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By G. T. Lapidus, R. Zárate-Gutiérrez

Selective leaching of lead from a Pb-Ag-Zn concentrate with hydrogen peroxide in citrate solutions was studied at room temperature. Leaching tests were performed, varying the H2O2 concentration and the solid-liquid ratio, holding the solution pH constant at 7, and the citrate concentration at 1 M. Lead extractions of 100 % were achieved with 4 and 5 times the stoichiometric quantity needed to form elemental sulfur, with only a small amount of metal impurities dissolved (Ag, Zn and Fe). The lead solubility limit at those conditions was found to be ~21 g L-1. X-ray diffraction analyses of the leach residues were free of galena (PbS), while other metal sulfides, such as sphalerite (ZnS), chalcopyrite (CuFeS2) and pyrite (FeS2), were basically unaffected.

Jan 1, 2014

By A. Wedepohl

Selective leaching of phases in charge chrome is used in a variety of industrial processes for the production of chromium chemicals. A mineralogical study was made of a range of local charge chrome samples, at various stages of leaching in sulphuric acid (20g/l at 90°C), using mainly a scanning electron microscope (SEM) together with an energy-dispersive spectroscopy analyzer (EDS), and X-ray diffraction techniques. It was found that the leaching behaviour of the different types of charge chrome depends largely on the nature of the secondary phases, which in turn depends upon whether the silicon content is above or below 4 per cent by mass. The leaching behaviour of high-chromium ferrite is anomalous, and it is postulated that the process is analogous to the corrosion of brass by dezincification. Keywords: charge chrome leaching, scanning electron microscope

Jan 1, 2000

By Zainab Nasrullah, MontanaFrank Agyemang, Mehran Sadat, Richard LaDouceur

Rare earth elements (REEs) are valuable for various modern technological applications, including metallurgy, machine building, radio electronics, instrument engineering, nuclear engineering, and manufacturing. The extraction and separa-tion of rare earth elements (REEs) from their complex ores is challenging due to their distinct physical and chemical properties, contributing to their market scarcity. At present, REE recovery utilizes traditional pyro- or hydrometallurgi-cal processes. The overall process in the recovery and sepa-ration of individual elements from complex REE systems suffers from high energy demands and the use of many haz-ardous chemicals that negatively impact the environment. With the growing trend toward a circular economy aim-ing to balance sustainability, efficiency, and environmental impacts, this research is focused on using deep eutectic sol-vents (DESs): a combination of a quaternary salt: Choline Chloride and five organic acids: Oxalic Acid, Urea, and Ethylene Glycol, Lactic acid and Glycerol for the selective leaching of REEs from their complex ore which is proven to be green, selective, non-toxic, biodegradable, and cheap. The effects of different DESs and leaching time on the REE leaching efficiency were determined, and the optimum DES media were found to be Oxaline and Lactic Acid at which a leaching efficiency of 25% and 15% was achieved at 80°C respectively for cerium.

Feb 1, 2025

By A. D. Paul, Yoon R. H., C. I. Basilio

Considerable amounts of Fe3+ ions are released into solution when coal is exposed to 1-3 M acid solutions. These ions superficially oxidize the coal surface, and are reduced to Fe2+ ions. When provisions are made to generate the Fe3+ ions in solution, e.g., by inserting an anode whose potential is above the reversible potential for the Fe3+/Fe2+ couple, considerable amounts of mineral matter are liberated from the coal matrix. With many eastern U.S. bituminous coals, this mineral liberation is achieved selectively without significant breakage of the coal. It is believed that this process is induced by the osmotic pressure set-up in the crevices between the mineral matter and coal that are exposed to the solution. A theoretical model predicting the osmotic pressure is presented in this work, along with some results obtained with different coal samples.

