Search Documents

By George S. Rice, C. W. Owings

"Brattice cloth is an important material in coal-mine ventilation practically all coal mines use some brattice cloth, gassy mines a large amount. It is employed in three ways:Crosscut brattices.Curtains in haulageways.Line brattices in gassy mines.In each case brattice cloth is used to deflect part or all of a split of the mine ventilating current into or toward the face of a working place. As a general rule, its use in a particular location is temporary.A crosscut brattice should be employed only until a permanent stopping has been erected. Such a brattice is subject to little wear when in actual service, the chief damage occurring when it is taken down and put up again.When used for curtains on haulageways or haulage crosscuts to deflect the air current up into rooms or headings, the wear on brattice cloth is considerable, as mine cars, machines, and personnel constantly pass under the curtains which last only a few days or a few weeks in an active part of the mine. For such purposes tightly woven smooth cloth is desirable, so that it will not be easily torn. Curtains should not be used back from the working places, as they sometimes are, to deflect the main. split, as the leakage of air is too great. Doors should be used in such places."

May 1, 1928

By 1928-05-01

"The carnotite ores of Colorado and Utah were the chief source of radium for many years. In the fall of 1922; news of the very rich deposits of radium ore discovered in the Belgian Congo caused almost complete cessation of domestic production. The Congo ore contains pitchblend and a number of alteration products, including the new minerals bequerelite, curite, kasolite, stasite, and dewindite. Reports indicate that a considerable amount of ore containing over 50 per cent U308 has been produced. It seemed certain that radium could be extracted from the Congo ore at a much lower cost than from the relatively low-grade carnotite; and in order to preserve their elaborate marketing organizations, the larger American producers made agreements with the Belgium syndicate to market the foreign product in this country. The price of radium has been held at $70 per milligram. Extraction of radium from carnotite by the usual methods does not appear to be profitable at that price. With one exception, all American firms ceased production after their accumulated stocks of ore had been treated. The United States Radium Co., which continued to treat carnotite for several years, has recently shut down its plant.Although there is probably a large profit derivable from the treatment of Congo ore, it is not likely that the Belgium Syndicate will meet sufficient competition to cause any reduction in the present quotations. It is not known how long the high-grade ore will last, but when exhausted the price of radium may be expected to advance. According to K. L. Kithil3 it is the opinion of interested parties that, so far as can be forseen, radium will in future years never again be obtained at the present low price.Carnotite contains the valuable element, vanadium, which is not present in the Congo ore. The recovery of-vanadium is an important factor in the cost of extracting radium from carnotite, and under favorable conditions carnotite can be profitably treated for the vanadium alone. Vanadifecous sandstones are found ranging all the way from roscoelite (vanadium mica), containing little or no uranium; to a high-uranium and low-vanadium carnotite. Ores containing 2 per cent or more U308 are classed as radium ore and are sold on the basis of the uranium content, which is proportional to the radium content. Only in exceptional cases have ores been evaluated on the basis of both the radium and vanadium contents, although the presence of vanadium has undoubtedly influenced the price of radium ore."

May 1, 1928

By Chase E. Sutton

The porosity of a sand is usually the measure of its capacity for holding fluid, although porosity is sometimes selective; that is, a small percentage of the actual pore space (voids), particularly in fine-grained sandstones, may be isolated by the cementing material which prevents the entrance of fluids under normal conditions. Obviously, however, porosity determinations are essential to an engineering study of underground conditions of an oil field, and a simple and reliable method of obtaining a reasonably accurate figure for average porosity is desirable. This report describes a method suggested by Ruasell,3 which was used by the writer in the preparation of a report on the Texhoma-Gose pool, Archer County, Tex.4 The conditions in this pool were particularly favorable for obtaining an average porosity figure, in that some 30 to 35 core samples of the pay sand were available for analysis.

