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By R. R. Rogers

ABSTRACT The experiments described demonstrate that crude commercial lithium containing in the order of 0.5 per cent sodium can be refined, the resulting metal containing as low as 0.001 per cent sodium. During the process, the metal is vaporized and condensed at a gauge pressure of less than 0.04 micron. Considerable operating data and a detailed description of the experimental equipment are included. INTRODUCTION DUE TO THE unusual properties of lithium metal, its use is likely to increase considerably during the next few years (1, 2). This is of particular interest to Canadians because there are important deposits of lithium-containing minerals, especially spodumene, in Canada and it is hoped that lithium compounds and lithium metal will be produced from these deposits in the fairly near future. In order to assist in the development of this industry, the Mines Branch of the Department of Mines and Technical Surveys has initiated a programme of research in lithium metallurgy. In 1948, a paper (4) was published on methods of producing lithium metal and its alloys. Data on the corrosion resistance of some lithium alloys were included. In 1949, a paper (3) was published which showed that the addition of a small percentage of lithium to zinc anodes used for cathodic protection will improve their usefulness under certain circumstances.

Jan 1, 1951

By Rees D. Groves

Cement copper is ordinarily converted to marketable metal by processing in a conventional smelter and refinery. Because of rapidly increasing cement copper production and limited excess smelting capacity, other techniques were investigated for preparing marketable copper products. One route was to make copper powder for industrial use. The process scheme employed flotation for rejecting the bulk of the impurities, acid leaching to remove residual iron and aluminum, reduction sintering to eliminate oxygen, and grinding to obtain powder. Another route was to sinter the floated and leached copper into the form of anodes and electrolyze these to yield refined copper cathodes. At a current density of 30 amperes per square foot, power consumption for electrorefining was 185 kwhr per ton of copper. The feasibility of preparing commercial-size anodes by sintering is still to be assessed.

Jan 1, 1970

By Senanayake G

A sample of crude copper powder produced by the CLEAR Process was refined by dissolution and recovery in sulfate media using the Parker Process. The Parker Process offers an alternative method of copper recovery to electrorefining and allows a range of Eh and pH conditions to be used to provide further discrimination of impurities. High purity copper powder was recovered by the Parker Process even in the presence of added impurities when the Eh and pH was maintained near constant throughout the refining step.

Jan 1, 1984

By P. Fossi

This report describes a pilot-scale study of a hydrometallurgical process to treat high-grade nickel matte or a nickel-cobalt sulphide precipitate to produce high-purity electrolytic nickel. The first step of the process is the oxidative leaching of the nickel-bearing material by nitric acid; the nitrous gases generated during leaching are reconverted to nitric acid. The crude nickel sulphate nitrate solution is purified and is then subjected to a denitrification step. Nitrate separation is effected either by the crystallization of nickel sulphate or by precipitation of basic nickel carbonate. The electrolyte is prepared from the nitrate-free material and nickel is then recovered by electrolysis of the sulphate solution using insoluble anodes. Some technical and economic problems encountered with this processing route are discussed and the method is compared to the "all-chloride" process developed by Société Le Nickel.

Jan 1, 1977

By R. F. Pearce

The paper in based on laboratory and pilot plant investigations which led to the development of a series of processes for production of high purity metals from nickel-copper-cobalt mattes of a wide range of composition. The selection of ammonia pressure leaching or acid pressure leaching for various mattes is discussed. This is followed by discussion of various methods for leach solution purification and metal separation. The metals of high purity are produced by reduction with hydrogen from purified solutions. Examples are given of complete flowsheets for a number of mattes. Drawing upon those examples, general principles for the selection of the most suitable treatment process for particular material are outlined. Under certain circumstances, those processes may replace part of the pyrometallurgical treatment and all of the electrolytic refining steps which are customary in the treatment of nickel-copper-cobalt mattes.

Jan 1, 1959

By Harold L. Hinds

The refining of precious metals from steel wool cathoodes is completed by one of two methods: 1) By direct fire smelting or: 2) Acid treatment of the cathodes to dissolve the steel wool and then followed by fire smelting. To further the refining of the cathodes, the Miller Process and the Wohlwill Process are used.

