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By D. G. Foot

The Bureau of Mines devised a direct flotation method for recovering potash from carnallite (KC1?MgC12?6H20) ore characterized by a high content of water-insoluble impurities. The method includes (1) a decomposition leach of the carnallite, (2) flocculation-depression of the insoluble slimes, (3) potash rougher, cleaner, and recleaner flotation, and (4) final product leaching. The technique eliminates the necessity for removing the water-insoluble slimes by mechanical or flotation de-sliming. Laboratory results demonstrated that the direct flotation procedure, when compared with conventional techniques, yielded equivalent or improved flotation results with equal or less reagent consumption. Locked-cycle testing of the direct flotation method recovered 87.8 pct of the potassium in the flotation feed in a final product containing 60.6 pct K20. A flowsheet incorporating the carnallite leaching-potash flotation procedure is presented.

Jan 1, 1982

By J. I. Paige

As part of a continuing effort to develop technology that maximizes mineral and metal recovery from domestic resources, the Bureau of Mines investigated a method to totally utilize copper converter slags without recycling them back through the matte smelting furnace. The research was directed toward (1) recovering the contained copper in converting slags by producing a recyclable copper-iron matte, (2) carbothermically reducing the slags to recover the iron, and (3) producing slag wool from the depleted slags. This report deals with the reduction of three industrial converting slags, containing 2.0 to 7.3 wt-pct Cu, in an 800-kVA electric arc furnace to produce a recyclable copper-iron matte. The addition of sufficient iron pyrite to provide 29 to 113 pct of the stoichiometric sulfur (based on producing 40-pct-Cu matte) produced a recyclable matte (36 to 61 pct Cu) at an energy consumption of 520 to 700 kWh per ton of solid material charged. The expected energy saving for treating molten slag in an electric furnace (5-to 9-MVA range) is about 400 kWh per ton of molten slag treated.

Jan 1, 1982

By Victor R. Spironello

The Bureau of Mines has conducted studies of the slags related to ferrous technology to evaluate experimentally acceptable substitutes for the auxiliary flux, mineral fluorspar, in steelmaking operations. Comparative heats were made in a 1/4-ton, pilot-scale, basic oxygen furnace (BOF) to evaluate a waste material known as "used potlining." Used pot lining is recovered from alumina reduction cells after its useful life and contains significant levels of fluorine and sodium in various compounds. This material in both lump and pelletized form provided adequately fluid slags, based on observations made during BOF operation. No adverse effects were found on furnace performance, metal and slag chemsitry, the strength of the steel produced, or the environment. Fluorine recovery in the slag was about the same as that obtained when using fluorspar, as were the losses to the scrubber water and solids. No difference was observed in furnace-refractory attack, as determined by the level of magnesia in the slag. The sodium recovered in the slag apparently also contributed to fluidity, since the fluorine input was at about two-thirds that of the fluorspar. Used potlining was determined experimentally to be a satisfactory substitute for fluorspar in basic oxygen steelmaking.

Jan 1, 1982

By David M. Hyman

The Bureau of Mines has developed two experimental designs for deter- mining the volumes and relative proportions of the various gas species, particularly methane (CH4), occluded in rock salt. To date, the rock salt samples analyzed have been relatively small (400- to 1,000-gram) grab samples from Louisiana Gulf Coast domal salt mines. The results obtained are comparable to results in Polish domal salt mines, in terms of occluded gas volumes per mass of rock salt. The notable difference between the Louisiana and Polish occluded gas mixtures is in the relative proportions of the individual gas species. The two methods used by the Bureau are ballmill crushing and dissolution. Of the two, the dissolution method appears to be more versatile because it can be performed in situ. The relevance and applicability of data on the occluded gas contents of rock salt are dependent on sample size, sample collection method, geologic context of the sample, and the correlation with gas emissions that occur as a result of mining-induced fractures and pressure differentials.

