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By Isauro Rivera Landero, Martín Reyes Pérez, Eduardo Cerecedo Sáenz, Javier Flores Badillo, Mauricio Guerrero Rodríguez, Juan Hernández Ávila, Eleazar Salinas Rodríguez, María Isabel Reyes Valderrama

During column flotation of mining tailings of the Dos Carlos dam, it was observed that the effect of surface liquid flow (JL) is a variable that determines the rate of rise of packing bubbles and therefore, causes the generation of gas retained within the columnar system. Also overall more stable laminar flows were observed, in a range of superficial flow of liquid in the bottoms stream (JLT) from 0.446 to 0.68 cm/s, showing the stability in the range of superficial gas flow (Jg) from 0.1 to 0.5 cm/s. Observing a uniform bubble size for the three JLT evaluated, with a diameter between 0.05475 and 0.2525 cm, at all the range evaluated of Jg. Furthermore, an uniform performance was obtained, and with the same rate of rise of packing bubbles, showing a greater packing bubbles at JLT = 0.446 cm/s, due to the lesser bubble size observed, in comparison with the values of JLT of 0.68 and 1.017 cm/s.

Mar 1, 2017

By Jianzhong Li, Yunkai Wang

Lead substrate anodes are widely used in the electroplating and electrolytic field. However, with the change of internal stress, the oxide films are gradually generated on the surface of lead anode. Their structure and stress properties were studied during the oxidation by means of Raman spectra, XRD, SEM. The result showed that the diffraction peaks of lead were mainly found at the initial oxidation stage. With increasing oxidation time, Pb diffraction peaks were weakened and the diffraction peaks of PbO/PbO2 strengthened remarkably. When the oxidation time was above 10 min, monoclinic PbCrO4 was also generated in the oxide film with CrO4 2 ions solution as electrolyte. Raman spectra revealed that Raman peaks of PbO/PbO2 were gained. In addition, Raman peaks of PbCrO4 at 830–840 cm−1 were found using the CrO4 2 ions as electrolyte. Based on the relationship of the internal stress of oxide film and Raman peaks shift, PbO/PbO2 induced obvious stress generation in CrO4 2 ion electrolyte. The nucleation style of oxidation film was 3D progressive nucleation at first. After the peak current, it turned to be 3D instantaneous nucleation. In the oxidation process, the internal stress of PbO/PbO2.

Mar 1, 2017

By R. Venugopal, V. K. Saxena, A. K. Mukherjee

"Coal, iron and manganese ore samples were exposed to different ultrasonic intensities of 250, 300 and 350 W/L for five minutes and to an ultrosonic intensity of 270 W/L for different time durations of 3, 5 and 7 minutes. The ultrasonically treated samples showed reductions in D80 particle diameters of 6 percent for the coal samples, 5.95 percent for the iron ore samples and 35.63 percent for the manganese ore samples during grinding. The ultrasonic treatment was also observed to assist in reducing ash content in the coal product by 8 percent and to reduce manganese losses in rejects by about 5 percent. Ultrasonic treatment was concluded to be capable of assisting in the comminution of friable ores more prominently than the hard and porous materials.IntroductionComminution is an important unit operation in the mineral-processing, cement-making, powergeneration and pharmaceutical industries. But most of the milling technologies are considered to be energy inefficient, with less energy consumed in real size reduction and most of the energy consumed in the machine. This is more critical for the mineralprocessing industry because of the growing need to exploit lower-grade ore bodies and process rejects (Blazy et al., 1994; U.S. Department of Energy, 2005). Low-grade ores require crushing and grinding to liberate the valuable minerals, which are further separated from gangues by various beneficiation methods such as gravity separation, flotation and leaching. Various studies have been carried out to minimize energy consumption during milling by developing pretreatment methods that can initiate new fractures or improve the fracture density in materials before comminution. These studies were mainly focused on chemical additives; thermal, ultrasonic and microwave treatments; and electric disintegration (Klimpel and Austin, 1982; Norgate and Weller, 1994; Bearman, Briggs and Kojovic, 1997; Gaete-Garreton, Vargas-Hermandez and Velasquez-Lambert, 2000; Kumar et al., 2010; Wang, Shi and Manlapig., 2011, Singh et al., 2012).The fragmentation effect of ultrasonic fields in solids has been investigated since the 1950s, and Gärtner was probably the first researcher who attempted it (Gaete-Garreton, Vargas- Hermandez and Velasquez-Lambert, 2000). Sound waves can propagate in solids in the form of longitudinal waves, shear waves and surface waves, and in thin materials as plate waves.In surfaces, fractures and interfaces, various types of elliptical or complex vibrations of the particles make other waves possible. During ultrasonic-vibration treatment, cavitation bubbles nucleate, grow and collapse, generating microjets, whose impacts on the particles initiate microcracks. The ultrasonic waves can enhance the nucleation, growth and coalescence of flaws, caused by tensile or shear stress. The mechanisms operating in the materials and inducing these stresses have been identified as spall and compression-induced tensile microcracks, nucleating at preexisting flaws. These mechanisms are driven by the shock wave and cavitation effects in the surrounding fluid (Chen, Huang and Shih, 2003)"