Jan 1, 1981

By S. Hartman

The Escalante Silver Mine in Southwest Utah produces an average of 71.000 kg (2.3 million troy ounces) of silver dore annually. Precipitates from a cyanide leach circuit are treated by either acid leaching prior to fusion or a direct fusion with nitre. Process development, plant experience, and a comparison of both methods will be discussed. Plant experience from the custom treatment of a gold/silver precipitate containing matte producing elements will also be covered.

Jan 1, 1989

By A Rantala, J Timperi and J Kaartinen, T Maksimainen, O Haavisto

"X-ray fluorescence (XRF) is the most common technique used for online slurry assaying in base metal flotation applications. Typically, assays from feed, concentrate and tailings slurries are used to monitor and control the flotation circuit, with possible additional sampling locations in other main slurry flows inside the circuit. The elemental content detection from the XRF spectrum is relatively straightforward as the spectrum contains element-specific peaks whose height corresponds to the element concentration in the sample. However, centralised XRF analysers measure the elemental concentrations line-by-line, which may increase the sampling interval for an individual line and cause unnecessary response delays, especially in large flotation plants. Reflectance spectroscopy is an emerging technique that can be used to obtain more frequent measurements from slurries. The measurement is based on the mineral-specific absorbance of light in the visible and near-infrared (VNIR) wavelength range. Due to this relatively inexpensive and simple measurement system, it is possible to conduct the measurement simultaneously in several slurry lines. However, the information contained in the VNIR spectra is more difficult to interpret as concentrations of all the minerals in the sample contribute to the measured spectrum and changes in solids content, particle size and mineralogy disturb the elemental content estimation. Therefore, frequent calibration of the measurement is required. This study presents the application of combined reflectance spectrum and XRF measurements for rapid online slurry assaying in a copper-nickel flotation plant. The XRF assays are utilised as calibration samples for the reflectance spectrum measurement, keeping the calibration model up-to-date. The rapid reflectance spectrum analysis is then used to provide an almost continuous estimate of the slurry contents, enabling further improved process monitoring and control.Citation:Haavisto, O, Maksimainen, T, Rantala, A, Timperi, J and Kaartinen, J, 2016. Reflectance Spectroscopy with X-ray Fluorescence for Rapid Online Assaying in a Copper-nickel Flotation Plant, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 85–92 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By Olli Haavisto, Juha Timperi

"Accurate on-line assays of mineral slurries are the basis for effective operation of flotation circuits. Typically the elemental content measurements are obtained by an X-ray fluorescence (XRF) analyzer, which samples the process lines and performs the analysis concurrently line-by-line. For a more frequent measurement of each slurry line the XRF measurements can be complemented with reflectance spectrum information. In reflectance spectroscopy the absorbance properties of the slurry in the visible and near-infrared wavelength range are analyzed. The advantage of reflectance spectroscopy is that measurements can be obtained quickly and simultaneously from several slurry lines. However, since the shape of the spectrum is only indirectly affected by the slurry elemental contents, frequent calibration of the measurement against the XRF analyzer is necessary. This study elaborates the combination of reflectance spectrum analysis with XRF. Results of laboratory tests for different slurries are presented and the operation of the system in a copper-zinc flotation plant is demonstrated.IntroductionElemental analysis of mineral flotation slurries is the most important factor in evaluating the performance of concentration processes. Timely on-line assays are also used as the basis for controlling the circuits and ensuring that the grade and recovery targets are reached. X-ray fluorescence (XRF) is the dominant technology in on-line elemental slurry analysis, and typically centralized XRF analyzers are used. The advantage of a centralized analyzer is that one measurement probe can be used to acquire the data from several slurry lines. This reduces the overall operating cost of the system when compared to distributed analyzer system design with several measurement probes requiring maintenance and spare parts. Slurry samplers are installed in the interesting process flows and representative sample flows are brought to the analyzer, where the slurry is further sampled and measured consecutively by the XRF analyzer. Due to the centralized structure of the analyzers and consecutively measurement of the sampling lines the sampling interval per slurry line can be relatively long. In larger concentration plants with several sampling lines a typical assay interval is in the range of 10-20 minutes."

