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By William L. Crentz

This study of the preparation characteristics of the coals in Indiana County, Pa., is the second in a series of Bureau publications appraising the Nation's coking-coal reserves by counties and the practicability of upgrading marginal deposits to metallurgical standards. The first publication dealt with the preparation characteristics of the principal coal beds in Cambria County, Pa. Over 95 percent of the coal remaining in Indiana County is in the Upper Freeport, Lower Freeport, and Lower Kittanning beds. Isolated patches of Pittsburgh-bed coal are present, and the Upper Kittanning bed is found in minable thickness at some locations, but production from these sources is not large. The greatest production is from the Freeport beds, which account for nearly 70 percent of the Indiana County coal output. These beds usually contain two or more shale or hone partings and in many places are high in sulfur. The large proportion of bony coal in the Freeport beds 'produces a relatively high-ash product. Mining practices vary from place to place, but it is frequently necessary to leave certain bony portions of the bed in place in order to load a satisfactory product. Table 1 shows the county's coal production, by beds, during 1948.

Jan 1, 1951

By J. Feldman

This report contains a description of the distillation laboratory at Bruceton, Pa., which was established to aid in the separation and identification of the products produced in the synthetic liquid fuel processes under study there. Compounds present in synthetic liquid fuels may include aliphatic from C1 to C60 or greater. Alcohols, ketones, esters, aliphatic carboxylic acids, saturated hydrocarbons, olefins, and diolefins are all found in Fischer-Tropsch products. Coal-hydrogenation products contain, in addition to aliphatic compounds, a large proportion of naphthenic material and aromatic compounds ranging from benzene to coronene; in addition, appreciable quantities of tar bases and tar acids are present. In designing the laboratory, therefore, provision had to be wade for the greatest amount of flexibility and versatility. A great deal of standardization of basic equipment had also to be designed to permit interchange of parts and services.

Jan 1, 1951

By Foster Fraas

Electrostatic separation depends on a number of electrical and mechanical properties such as conductance, contact potential, dielectric constant, and particle shape. In routine testing it is desirable that the application of each of those properties be investigated. The conductance property is best utilized in a separator having an ionic field, whereas the contact potential requires a separator with a pure static field. Dielectric constant and particle shape also influence the response in these two fields. There is no separator on the market that can be adjusted for all these requirements. The separator described in this paper is satisfactory for this purpose and is provided with a dielectric electrode, which permits formation of high-intensity static fields.

Jan 1, 1951

By K. C. Dean

During investigation of the occurrence of manganese deposits in the western United States, examining engineers of the Bureau of Mines collected samples from several properties in Montana. Extensive laboratory tests were made to determine the amenability of these ores to standard ore-dressing methods of concentration to produce marketable-grade products. The Tzarena claim, one of the properties sampled, is on the western end of the Rama or Black Chief vein in the city of Butte, Silver Bow County, Mont., on the southwestern periphery of the mining district. The Black Chief 'WAR system contains one of the largest and most extensive known rhodochrosite deposits in the world. Test work was conducted on two samples of Tzarena ore. Sample 1 is representative of a vain 5 feet wide on the 150-foot level of the Tzarena shaft. Sample 2 is representative of a vein 8 feet wide in the 100-foot level of the shaft. The Minnie Jane mine, 1/2 mile northwest of the Tzarena claim, contains ore similar in mineralogical composition to Tzarena ore but differing materially in manganese content and to some extent in physical characteristics. Ore-dressing investigations were made on three samples of Minnie Jane ore. Sample 1 represented stock-piled ore, sample 2 represented ore from Minnie Jane mine having a considerable sulfide content, and sample 3 represented low-grade ore.

Jan 1, 1951

By Ralph H. Espach

In the spring of 1943, when it was evident that the Tensleep sandstone in the Elk Basin field, Wyoming and Montana, held a large reserve of petroleum, Bureau of Mines engineers obtained samples of oil from the bottom of nine wells and analyzed them for such physical characteristics as the volumes of gas in solution, saturation pressures or bubble points, shrinkage in volume caused by the release of gas from solution, expansion of the oil with decrease in pressure, and other related properties. The composition of the gas in solution in the oil was studied. The pressures and temperatures existing in the reservoir and the productivity characteristics of the oil wells were determined. The data obtained indicate that the oil in the Tensleep reservoir of the Elk Basin field has unusually varying physical characteristics, such as a saturation pressure of 1,250 pounds per square inch absolute and 490 cubic feet of gas in solution in a barrel of oil at the crest of the structure, and a saturation pressure of 530 pounds per square inch absolute and 134 cubic feet of gas in solution in a barrel of oil low on the flanks. The hydrogen sulfide content of the 6a r; in solution in the oil varies from 18 percent for oil on the crest to 5 percent for oil low on the flanks of the structure. Of even greater significance is the fact that these and other variable characteristics of the reservoir oil are related to the position of oil in the structure. Many geologists and petroleum engineers have considered all the oil in a petroleum reservoir to have uniform physical characteristics and that equilibrium conditions prevailed in all underground accumulations of oil and gas. That such is not always so is borne out by the results of the study made by the writers.

