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By R. J. Davidson, M. V. Nkosi, V. Veronsee

When activated carbon is used for the recovery of gold and silver from Witwatersrand gold-plant solutions, severe fouling of the carbon by calcium carbonate is experienced. Also, difficulty is encountered in the retention of the adsorbed silver on the carbon because it is displaced by gold. The acidification of plant pregnant solutions before they are contacted with carbon was therefore investigated as a means of overcoming these shortcomings. The results from batch laboratory experiments on the effect of pH on gold adsorption from plant solutions and from synthetic solutions of high ionic strength indicated reaction rate optima in the region of pH 5 and below pH I. The effect of pH on the equilibrium capacity constant for gold adsorption onto activated carbon was also studied, using both a plant solution and a synthetic solution of high ionic strength. In the case of the plant solution, the results suggested only a marginal change in carbon capacity for gold in the pH range 12 to 6, with significant increases in capacity at lower pH values. In the case of the synthetic solution of high ionic strength, the capacity constant was found to increase steadily as the pH was lowered from 12 to I. It was also found that the gold adsorption capacity of the carbon was significantly better for the synthetic solution. No precipitation of gold from the pregnant solution (gold content approximately 6 g/t) was noted as the pH was decreased to values as low as ,. However, about 25 per cent of the 0,6 g/t silver content was found to have precipitated when a pH value of 3,0 was attained. Further substantial precipitation of silver took place as the pH was lowered further. The investigation was extended by the passing of suitably acidified gold-plant solutions through one or more columns containing activated carbon. Preliminary results showed that the particle size of the carbon had a significant effect on the rate of gold adsorption. No displacement of adsorbed silver by gold was observed to take place at an influent pH of 5. In a typical continuous 'merry-go-round' operation involving three columns in which gold was eluted from the lead column every 48 hours, effluent values averaging 0,001 g/t gold could be consistently achieved under simulated plant-operating conditions. The results were obtained at relatively high velocities of influent solution, resulting in very little hold-up of gold in the carbon-recovery circuit. More than 99,9 per cent of the gold and more than 99,8 per cent of the silver was recovered in the adsorption circuit, while the elution data indicated an average elution recovery of 99,8 per cent of the adsorbed gold and 98,2 per cent of the adsorbed silver. Elution of the carbon was carried out at 91 QC. This involved pretreatment of the carbon with a sodium cyanide solution, followed by elution with deionized water. At a loading flowrate of 66 bed volumes per hour, the indicated take-up of metals on the carbon in the lead column was as follows; 53 k g/t gold, 6 k g/t silver, 57 k g/t copper, 14 k g/t nickel, and I k g/t zinc. Only a trace of cobalt was adsorbed. At an elution rate of 1,7 bed volumes per hour, the lead column was found to be completely stripped in under 5 hours, with concentrations of gold in the eluate reaching 6 to 7 g/l. Besides the excellent adsorption and elution results obtained when acidified pregnant solution was used, no fouling of the carbon was indicated, and the pressure drop across the three columns was considered to be well within practical limits. When compared with conventional zinc precipitation, the carbon process would appear to have considerable economic merit, with strong indications that significant savings would be possible both in capital and operating costs. Further pilot-plant experiments, preferably on a gold plant, would be required before a meaningful cost comparison could be made with the existing process.

Jan 1, 1979

By G. C. Mackenzie

At the last Annual Meeting of the Institute, Dr. C. V. Corless sketched the potential mineral wealth of Canada so clearly, graphically and with-all so entertainingly that one's imagination was fired with the promise held out to future generations for the tremendous expansion of the mining industry in the Dominion. Posterity will undoubtedly witness the fruit of much of the geographical search and survey that is now carried on by our government mining departments. Year after year the work advances, slowly but surely, new areas are . explored, older areas are surveyed in detail, the information being compiled in maps and reports of incalculable value to the prospector, the engineer and the general public. The immensity of the task of exploring, geologically, the outlying portions of the country, with the ultimate view of making valuable mineral discoveries, may be visualized from a study of Dr. Corless' paper and the subsequent discussion which took place and one becomes impressed with the fact that three-quarters or more of the problem can be included under the word "transportation". For instance Dr. Corless said, "The few geological explorers who have penetrated to these remoter regions . . . . . . have as a rule been compelled to stick closely to canoe routes,"; Dr. Goodwin remarked, "This barren Laurentian granite, which is put down on the maps as covering the greater part of this area, is the best guess the geologist could make from travelling along watercourses Within the next few years . . . . . . the Timiskaming and Northern Ontario railway will undoubtedly be extended to James Bay . . . . . . In order that we may be prepared for the probable influx of prospectors when transportation facilities to tidewater are provided, I think all available information on this district should be gathered together in handy form." All three-Corless, Goodwin and Cole-emphasize the well-known fact that explorers, geologists and prospectors working in new country must stick to the watercourses and that transportation by rail, road or water has always been the all-important deciding factor in facilitating the exploration and development of remote districts. Dr. Corless did, however, suggest other means of transportation in stating, "The aeroplane will be of assistance in future study of some parts of these remote areas."