Jan 1, 1992

By Harry L. McNeill

THE Selective Media Process was developed by the author in a laboratory provided by The Steårns-Roger Manufacturing Co. It is the outcome of an [ ] investigation into the possibilities of coarse beneficiation by sink and float without using the conventional heavy media. Commercial work to date has been limited to the treatment of minus 3/8-in. iron ore at the Hill Trumbull washing plant of the Cleveland Cliffs Iron Co., at Calumet, Minnesota. Two cut away prints of the machine are shown (Figs. I and 2). A rotary conical impeller is mounted within a stationary cone (Fig. 2). This impeller is adjustable vertically by a 12-ton screw jack. The speed of the impeller can be varied from 14 to 32 r.p.m. by the Reeves variable-speed motor pulley mounted on the 7 ½ -hp. motor drive. Attached to the bottom of the stationary cone is the automatic control valve for sink product, actuated by a ¼ -hp. gear motor. The sink product is dewatered in a conventional drag driven by a 7 ½ -hp. motor and discharged onto an inclined conveyor containing from 6 to 10 per cent moisture. Two plants are operated at the Hill Trumbull property. All the ore is first treated in a typical washing plant (Fig. 3). When treating "wash ore" a finished concentrate can be produced by the log washers and Akins classifiers, as the separation involves only fine silica (minus 48-mesh) and free iron. However, when "jig ore" is fed to the washing plant the coarse

Jan 1, 1946

By V. K. Kuppusamy, M. Holuszko

"Lamps and lighting products are the most commonly used electrical products around the globe. With the improvement in lamp technologies, lighting products have grown complex and hence require an improved recycling process. The LED lamps consist of various valuable metals such as iron, copper, aluminum, chromium, silver, and gold, as well as non-metals such as glass, plastics, and fibers. In addition, there are also traces of hazardous substances such as lead, arsenic, and mercury. A major step in the recovery process is size reduction, and researchers have suggested that up to 40% of the total valuable material is lost during the shredding and grinding processes. SELFRAG is a high voltage selective fragmentation comminution technology that uses high voltage pulses in a water medium to efficiently separate the metals at a coarser size without generating many fine particles. It has been proposed that during the fragmentation process of electronic waste (e-waste), the metals can be separated without fine grinding. This research considers the applicability of high voltage pulse fragmentation for LED lamps. Eight different types of LED lamps were processed through the SELFRAG unit at varying pulses to study metal liberation. The product obtained was characterized for metal liberation, metal grades, and liberation analysis. The specific energy consumption for this size reduction process was also monitored. INTRODUCTION Lamps and bulbs are the most commonly used electrical products in homes, offices, industrial operations, and streets. According to Energy Star research (2006), an average US household has more than 40 sockets for light bulbs and consumes approximately 2100kWh every year for lighting. The development in lamp technology has pushed the boundary for newer products. The LED lamps have been taking over the market from the incandescent bulbs and compact fluorescent lamps (CFL). According to the US Department of Energy (2012) and myLEDlight.com (2007), LED lamps have several benefits over other lamps. LEDs produce light hemi-spherically, which increases their efficiency in directional light emission. It has higher breakage resistance from vibration or transportation. LED lamps use up to 90% less power than incandescent bulbs thus making them highly energy efficient; They have a longer lifespan, lasting 10 times longer than a CFL and 133 times longer than the traditional incandescent bulb. Because of all the benefits, Smallwood (2014) suggested that the market of LED lamps will grow to $12.2 billion by 2018."

Jan 1, 2018

By Farzad Mohammadi, Patrick Littlejohn, David Sanguinetti

Arsenic levels in metal concentrates are increasing as mining companies turn to developing low grade and complex ores. When arsenic bearing minerals are smelted, arsenic deports as gases which must be neutralized by a scrubber system. The resulting scrubber effluent is high in dissolved arsenic and requires treatment before the wastewater can be discharged or re-used. Conventional arsenic removal relies on lime addition followed by calcium arsenate formation and precipitation as hydroxides. As an alternative, arsenic removal with sulphide precipitation is receiving more attention due to potential advantages of the technology. Process streams high in arsenic often contain concentrations of dissolved metals that may be selectively recovered during sulphidization, producing a product that can be reprocessed and reducing waste generation. This paper will review laboratory testing completed for arsenic removal through sulphide addition and precipitation of arsenic (III) sulphide in combination with metals recovery to offset arsenic removal costs.