Jan 1, 1951

The United States has not begun commercial operations to tap its largest poten-tial sources of oil supply - oil shale and coal. The reason is that domestic petrol-eum has been plentiful in the past and liquid products probably could be produced from it at the lowest cost. In view of the ever-increasing need for petroleum in the United States, the critical international situation threatening foreign supplies, the growing demands for steel, and the heavy costs to industry of constantly discovering and developing new oil fields, it is believed that the prompt development of a synthetic fuel industry based on oil shale and coal is not only requisite to safeguard our oil supply but is an economically sound course for the foreseeable future. To neglect its development is to close our eyes and minds to our own resources at a time when they are needed critically. It also is apparent now that neither the Government nor industry would be taking any considerable economic risk in starting the initial plants, especially as measured against their potential value in meeting critical oil and chemical demands and in building a new industry in the West.

Jan 1, 1951

The United States has not begun commercial operations to tap its largest poten-tial sources of oil supply - oil shale and coal. The reason is that domestic petrol-eum has been plentiful in the past and liquid products probably could be produced from it at the lowest cost. In view of the ever-increasing need for petroleum in the United States, the critical international situation threatening foreign supplies, the growing demands for steel, and the heavy costs to industry of constantly discovering and developing new oil fields, it is believed that the prompt development of a synthetic fuel industry based on oil shale and coal is not only requisite to safeguard our oil supply but is an economically sound course for the foreseeable future, To neglect its development is to close our eyes and minds to our own resources at a time when they are needed critically. It also is apparent now that neither the Government nor industry would be taking any considerable economic risk in starting the initial plants, especially as measured against their potential value in meeting critical oil and chemical demands and in building a new industry in the West.

Jan 1, 1951

The United States has not begun commercial operations to tap its largest poten-tial sources of oil supply - oil shale and coal. The reason is that domestic petrol-eum has been plentiful in the past and liquid products probably could be produced from it at the lowest cost. In view of the ever-increasing need for petroleum in the United States, the critical international situation threatening foreign supplies, the growing demands for steel, and the heavy costs to industry of constantly discovering and developing new oil fields, it is believed that the prompt development of a synthetic fuel industry based on oil shale and coal is not only requisite to safeguard our oil supply but is an economically sound course for the foreseeable future. To neglect its development is to close our eyes and minds to our own resources at a time when they are needed critically. It also is apparent now that neither the Government nor industry would be taking any considerable economic risk in starting the initial plants, especially as measured against their potential value in meeting critical oil and chemical demands and in building a new industry in the West.

Jan 1, 1951

By Russell R. Trengrove

The Copper Canyon lead-zinc mine is in the Battle Mountain. District, Lander County, Nev. It was discovered in 1866 and mined for copper until 1935 and for copper and gold until l948, when the main production became lead-zinc ore. The rocks in the area are carboniferous (Pennsylvanian and Mississippian) sedimentaries that have been intruded by quartz monzonite of Mesozoic age. They have been intensely folded, faulted, and tilted. Lead-zinc ore occurs as sulfides disseminated along fractured zones in a conglomerate arid hornfels. Development was carried out by the Bureau of Mines in cooperation with the U. S. Geological Survey and comprised a study of the geology, making maps and. cross sections, and exploring the deposit by diamond drilling from underground. Eighteen holes were drilled, for a total of 2,594 feet. This report contains a brief history of the property and a description of mining methods and beneficiation of the ore, geology, ore deposits and drilling done by the Bureau of Mines. It also contains detailed analyses of the ore samples taken and logs of the holes drilled.

Jan 1, 1951

By H. R. Batchelder

Much information on oxygen production and the manufacture of synthetic liquid fuels has been published during the past several years. From time to tine the investment and operating cost of oxygen plants of various sizes has been estimated. Surveys have been made so that the various processes by which oxygen is produced commercially might be compared. The gas-making processes in which oxygen is employed, which wore used in Germany during the war, have been described in T.O.M. reels, and this information has been published. Descriptions of pilot-scale or proposed commercial plants for the production of synthesis gas or hydrogen and their conversion to synthetic liquid fuels also have been published. In general, each of these publications has dealt with a particular phase of the over-all problem. The present paper will discuss the relationship between these phases: The factors that affect oxygen manufacture and costs, the methods for the use of oxygen and for the production of synthetic liquid fuels, and, to some extent, the economic factors that must be considered.