Jan 1, 1928

By Will H. Coghill

[The supply of gravel spar and of acid spar is not well balanced. Gravel spar -- 85 per cent flourspar, 5 per cent silica -- gluts the market, whereas acid spar -- 98 per cent fluorspar, 1 per cent silica -- is somewhat scarce. Hence it is desirable to convert some of the gravel spar into acid spar. Knowledge of this condition prompted the Franklin. Fluorsrar Co. at Paducah. Ky., to enter into cooperation with the U. S. Bureau of Mines and the Missouri School of Mines and Metallurgy to improve the methods of fluorspar, milling so that morn acid spar would be available. The fluorspar company detailed Mr. Omar Greeman for the work. During the course of the investigation, while Mr. Greeman was also doing work for a master's degree in the School of Mines? an extensive study was made of gravity concentration of fluorspar ores. Decrepitation by heat treatment was also given a laboratory try-out. A part of tie time was spent on flotation; these notes relate only to the flotation. The results of one of the flotation runs is appended. The test was made in a 500-gram mechanical-agitation machine. The sample was ground to 100-mesh in a pebble mill.]

Jan 1, 1928

By J. D. Davis

From the chemist's point of view it would be ideal if specifications for coke for any stated purpose could be written on the basis of chemical composition and burning characteristics. Unfortunately this is not possible. In fact, the physical properties of a coke are often of such major importance as to render any specified chemical requirements totally inadequate to show the quality of coke desired. For example, a furnace coke may admirably fill all chemical requirements, such as for low phosphorus, sulphur, moisture, and high fixed carbon, and still be too soft to support the burden of the furnace without excessive crushing. Again, a domestic coke though a good fuel as judged from Chemical analysis, may be of unmarketable size. Thus one can not define the quality of a coke for a specified purpose without taking into account both its chemical and physical characteristics even when this has been done the specification may fail because neither coke user nor producer can accurately define by quantitative tests the qualities most desired. In other words, there is need of accurate test methods for measuring the properties of coke and, what is equally important, for correlating the results with the behavior of the coke in use. Coke quality is determined by the kind of coal used, the coking process, and the type of equipment used in the coking process. Chemical analysis of the coals, together with small-scale coking tests, will give a good indication of their suitability; but, in general, coke must be produced on an industrial scale and tested in the equipment for which it is intended before conclusive information as to its quality is obtained.

Jan 1, 1928

By R. R. Brandenthaler

A series of open-flow tests was conducted in the Chickasha gas field, Grady County, Oklahoma, during June, 1927, under the direction of the U. S. Bureau of Mines and at the request of the Oklahoma Corporation Commission. The purpose of these teats was to determine whether or not any differences existed in the open-flow volume of a gas well when taken through well-head nipples of different diameters, and further, to establish if possible a relationship between open-flow volumes taken through well-head nipples of various diameters. The open flow of a well is the volume or quantity of gas, measured under standard conditions, that a well will produce when open to the atmosphere. There are several methods used for determining the open flow of wells; some of the methods are more suitable under certain conditions than others. The Pitot tube method is the simplest, is applicable to almost any condition, and is the one most commonly used. In the tests described in this paper no attempt was made to compare the Pitot tube method with the minute pressure measurement method or the orifice measurement method.5

Jan 1, 1928

By R. D. Leitch

"The pollution of streams has received much attention during the last few years, and although there are many other and more serious forms of pollution, the problem of acid mine drainage is important in certain sections of the country, particularly in Pennsylvania. At the request of the United States Public Health Service the Bureau of Mines undertook to determine some of the factors contributing to formation of acid mine waters, the yearly variations in quantity and quality of drainage, effect of mining methods, and various other questions arising in connection with the problem; some attention was also given to its economic phases.In acknowledgment, the writer wishes to thank Dr. R. R. Sayers, Chief surgeon; A. C. Fieldner, chief chemist; and W. P. Yant, supervising chemist, health laboratory section of the Pittsburgh Experiment Station, all of the Bureau of Mines, under whose direction the work was conducted.Because no data of a like nature had previously been determined, and with the thought that such data would throw additional light on the general subject, a stream having a number of mines draining into it was selected for observation in both high-sulphur and low-sulphur bituminous-coal districts, as designated in commercial rating. These mines and streams were visited in both wet and dry seasons to note the quantity and variations in acidity of mine drainage and the subsequent effect on streams. Maps of these streams with the sampling points are shown in Figures 1 and 2. In a report of this nature a great deal of tabular data is best emitted, but reference to the maps will serve to indicate the factors that determined sampling points, such as tributary streams and gobs."