Jan 1, 1924

By Jim Smith, Jeff Hudreth, John White

Jan 1, 2000

By J. K. Conibear

Since the 1948 introduction of hydraulic fill at the Sudbury Ontario Mines of the International Nickel Company of Canada, 32,000,000 tons of water-borne sandfill and 420,000 tons of portland cement addition have been placed in underground workings. Fill method mining, currently conducted at six of the ten operating mines, accounts for 28 percent of the total mines underground production. Both classified mill tailings and screened alluvial pit sand are used as fill for cut-and-fill primary mining, undercut-and-fill pillar recovery, and backfilling of blasthole and shrinkage stopes. Cemented fill, consisting of a lean mixture of portland cement, is used in areas where a stabilized fill is required to reduce dilution and aid in the recovery of adjacent pillar ore.

Jan 1, 1970

By F. C. Lendrum

Introduction The property of Normetal Mining Corporation is in Desmeloizes township, Quebec, twelve miles north of Dupuy on the main line of the Canadian National railway from Quebec city co Cochrane, Ontario. The ore bodies occur within a band of highly sheared and sericitized agglomerate which strikes N.60°W. and clips 82° north. Along a zone 1,000 feet or more in length and of variable width, the agglomerate has been replaced by copper, zinc, and iron sulphides, with copper usually predominant on the hanging-wall side and pyrite replaced in part by sphalerite on the footwall. A northsouth diabase dyke cuts through the ore zone near its east end. The Normetal mill produces a copper concentrate and a zinc concentrate which are shipped, respectively, to Noranda, Que., and Newcastle, Penn., U.S.A., for further treatment. The present paper deals with the milling of ore from what is known as No. 3 orebody. This is a lenticular body of high-zinc ore lying co the east of the diabase dyke, along the line of strike of the main ore zone, which extends westward from the dyke. On its northern side, No. 3 orebody is in contact along most of its length with a narrow band of copper ore which is highly oxidized.

Jan 1, 1948

By C. H. Grant

On the Mesabi Range, Ammonium Nitrate is used for blasting a variety of materials having widely varying blasting characteristics. The materials vary from hard, dense, magnetic taconite, which requires heavy blasting, through relatively soft, earthy, direct shipping ores, which require only light blasting to facilitate shovel operation. In view of the fact that materials gradational between these two end members are encountered in large tonnages, it is evident that a wide range of blasting situations face the mine operators on the Mesabi Range. In April of 1956, at Cleveland-Cliff s Hawkins Mine near Nashwauk, Minnesota, a fertilizer grade of Ammonium Nitrate prills was first used as a blasting agent. This first attempt was made without the addition of any carbonaceous material and even though it did go off, the force was not sufficient to produce the required results. Fuel oil was then added In the amount of one gallon for each 80 pounds of Ammonium Nitrate, with the oil and Ammonium Nitrate being added to the hole simultaneously. This blast was successful. Since then most of the mining companies have used Ammonium Nitrate, experimenting with various ratios of oil and fertilizer, mixing these ingredients either before or during loading of the holes. Since the additional of fuel oil to the Ammonium Bitrate before loading produces a more uniform saturation, most companies have adopted the method of pouring the fuel oil directly into the Ammonium Nitrate bags and then pouring the mixture into each hole. The ratio of 3- ½ quarts of fuel oil to each 80 pound bag of Ammonium Nitpate prills is now being used.