Jan 1, 2014

By R. W. Harnmack

Hydrogen sulfide generated by the anaerobic respiration of sulfate-reducing bacteria was used to treat pH 2.2 water from the abandoned Rio Tinto copper mine in Nevada. The untreated water contained 550 mg/L Fe, 140 mg/L Al, 90 mg/L Cu, 80 mg/L Mn, 60 mg/L Zn, 4 mg/L Co, and 2 mg/L Ni. The bench-scale treatment system examined consisted of a bioreactor for H2S generation and three precipitator/clarifier units for metal sulfide precipitation and recovery. The treatment system reduced the concentrations of all metals except Mn to less than 0.1 mg/L. Manganese concentrations were reduced by 96 percent to 3.3 mg/L. A CUS/SO concentrate (33 pct Cu) and a ZnS/5° concentrate (28 pct Zn) were produced that may be suitable for metal recovery at existing smelters

Jan 1, 1994

By D. C. Shumway

Mining in Cushenbury Canyon began in 1860 when John Cushenbury left his Holcomb Valley gold prospect and discovered a silver vein in the limestones of the present day Cushenbury Mine. Cushenbury Canyon is located along the western boundary of the Mojave Desert in Southern California and on the north slope of the San Bernardino Mountains. The Holcomb Valley, immediately southeast of Cushenbury Canyon was the most prolific gold producer in Southern California. Gold mining dominated the area until World War II when interest in the Lucerne Valley Limestone deposits was peaked by the construction of the Kaiser Steel Plant in Fontana, California. The steel making process required large amounts of metallurgical grade limestone and Kaiser geologists located claims in most of the limestone deposits. Kaiser Cement constructed a cement plant and limestone mine in Cushenbury Canyon in 1956. Kaiser Cement modernized the facility in 1982 to a four stage preheater-precalciner system. Mitsubishi Cement Corp. purchased the property in April, 1988, and through further system modifications have created the most efficient and modern cement plant in the United States.

Jan 1, 1992

By Douglas C. Shumway

Mining in Cushenbury Canyon began in 1860 when John Cushenbury left his Holcomb Valley gold prospect and discovered a silver vein in the limestones of the present day Cushenbury Mine. Cushenbury Canyon is located along the western boundary of the Mojave Desert in southern California and on the north slope of the San Bernardino Mountains. The Holcomb Valley, immediately south of Cushenbury Canyon, was the most prolific gold producer in southern California. Gold mining dominated the area until World War II. Interest then turned to the Lucerne Valley limestone deposits when Kaiser Steel built a plant in Fontana, CA. The steel making process required large amounts of metallurgical grade limestone. In 1956, Kaiser Cement constructed a cement plant and limestone mine in Cushenbury Canyon. In 1982, Kaiser modernized the facility to a four-stage, preheater-precalciner system. Mitsubishi Cement Corp. purchased the property in April 1988. The company further modified the facility to create the most efficient and modem cement plant in the US.

Jan 1, 1992

By Ahmad Ghahreman, James McNeice

Separation of rare earth elements (REE) is often achieved by acid leaching of mineral concentrates followed by subsequent solvent extraction (SX), to purify individual rare earth metals (REM). Cerium, the most abundant REE, is usually the largest component of these ores. Demand for less prevalent REE, such as praseodymium and dysprosium; have led to a market saturation and price collapse of cerium. One method of improving the economics of REE separation is to remove cerium from solution prior to SX. This is accomplished via the oxidation of cerium (III) to cerium (IV), which precipitates as cerium hydroxides. This study probes the efficacy of four oxidants; hydrogen peroxide, sodium hypochlorite, potassium permanganate, and Caro’s Acid with the goal of improving cerium removal whilst minimizing REE and reagent losses. The effect of oxidant type and dosage, pH, cerium concentration, and temperature on the kinetics of the process will be discussed.