Jan 1, 2016

By S. M. Geerts, M. T. Wild

In this paper the performance effects of various shaped charge liner designs will be discussed. Several different charges will be tested and the liner design will be reviewed based on the performance in testing. The first type of shaped charge to be tested is a conical charge with dual confinement. For the purpose of this paper, dual confinement is a shaped charge with two liners but containing one explosive charge. Several charges with different dual confinement designs will be tested. Variations in configuration include charges with similar angle and similar diameter. The second type is a double conical shaped charge configuration. A double shaped charge will be considered to be two complete charges formed into a single cone. The goal of the project is to determine if any of the designs increase the efficiency and/or effectiveness of the shaped charge in comparison to the standard conical shaped charge. A standard conical charge will be detonated against a witness plate to get a standard depth of penetration or a baseline. All charges will have a seven cone diameter standoff, allowing the data to be compared to the control charge. Computer modeling will be used to predict the results of the testing that will be conducted. The actual results will be compared to the computer simulation for validation.

Jan 1, 2010

Under the AMIRA P9 project the three-product cyclone-an off-shoot of the conventional hydro-cyclone-that produces three distinct products has been developed. The three-product cyclone shows great promise as a classifier in mineral processing. Industrial and pilot plant trials performed to assess its performance in the classification of the UG2 platinum ore, indicate that the presence of an extra overflow product stream that captures the mid-sized particles, provides improved classification efficiency. To assess the split on component density, samples from the feed and product streams were screened and assays by size for chromite (? = 4.8) and silica (? = 2.65) were obtained. Results from tests performed using this type of hydrocyclone in a number of applications indicates that it can be applied successfully in circuit configurations where the conventional hydrocyc-lone is not suitable. Utilising the three-product cyclone to classify the UG2 platinum ore resulted in an intermediate overflow product stream containing the mid-sized low density silicates and relatively fine high density chromite particles while the finer overflow contained mostly fine silicates and chromite particles. The coarse chromite and silicates reported to the underflow. Due to the increased number of products, the method of using efficiency curves was extended to cater for the increased number of products in the three-product cyclone. Although significant differences in the classification performance of the three-product cyclone were noticed with variations in machine variables a consistent method of assessing the performance was applied. The efficiency curve was adopted and applied and separate efficiency curve properties were obtained for each product stream. The methodology was applied to the component data, and efficiency curve proper-ties for each key component were obtained and compared. This paper discusses the application of the efficiency curve to cyclones producing more than two products and extending the methodology to the different components in the feed.

