometime dissolved impurities and slime particles get entrapped in cathode due to disturbances in operational conditions. Metals dissolving in the electrolyte are the elements such as Ni, Co, Fe, Zn. The electrode potential of As, Sb and Bi being close to that of copper, these elements partly dissolve in the electrolyte. Noble metals like Ag, Au, Pt and Pd are generally insoluble and are thus expected to report to the anode slime. A small amount of the sliver content from the anode is dissolved in the electrolyte. Because the dissolved silver electroplates on the cathode at a smaller applied potential than copper, the cathode typically contains up to 8 ppm of silver. This is referred to as ‘silver loss’ in cathode (Cooper, 1987). Fortunately, silver is a rather benign impurity in copper due to its electrical conductivity being higher than copper. However, higher silver loss in cathode is loss of revenue for Copper smelter due to significant difference in their LME price.

Jan 1, 2019

By D. F. Rodríguez-Pérez, J. Salinas-Reyes, Luis R. Salazar-Garza, C. A. Gómez-De-La-Garza

The Pickling Line Tandem Cold Mill (PLTCM) from Ternium Pesquería started in 2013. It is a line with 5 stands, 6 high; focused mainly on the exposed automotive market, with a wide spread of products with high quality requirements. In addition the operational continuity is very important, for this, one of the greatest challenges is to ensure operational discipline, the order of production, the quality of the input (hot band), operational interruptions, equipment failure, breakage of strip in the mill, among others. In relation to this, it has a strong impact on productivity, customer compliance, damage to equipment, rolls, safety, quality, reprocessing among others. Here is present the results obtained in the project "decrease of strip breaks" which focused on several fronts, discipline in the order of production, previous review of raw material in surface and dimensional defects with automatic inspection equipment in the hot mill, as well as in PLTCM, generation of logic in the redundant systems of alerts and prevention to avoid or minimize strip breaks that were high impact in the past. All these multidisciplinary actions led as a whole to a significant improvement in the performance indicators of the PLTCM, in productivity, compliance, reprocessing and quality in the cold rolled mill.

Oct 1, 2019

By G. Tairova, M. Murchie, B. Esford, E. Lam

"The objective of this project is to investigate methods to lower the sulphate concentrations in the mill effluent. Currently, the concentration of sulphate in mill effluent is approximately 2 g/L. The high concentration of sulphate ion in the effluent has the potential to become a regulatory issue. The target sulphate concentration in mill effluent for this work was less than 500 mg/L. The pilot studies, using sulphate precipitation, were carried out at the mill. The results of the sulphate precipitation pilot study, using calcium hydroxide and sodium aluminate, indicated that:• The sulphate concentrations in effluent could be reduced to less than 500 mg/L.• The concentrations of most other elements of concern, such as selenium, arsenic, cobalt, nickel and vanadium, were also reduced.INTRODUCTIONHistorically, the concentration of sulphate, SO4 2-, in water has not generally been subject to regulation. However, with the increasing global consumption of water, stricter regulations on sulphate quantity may be imposed. Sulphate is a concern in process waters as it forms scale on process equipment and leads to operational problems. High sulphate concentrations may result in adverse health effects. The taste theshhold for the most sulphate salts in drinking water ranges from 250 to 500 mg/L.A literature search and review to identify methods to reduce sulphate concentration in the mill effluent was carried out. A number of methods were selected and tested in the lab. The experimental results indicated that the precipitation methods, using calcium hydroxide and aluminum compounds, barium compounds, as well as the ion exchange and the membrane methods, were effective for the removal of sulphate to below the required limits. Some other elements, such as vanadium, nickel, cobalt, selenium and molybdenum, were also removed.The process, using calcium hydroxide and aluminum compound for sulphate precipitation, similar to the Cost Effective Sulphate Removal (CESR), also known as “Walhalla” process, described in the Montana Tech report (“Demonstration Of Sulfate Removal” 1999), was selected for further consideration [1]. In the CESR process, the water is treated with lime for precipitation of gypsum, followed by the reaction with a proprietary aluminum compound for removal of a residual sulphate. The final pH adjustment is carried out using carbon dioxide. Results of a preliminary cost estimate indicated that the removal of sulphate using calcium hydroxide and aluminum compound was the preferred method of treatment, considering its low cost, availability of chemicals and minimal changes to the existing plant circuit."