Jan 1, 2016

By Susanne Pignolet-Brandom

Flash smelting products of a copper sulfide concentrate collected at successive levels in an experimental reactor have been studied by reflected light microscopy, scanning electron microscope - energy dispersive analysis and electron nicroprobe analysis. Chalcopyrite, intermediate solid solution, bornite, chalcocite, metallic copper, magnetite, iron-copper spinel, pyrrhotite, hematite, delafossite and cuprite have been identified in the product samples. The detailed reflected light microscopy study of these phases and their abundance in the samples has resulted in the identification of the series of reactions during flash smelting.

Jan 1, 1985

By James W. Cooksley

This report concerns a seismic geophysical exploration program which was conducted 3 miles southeast of the Carlin Mine, in Lander County, about 18 miles north of Carlin, Nevada. A twelve-fold reflection seismic line was executed over a one-mile traverse in section 32, Township 35 North, Range 51 East. This study is part of an exploration pro- gram directed toward finding Carlin-type gold deposits which are concealed under younger alluvium and volcanics. The exploration objectives of this program are as follows: 1) measure the thickness of the younger, sedimentary and volcanic deposits which overlie the "productive rock sequence", 2) delineate the Roberts Mountains thrust fault, 3) investigate the origin of the geochemical anomalies present in the western portion of section 32.

Jan 1, 1985

Scheduling mine development and underground construction has been the bane of most mine managersÆ lives at one time or another. Even though scheduling software has developed significantly over the last 20 years, mining projects continue to take far longer than expected to complete. It would appear that possession of a gleaming 1000 activity bar chart generated by the latest project management software and plotted in multiple colours offers no guarantee at all that any of those 1000 activities will be completed on time, let alone the project as a whole. The author has earned his æmasters in disastersÆ with more than one project running over time and budget. This paper describes some of his experiences in scheduling major mine development and construction projects and the lessons he has learnt along the way. In particular, the paper examines a range of key issues that mine schedulers must take into account when planning mining projects. The paper also examines the development of scheduling software and particular advance rates used in scheduling mine development projects in Australia.

Jan 1, 2000

By Russell H. W. Chadwick

Reviewing events in the minerals industry, in economic geology, and in my own exploration work, I find that the most compelling subject for comment is the increasing ferment in ore deposits theory. New discoveries and continued investigations of bedded deposits of lead and zinc, copper, iron, uranium, etc., coupled with the availability of much new and significant data from sedimentary and metamorphic petrology, geochemistry, and oceanography, has led many economic geologists like myself to become disenchanted with former simplistic notions. Now disenchantment among serious people should presuppose both valid objections to the old, and valid new substitutes. I can sum up my own position and, I believe, what most of the recent writers on ore deposits theory are trying to tell us, by saying that a physico-chemical (bench science) approach to a natural science is neither correct nor useful, and that the obvious cure is a return to the study of the geology of ore deposits. More specifically, ore should be viewed merely as an unusual concentration produced, in stages, by the natural processes inherent in the geochemical cycle. In criticizing the conceptual basis of a science, one is involved simultaneously in the inherent character of the science, its subject matter, and the old and new concepts. I have found it impossible to make a clean separation along those lines. As a result, and as the title suggests, these are not-quite-random reflections on genesis, a matter near and dear to all true treasure hunters since Agricola.