Jan 1, 1982

By John Durkin

The Bureau of Mines has conducted field studies in coal mines through- out the United States to determine the effectiveness of electromagnetic techniques in locating miners trapped underground following a mine accident. Data from these tests have been used to generate models of expected signal and noise distributions as found above mines throughout the coalfields. These distributions have aided in placing the expected performance of a through-the-earth electromagnetic communications technique into a probabilistic framework. Results show that at a 10-pct false alarm rate, the expected probability of detecting a miner's signal from a depth of 1,000 ft is 54 pct; at 500 ft it is 95 pct. These depths exceed the actual depths of 90 pct and 50 pct, respectively, of U.S. coal mines. Sensitivity studies have shown that at a depth of 1,000 ft, for every 3 db of improvement in signal-to-noise ratio, the probability of detection increases 6 to 8 pct.

Jan 1, 1982

By Yael Miron

ANFO blasting agents may undergo an exothermic reaction when they contact warm ore bodies that contain pyrite and its weathering products. The reaction is very fast at temperatures above 80° C. Urea, when present in sufficient amounts, inhibits this reaction at temperatures below 180° C. But urea-ammonium nitrate mixtures are very hygroscopic and, in certain climates, may be difficult to handle in the field. Reaction-inhibiting characteristics of three compounds were reported by the Bureau of Mines in 1979. Recently, the Bureau investigated the reaction-inhibiting qualities of five additional compounds. Mixtures of ANFO, pyrite, weathering product, and prospective inhibitors were slowly heated, under conditions simulating a hot borehole, to determine prospective inhibitor capability at temperatures up to ~175° C. Small-scale thermal tests of the same mixtures were used for verification and clarification of results. Two organic compounds, phthalimide and xanthine, similar in structure to urea, failed to inhibit the reaction. Zinc oxide and calcium carbonate were found inferior to urea, though zinc oxide raised the onset of reaction from 80° C to about 140° C. Only magnesium oxide was found to be similar to urea in its inhibitory ability at temperatures below 175° C. Based on results from analysis of quenched residues, the use of more than 5 wt-pct magnesium oxide is recommended.

Jan 1, 1982

By R. H. Lien

The Bureau of Mines has conducted research on a flue gas desulfurization (FGD) process as part of its goal of minimizing the undesirable environmental impacts associated with sulfur dioxide (S02)-bearing waste gases. This FGD process, referred to as the modified citrate process, involves absorption of S02 in a buffered citric acid solution. The absorbed S02 is subsequently stripped from the solution using steam, which regenerates the solution and produces a wet S02 product. This product can be further processed to make sulfuric acid or liquid S02. Economic evaluations showed the process to be expensive when the stripper was operated at or near ambient pressures because of the large amounts of steam required for solution regeneration. Research was directed at reducing steam consumption in the stripper. The effect of stripper pressure on steam consumption was investigated. A process research unit (PRU) was operated with the stripper pressurized in the range of 5 to 150 psig. Test results showed that steam consumption decreased with increased stripper pressure. For example, when operating the PRU stripper at 150 psig, 4.1 grams of steam per gram of S02 was required to remove 90 pct of the S02 from a 1.0-vol-pct-S02 gas. This compares to 7.1 grams of steam per gram of S02 required for 90-pct S02 recovery at 5 psig.

Jan 1, 1982

By Roy C. Bartholomae

This Bureau of Mines report presents the results of a laboratory investigation of coal cutting mechanics and noise. These experiments were performed using linear cutting apparatus that operates over a broad cutting speed range. The influence of several coal cutting parameters on the noise, force, productivity, and specific energy associated with linear cuts was ascertained. Some basic theoretical aspects of coal cutting mechanics and noise generation are discussed, and the results of the laboratory experiments are used to formulate analytical models of the coal cutting forces and noise. The analytical model for coal cutting noise is then generalized to account for the more important effects of rotary cutting. Based on the generalized model, an estimate of the sound pressure level at an operator's position is made for a typical continuous mining machine. It is concluded that by employing linear rather than rotary cuts, using deeper depths of cut, slower cutting speeds, and more efficient cutting tools, it is possible to reduce the level of coal cutting noise, as well as provide benefits to other important areas of health and safety in underground mining.