Mar 1, 2018

02, NaCI03, H202, Na0CI and Ce+4 have been examined as oxidants in an alkaline carbonate system for uranium in in situ leaching. The South Texas and New Mexico ores contained up to 2.6 meqJg of reducing compounds which consume oxidants in the leading operation. Leaching rates did not increase linearly with the oxidation potential of the oxidants. A mild oxidant can be used to maximize uranium oxidation selectively and oxidant efficiency. 02 can oxidize most of the uranium mineral with an adequate rate and high oxidant efficiency.

Jan 1, 1990

By J. H. Huang

In this investigation, the selective precipitation of cobalt and molybdenum from Co-Mo aqueous solutions was studied in order to recover efficiently valuable elements from industrial effluents generated from a novel electrodeposition of nanocrystalline Co-based alloys process and reduce the effluent impact on environment. It was found that the behavior of cobalt in aqueous solutions was substantially affected by the presence of molybdenum. When adding 11.6 to 46.6g/L molybdenum to a 50g/L cobalt solution, the co-precipitation of molybdenum and cobalt started to occur at pH value of 3-4. However, without the presence of molybdenum, cobalt could only be precipitated out of the solution at about pH 6. Most of the molybdenum was found in the solid phase when the solution pH reached 5. After further increasing pH to greater than 7, the molybdenum dissolved back into the solution. Cobalt kept precipitating as the pH increased. When the pH was greater than 7, most of the cobalt was present in the solid phase. The chemical and physical characteristics of the precipitated materials were investigated by SEM, XRD, AAS and EDX. It was revealed that the precipitate was initially present as cobalt molybdate oxide hydrate and subsequently transformed as sodium cobalt molybdenum oxide. With further increasing the solution pH, the precipitate was transformed into cobalt hydroxide. Further investigation implied that most of molybdenum was chemically tied to the precipitate produced at the low pH, yet at the same time, physically entrapped at the high pH. The paper also presents the influence of reaction temperature and time on the precipitation process and kinetics.

Jan 1, 2003

By EDER DOMINGOS OLIVEIRA, Leandro Viana Teixeira, Carlos Antonio Morais, Ruberlan Gomes Silva

Special attention must be considered in the production of high-grade rare earth products, such as mixed rare earth oxalates or carbonates. In the main minerals used industrially, the rare earth elements (REEs) are finely associated with impurities like calcium (Ca), magnesium (Mg), manganese (Mn), iron (Fe), aluminum (Al), thorium (Th), uranium (U) and phosphorus (P). Most of these impurities must be removed to avoid losses of rare earth oxides (REOs) as well as to prevent product quality degradation and low operational performance in the downstream steps of solvent extraction or ion exchange. The present study aims at investigating the conditions required to precipitate REEs, either as rare earth oxalates or carbonates, from purified rare earth sulfuric liquor with low Al3+ and UO22+ concentrations and very high Ca2+, Mg2+, Mn2+, and SO42− impurity contents.

By Éder Domingos Oliveira, Leandro Viana Teixeira, Carlos Antonio Morais, Ruberlan Gomes Silva

The purity of rare earth products depends on the ability of the reagents used to selectively promote the precipitation of the rare earth elements (REE) from impurities present in sulfuric liquors. The present study aims at investigating the conditions required to precipitate REE, either as rare earth oxalates or carbonates, from purified rare earth sulfuric liquor with a low Al3+ and UO2 2+ and a very high Ca2+, Mg2+, Mn2+, and SO4 2− impurity content. The rare earth sulfuric liquor was obtained in a previous study by the reaction of a rare earth ore with sulfuric acid, pyrolysis at 700 °C/2 h, cooling at 20 °C, and water leaching. The impurities such as Fe3+, Th4+, and PO4 3− were completely removed from the liquor in two consecutive neutralization steps. In order to recover the REE, the purified rare earth liquor was then treated with oxalic acid and sodium carbonate. Rare earth oxides (REO) precipitated with oxalic acid displayed a very high purity (99.2% w/w) and low impurity content. In contrast, the rare earth carbonates precipitated with sodium carbonate presented a comparatively lower REO content (68.5% w/w) and 94.2% of purity, but with a higher content of impurities. Better precipitating conditions were achieved at 60 °C, compared with 20 °C, and under stoichiometric reagent consumption, with REE precipitation efficiencies higher than 96%. The dosage above the stoichiometric condition caused the precipitation of calcium oxalates and co-precipitation of rare earth sulfates when oxalic acid is used, and precipitation of calcium, manganese, and uranium carbonates and also a co-precipitation of rare earth sulfate when sodium carbonate were used. An integrated flowsheet to produce a high-quality rare earth product from rare earth sulfuric liquor containing some impurities is proposed.