Jan 1, 2012

By P. R. Taylor

A cyclone reactor system for the partial reduction and melting of taconite concentrate fines has been engineered, designed and operated. A non-transferred arc plasma torch was employed as a heat source. Taconite fines, carbon monoxide, and carbon dioxide were fed axially into the reactor, while the plasma gas was introduced tangentially into the cyclone. The average reactor temperature was maintained at above 1673 K (1400 C), and reduction experiments were performed under various conditions. The influence of the following parameters on the reduction of taconite was investigated: carbon monoxide to carbon dioxide inlet feed ratio, carbon monoxide inlet partial pressure, and average reactor temperature. The interactions of the graphite lining with carbon dioxide and taconite were also studied.

Jan 1, 1993

By Robert Peretti, Antonio Zucca, Andrea Manni, Silvia Serranti, Paolo Massacci, Marcello Ghiani

"This research study aims to identify the best way of processing colemanite concentrates, which is sometimes characterised by a high content of As sulphides, finely disseminated in the matrix of the boron mineral.Scanning Electron Microscopy analyses have been carried out to identify all the mineralogical constituents and to evaluate their distribution, frequency and mutual relationships.Colemanite concentrates are mainly used by chemical plants producing boric acid and gypsum. A high As content is unacceptable for further use of tailings coming from the leaching process and is very dangerous if the tailings are released into the environment.Grinding tests were conducted under dry and wet conditions in order to assess how As sulphide minerals are released from colemanite minerals.Some of the difficulties involved in obtaining selective liberation of As sulphides from colemanite minerals were overcome, although a certain decrease in As grade in the higher size classes was registered.All comminution products have been analysed by SEM, monitoring the degree of liberation of the mineralogical constituents.Flotation tests have been carried out, following different comminution flow sheets and adopting different modulating conditions in order to evaluate the influence of the following parameters:- collector concentration versus contaminants concentration (As minerals) in the froths;- kind and quantity of the frothing agent to maximise mineral recovery in the froths;- kind and quantity of the modulating agents to maximise the selectivity of the process;- conditioning modalities in order to obtain a suitable dispersion of fines and avoid segregation of Asbearing particles together with colemanite ones;- solid/liquid ratio of the pulp to minimise the water flow into the plant.Information obtained from SEM analysis has been adopted to evaluate segregation phenomena in pulp and in flotation products."

Jan 1, 2003

By Liangying Wen, Feng Xia, Chenguang Bai

"The situation of the Ti-V-Magnetite samples reduced with microwave has been investigated in laboratory. Firstly, the paper focuses on the heating behaviors of vanadium-titanium magnetite and characteristics of carbothermic reduction of V-Ti-magnetite in the microwave field. The effect of concentrate's size, quality on heating behaviors and reduction processes were researched. Results show that microwave heating may be a new heating resource replace of carbonic combustion reaction in reducing reaction. When the allocation of carbon is (16.7-30)%, carbothermic reduction of V-Ti-magnetite in the microwave field can proceed; with the increasing of carbon mixed, the metallization rate increases; and Fe, V can be reduced from their oxides in the microwave field; Titanic low oxide can be reduced from TiO2.1. IntroductionThe resource of Ti-V-Magnetite is abundant in the western area of Panzhihua in China, so far a mineral deposit of 4.64 billion tons have been proved up, it contains 14.75 million tons of V2O S which accounted for 87% of the vanadium and 5.93 hundred million tons of TiO2 accounted for 94% of the titanium resource respectively in China. The previous study proved that the major composition of mineral of the Ti-V-magnetite are Ti-magnetite, limonite, iron spinel, magnesium spinel etc, and the main elements of the Ti-V-magnetite in this area are Fe, Ti, V, Cr, Co, Ni, Ga, Sc etc[1] Due to the restrict of the BF-BOF process technical, during the smelting of the iron, the level of extracting the vanadium, titanium as well as other metal elements is limited. This results serious wasting of resources. To develop a new reduction process of Ti-V-magnetite is on the agenda, the microwave assistant reduction could meets this need, based on its characteristic of easy controlling of heating rate. To make use of the microwave energy to substitute the released heat sources of carbon combustion with air, use the solid phase state reduction at a relative lower temperature, make the beneficial element in Ti-V-magnetite transferred into the metal phase, then separated from the impurity. It is well worth to point out that once the microwave based reduction method has its industrial scale, it will take an outstanding position by its less release of carbon dioxide. This new environment-friendly process will play a vital role in the development of social industry and economy."