Jan 1, 2014

By J. Paturaud, A. G. Villemiane, J. Y. Buffiere, D. Fabregue, M. Perrier

In this work, a detailed characterization of the cyclic damage mechanisms on duty in car heat exchangers has been carried out in order to improve their reliability. The material which consists in very thin (<0.3 mm thick) sheets formed of 3 co-rolled aluminum alloys (4045 /3916/ 4045) has been brazed in order to obtain metallurgical and surface conditions representative of those of the real components. Fatigue tests at constant stress amplitude have been performed at room temperature and 120°C in order i) to characterize the cyclic resistance of the studied materials and ii) to study the effect of temperature on the fatigue damage mechanism. The mechanisms leading to failure have been identified from post mortem fractographic analysis. The Wohler curves obtained show that, contrary to common structural Al alloys, this type of thin sheet brazed multi material can be cycled for several hundred thousand cycles at very high stress level (> ~ 80 % of the tensile strength). This behaviour is analysed with respect to the microstructure resulting from the brazing process and the low number of grains present in the sample thickness (around 5 grains).

Jan 1, 2015

By V A. Maltsev, V I. Panin

The question of prediction and prevention of dynamic events û rock bursts (RB), tectonic rock burst (TRB) and mining-induced earthquakes (MIE), induced by large-scale mining, are discussed. The mine itself and the host geological environment are taken as a natural-technical system (NTS) whose evolution is characterised by alteration of the adaptation-bifurcation (catastrophes) periods. So, to predict TRB-MIE means to predict the limiting NTS states that are determined from the NTS geological monitoring data, and to prevent the said events means to control the processes of rock deformation and failure within the critical zone. The study considers particular examples of how TRB-MIE-events are predicted and prevented in apatite mines, Kola peninsula, Russia.

Jan 1, 2000

By I. Y. Motovilov, S. A. Telkov, M. B. Barmenshinova, Z. S. Abisheva

As a rule, removing waste rock at the beginning of the process improves the conditions for the flotation of minerals, and also reduces the operating costs of crushing, grinding and flotation. Lead-zinc ores in the Shalkiya deposit of the Republic of Kazakhstan are classified as difficult for enrichment, but taking into account their significant reserves, they are one of the main potential ores for the production of lead and zinc. Under industrial conditions, for processing ores of the Shalkiya deposit, a selective flotation concentration scheme with the production of lead and zinc concentrates is recommended. However, according to the recommended scheme, it is not possible to obtain high-quality concentrates of lead and zinc, with high metal recovery. The paper presents the results of studies of preliminary gravitational enrichment of lead-zinc ore in the Shalkiya deposit. Based on the fractional analysis for the particle size range of -40+8 mm, Henri- Reingard enrichment curves were constructed, separation density (2730 kg /m3) was established to isolate the light fraction with the lowest possible lead and zinc content, and gravity enrichment indices (0.7-0.71) were determined. It was found out that when using gravitational enrichment of the original large-sized ore in the Shalkiya deposit, tails are released at the beginning of the technological process with a yield of up to 20% with the extraction of silica up to 30%, calcite up to 11% and carbonaceous matter up to 12%. As a result of the studies, it was found that the beneficiation of crushed lump ore could be conducted in heavy suspensions. One of the positive aspects of the use of gravitational enrichment is the reduction of energy costs for grinding the heavy fraction, which was experimentally proved in this article. Keywords: Lead-zinc ores, Shalkiya deposit, fractional analysis, gravitational enrichment, floating fraction, sunken fraction, separation density

Jan 1, 2020

By Yihan Liu, Jintao Zhang, Chen Xiao, Xiaomeng Zhao, Guanglei Song

To estimate the performance of the inert anode materials based on NiFe2O4 spinel ceramic during it used for aluminum electrolysis, we investigated the wetting process of cryolite molten salt which is in composition of industrial aluminum electrolysis with carbon anode and NiFe2O4 based cermet materials, by means of determination the interface wetting angle between the molten cryolite electrolyte and the solid anodes interface. The results show that the wetting angle between the electrolyte and carbon anode is larger than 90 angulation, this means that they basically can not wetting; however the nickel ferrate spinel ceramics behaves much better. In regard to the NiFe2O4 matrix materials, their initial wetting angles is 76.9. The initial wetting angles for 1.0wt%MnO2, 2.5wt%TiO2 and 0.5wt%V2O5-doped samples are respectively 56.86°, 52.98° and 51.93°. However, after 50s later, all the wetting angles came down below 15°.