Jan 1, 1983

By Roy E. Peterson

The Bureau of Mines conducted bench-scale research to evaluate materials which showed potential as low-cost reductants for use in the ironmaking industry. These materials were lignite, subbituminous coal, coal char, tree trimmings, refuse--derived paperboard, used crankcase oil, and peat. To compare their effectiveness, the materials were tested in the reduction roasting of nonmagnetic taconite and, except for oil and peat, in the reduction of iron oxide pellets to metallized pellets. Reduction was conducted in a 18-cm-diameter, rotary drum, which was externally heated in an electric furnace. Over 92 pct of the iron was magnetically recovered from a nonmagnetic taconite after roasting with any of the reductants, but greater quantities of reductant were required to achieve this when the waste materials were used. The fossil fuels were also more effective for metallizing pellets, although metallizations above 90 pct were also obtained with tree trimmings and refuse paperboard. However, refuse paperboard had to be frequently recharged to the furnace because it depleted rapidly.

Jan 1, 1983

By G. R. Smith

Critical and strategic metals are often present in small quantities in low-grade domestic ores. When these ores are leached, the resulting solution usually contains the metals in very dilute quantities. Selective electrowinning from dilute electrolytes was investigated by the Bureau of Mines. A metal deposit containing 84 pct nickel was electrowon from the leach solution of a complex domestic ore bulk flotation concentrate originally containing approximately 2 wt-pct nickel. Key to achieving accelerated deposition rates, in the case of dilute solutions, is the rapid movement of the electrolyte through the electrowinning cell. Pure, synthetic nickel electrolytes were used to establish deposition parameters, and to optimize electrolyte velocity or mass transfer rates. Hydrodynamic and electrodeposition parameters for both the synthetic and leach electrolytes are presented and the experimental research described. Selective electrowinning appears to offer a viable alternative to physical separation methods to obtain separate metal "concentrates" from low-grade ores.

Jan 1, 1983

By B. W. Madsen

Bureau of Mines research to recover arsenic from mining industry waste material and process streams is reported. Batch and column approaches were investigated for adsorbing arsenic from acid leach solutions and ion-exchange eluate solutions with hydrated titanium dioxide granules. A method for producing hydrated titanium dioxide granules was devised to provide material suitable for use in a packed adsorption tower. Selective adsorption of arsenic from acidic leach solutions was achieved. The loading capacity of arsenic on the granules was 14 wt-pct when synthetic solutions were used, but lower when actual leach solutions were used. Other elements in the leach solution were Zn, Cd, and In. The granules were used in an attempt to lower the arsenic content in a solution containing 0.95 g/l W and 0.027 g/l As from a process devised by the Bureau of Mines to treat Searles Lake brine. The arsenic content was lowered to less than 0.001 g/l, but unacceptable amounts of tungsten also were adsorbed by the granules. Adsorbed tungsten was partially stripped with pH 11.5 NaOH, and both tungsten and arsenic were completely stripped with 5M NaOH solution. Repeated loading and stripping of the granules had no effect on the loading capacity for arsenic.

Jan 1, 1983

By Andrew B. Cecala

The Bureau of Mines conducted a brief laboratory study on the 10-mm diam Dorr-Oliver nylon cyclone to investigate (1) whether high wind speed (>300 ft/min), or sampler inlet orientation with respect to wind direction, can introduce errors when sampling respirable dust, and (2) whether any such errors can be reduced by using an inlet shield. Being preliminary in nature, the study was not structured to produce definitive results, but rather to discern likely trends and to indicate whether or not a more in-depth study of the problem is warranted. Photometric mass sensing measurements suggested that as the wind velocity increased, the cyclone sampling directly into the high-velocity airstream tended to oversample, relative to the cyclone sampling in a low-velocity airstream. Orientation of the sampler introduced measurable differences in sampling efficiency at higher wind velocities. A shield placed around the cyclone diminished the effects of wind velocity and sampler orientation on sampler performance. Results of this work offer sufficient evidence to substantiate the need for a more in-depth study.