By José Maria Silva, Eugênio Oliveira, Ruberlan Silva, Thiago Souza, Lucas Reis, Lorena Guimarães, Matheus Bianchetti

Copper mine operations consistently generate a large quantity of tailings after their concentration processing. These tailings are either piled up or stored in a dam, where both alternatives of disposal lead to environmental impacts. The dam copper tailings have a huge potential for by-product production thus improving sustainability and profitability in industrial operations. This paper describes a study aiming at producing a magnetite pellet feed as a by-product from a dam chalcopyrite flotation tailings and generating free magnetite non-magnetic rougher tailings. The chemical assay and mineralogy analysis of dam copper flotation tailings indicate low Fe grade (6.34 wt%), high SiO2 grade (63.14 wt%), low magnetite (3.6 wt%), and high iron silicates content (22.72 wt%). The complex mineralogy of these tailings leads to the need of grinding the rougher magnetite pellet feed as fine as 80% of particles smaller than 20 μm ( P80) aiming at improving magnetite liberation. The proposed process route comprises a scalping screen, low field rougher, and cleaner magnetic separations using a drum magnetic separator (80 kA/m or 1000 Gauss), followed by silicates reverse cationic flotation as a recleaner step. With this process route, it was possible to produce a high-quality magnetite pellet feed reaching 68.00 wt% of Fe, 2.13 wt% of SiO2, 0.51 wt% of Al2O3, and 95.1 wt% of magnetite. The Blaine specific surface area was 2300 cm2/ g, being in the range recommended for pelletizing (1900 up to 3000 cm2/ g). The total mass, Fe, SiO2, Al2O3, and magnetite recoveries were 2.77%, 29.71%, 0.09%, 0.12%, and 73.17%, respectively. Most of the magnetite losses, around 20% of total magnetite fed, occurred in the oversize of the scalping screen. Additionally, it generated non-magnetic rougher tailings with less than 1.0 wt% of magnetite that could be used as by-products and reduced the amount of tailings disposal in a dam. This study contributes toward the sustainability of operation, minimizing tailings disposal.

Sep 28, 2022

By NEHA PANDEY, V.K. REDDY KALLAM, SUNIL KUMAR TRIPATHY, ARIJIT BISWAS

This work discusses the sulfur dioxide (SO2) leaching of low-grade ferruginous manganese ores to selectively recover manganese (Mn) as manganese sulfate (MnSO4), followed by electrowinning of the purified MnSO4 to produce electrolytic manganese dioxide (EMD). The effects of the leaching process parameters on Mn recovery were studied, and the leaching duration and SO2 flow rate were found to have significant effects. Under the optimum conditions derived for grade 1 ore (with total Mn content of approximately 17.16 percent), the specific SO2 requirement (SSR) — that is, the SO2 flow rate per gram of Mn in the leach slurry — was calculated to be 0.014 L/min. At the SO2 flow rate calculated using SSR for grade 2 ore (with total Mn content of approximately 26.29 percent), a Mn recovery rate of 94 percent was realized. Electrowinning of the purified MnSO4 generated after leaching resulted in EMD with 88.01 percent purity and a γ structure.