Sep 1, 1928

By G. E. McElroy

When mechanical ventilation is to supersede the natural ventilation of a mine it is desirable to determine what resistance the mine as a whole offers to the flow of air in order to specify properly the limiting duties of a ventilating fan. The relation of pressure to volume of flow for the mine as a whole may be calculated from experimental data, or it may be determined directly by measurements of volume of flow and the natural draft pressures causing flow; but in both methods the determinations are affected by many variables. With the intention of making a practical application of both methods, a small metal mine in process of development at Butte, Mont., was selected by the writers as the object of experiments planned to compare the mine resistances determined by measurements of natural draft and volume of flow with those calculated from experimental data. Four sets of teats were made with natural draft in October, 1925, December, 1925, April, .1926, and September to December, 1926; the last set consisted of a series of weekly observations. DESCRIPTION OF MINE The mine selected for the experiments was a typical vertical shaft metal mine in the development stage. No stoping had been done, and ventilation was confined to shafts, crosscuts, drifts, and raises. Figure 1 is a dia¬grammatic sketch of the main openings. All were timbered with full sets on approximately 5-foot centers. The shaft compartments were 4 by 4.5 feet, and one in each shaft was partly blocked by staggered manway landings. A pump column in the upcast shaft was discharging about 280 gallons a minute of water at 70° F. from the 1,000-foot level. The drifts were slightly sinuous, but the crosscuts were exceptionally straight and uniform in area; both drifts and crosscuts were about 5 by 7 feet in cross section. The raises were composed of vertical sections joined by frequent 450 offsets; each had three 4.5 by 4.5-foot compartments, of which two were plank-lined ore chutes and one was partly

Jan 1, 1928

By Ralph H. Espach

The value of careful fractionation in the manufacture of petroleum products is recognized more and more by petroleum refiners. Recent studies have shown that the quality of the products depends largely on the type of fractionating equipment and on the care used in operating the equipment. For example Rue3 has shown that careful fractionation of pressure distillate will greatly reduce the amount of chemical treatment necessary to produce finished gasoline. The advantages of the combination of pipe still and bubble tower in obtaining good fractionation are well recognized in the petroleum industry. However, the equipment designed in the past has in general been much too large for convenient laboratory use. The present paper describes a continuous-distillation apparatus for the laboratory study of fractionation. This apparatus has given very satisfactory results in the study of different crude oils and petroleum products. A discussion of the theory and action of bubble towers has not been given, as this subject has been discussed previously by Cooke and Rue4. It is believed that the distillation curves of the products obtained from this apparatus show clearly its capabilities.