Jan 1, 1967

By Peter A. Hacquebard

"The early history of the Geological Survey of Canada is closely connected with coal geology investigations in the Atlantic Provinces. In 1843, Sir William Logan, the first director of the Geological Survey, measured the 4441m thick shore section at Joggins in Nova Scotia. Detailed mapping of the coalfields were subsequently carried out by H. Fletcher during the latter part of the nineteenth and first part of the present century. During the 1920-1940 period, the stratigraphy of the carboniferous WIZS' established by WA. Bell, who later also became a diretor of the Survey. Bell's work WIZS' followed by coal geology investigations of A.A. Hayes, W.S. Dyer, EA. Goranson, G. W.H. Norman, J.E. Muller, T.B. Haites and P.A. Hacquebord.The activities and accomplishments of the Survey geologists during the past 150 years are presented in this paper.General Outline of Survey Activities in Coal Geology During the Past 150 YearsIn 1842, when the Geological Survey of Canada (GSC) was established, the industrialization of the major countries of Western Europe and North America was actively persued. The energy required for this industrialization was obtained from the only fossil fuel then available, namely coal. The measure of a country's major mineral wealth at that time was the availability of mineable resources of coal. Eastern Canada, where mining had been carried out since 1720, was known to be well endowed with valuable coal deposits. In the major fields of Nova Scotia (Fig. I) several large-scale operations had been started during the middle and latter part of the nineteenth century.The significance of coal, therefore, was well understood, and exploration surveys specifically oriented toward coal were carried out by the Geological Survey from its earliest beginning. The first report of a detailed geological description of the coal measures of eastern Canada was prepared in 1843 by Sir William Logan (1845), the founder and first director of the Geological Survey of Canada. This early work was continued and complemented in 1896 by H. fletcher (1906), who during the latter part of the nineteenth century and first part of the present century systematically mapped the coal-bearing regions of Nova Scotia, which he considered all to be of approximately the same age."

Jan 1, 1992

By A. D. Hunt

THIS PAPER will review Canada's fossil fuel situation as we understand it today and indicate some of the options available to meet our energy requirements during the next 15 years. It would therefore be helpful to examine Canada's total energy requirements and discuss the un certainties of the data base on which we must base future energy investment decisions. On the world scene, Canada is at the top of the energy-consuming nations, using about 49 bbls of oil equivalent per caput/ year. This appears to be slightly ahead of the U.S. and of course much higher than that of many countries. It is generally accepted that there is a more or less direct relationship between energy consumption and material standard of living. However , as we know, Canada, when compared with other industrialized countries on a GNP, an individual-income or some other standard basis, is lower in the list. This situation may be explained by our more severe climate and a relatively small population distributed over a land mass second only to that of the Soviet Union.

Jan 1, 1977

By Zou Lisheng

The culture of safety is very important to coal mining production. About 90% of mine accidents are caused by human error. This paper analyzes the status of China?s coal mining accidents, and accident cause. This paper explains the concept of safety culture, the value of safety culture, as well as the relationships between safety culture and safety behavior, and between safety culture and science and technology. The paper proposes the model of safety culture and the ways to enhance safety culture of coal enterprises. Safety culture and safety production is closely related and are significant to the improvement of mine safety situation in China.

Aug 1, 2013

By C. Yi, M. Onifade, B. Genc, S. Dineva, T. Zvarivadza, M. Khandelwal

Deep hardrock mines worldwide increasingly face rockbursts as mining depths increase. These events result from the accumulation and sudden release of stress, causing rockmass damage and posing major safety and operational challenges. This paper focuses on destress blasting as a critical strategy to mitigate rockburst hazards. Although limited practical experience exists in Swedish deep hardrock mines, international case studies demonstrate that, when well implemented, destress blasting redistributes peak stresses by promoting controlled fracturing around mining excavations. The success of such techniques is highly dependent on site-specific factors such as stress regime, rockmass brittleness, structural geology, and blast layout. Although destress blasting is especially effective in massive, brittle rock under high stress, typical conditions for strainburst prone environments, its design cannot rely solely on numerical models. Simulations can offer preliminary evaluation of stress redistribution trends and guide early design assessments but their current limitations, including sensitivity to input data and simplified fracture mechanics, mean they are best used as supplementary tools rather than final decision-makers. Field trials, supported by microseismic analysis and fracture mapping, remain essential for validation. The study critically synthesises international experiences and presents a structured framework for destress blasting design, offering practical and academic perspectives aligned with Swedish geological conditions to support safer and more efficient application in deep hardrock mines.

