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By John D. Sullivan

In leaching copper ores knowledge of the rate of dissolution of the copper minerals and of the impurities is desirable. With knowledge of these two factors and data as to what minerals are present in the ore the metallurgist has an excellent start on planning a leach¬ing cycle to fit that ore. The rate of dissolution is rather difficult to predict, and the time required to leach a given ore may differ markedly from that required by another ore. The whole study as related to mixed oxidized and sulphide ores is one of relative rates of dissolution of the different copper minerals and the impurities in sulphuric acid and in ferric sulphate. The aim of leaching is to choose a cycle and strength of solvents to ex¬tract a maximum amount of copper and a minimum of impurities. The consumption of reagents per unit of copper dissolved is a function of the strength of the reagents used and the relative rates of attack on copper minerals and impurities. An opportunity may exist of ob¬taining the kind of electrolyte wanted for electrolytic precipitation and yet of saving on the consumption of reagents by modifying the strength of ferric sulphate and of sulphuric acid during the cycle to fit the time needed for dissolving the sulphide and oxidized minerals present. Former papers have considered the rate of dissolution of azurite, malachite, tenorite, chrysocolla, cuprite, chalcocite, boruite, and covellite in common leaching solvents. A paper soon to be written will consider some of the less important copper minerals. The present paper considers the rate of dissolution of copper from ores of the Southwest in sulphuric acid of varying strength and the ratio of sulphuric acid consumed to copper dis¬solved. In this study two ores containing the copper principally in an oxidized condition were used. A study of other ores, especially those containing high percentages of sulphide copper minerals, would be desirable, but since consumption of acid has paramount interest,

Jan 1, 1931

By Jr. Harty

Intensive work on the deoxidation of steel with manganese-silicon alloys by the U. S. Bureau of Mines has shown that the use of those alloys, which may be produced from our domestic manganese ores, would decrease the ferromanganese requirements of a very large tonnage of our steel by from 60 to 80 per cent and in some cases by 100 per cent. The open-hearth heats made with these alloys have been of excellent quality. The tonnage of our ferro-grade ores Which has been made available by the bureau's ore-dressing studies, combined with the products resulting from such processes as those developed by the bureau and by Bradley for Cuyuna ores, should easily fill our reduced ferromanganese requirements when manganese-silicon alloys and ordinary Spiegel are used in the way described in this report. There are no technical difficulties in the application of this practice, and any difficulties involved in its wide and immediate application would only be those arising from habituated ideas of the necessity of ferromanganese. General acceptance of this practice and development of the available sources of domestic ferro-grade material by already proven processes should make this country independent of foreign ores. This paper resents the results of work done under a cooperative agreement between the Pittsburgh Experiment Station of the United States Bureau of Mines and the Carnegie Institute of Technology, the Metallurgical Advisory Board, and the University of Pittsburgh, Pittsburgh, Pa.; between the Mississippi Valley Experiment Station of the United States Bureau of Mines and the Missouri School of Mines and Metallurgy, Rolla, Mo.; between the North Central Experiment Station of the United States Bureau of Mines and the University of Minnesota, Minneapolis, Minn.; and between the Rare and Precious Metals Experiment Station of the United States Bureau of Mines and the University of Nevada, Reno, Nev.

Jan 1, 1931

By G. St. J. Perrott, G. W. Jones

"In cooperation with The Edison Electric Illuminating Co. of Boston, Mass., a survey was conducted in 1929 and 1930 by the United States Bureau of Mines to determine the general hazards of combustible gases and vapors in manholes and other underground openings owned by this company. The territory served approximates 650 square miles and includes 46 cities and towns. The transmission and distribution systems are on overhead construction and underground wires and cables run in underground conduits and manholes. There are 17,000 manholes on the system, and also an area in Boston proper served by the Edison tube system. These conduits and manholes are laid in various types of streets from the most modern type of cement roadbed to the older type of loose macadam. The conditions as found could be considered as typical of any public utility in the electric-light and power field. The survey extended over a period of about a year beginning in June, 1929, and ending in July, 1930, and during this time 1,765 different manholes were tested and a total of 4,068 tests were made.Previous to starting the actual survey, one of the writers, G. W. Jones, spent considerable time in Boston determining the best methods of practical· test procedure. In this work cooperation was given by John Campbell, superintendent, special service department, who for a number of years has been making a study of explosions in underground street areas and preventive measures in Boston and various cities.After this preliminary investigation the tests were continued by employees of the Edisun Company. Copies of all records of tests were forwarded to the United States Bureau of Mines Pittsburgh Experiment Station so that the writers were in close touch with the progress of the survey, and changes could be made in the test procedure whenever deemed necessary."