Jan 1, 1928

By R. E. Heithecker, Van A. Mills

"Crude oils are capable of dissolving quantities of gas under pressure. This fact has been known for some time, but questions have arisen as to the effects of gas in solution upon the characteristics of the oil. Previous investigations4 show that gas in solution in an oil affects the viscosity and surface tension of the oil, but the effects on the volume and A. P. I. gravity of the oil have not been known. The results given in this report show that there is a decided change both in volume and in the A. P. I. gravity of the oil due to the solution of the gas in the oil under pressure. As gas is dissolved, the volume of the oil and the A. P. I. gravity increase. The converse of this phenomenon is also true: if the gas is released from a saturated oil, there is a shrinkage in volume and a decrease in A.P.I. gravity due to the release of gas from solution. However, various oils show marked tendencies to retain a portion of the dissolved gas upon releasing the pressure to that of the atmosphere. This retained gas has an appreciable effect on the volume and A. P. I. gravity of the oil because the oil does not resume its initial volume or gravity while it retains dissolved gas. In a sense the oil has been ""freshened"" and will not return to its original or weathered volume until it loses some of the lighter fractions. Wiggins5 has shown that a fresh oil decreases both in volume and in gravity because of the weathering of the lighter fractions while the oil is standing in storage tanks.This paper includes data attained during the determination of volume and gravity correction factors to be applied in the oil recovery investigations of the Bureau of Mines. Three oils having a wide range in gravity were used in determining the correction factors. These oils were from the Bartlesville-Dewey field, Oklahoma, the Seminole field, Oklahoma, and the Inglewood field, California. The same gas that was used in the oil recovery experiments was used throughout this investigation. Determinations were made of the volume and A.P.I. gravity increases resulting from the gas going into solution at 200, 400, 600, 800, and 1,000 pounds pressure; also the increases in the volume and gravity of the oil due to retained gas were determined after the dissolved gas was liberated from solution by releasing the pressure to that of the atmosphere.Samples of residual and liberated gas were taken throughout the investigation in order to study the selective absorption and selective retention by the oil of the various constituents of the gas. The analyses of these gas samples showed that there was selective absorption and selective retention of the constituents of the gas. The tests on Inglewood crude gave the most pronounced example of selective absorption and selective retention of the gas.All of the tests were conducted at a constant temperature of 709F."

Oct 1, 1928

By R. Van A. Mills

Crude oils are capable of dissolving quantities of gas under pressure. This fact has been known for some time, but questions have arisen as to the effects of gas in solution upon the characteristics of the oil. Previous investigations4 show that gas in solution in an oil affects the viscosity and surface tension of the oil, but the effect's on the volume and A. P. I. gravity of the oil have not been known. The results given in this report show that there is a decided change both in volume and in the A. P. I. gravity of the oil due to the solution of the gas in the oil under pressure. As gas is dissolved, the volume of the oil and the A. P. I. gravity increase. The converse of this phenomenon is also true: if the gas is released from a saturated oil, there is a shrinkage in volume and a decrease in A.P.I. gravity due to the release of gas from solution. However, various oils show marked tendencies to retain a portion of the dissolved gas upon releasing the pressure to that of the atmosphere. This retained gas has an appreciable effect on the volume and A. P. I. gravity of the oil because the oil does not resume its initial volume or gravity while it retains dissolved gas. In a sense the oil has been "Freshened" and will not return to its original or weathered volume until it loses some of the lighter fractions. Wiggins5 has shown that a fresh oil decreases both in volume and in gravity because of the weathering of the lighter fractions while the oil is standing in storage tanks.

Jan 1, 1928

By C. C. Furnas

In the course of an investigation3 of the flow of gases through beds of broken solids the author obtained a number of data .on the specific volume of beds of broken solids of variously mixed sizes. A mathematical theory of the limiting conditions has been developed and some generalizations have been made for intermediate cases. A more definite knowledge of the relation between space occupied and size composition would be valuable to all those who are handling large quantities of broken materials. Such knowledge might be advantageously applied to the operation of a coke oven. For example, the output of the oven depends in general upon the number of pounds of coal which can be put in the oven at charging. It is known that the capacity of one battery of ovens was increased several per cent by slightly increasing the proportion of fine material in the charge.

Jan 1, 1928

Heavy liquids have come into use in ore-dressing investigations, as they make possible the separation of an ore into its specific-gravity components. A paper containing a general dissertation on heavy liquids has been written by John D. Sullivan,4 and the practical application of heavy liquids is explained by Box and Crabtree5. Some heavy liquids become discolored after continued use, and the lack of transparency impairs their value. Since they are fairly expensive, reclaiming is desirable. This paper briefly discusses the preparation and care of some of the more common heavy liquids.