Jan 1, 1951

By Boyd Guthrie

As the American petroleum industry surveyed its position in early 1937, it had many reasons to be optimistic concerning its future. The industry had emerged successfully from the depression, and for the first time since 1929 it had produced over one billion barrels of crude oil in a single year. The demand for gasoline and fuel oils was up, and reserves of crude petroleum and production capacity seemed adequate for the future. Although production of crude oil dropped slightly in 1938, the oil industry was still in a good position with respect to its supply of raw material, which improved economically in 1939 with the decrease of crude-oil stocks in storage above ground. However, by 1940 a threatening cloud (the invasion of France and its rapid surrender) had appeared on the horizon. This aroused Somme fears as to the industry's immediate future, and these fears were intensified the following year when the United States entered World War II. As the war progressed, more and more ships, planes, and vehicles were produced, and the problem of obtaining enough liquid fuels to supply them intensified. Hearings were held in August 1943 before a subcommittee of the Committee on Public Lands and Surveys of the 78th Congress to determine the advisability of passing legislation to promote the development of synthetic liquid fuels.

Jan 1, 1951

By H. A. Watson

The introduction and use of synthetic materials in various applications may lead to potential hazards from toxic, gaseous, decomposition products if these materials are subjected to conditions abnormal to their intended use, such as high temperatures or burning from accidental causes. This report covers an investigation of such possible hazards from toxic gases produced by the burning or thermal decomposition of some low-density, expanded, synthetic materials, three of which consisted of polyvinylchloride and one of acrylonitrile. In the production of certain expanded plastic materials, Chemical blowing agents frequently are used to produce a cellular structure. One of these blowing or foaming agents contains azo-bis-isobutyronitrile, which is designated in this report as PN. Information indicates that a product of decomposition of this blowing agent, formed in the blowing operation, is tetra-methyl-succino-nitrile, designated as TSN, Which is significantly toxic. Decomposition of the blowing agent, with release of its azo nitrogen, is represented by the following reaction:

Jan 1, 1951

By William E. Eckard

Production of oil from a narrow shoestring sand presents problems unique in the oil industry. Especially important, from both an engineering end an economic standpoint, are the limitations imposed upon well patterns and spacings by the shape of the field. This report concerns a study of the Paola shoestring, Miami and Franklin Counties, Kane., where well density of 0.85 acre per well was not uncommon to insure profitable primary recovery in a reasonable time. However, such a great number of wells increased the operator's investment and reduced his profit considerably. It was the purpose of this study to investigate various well patterns and spacings applicable to water-flooding a shoestring reservoir and the effect of these factors upon recovery of oil and the most profitable operation of the pool. The designer of well patterns for a shoestring sand should evaluate carefully the edges of the shoestring, even though they may be considered too thin to drill. These comparatively thin edges contain large quantities of recoverable oil; moreover they are resaturated with oil as the pool is water-flooded.

Jan 1, 1951

By T. F. Mitchell

As a part of the program of investigation of domestic sources of manganese ore, mining engineers of the Bureau of Mines examined and obtained samples of ore from two properties in the vicinity of Bettie Mountain, Lander County, Nev. In addition, samples from three claims in the Carico Lake region, Lander County, Nev., were submitted by private interests. RS the ores were too low in grade to be acceptable for the direct production of ferromanganese, their amenability to concentration by ore dressing was investigated. The Black Bock property is 16 miles south of Valmy, Nev., and is owned by Western Alloys, Inc., Salt Lake City, Utah. The deposit is a replacement of sedimentary rock by manganese oxides. Ore occurs in two main ore bodies designated as the "upper bench" and "lower bench", which could be mined separately. Examining engineers obtained samples from each ore body, and laboratory experiments were made on each sample. The Black Eagle group of claims is in Lander County, Nov., about 43 miles southwest of Battle Mountain. Ore occurs as a replacement of manganese oxides in shale and chert. The 2-ton sample of ore used for laboratory testing was taken by a Bureau of Mines examining engineer from an adit that partly transversed a 28-foot bed of ore. The property is controlled by Western Alloys, Inc.

Jan 1, 1951

By H. R. Batchelder

The Bureau of Mines Gas Synthesis Demonstration Plant at Louisiana, Mo., includes apparatus for the gasification of pulverized coal with oxygen and superheated steam. A pebble heater constructed by the Babcock & Wilcox Co. is used to superheat nominal 5-pound steam for the gasification process, usually to temperatures of 1,600° to 2,300° F. with flow rates of 1,400 to 2,300 pounds per hour. Heaters of this sort have been described. So far as is known, the Babcock & Wilcox Co. is the sole commercial manufacturer of equipment of this type. Units have been built with capacities above 18,000 pounds of steam per hour.