Sep 1, 2022

By V. K. Reddy Kallam, NEHA PANDEY, Sunil Kumar Tripathy, ARIJIT BISWAS

The study investigates SO2 leaching of low-grade ferruginous manganese ores to selectively recover manganese as MnSO4 and produce battery-grade electrolytic manganese dioxide (EMD). The effects of leaching parameters (duration, temperature, SO2 flow rate) on Mn recovery were studied. Under optimum conditions, 97.9% Mn recovery was achieved. The MnSO4 leach liquor was purified and used for electrowinning EMD with 88.01% purity and battery-active γ structure.

Apr 20, 2022

By Shigeru Ueda, Shin-ya Kitamura, Dong Jun Shin, Xu Gao

Steelmaking slag contains useful elements such as P and Mn. Generally, in the carbothermic reduction of slag, not only P but also Mn are reduced and a Fe–P–Mn alloy is formed. In this study, the possibility of the separation of Mn and P was investigated. A mixture of synthesized slag and graphite was heated at 1773 K, and the compositions of the separated slag and metal were analyzed. The results showed that with a decrease in basicity, the reduction of P was enhanced but that of Mn was suppressed. Thus, under an optimum condition, steelmaking slag was separated into a Fe–P alloy and a high MnO-containing slag. Although further investigation is necessary, the formed alloy and slag could be used as raw materials for fertilizers and Fe–Mn alloys, respectively. This paper elucidates the concept of this process and the results of the fundamental experiments.

Mar 1, 2018

By Hongmin Zhu, Kai Huang, Shuqiang Jiao

"Garlic peel was used as the raw material to synthesize the biosorbent for the selective recovery of precious metals from the acid chloride solution. Garlic peel is rich in carboxyl-, amino- and thiol-groups, has the potential of exhibiting high affinity to Au(III) when appropriate chemical modification process was employed. Here in the present study, the biosorbent was prepared by cross-linking garlic peel particles with concentrated sulfuric acid. Adsorption tests for mixing different metal ions such as Au(III), Fe(III), Cu(II), Ni(II) and Zn(II) from various concentrations of hydrochloric acid media indicated that Au(III) was selectively adsorbed on the cross-linked garlic peel gel over the other coexisting base metal ions investigated. The crosslinking mechanism and selective adsorption of Au(III) were also investigated briefly.IntroductionPrecious metals are quite popularly applied in the modern industries such as jewelry, electronics and electrical devices, catalysts in chemical industry, etc. While their high values, limited deposit and quite large demand in industry makes its recovery from the industrial wastes, typically e-wastes, quite necessary. Actually, many techniques have been developed to recycle and recover the precious metals from various industrial wastes effectively in last decades, but the cleaning and ecofriendly processes are still seriously scarce [1]. Taking into account of the typical recovery processes using cyanide lixiviant in the alkaline media, or aqua regia, followed by the further recovery process using activated carbon adsorption or cementation with zinc, iron or aluminum plate or powder, though they both are quite effective recovery processes, if considering the special requirements on safety and ecofriendliness for the modern hydrometallurgical processes, various improved or novel extraction processes are greatly demanded [2]. Recently, the biosorption technology applied to the recover precious metals in the hydrometallurgical process has become a concern [3,4]. Inoue’s research group made great progress in the recovery of precious metals such as gold, palladium and platinum from the e-wastes such as spent mobile phone by using biosorption from the hydrochloric acid media [5,6]. This new hydrometallurgical process exhibits the prominent advantages of being cost-effective for its short process, easy operation and near-zero emission. In the above recycling process for e-wastes treatment, the preparation of biosorbents is the key and backbone of the whole recovery process. For this purpose, they developed a series of suitable sorbents for precious metals recovery by using the tanning-based or cellulose-based biomass such as persimmon peel, grape peel, orange juicing residue, waste cotton, waste paper through the crosslinking process with concentrated sulfuric acid and relative chemical modification processes [7-10]. In the present study, we also applied this technique to prepare the biosorbent of precious metal uptaking by using garlic peels as the raw materials, and investigated the adsorption properties of such-obtained gel in the hydrochloric acid media."

Jan 1, 2012