Jan 1, 1928

By Will H. Coghill

The jig men of the Tri-State (Joplin-Miami) zinc district complain about the flakiness of their mill feed. They believe that the flakiness of the composite grains of gangue and mineral are to blame for losses of zinc; that is, that the flaky grains in the jig tailings have higher zinc tenor than the cubical grains. Although the evidence which follows contradicts this belief, no effort is made to give a final and conclusive answer. On the other hand, there is outlined a positive and mechanical method which the operator may use to pursue this and similar investigations. DISCUSSION OF SCREENING METHOD Hand-sorting is obviously not satisfactory for separating cubical grains from flaky grains because the personal influence can not be removed. Screens, however, may be used with success. A set of each of two types of screens is required; namely, the square-hole type and the rectangular (rectang, oblong) type. The square-hole screens must be of the double Tyler scale; that is, the order of the sieves should be after the fourth root of two instead of the customary square root of two; close sizing is important. The size of the rectang screens may be selected by trials so that a part of the material already closely sized on the square-hole screens, will pass the oblong holes. Obviously, the cubical grains will remain on the rectang and the flaky grains will pass through. Hence the mode of operation is to screen first on square-hole screens and then split the products on the oblong-hole screens.

Jan 1, 1928

By F. S. Wartman

The presence of magnetite, either dissolved or suspended as solid crystals, in slags from the copper reverberatory furnace is a frequently mentioned cause of an abnormally high copper content in those slags. The presence of this oxide in the slag is to be expected, since it is present in appreciable amounts in both converter slag and roaster calcine which comprise a considerable proportion of the furnace feed. Magnetite is also a product of some of the furnace reactions. These abnormal losses result in several ways. Magnetite is supposed to favor the formation and retention of copper ferrite, in the slag. Crystals of solid magnetite suspended in the slag are objectionable-because they make the slag less fluid and often entrap globules of matte. Frequently these crystals settle into a layer at the slab-matte interface which may have such mechanical strength as to create a false bottom and interfere with furnace operation by preventing separation of matte from slag. Magnetite may, by crystallizing on the furnace bottom, build the bottom to such a level that the furnace can no longer be operated.

Jan 1, 1928

By F. D. DeVaney

The supply of manganese is a subject of much interest. The idea of obtaining it from rhodochrosite-MnC03 is attractive because the carbonate is supposed not to be so contaminated with impurities as the commonly utilized oxides. Large bodies of rhodochrosite-bearing rock have been known for a long while to exist at Butte, Mont. Hence samples were obtained from that place. In the two samples examined quartz was the chief diluting substance. The leaner sample was about one half quartz; some copper, lead, zinc, and iron sulphides were also present. The rhodochrosite amounted to about 40 per cent, so that the sample had a tenor of about 20 per cent manganese. This sample was the subject of the examination reported herein.

Jan 1, 1928

By W. W. Odell

Engineers interested in the manufactured-gas industry have witnessed p pronounced improvements in gas-generating equipment and marked changes in operating procedure during the past decade. In spite of these changes, however, the trend of development in the near future seems to be doubtful. Uncertainty exists mainly because no one can yet accurately calculate the number of years which will elapse before petroleum products become too expensive for, general use in making gas. Research in this field has been active, and the ultimate results are awaited with interest. Some engineers predict that in the future coking coal will be carbonized on such a large scale that coal gas will be used (straight or modified) for city distribution; others maintain that gas oil will be used in large quantities in the production of base gas; they believe that it will be economical to use oil even at appreciably higher prices. The question involves, among other; factors, consideration of initial and relative costs of equipment, flexibility of operation, salability of coke, cost of distributing different gases, and the relative value of by-products, It is common belief that for many years large quantities of oil will be used in gas-making, particularly in the generation of peak gas or that water gas will be used for the synthetic production of hydrocarbons to enrich additional water gas. In this paper interest centers in a discussion of the practicability of employing synthetic processes in view of reported investigations of the chemistry of the synthetic reactions. For many years it has been known that the chief components of water gas would react chemically under proper conditions to form methane. As long ago as 1903 a patent3 was issued in this country for a gas-making process which included the synthetic production of methane. More recently the studies of numerous investigators here and abroad have shown that besides methane it is possible to produce other paraffins, olefins, and additional, materials adaptable for enriching water gas or for other uses. The question arises: In what manner, if at all, can such processes be incorporated, as a part of the gas-making scheme in a city-gas plant?