Jan 1, 2015

By D. Endara, E. De la Torre, S. Echeverria

"The study was conducted with the sulfide mineral from the province of Zamora Chinchipe. It was characterized physical, chemical and mineralogical, obtaining between its main results a copper concentration of head ore of 0,58 %. The mineral was homogenized and taken to direct closed circuit: rollers mill - vibratory sieve (mesh # 16). Flotation was carried out in two stages: the collective and selective where in each one were performed 6 water recirculation as suggested by the technique used to relate information of a batch flotation to a continuous circuit called cyclic flotation tests (LCT). In the collective flotation (bulk) 2 Kg of mineral were grinded with 10 Kg of balls for 30 minutes and 62.5% of solids, the pulp was taken to the flotation process with solids percentages of 33.3% and pH 7, it was conditioned with 45 g / t of KAX 1%, 50 g/t of Aerofloat 208 and 20 g /t of Pine oil. The concentrate and tailings bulk obtained were filtered separately for the recovery of water and it was recirculated to the next grinding of 2kg mineral. In the selective flotation 1Kg of bulk concentrate was carried to regrind for 40 min, 62.5% percent of solids, 10 g of lime and 5 g of tannin FLOATAN T5, the pulp was taken to the roughing-collection-refining flotation circuit controlling the pH between 10.5 and 11 where conditioning (60 g/t of Aerofloat 208 and 30 g/t of Pine oil) and adding lime to the circuit and FLOATAN according to the procedure. The four fractions obtained from the circuit were filtered; the water was recirculated to the regrind process of the bulk concentrate. In the collective flotation process tends to stability in the fourth recirculating water to obtain a copper content of 4.5% and a recovery of 87%, recirculated water represents 69.8% of all water used in the 6 recycles. In the selective flotation circuit the fifth recirculating of water is the optimal where obtaining a copper content of 13% and a recovery of 72%, recirculated water in the selective flotation circuit represents 95% of the total water used in the 6 recycles."

Jan 1, 2018

By C. A. Pickles, K. Mackowiak, D. Gajonera

"Shake-flask oxidation tests were performed on Red Dog mine waste to study the initial dissolution behaviours of lead, zinc, and iron. The conditions for accelerated acid generation in terms of Eh and pH were determined. Each mineral behaved distinctly, with galena dissolving first, followed by sphalerite, then pyrite, although there was some overlap in behaviour. Iron was not detected in solution until approximately day 40 and was present at low concentrations. The experimental conditions and the theoretical model results indicated the formation of iron oxyhydroxides at low weathering times and jarosite at longer times.RÉSUMÉ Des tests d’oxydation par agitation en flacon ont été effectués sur les déchets miniers de l’exploitation Red Dog afin d’étudier les comportements initiaux de dissolution du plomb, du zinc et du fer. Les conditions entraînant la production accélérée d’acide en termes d’eH (potentiel d’oxydoréduction) et de pH (potentiel d’hydrogène) ont été déterminées. Chaque minerai se comportait différemment ; la galène a été la première à se dissoudre, suivie de la sphalérite, puis de la pyrite, mais un certain chevauchement des comportements a été observé. La présence de fer en solution n’a été détectée qu’après environ 40 jours et ce, à de faibles concentrations. Les conditions expérimentales et les résultats du modèle théorique signalaient la formation d’oxyde-hydroxyde de fer sur de courtes périodes d’altération atmosphérique, et de jarosite sur des périodes plus longues."