Jun 27, 2025

By F T. Suorineni

Empirical methods are deeply rooted in geomechanics. This is a consequence of the recognised complexity of the nature of the rock mass. The usual assumptions of material continuity, homogeneity, isotropicity and linear elasticity often assumed for soil, concrete and steel are difficult to justify in a rock mass except for mathematical convenience. These assumptions form the bases for most mechanistic, analytical and numerical methods in geomechanics. Believers in empirical methods argue that the complexity of the rock mass and its interaction with structures developed in it is adequately accounted for in empirical methods, which compensate for our ignorance.Franklin (1993) defines empirical design as quantified judgement based on experience. He further states that empirical methods often prove ‘closer’ to the ‘truth’ than the apparently more precise predictions of theoretical analysis, adding that based on real data empirical methods provide a standard against which theoretical predictions are measured and can be judged. This paper takes a critical look at the common empirical methods in geomechanics – rock mass classification systems (Bieniawski, 1973; Barton, Lien and Lunde, 1974; Hoek, 1994a), Laubscher block caving design rules (Laubscher, 1994), the stability graph (Mathews et al, 1981), pillar design equations (Salamon and Munro, 1967; Hedley and Grant, 1972; and their derivatives), pillar design chart (Lunder and Pakalnis, 1997) and failure criteria (Hoek and Brown, 1980; and its derivatives). The common thread in the application of these methods is that in most cases they are often applied blindly without an understanding of the underlying assumptions and database limits. This paper emphasises that users of these methods need to know the underlying assumptions, database limits and inherent hidden risks that are often unmentionable for their satisfactory use. Finally, suggestions are provided for the efficient use of empirical methods and how they can be improved.CITATION:Suorineni, F T, 2014. Reflections on empirical methods in geomechanics – the unmentionables and hidden risks, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 143–156 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By J. N. Van der Merwe

"Platinum is a highly valuable resource, its safe and economic extraction is paramount. The success of platinum mining by the bord and pillar method depends heavily on a comprehensive and dependable pillar design method. Pillars need to be large enough to safely support the load and small enough to avoid loss of resources. A critical evaluation of current pillar design systems used in narrow-reef platinum mining was undertaken using practical experience from a large feasibility-stage platinum exploration project, supplemented by observations from several platinum mines in Zimbabwe. An extensive literature survey was undertaken in order to determine the current status of design systems. Through this approach, the shortcomings of current pillar design systems are highlighted. Areas are proposed for further research to obtain a better understanding on how additional factors influence pillar system stability. The exploration work highlighted how rock mass classification methods can be utilized in determining the overall strength of pillars. Current pillar design systems for narrow-reef platinum mining consider width-to-heightratio (usually with different exponents for width and height) and the strength of the pillar material. However, there are many more important factors that are not considered and which have a bearing on pillar system stability. An in-depth study of these parameters with a view to establish effective narrow- reef platinum mining pillar design systems needs to be undertaken. IntroductionPillars have been used as a means of support since the early days of mining. Pillarsupported mining methods such as bord and pillar require a reliable design system for them to be successful. This paper presents an evaluation of the current hard-rock mining pillar design systems as applied to a practical large-scale narrow-reef platinum mining feasibility study. It is vital to have a dependable pillar design system for economic and sustainable mining. Using an extensive database collected from the project, the pillar strength formulae were tested and several discrepancies noted. This necessitates the establishment of more reliable pillar design systems. In narrow-reef platinum mining, large compressive stresses accompanied by geological and geotechnical factors contribute to pillar instability. A well-formulated pillar design system is required that accounts for such factors so as to minimize pillar failures."

Jan 1, 2017

By Arturo Ressi di Cervia

From the times when men in lacustrine environments drove wooden piles into the mud to elevate their dwellings, until the beginning of the twentieth century builders reacted to the conditions found in the location of their proposed structures by attempting to distribute their loads in ways that could be supported by the foundation's soils; or, if those were unsuitable, by moving the structure, whenever possible. While many major structures were built on stable ground (the pyramids were founded on rock), others were built on [ ]

Jan 1, 2000