May 1, 1931

By J. W. Paul, J. N. Geyer

"GENERAL STATEMENTThe purpose of this report, which is the first of a series of three covering mines in the Fairmont district of West Virginia, is to give the result of a' study conducted in seal mines to ascertain the nature of the safeguards employed to prevent injury to the workmen from falls of roof and coal. In presenting the subject matter, consideration must necessarily be given to factors, features, and conditions such as method of mining, timber regulations and practices, supervision and natural conditions; and, for comparative purposes, a certain amount of statistical matter bearing upon the relation of fatalities and injuries to their causes, tonnage produced, men employed, days worked, and time lost.Those features and practices found to promote safe protection are summarized and suggestions made for such additional safeguards and practices as appear to give greater protection against injury from falls of roof or coal.ACKNOWLEDGMENTSThis study of falls of roof and coal in mines in Harrison County has been conducted by the U. S. Bureau of Mines in cooperation with R. M. Lambie, chief of the Mining Department of the State of West Virginia who assigned L. W. Brown, a district mine inspector, to assist in the field work and in the preparation of individual reports on each mine visited in this study. The writers acknowledge the helpful suggestions and cooperation given by these officials, the latter of whom assisted in the field work and prop red most of these sketches for the individual reports which wore submitted to the operator by the chief of the department. Thin report is a summary of the contents of the individual reports heretofore furnished the individual operator."

Aug 1, 1931

By H. F. Yancey

A relatively large proportion of the coal produced 1n the State of Washington, especially in the coking coal areas is of fine size; hence washing by means or coal-washing tables to reduce the ash content is commonly practiced. For this reason the program of research in coal washing conducted jointly by the U. S. Bureau of Mines and the College of Mines, University of Washington, has given special attention to the mechanism or the separation of coal from its impurities as effected by the coal-washing table with the object of increasing its efficiency. Previous work has evaluated the role of stratification the influence of size, specific gravity and respective shapes of particles in the feed, and the affect of hindered-settling classification of the feed prior to tabling.

Jan 1, 1931

By H. F. Yancey

A relatively large proportion of the coal produced in the state or Washington, especially in the coking coal areas is of fine size; hence washing by means of coal-washing tables to reduce the ash content is commonly practiced. For this reason the program of research in coal washing conducted jointly by the U. S. Bureau of mines and the College of Mines, University of Washington, has given special attention to the mechanism of the separation of coal from its impurities as affected by the coal-washing table with the object of

Jan 1, 1931

By R. S. Dean

The principle of explosive crushing depends upon the fact that an expandable substance contained within the pores of a solid body will disrupt such a body upon expansion. Such expansion may be obtained by the detonation of an explosive or by the sudden release of pressure of a superheated liquid. That this principle of disruption may be applied to minerals rests on the fact that cracks, cleavage planes, and pores exist in all mineral to an extent hardly conceived possible heretofore. Crushing by this method takes advantage of force applied from within the mineral rather than from forces applied from without. The application of a force from within would appear to be more effective. A consideration of the possibilities of such a method for crushing led to some experimental work of a preliminary nature, the results of which are embodied in this paper. No systematic program was followed in the work and the results are, therefore, not final and far from complete. The success attained so far, with the mediocre apparatus available seems to warrant a preliminary report, with the expressed hope that the work may be carried on as well-outline program covering such phases as have been impossible to investigate at this time.

Jan 1, 1931

By R. S. Dean

The principle of explosive crushing depends upon the fact that an expandable substance contained within the pores of a solid body will disrupt such a body upon expansion. Such expansion may be obtained by the detonation of an explosive or by the sudden release of pressure of a superheated liquid. That this principle of disruption may be applied to minerals rests on the fact that cracks, cleavage planes, and pores exist in all minerals to an extent hardly conceived possible heretofore. Crushing by this method takes advantage of forces applied from within the mineral rather than from forces applied from without. The application of a force from within would appear to be more effective.