Jan 1, 2008

Reduction of titania and ilmenite ores by Cf4-H2-Ar gas mixture was investigated in a laboratory fixed bed reactor. Titania was reduced to titanium oxycarbide in the temperature range of 12OO-1500°C. At 1400-15000C, the extent of reduction of titania to titanium oxycarbide achieved more than 85% in 90 min. Optimum conditions for titanium oxycarbide synthesis by reduction of titania include temperature in the range of 1300-1450°C, methane content 8 vol% and hydrogen content above 35 vol%. Ilmenite ore was reduced by Cf4-HrAr gas mixture to metallic iron and titanium oxycarbide. Metallic iron catalyzed methane cracking and solid carbon deposition. Titanium oxycarbide formed at temperatures as low as 950°C. The optimum temperature for reduction of ilmenite is 1200°C and the optimum methane content is 8 vol%. Increase in hydrogen content increased both rate and extent of reduction. With 5 vol% CH4-75 vol% Hr20 vol% Ar gas mixture, the reduction of ilmenite completed in 60 min. Reduction of titanium oxides to oxycarbide with following chlorination may be an efficient alternative technology for processing of titanium minerals.

Jan 1, 2001

By D. Sanguinetti, A. Consigny, M. Nodwell

"Alkali precipitation of dissolved metals is an inexpensive but non-selective means of treating mine wastewater. Alternatively, sulphide precipitation can treat to below parts-per-million concentrations while selectively recovering valuable metals. While technically feasible, sulphide treatment of dilute waste streams increases the size and cost of the plant relative to the metals loading. Ion exchange has been applied at two separate sites to pre-concentrate nickel containing wastewater prior to recovery in smaller and more cost effective sulphide precipitation circuits. The result is a dual-circuit system that can maintain high selectivity and reduce overall facility cost while meeting strict effluent regulations.INTRODUCTIONAlkali precipitation using lime is the most common method of treating mining effluents for dissolved metals removal. This method is generally sufficient for waste streams containing mixed metals of little value, and for meeting modest metal concentration limits in the final effluent. Due to the non-selective nature of the lime process, the produced metal hydroxide sludge is of little value. All metals are removed together in a sludge product which cannot be re-processed for further value recovery.By contrast, sulphide precipitation can be used to selectively remove and recover valuable base metals (such as copper, zinc, nickel and cobalt), since the sulphide will preferentially target these metals without reacting with less valuable metals (such as iron and aluminum). The low solubility of the metal sulphide solids also supports the removal of base metals to lower concentrations than can be achieved with alkali precipitation in addition to other benefits discussed more fully in a prior paper (Bratty, Lawrence, Kratochvil & Marchant, 2006). The corollary to this solubility feature is that sulphide precipitation can function on influent streams containing low (< 10 mg/L) metals concentrations to meet very low parts-perbillion final effluent concentrations. Reagent overdosing is also minimized when compared to alkali precipitation."

Jan 1, 2012

By Zhao Hengxian

We studied the phase diagram of Na3AlFe-ZrO system, reduction of ZrO2 by aluminium and electrochemical behaviours of ZrO2 in the system. The results show that Na3ALF6-ZrO2 system is a simle eutectic one, that the velocity of reduction of ZrO2 in the system is rapid al 960&apos;C and that the Zr content in the alloy abtained can reach as high as 2.5wt%. Potential scanning shows that there exist new current peaks on the potential scanning plats except for the cuurent peaks corresponding to the oxidation of aluminium. The method of making Al-Zr alloy in our paper has advantages over the traditional method of mixing metals.

Jan 1, 1992

By Yoon-Bong Hahn

A mathematical model has been developed to analyze and predict the reduction process of iron ore particles in a two-stage fluidized bed system. This model includes the effect of particle degradation to elucidate its effect on reduction of iron oxides. Although the particle degradation is dependent on kind of iron ores, it was found that eighty to ninety percent of overall degradation is occurred in the prereduction stage mainly due to thermal stress and volume expansion. The degradation of particles in the?final stage is not much, but is mainly due to interparticle collision and abrasion. It was also found that to obtain a target reduction degree, it is of great importance to control the bed temperature and the residence time of paarticles in R1 rather than in R2. Optimum range of residence time was 15-20 minutes in the prereduction stage; 30-35 minutes in the final reduction stage.

Jan 1, 1996