Jan 1, 2017

By T. Mulpeter, G. Deschênes

Sadiola Gold Mine is an open pit operation located in Mali and owned by Anglogold Ashanti Ltd, Iamgold Corporation and the State of Mali. A conventional cyanidation process (cyanidation/CIP) treats 15,000 tpd (of a mixture of oxide and sulphide ores) at an average grade of 3 g/t Au. In 2002, the increasing tonnage of sulphides caused an increase in production costs and a decrease in gold extraction (from 95% to 70-76%). Because of the short retention time of the leach circuit (18 hours) and the refractory nature of the sulphides, gold leaching kinetics are critical. A laboratory investigation was initiated to evaluate actual plant practice and identify a means of improving the gold leaching rate. The study was conducted on a "soft" sulphide gold sample containing 4.96 g/t Au, 0.4 g/t Ag, 2.5% pyrite, 1.2% arsenopyrite, and 0.2% pyrrhotite with a P80 of 74microns. Pre-leaching significantly influenced the gold leaching rate. A short pre-leach (2 hours) performed at pH 8, a DO of 8 ppm, and with 300 g/t lead nitrate added at the start or the end, produced the preferred conditions. Pre-leaching for more than 2 hours was detrimental to gold extraction. The cyanide concentration had to be maintained at 450 ppm NaCN to reach a maximum gold extraction within the retention time of the circuit. A maximum extraction of 81.3% Au was obtained in 20 hours (leach residue at 0.97 g/t Au). A high level of dissolved oxygen in the pre-leach was not of any benefit. Extension of gold leaching beyond 20 hours indicated that all leachable gold had been extracted by that time. Plant modifications were made to allow leaching of oxides and sulphides in separate circuits. Treatment of oxide ores is now performed at a higher rate. Sulphides are processed at a lower throughput, with 300 g/t lead nitrate, to allow a retention time of 22 hours. Combined throughput remains the same, and total gold recovery has increased from 76% to 80% for an additional gold production of 16,000 ounces per year.

Jan 1, 2005

By Langtry E. Lynd

Ilmenite concentrates prepared from beach and dune sands of Florida, India, Australia, and other localities deviate to varying degrees from the theoretical composition of pure ilmenite, and generally contain more Ti02 than the formula FeTiO3 would indicate, and some Fe203. This variation in composition is due to different amounts of altered ilmenite in the concentrates.(l) The alteration has been shown to take place by oxidation and leaching of the iron in ilmenite, to yield residual products consisting of amorphous or very finely crystalline titanium dioxide and ferric oxide, Other studies (2) have stressed that ilmenite may alter first to an amorphous titanium-iron oxide, or to an amorphous mixture of titanium and iron oxides, with later alteration to crystalline titanium dioxide. There has been some speculation as to whether alteration of ilmenite is usually caused by weathering or by hydrothermal processes,(3, 4, 5) Three main methods of approach were used to study the mechanism and rate of ilmenite weathering, (1) Etch tests were used to learn the relationship between crystallographic orientation and the rate of chemical attack on ilmenite. (2) Altered ilmenites in New Jersey sands were compared with ilmenite in rocks of the area from which the sands were probably derived, (3) Experiments were carried out to determine at what rate, and by what agents, originally fresh ilmenite could be altered in the laboratory under simulated weathering conditions.

Jan 1, 1959

By Zhihe Dou, Jiang Liu, Ting-an ZHANG, Yukun Huang

The paper aimed to propose that mixed rare earth concentrate was decomposed by pressurized calcification where mechanical milling was applied simultaneously (also known as mechanochemical calcification). The bastnaesite and monazite were both decomposed by OH−, where released rare earth formed RE (OH)3, released fluorine and phosphorus formed CaF2 and Ca2P2O7. Then, the calcified slag was leached by diluted hydrochloric acid to extract rare earth and both recover fluorine and phosphorus. The phase transformation regularity, the behavioral trends of rare earth, fluorine and phosphorus were investigated. Results showed under the optimal conditions of ball to material weight 80:1, the calcification temperature 250 °C, the liquid-solid ratio 5:1, the leaching yield of rare earth reached to 92.16%, Ce was 86.47%, La was 97.58%, Nd was 99.99% and the mass fraction of F, P entering into calcified liquor were 8.27, 0.21% respectively. The micromorphology of the mineral has a transition from dense to fluffy, and then became dense again.