Jan 1, 1983

By M. M. Wong

The Bureau of Mines, under a cooperative research program with four lead companies, has investigated a nonsmelting process for the production of lead metal. The process, which would eliminate sulfur dioxide generation and minimize particulate lead emissions, involves ferric chloride leaching of galena concentrate to produce lead chloride, followed by molten-salt electrolysis of the lead chloride to yield lead metal and chlorine. This chlorine is used to regenerate ferric chloride in the leaching solution. The process was tested in an experimental unit with a capacity of 500 lb of lead metal per day. The tests were performed in three 10-day and six 5-day campaigns, during a period spanning 28 mo. The study was carried out using a southeastern Missouri lead concentrate. Typical lead recovery was about 98 pct. Process problems related to impurity buildup and control were studied. When copper and silver impurities were removed from the leaching solution, a lead metal purity of 99.999 pct was obtained. Lead-in-air levels and lead-in-blood levels of operating personnel were monitored. The process has potential for producing lead with minimum pollution, but is not ready for commercial utilization. Operation of a prototype commercial electrolytic cell and a full-scale pilot-plant investigation by industry are needed to evaluate the commercial viability of the process.

Jan 1, 1983

By D. K. Steele

An 18-in-diam column water elutriator was designed, tested, and operated by the Bureau of Mines for recovering nonferrous mixed metals from automobile shredder rejects. The waver elutriator separated metals from nonmetals contained in shredded nonmagnetic rejects. The unit was constructed and integrated into a local automobile shredding operation. Nonmagnetic rejects from the automobile shredder were fed onto the surface of a column of rising water. Dense materials fell through the rising water and were collected as a sink product at the bottom of the column; medium-density materials were removed as an intermediate product in a water flow through a discharge port located between the overflow and sink; and light materials were immediately carried out in the overflowing water at the top of the column as a float product. Nearly 99 pct of the mixed metals were recovered from the nonmagnetic rejects as a 70-pct-metal concentrate. Other operating conditions yielded a 93.7-pct-pure-metal product resulting in a 93.1-pct metal recovery. Float rejects are combustibles, light plastics, foam rubber, and minimal amounts of coated and uncoated copper wire. The middling discharge contained mainly medium-density rubber, plastics, glass, rock, coated and uncoated copper wire, and frequently some thin-sheet stainless steel and wrought aluminum. Maximum metal recovery in the operating program was achieved using a water velocity of 52 fpm (650 gpm). Maximum purity was obtained with a velocity of 88 fpm (1,100 gpm). .Water was recycled through a 12,000-gal baffled clarifying tank. Entrainment water losses with the float and middling rejects averaged 50 gpt of reject feed. Records maintained by the shredder operator show a 34-pct increase in nonmagnetic metals recovery during a 1-yr operation of the water elutriator as compared to recoveries from a previously used air classification system.

Jan 1, 1983

By Victor R. Spironello

The Bureau of Mines has studied slags associated with ferrous melting, to evaluate substitutes for the auxiliary flux mineral, fluorspar. A waste material recovered from alumina reduction cells, "used potlining," was tested in an 18-in-ID basic-lined cupola and in a 1/4-ton, pilot-scale, basic oxygen furnace (BOF). One potlining fraction, No. 1 cut, is a carbonaceous (graphitic) material and represents the bulk of the entire cell lining. The other fraction, No. 2 cut, is a refractory backup. These materials contain significant quantities of fluorine and other elements fn various compounds. The potlining fractions were blended in ratios believed representative of available materials. Both lump and pelletized forms provided extremely fluid slag. No adverse effects were found on furnace performance, chemistry or strength of the metals produced, or the environment. Fluorine recovery in the slag and fluorine losses to the scrubber water and solids were about the same as when fluorspar was used. There was apparently no lining loss from the cupola, but there was lining attack in the BOF. Since the fluidizing ability of potlining is due in part to sodium and other elements such as aluminum and silicon, less fluorine is needed in the slags when potlining is used.