Jan 1, 1928

By C. C. Furnas

Despite the fact that a great many industrial processes depend on efficient contact between a gas stream and a bed of broken solids for their operation, the data in the literature are very meager. Several investigations3 have been undertaken, but the work has been limited in scope and application. BUREAU OF MINES PROGRAM OF RESEARCH For the past 10 years the United States Bureau of Mines has been engaged in research with the object of formulating a more or less complete quantitative theory of the workings of the iron blast furnace. Obviously, in order to do this one of the essentials is to have considerable definite information on the laws of gas flow through beds of broken solids. This report in a brief summary of the experimental work on the problem which has been done at the North Central Experiment Station. The complete report with more detailed tabulation of the data and explanations of the experimental procedure is in process of publication in the form of a bulletin.

Jan 1, 1928

By David F. Smith

[The U. S. Bureau of Mines at its Pittsburgh Experiment Station is frequently called upon to determine by laboratory tests the explosibility of suspensions in air of various dusts encountered in mines and elsewhere. Not all dusts which are combustible or contain combustible material will form explosive mixtures with air under ordinary conditions of temperature and pressure. They may not be highly combustible enough. They may contain a considerable amount of inert or non-combustible material or, the dust particles may not, be fine enough to form explosive mixtures. A knowledge off the chemical composition of a dust together with a determination of the size of the particles often gives valuable indications. But in many cases actual explosibility tests are necessary. Such a case is evidently that of powdered soap, whose explosibility hazard the Bureau was recently called upon to determine, Although an explosion which occurred in a soap plant as early as 1890 was attributed4 to powdered soap, it is apparent, due to the great number of inquiries received by the Bureau, that the hazard presented by powdered soap has not been at all generally appreciated. To the writers' knowledge, no extensive investigation of the explosibility of powdered soaps has been made. It is only recently that pure powdered soap has been manufactured on a large scale. The familiar "soap powder" in the past was usually a mixture of soap with a relatively large quantity of sodium carbonate. Often it contained large amounts of moisture and abrasive material. Even a highly combustible dust when mixed with large quantities of inert dust will not form explosive mixtures with air. Pure powdered soap, however, presents a different aspect. Pure soap is formed by combination of alkali (incombustible material) with fatty acid (combustible material). Toilet soap fray also contain a certain amount of glycerin and essential oil winch, being combustible influence the explosibility]

Jan 1, 1928

By W. P. Yant

Public interest in atmospheric pollution by automobile exhaust gas and in the ventilation of vehicular tunnels makes it desirable to ascertain whether the use of modern automobile fuels is tending to change the amount and composition of the products of combustion. The Bureau of Mines, in cooperation with the Ethyl Gasoline corporation4, has completed a series of testis to determine whether any significant difference exists in the carbon monoxide content of the exhaust gas produced by an internal-combustion engine when its fuel is changed from straight gasoline to the same gasoline containing Ethyl fluid whose active ingredient is tetraethyl lead. In the tests data was sought relative to the composition and mount of the gas produced by ordinary comparatively low-compression motors as well as by higher-compression motors in which distinct detonation occurred with straight gasoline, but which operated without detonation when using the same gasoline containing tetraethyl lead.

Jan 1, 1929