Mar 1, 2018

By Charles Austin

IT has been known for several years1 that certain alloys of the Konal type, containing commercial cobalt (99.32 per cent C0 and 0.42 per cent Ni) and varying amounts of ferrotitanium, exhibit very high tensile strengths at 600°C. However, their pro-portional limits and yield points are rela-tively low. Published data1 for the alloys quenched in water from 950°C. and then tested at 600°C. are summarized in the upper section of Fig. I. Similar specimens that were aged at 650°C. for 72 hr., after quench and prior to testing at 600°C., gave the results shown in the lower section of Fig. I. TABLE I.-Analysis of Material I Percentages Constituent Sample Sample Sample 3125 3124 3123 Si 0.25 0.51 o.6o Fe 4.15 10.70 13.17 Ti I.15 3.58 4.70 Mn 0.30 0.41 0.42 Co (by difference)^ 94.15 84.80 81.71 The cobalt from all three samples, united and tested for nickel, gave 0.54 per cent Ni based on the weight of cobalt. In the present work the investigation of the properties of these materials has been extended by a study of the tensile deforma- tion characteristics in moderately long-time tests at 600°, 700° and 800°C. after quenching from various solution tempera-tures. In addition, some metallographic studies have been made to correlate with the deformation tests, and to obtain in- FIG. 1.-EFFECT OF VARYING AMOUNTS OF FERROTITANIUM (FE2TI) ON PHYSICAL PROPER-TIES OF COMMERCIAL COBALT. (C. R. Austin.1) Upper section. Tested at 600°C. after water-quenching from 950°C. Lower section. Tested at 600°C. after water-quenching from 950°C. and aging 72 hr. at 650°C. FIG. 2.-PORTION OF QUASI-BINARY DIAGRAM COBALT-FE2TI AS DETERMINED METALLOGRAPH-ICALLY. formation on the quasi-binary system Cobalt-Fe2Ti. The material, very kindly furnished by the Westinghouse Electric and Manufac-turing Co. in the form of hot-swaged rods of 3/16-in. diameter, analyzed as shown in Table I. The alloys, when originally made up,1 were based upon an iron-titanium com-pound, Fe3Ti, as indicated by the work of

Jan 1, 1940

By W. Dong

This paper presents the fundamental study of the temperature distribution in a reforming planar solid oxide fuel cell (SOFC) using mathematical modeling and experimental testing approaches at Versa Power Systems (VPS). In order to investigate the on-cell temperature distribution under high rates of Natural Gas direct internal reforming (DIR), both the computer simulation approach and the experimental testing approach have been developed. In this work, comprehensive in-house DIR and SOFC models were developed and employed for the computational fluid dynamics (CFD) based 3D computer simulation. The current SOFC module has been corrected to take into account both the on-cell electrical leaking effect and the stack stage structural resistance. Meanwhile, an instrumented single-cell test jig with multiple thermocouples was built, and a series of experimental tests were performed at various conditions. The numerical results based on the single-cell jigs are in very good agreement with the physical test results.

Jan 1, 2005

By K. Wu, X. Yuan, R. Du, C. Chao

"Lump coals are currently employed to replace part of coke in the COREX melter-gasifier for ironmaking. In order to optimize the process, the pyrolysis kinetics of Datong coal used in the COREX process was studied. A sectioning method is proposed to overcome certain shortcomings of traditional methods for studying the pyrolysis of coal. Based on the sectioning method and the characteristics of the coal pyrolysis process, the temperature range was divided into three intervals. In the first, the adsorbed gas and water of crystallization were removed; in the second, the coal was transformed into semi-coke; and finally, the semi-coke was further coked. Three models of reaction were then established to study the different stages of the pyrolysis process: an interfacial chemical reaction model, a random pore model, and internal diffusion with shrinking volume. The results showed that the experimental data fitted the models well, with all correlation coefficients (r2) exceeding 0.97. Finally, the mechanisms of reaction and kinetic parameters for each temperature range were derived, which laid a necessary foundation for optimizing the usage of non-coking coal in the COREX process. IntroductionIn view of environmental concerns and the shortage of good-quality coking coal, the COREX process was designed as a new ironmaking technology, attracting wide attention (Fang et al., 2005). In this process, lump coal and a small quantity of coke are directly charged into the melter-gasifier, where a high-quality reducing gas is generated for the reduction of the iron ore (Kumar et al., 2009). In contrast to the conventional blast furnace (BF) process, non-coking lump coal is used as the reducing agent and as the energy source, and the iron charge consists of lump ore and/or pellets, which results in the elimination of the coke oven and sintering plant as well as a decrease in investment (Kumar et al., 2009; Liu et al., 2012).Although the COREX process has made great progress, in current production practice the energy consumption greatly exceeds that of the BF, and it requires a certain amount of coke to maintain permeability of the semi-coke bed (Wang et al., 2008). In addition, the process consumes a lot of good-quality lump ore and lump coal. The pyrolysis of coal is the first step in most coal conversion processes, such as carbonization, gasification, and combustion (Aboyade et al., 2013). The reaction behaviour of lump coals in the COREX melter-gasifier is crucial, as it determines energy utilization and gas composition, as well as the metallurgical properties and particle size of the semi-coke produced (Prachethan et al., 2011; Zhang et al., 2014). In order to optimize the process and improve its competitiveness, the pyrolysis kinetics of Datong coal used in Baosteel’s COREX C-3000 facility was studied."