Jan 1, 1951

By D. E. Stone

Solid and liquid impurities must be removed almost completely from synthesis gas for the production of synthetic liquid fuels because of their effect on the synthesis catalyst and turbocompressors. The maximum permissible concentration of dust has been set at 0.05 grain per 100 cubic feet.5/ This is one part per million by weight, or about the same concentration as in average city air. The cost of synthesis gas is estimated to constitute 60 to 70 percent of the total cost of the synthetic liquid fuel. For this reason this station is developing processes using coal instead of the more valuable coke as raw material, which promises reduction in cost of the synthesis gas. This, however, increases the difficulty of attaining the above dust value. As failure of the dust-removing equipment to produce high-purity gas may ruin valuable equipment within a few minutes, it is imperative that a reliable and continuous method be obtained for determining such extremely low concentrations .of dust in the purified gas. A suitable device must also instantly sound an alarm and, if necessary, automatically actuate the proper valves to prevent damage. The Ess Instrument Co. designed and built an instrument which they believed might fulfill these specifications. It' continually compared, by means of photoelectric cells, the intensity of a light beam passing through the gas and a similar beam passing through clean air. For maximum sensitivity, the photocells were connected back to back, i.e., anode to cathode and cathode to anode. The difference in voltage produced by the two cells was amplified and operated an indicator.

Jan 1, 1951

By John W. Cole

The Butte district has been the principal producer of metallurgical-grade manganese in the United States since World War I. Manganese dioxide nodules are produced from rhodochrosite ore by concentrating the rhodochrosite and roasting the concentrate in rotary "cement-type" kilns. The Anaconda Copper Mining Co. is the only producer at present. Under the stimulus of a purchasing program administered by Metals Reserve Company during World War II, however, several independently owned or operated mines (including the Norwich) produced manganese carbonate ore. These mines were examined in Juno 1949 by John W. Taber, mining engineer, Bureau of Mines. A core-drilling program to develop ore in the Norwich mine was recommended and approved. drilling was completed early in 1950. This report gives factual data obtained.

Jan 1, 1951

By K. C. Dean

During the investigations of the occurrence of manganese in the Western United States, a Bureau of Mines examining engineer collected samples frame two properties in Beaver County, Utah. As the ores were too low in grade to be acceptable by manufacturers of ferromanganese, beneficiation studies were made to determine the amenability of the ores to concentration. The Steelville property is about 37 miles southwest of Frisco, Utah. The deposit is an example of manganese occurring as a replacement of limestone in a bedded vein or as layers in limestone associated with shale and rock decomposition products. The Susie Q deposit, about 33 miles southwest of Milford, Utah, is also a tabular replacement deposit in limestone, apparently of limited extent. Test work was done on representative samples of 2-ton lots obtained by the examining 'engineer from each of the properties mentioned.

Jan 1, 1951

By T. A. Hendrickson

The Bohemia district, situated about 30 miles southeast of Cottage Grove, Oreg., in the Calapooia Range, has been the major producer of lead and zinc in Oregon. Sporadic production has been Maintained from the district since its early discovery about 1858. In 1942, a selective-flotation mill was built at the Champien mine, which operated for only a short time and was forced to close because of the war and lack of labor. The Champion mill reportedly has been operated as a custom mill for the treatment of ore from the Musick and Helena mines, located in the district sometime in the past. This report summarizes the results of laboratory ore-dressing studies made on ore samples from the Musick and Helena Mines.

Jan 1, 1951

By W. E. Robinson

A laboratory study wan made to determine whether drying and preheating Colorado oil shale with waste retort gases has any appreciable effect on its oil yield. Samples of crushed oil shale were heated at subretorting temperatures in a specially constructed electric furnace by gases similar in composition to waste gases from oil-shale retorts. The results of this study showed that preheating oil shale with nitrogen or a reducing mixture had no effect upon the oil or water yield. However, oxygen in the preheating gas caused a decrease of oil and an increase of water. In general, the oil yield decreased with (1) increase in oxygen content of the heating gases, (2) increase in temperature of the heating gas, (3) increase in heating time, and (4) decrease in the particle size of tho shale. The decrease in oil and the increase in water resulting from preheating were due to oxidation of the benzene-insoluble organic material (kerogen) rather than to oxidation of the benzene-soluble organic material (natural bitumen) in the shale, A small amount of oil was volatilized during preheating, which would constitute an additional loss if prober precautions were not taken to recover it. The results obtained in this laboratory study indicate that oil shale can be preheated without appreciable decrease in oil yield by proper selection of preheating conditions.

Jan 1, 1951