Jan 1, 1983

By V. R. Miller

The Bureau of Mines conducted research on substitute brazing filler alloys with properties similar to those of silver filler alloys in an effort to conserve silver and reduce hazards from cadmium emissions. Experimental work was conducted first on the commercial silver brazing alloys BAg-I, BAg-la, BAg-2, and BAg-3 to establish criteria for evalu-ating the substitute alloys. Properties investigated included the wettability of copper, brass, and steel substrates, and the strength of joints made with the filler alloys. A series of experimental alloys containing 50 to 60 pct Cu, 20 to 28 pct Mn, and 17 to 30 pct Zn was prepared and evaluated, together with Cu-Mn-Zn alloys with 5 pct Pb or 2 pct Ni. Wetting properties and joint strengths were not as good as those for silver filler alloys, and the high application temperatures reduced the copper and brass base metal strengths. However, experimental alloys containing 70 pct Cu, 15 to 20 pct Mn, and 10 to 16 pct Sn had wetting and strength properties approaching those of the silver filler alloys. The application temperatures for these alloys were high-er than those for silver fillers, but not as high as those for the Cu-Mn-Zn alloys. With the Cu-Mn-Sn alloy fillers, copper alloy joint members are less deteriorated by recrystallization than when applying Cu-Mn-Zn alloys. The Cu-Mn-Sn system has potential for further devel-opment as a substitute brazing alloy system, particularly if the melting temperature can be reduced by the addition of other elements without decreasing the ductility and wetting.

Jan 1, 1983

By Frank E. Chase

Kettlebottoms are columnar masses of rock--the preserved casts of ancient tree stumps--embedded in coal mine roof strata (of which they are a part). Because unsupported kettlebottoms can detach from a mine roof without warning, they are a hazard to miners. The primary objectives of this investigation were (1) to better define and describe kettlebottoms and (2) to evaluate kettlebottom support techniques in terms of safety and effectiveness. A telephone survey of mine operators, interviews with Mine Safety and Health Administration (MSHA) personnel, and underground mine visits were conducted in Pennsylvania, West Virginia, and Kentucky. Information gathered during this investigation indicates that the size and frequency of kettlebottoms in mine roof are dependent upon past geologic events and biological processes active during the deposition of roof sediments. To ensure the safety of mine personnel, all undermined kettlebottoms should be supported. The roof should be bolted next to kettlebottoms less than 3 ft in diameter, close enough to allow a portion of a wood or steel header to be extended beneath each kettlebottom for support. Two bolts and a wood plank or steel strap should be employed to support kettlebottoms over 3 ft in diameter.

Jan 1, 1983

By W. C. McBee

Over the past several years the Bureau of Mines has developed a sulfur concrete (SC) technology in which chemically modified sulfur is mixed with suitable mineral aggregates to produce construction materials that are resistant to corrosion by acids and salts. Modified SC materials have been tested in actual operating conditions in 50 corrosive process environments at 40 commercial plants. SC components ranging from small test coupons to 4-ton acid sump tanks were fabricated and installed at plant locations where chemical corrosion was destroying conventional concrete materials. Through cooperative agreements with several companies, floors, retaining walls, and foundations were cast in place us-ing SC materials, then monitored for resistance to corrosion and retention of strength properties.

Jan 1, 1983

By W. W. Simpson

The Bureau of Mines conducted research to determine the effects of potassium trithiocarbonate (KTTC), a degradation product of potassium ethylxanthate (KEX), on flotation of chalcopyrite and molybdenite. Small amounts of KTTC were identified in fresh and aged solutions of KEX using thin-layer chromotography. Hallimond tube flotation tests on pure minerals showed that KTTC acts as a weak collector for chalcopyrite. Both KEX and KTTC tend to depress molybdenite, but the depression effect is easily overcome by addition of a small quantity of fuel oil. The results of the Hallimond tube tests were confirmed in batch flotation tests using a porphyry copper ore.

Jan 1, 1983

By B. W. Dunning

The Bureau of Mines investigated the concentration and distribution of precious metals in the various fractions produced from mechanical processing of obsolete military electronic scrap. Whole avionic units, printed circuit cards, and electrical connectors were processed and analyzed. Materials recovered included baghouse lights, wire bundles, mag-netics, and metal concentrates from eddy-current and high-tension sepa-ration. Higher value fractions were processed by a commercial toll refiner for recovery of gold and silver. Lower value fractions were analyzed by the Bureau. Three fractions, the lights, wire bundles, and metallics from high-tension separation, contained most of the precious metals. Depending on the type of scrap feed, these fractions represented 34 to 60 pct of the original sample weight. Collectively, they represented 68 to 97 pct and 75 to 98 pct of the contained gold and silver, respectively.

Jan 1, 1983