Jan 1, 1932

By R. D. Leitch

The work of the United States Bureau of Mines on stream pollution by coal-mine drainage has included a study of seasonal variations in acidity and volume of several streams in Pennsylvania. The acidity of these streams has been determined during the two or three years prior to 1930 and the results may be considered to represent "normal" low water conditions. The summer of 1330, however, was unusually dry and represents what may be termed "extreme low water conditions on these streams. This report is a comparison of the results obtained for extreme low water of 1930 and for other years. The streams investigated were Buffalo Creek in Somerset County, Indian Creek (lower 5 miles) in Westmoreland County, Little Toby Creek in Elk and Jefferson Counties, Daguscohonda Run in Elk County and West Creek in Elk and Cameron Counties. These will be treated separately in the order given. Most of the descriptive matter and physical data pertinent to the streams and drainage basins are taken from published reports of the Pennsylvania State Water Supply Commission, 1917.

Jan 1, 1931

By R. D. Leitch

The work of the United States Bureau of Mines on stream pollution3 by coal-mine drainage has included a study of seasonal variations in acidity and volume of several streams in Pennsylvania. The acidity of these streams has been determined during the two or three years prior to 1930 and the results may be considered to represent "normal" low water conditions. The summer of 1930, however, was unusually dry and represents what may be termed "extreme" low water conditions on these streams. This report is a comparison of the results obtained for extreme low water of 1930 and for other years. The streams investigated were Buffalo Creek in Somerset County, Indian Creek (lower 5 miles) in Westmoreland County, Little Toby Creek in Elk and Jefferson Counties, Daguscahonda Run in Elk County and West Creek in Elk and Cameron Counties. These will be treated separately in the order given. Most of the descriptive matter and physical data pertinent to the streams and drainage basins are taken from published reports of the Pennsylvania State Water Supply Commission, 1917.4

Jan 1, 1931

By Lathrop E. Roberts

The opinion is general among smelter operators that magnetite formed in the converter and reverberatory furnace has much to do with the loss of copper in the slag. Its action appears to be due in part to its relatively high infusibility, chemical stability, and specific gravity, as a result of Which it tends to form a layer of highly viscous "magnetite mush" between slag and matte. Particles of matte which might otherwise settle out of the slag are unable to pass through this layer. Maier and Van Arsdele have shown that the inclusion of grills of matte in the slag is also at tires very probably due to chemical reaction between magnetite and the constituents of the matte. In smelter control and in any laboratory study of slats the determination of magnetite is therefore a matter of some importance. The difficulties in the ray of making such a determination with any accuracy are rather obvious. Iron may occur in slag as ferric oxide, magnetite, various intermediate oxides, sulphides, silicates, as free metal, and in solid solution of several of these substances. Even if only the total iron content is to be determined, accuracy can be obtained only by painstaking and time-consuming separations from interfering elements. The determination of ferrous, ferric, and free iron in the presence of each other is a difficult matter under the most favorable conditions, and when present in a slag the difficulties are increased by the refractory nature of the sample, by the presence of sulphides, and by such elements as vanadium and molybdenum.

Jan 1, 1931

By Lathrop E. Roberts

[The opinion is general among smelter operators that magnetite formed in the converter and reverberatory furnace has much to do with the loss of copper in the slag. Its action appears to be due in part to its relatively high infusibility, chemical stability, and specific gravity, as a result of which it tends to fern a layer of highly viscous. "magnetite mush" between slag and matte. Particles of matte which might otherwise settle out of the slag are unable to pass through this layer. Maier and, Van Arsdale4 have shorn that the inclusion of prills of matte in the slag is also at times very probably due to chemical reaction between magnetite and the constituents of the matte. In smelter control and in envy laboratory study of slats the determination of magnetite is therefore a matter of some importance. The difficulties in the ray of making such a determination with any accuracy are rather obvious. Iron may occur in slog as ferric oxide, magnetite, various intermediate oxides, sulphides, silicates, as free metal, and in solid solution of several of these substances. Even of only the total iron content is to be determined, accuracy can be obtained only by painstaking and time-consuming separation ions from interfering elements. The determination of ferrous, ferric, and free iron in the presence of each other is a difficult matter under the most favorable conditions, and linen present in a slag the difficulties are increased by the refractory nature of the sample, by the presence of sulphides, and by ouch elements as vanadium and molybdenum.]