Jan 1, 2016

By Jefferson Caponero

The tire is an expressive component of Municipal Solid Waste, manly when its occupied volume is considered. Its treatment by pyrolysis stands for a list of advantages, such as: landfill releasing and a production of a high quality fuel. The exploitation of new natural resources is becoming more difficult each day, basically due to the environmental damages caused by this type of activity. This work presents a study on the thermal behaviour of Brazilian tires using thermogravimetric analysis and differential thermal analysis, in order to optimise the pyrolysis process of tires. Samples of I to 2 mm were investigated at atmospheres of nitrogen, argon, oxygen and mixtures of these gases at temperatures up to 1273K, under heating rates between 1 to 50 Klmin . The results showed that the behaviour of each sample is related to both the atmosphere composition and the heating rate.

Jan 1, 2001

By Sayan Sarkar

HAMR (Hydrogen Assisted Magnesiothermic Reduction) process is a promising alternative route of titanium production, which is convenient due to reduction at relatively lower temperatures below 750 °C and usage of cost-efficient TiO2 as the starting material. A crucial step involved in this process requires the Mg reduction of TiO2 subjected to H2 atmosphere which produces porous TiH2 along with residual magnesium impurities. Before the final heat treatment and deoxygenation steps for consolidation of the Ti powder, leaching plays a significant role in the removal of Mg impurities. In this report, we present a systematic study on the role of acid concentration (HCl), temperature and the kinetics of MgO dissolution. In addition, we also report the controlling mechanism during kinetics of MgO dissolution in acid. This parametric study will provide a platform to ensure very low Mg content that meets with ASTM standards during production of Ti in the HAMR process.

By Ranjeet K. Singh

Kelsey Centrifugal Jig was found to be promising for the beneficiation of fine coal particles. The present study was aimed at in-depth understanding of the separation features of Kelsey Jig through detailed experimentation. Beneficiation of fine coal of size 150 x 300 µm was studied in a laboratory Kelsey Jig. The thickness of the ragging bed is found to be an extremely crucial parameter apart from the other process parameters such as rotational speed and pulsation frequency. A constant pulp density (25% solids) of the feed slurry was maintained in the study. The feed rate was also kept constant at 50 kg/hr dry solids. Silica sand of size -1.68+0.85 mm was used as ragging material to avoid the pegging of internal screen having an opening of 425 µm. The rotational speed was found to have significant effect on the depth of the ragging bed and its porosity, which influenced the separation performance considerably. Pulsation was identified as the key factor in stratifying the coal bed and defining the misplacement as well as ragging bed porosity, which influenced the mass yield and quality of the products. Beneficiation studies were carried out with rotational speed varying between 900-1000 rpm while pulsation frequency was kept within 850-925 rpm. In a single pass through the Kelsey Jig 7-8% (absolute) reduction in the ash content of the feed material was observed at more than 55% mass yield. High rotational speed, moderate pulsation, and low ragging bed depth favored good cleaning. A high bed depth was found to facilitate rejection of high ash materials. It was established that Kelsey Jig is effective in fine coal cleaning though a controlled operation is required in order to achieve superior performance. Keywords: enhanced gravity separator, g-force, separation performance, ragging material, coal beneficiation

Sep 1, 2012