Jan 1, 1931

By C. W. Owings

"PURPOSE OF REPORTThe safety and efficacy of permissible storage—battery gathering locomotives are becoming recognized more and more in coal mines. The great mobility of this type of haulage equipment is due to the fact that no trolley wire and bonding of rails are needed; hence wherever there is track and adequate ventilation to dilute properly any dangerous gases, the storage—battery gathering locomotive may go. As coal near the outcrop or the surface is mined out, coal farther from the outcrop or deeper in the ground must be mined, and gassiness of the coal bed often increases under these conditions. The use of electrical equip¬ment capable of giving off arcs or sparks while operating near or at the coal faces constitutes a serious explosion hazard. Often, it is uneconomical or impracticable to use animal haulage, and locomotives must be employed. The operator should consider the safest and most economical unit; permissible equipment is the answer to this problem, and storage—battery locomotives are the only permissible electric haulage units.A comparison of permissible storage—battery locomotives with cable—reel locomotives of the latest enclosed ""explosion—tested"" type has been made at the Keystone No. 1 mine of the Houston Collieries Co., at Keys one, W. Va. The information and data contained in this publication were obtained by the writer during an inspection of haulage at this mine.ACKNOWLEDGMENTSThe writer is indebted to P. C. Thomas, vice president and general manager, the Koppers Coal Co., operator of the Keystone mines, who granted permission for making the study. W. A. Wilson, general superintendent, Houston Collieries Co., arranged for the investigation and for obtaining the data. C. E. Zuspan, chief electrical inspector, and J. C. Newman, division electrical inspector, accompanied the writer underground and assisted materially in obtaining information and data upon the haulage methods and performance of the locomotives. The assistance or general mine Foreman Pierman and of mine foreman White is gratefully acknowledged."

Aug 1, 1931

By John M. Devine

Hydrogen sulphide associated with natural gas was noted as early as 1892, at Point Albino, Canada.4 The presence of this impurity was recognized also in other of the earlier oil and gas fields, although the occurrence urea by no means common. However, in recent years, with the development of the producing zones of west Texas and the Texas Panhandle, the production of "sour" crude has increased greatly and hydrogen sulphide has proved a generally troublesome factor--frequently a major problem--in the drilling and operation of many wells in those areas. The problems arising from the drilling and producing of oil or gas wells in hydrogen-sulphide areas, fall under two general divisions: safety problems and corrosion problems. Mention is mane of a third division which is closely related to the other two, that of treating--or the development of processes for the removal of hydrogen sulphide. From the standpoint of safety end health hazards, hydrogen sulphide in the petroleum industry has been discussed in a number of publications. 5 Likewise, the problem of hydrogen-sulphide

Jan 1, 1931

By C. W. Owings

"Ventilation is one of the most important features of coal mining, and if a mine is exceptionally gassy it is often difficult to ventilate it in such a way as to make it safe. The general system of splitting the main air current so that two, three, or more sets of room entries are ventilated by the same current of air does not provide a safe method if non-permissible electrical equipment, such as cable-reel, crab-reel, or trolley locomotives are used on gathering haulage, or if open-type hoist or pump motors are used. The problem has been greatly simplified at the Crucible mine of the Crucible Fuel Co. at Crucible, Pennsylvania.The system is not only applicable to the room-and-pillar method of mining, but it may be adopted for any panel system of mining. There also appears to be a definite application in mechanized mining, where the rapid extraction often results in inadequate attention to ventilation and where the gassiness of the section generally increases because, as compared to hand loading, the methane has less time to drain off. The system to be described should commend itself to coal-mining men.ACKNOWLEDGMENTSThis investigation was made possible through the courtesy of H. J. Nelms, general superintendent. E. M. Marshall, safety inspector, E. G. Sauers, assistant superintendent, and Thomas Mark, mine foreman, assisted in the collection of information."

Sep 1, 1931

By John M. Devine

Hydrogen sulphide associated with natural gas was noted as early as at Point Albino, Canada. The presence of this impurity was recognized also in other of the earlier oil and gas fields, although the occurrence was by no means common. However, in recent years, with the development of the producing zones of test Texas and the Texas Panhandle, the Production of "sour" crude has increased greatly and hydrogen sulphide has proved a generally troublesome factor--frequently a major problem--in the drilling and operation of many wells in those areas. The problems arising from the drilling and producing of oil or gas wells in hydrogen-sulphide areas, fall under two general divisions: safety problems and corrosion problems. Mention is made of a third division which is closely related to the other two, that of treating--or the development of processes for the removal of hydrogen iron the standpoint of safety and health hazards, hydrogen sulphide in the petroleum industry has been discussed in a number of publications. Likewise, the problem of hydrogen-sulphide corrosion of production equipment has been given considerable attention in the literature.

Jan 1, 1931

By C. J. Wilhelm, John M. Devine

"Hydrogen aulphide associated with natural as was noted as early as at Point Albino, Canada. 4 The presence of this impurity was recognized also in other of the earlier oil and gas fields, although the occurrence ma by no means common. However, in recent years, with the development of the producing zones of west Texas and the Texas Panhandle the production of ""sour"" crude has increased greatly and hydrogen sulphide has proved a generally troublesome factor-frequently a major problem—in the drilling and operation of any wells in those areas.The problems arising from the drilling and producing of oil or gas wells in hydrogen-sulphide areas, fall under two general divisions: safety problems and corrosion problems. Mention is made of a third division which is closely related to the other two, that of treating--or the development of processes for the removal of hydrogen sulphide. From the standpoint of safety and health hazards, hydrogen sulphide in the petroleum industry has been discussed in a number of publications. 5 Likewise, the problem of hydrogen-sulphide corrosion of production equipment has been given considerable attention in the literature.6"

Sep 1, 1931

By E. C. Lane

This paper is the first part of a report giving the results of the Bureau of Mines' twenty-third semiannual survey of motor gasoline marketed in the United States. A companion report, Part II, is in preparation and will give a more detailed discussion of the whole survey. Results of the determination of copper-strip corrosion, color, sulphur content, copper-dish evaporation residue, and gum content as given by the Bureau of Mines steam-oven method will be presented in the second paper, which will also include the prevailing retail price and the tax at the time the sample was taken. This paper deals specifically with data relative to gravity, Reid vapor pressure,5 and distillation (method 100.13).6 The samples tested were divided into "competitive-price gasolines" and "premium-price motor fuels," a method of presentation that was begun with the twenty-second semiannual survey.7 A total of 312 samples were collected from service station pumps in 20 cities throughout the United States. Of this number of samples, 207 were "competitive-price gasolines" and 105 were "premium-price motor fuels." All of the samples were collected in March, 1931, and analyzed at the Petroleum Experiment Station of the United States Bureau of Miner at Bartlesville, Okla.

Jan 1, 1931

By E. C. Lane

This paper is the first putt of a report giving the results of the Bureau of Mines' twenty-third semiannual survey of motor gasoline marketed in the United States. A companion report, Part II, is in preparation and will give a more detailed discussion of the whole survey. Results of the determination of copper-strip corrosion, color, sulphur content, copper-dish evaporation residue, and gum content as given by the Bureau of Mines steam-oven method will be presented in the second paper, which will also include the prevailing retail price and the tax at the time the sample was taken. This paper deals specifically with data relative to gravity, Reid vapor pressure,' and distillation (method 100.13).6 The samples tested were divided into "competitive-price gasolines" and "premium-price motor fuels," a method of presentation that was begun with the twenty-second semiannual survey. A total of 312 samples were collected from service station pumps in 20 cities throughout the United States. Of this number of samples, 207 were "com-petitive-price gasolines" and 106 were "premium-price motor fuels." All of the samples were collected in March, 1931, and analyzed at the Petroleum Experiment Station of the United States Bureau of Mines at Bartlesville, Okla. "Competitive-price gasoline" includes those fuels that are sold at the generally recognized local base price and all fuels that are sold below that price. All fuels that are sold at an advance over the generally recognized base price are placed in the class of "premium-price motor fuels." These fuels include Ethyl gasolines, benzol blends, "high-test" fuels, and those fuels that owe their "anti-knock" rating to the process of manufacture rather than to the addition of other material such as Ethyl fluid or benzol. The term "high-test" is generally applied to motor fuels that are more volatile than the regular competitive-price gasolines. "High-test" fuels may also have a high anti-knock rating.

Jan 1, 1931

By Ludwig Schmidt

This report, the second of a series, presents the results of laboratory corrosion studies which were made in connection with a one-year test on aluminum lease tanks conducted by the United States Bureau of Mines. Part I of the report contains the results of the field teats.5 The studies were made on an oil lease in a so-called "sour district," near Borger, Tag., where free hydrogen sulphide accompanied the production of oil, gas, and salt water. Steel tanks previously used on the lease had suffered severe corrosion, because steel is inherently susceptible to attack by hydrogen sulphide. Because of the high resistivity of aluminum to the action of hydrogen sulphide, it Was believed that this metal had promising possibilities as a material for the construction of lease tanks in "sour districts." The results of the one-year field teat proved that aluminum lease tanks will withstand corrosion by hydrogen sulphide, but it was found that aluminum was susceptible to attack by salt water, which was invariably present in certain portions of the tanks, and that hydrogen sulphide accelerated this salt-water corrosion in an indirect manner, as will be explained hereinafter. In order to study corrosion conditions encountered in the tanks during the test period, a laboratory was maintained at the site of the aluminum lease tanks.

Jan 1, 1931