Jan 1, 1958

To enable ammonium nitrate-fuel oil (AN-FO) to be used on an equal weight basis with nitroglycerine explosives, smaller diameter bore holes became necessary with consequent modifications to drill steel and burden on holes. Detonation of AN-FO in small diameter holes proved successful both with and without primer charges but some alterations were required to adapt anoloders to the smaller holes.Important factors in training all operators in the new charging method were the retention of improved fragmentation, avoidance of excessive overbreak and keeping wall rock dilution to an absolute minimum. The successful storage of ammonium nitrate in climatic conditions with daily temperature fluctuations above and below the critical 90°F has been achieved.INTRODUCTIONTechnical aspects of ammonium nitrate-fuel oil (AN-Fa) blasting agent are well covered in recent literature. This paper deals primarily with the manner of its introduction as the principal explosive underground at Great Boulder Gold Mines Ltd. and with the many problems encountered in the process. Following reasonably successful experimental firings in June 1962', using granular ammonium nitrate and an anoloder, permission was granted by theWestern Australian Mines Department to carry out test work in selected areas of the mine. The permit allowed for fuse firing only, and for a mixture of AN-Fa containing between 5t and 6 per cent fuel oil, with an adequate primer.The use of AN-Fa on an equal weight basis with nitroglycerine explosives, involved smaller diameter holes with alteration to ground burden and modification to drill steel.Initial tests indicated that it was apparent that AN-Fa could not replace gelignite on an equal weight basis if the...

Jan 1, 1965

A number of suggestions have been made to improve the design of cells used for electro winning and electro refining of metals. Most of these designs have been aimed at increasing the current density used in order to improve cell capacity, although the purpose of some has been to produce electro deposited metals in a continuous manner. Improvements in the electrolyte flow pattern in conventional cells have resulted in an increase in the rate of mass transport of metal ions to the electrode surface; giving rise to lower concentrat- ion polarization and an improvement in the nature of the product obtained, Other cell designs are based on a moving electrode, usually a rotating disk, and these may include provision for removal of the product in a continuous manner, The maximum current density which can be used in an electro- lytic deposition process is determined by the limiting diffusion current, the physical nature of the, product, the purity of the product required and by the increase in power costs which result from the higher cell voltages, This paper examines the properties of an agitated bed of particles as an electrode system when used for a metal deposition Process,

Jan 1, 1969

By L. Yuan, J. H. Rowland III

"In 1995 and 2003, the Mine Safety Health Administration (MSHA) conducted surveys to determine the number of atmospheric monitoring systems (AMS) being used in underground coal mines in the United States. The survey reports showed data for the different AMS manufacturers, the different types of equipment monitored, and the different type of gas sensors and their locations. Since the last survey in 2003, MSHA has changed the regulation requirements for early fire detection along the belt haulage entries. As of December 31, 2009, point-type heat sensors were prohibited for use for an early fire detection system; instead carbon monoxide (CO) sensors are now required. This report will examine the number of AMS currently used in underground mines in the United States to see if there is a change in their use. The locations and parameters monitored by AMS are also discussed. INTRODUCTION The last survey conducted by the Mine Safety and Health Administration (MSHA) on atmospheric monitoring systems (AMS) used in underground coal mines in the United States (US) was in 2003 [1]. The survey report states that since 1995 there had been a steady increase in the use of AMS in underground coal mines as the technology of CO sensors was improved by manufacturers. AMS had become more reliable and some CO sensors could be purchased with the capability to discriminate between the CO produced from a fire versus CO produced from diesel equipment. This increase in reliability had reduced the number of false alarms and the response time. The faster response time to a developing fire allowed for the miners to take the necessary action to put out the fire or exit the mine. It should also be noted that at the time of last MSHA survey, some mines still used point-type heat sensors to detect the presence of a fire on conveyor belts. This detection method works by measuring the temperature of the air around the sensor. As a fire starts to develop, smoke and hot gases are produced from the combustion process, and the air is heated up. Once the air and gases reach a designated temperature detected by the point-type heat sensor, a fire alarm signal is generated. Studies have shown that the response times for detecting the presence of a fire using CO sensors are much shorter than using point-type heat sensors [2]. Finally, since the last MSHA survey, regulations have changed on the type of automatic fire detection systems permitted to be used in conveyor belt entries. As of December 31, 2009, point-type heat sensors are not permitted to be used for fire detection in underground coal mines in the US; instead CO sensors are required as a replacement (30 CFR 75.1103-4). This study will examine how the changing of the above regulations has impacted the use of CO sensors in underground coal mines in the US compared to their use based on the last MSHA survey. Importantly, in the previous MSHA survey, the data was recorded for producing and non-producing coal mines. In this study, only the data from the producing coal mines was recorded. Data was collected from a total of 235 coal mines for this study with the help of the MSHA district offices."

Jan 1, 2017

By K. R. Robilliard

The Peru based tin mining company, Minsur S.A., commissioned Ausmelt Limited to design, supervise construction and commission a tin smelter and refinery for production of refined tin metal. The plant is located 240km south of Lima, near Pisco, Peru and is operated by Funsur S.A., the wholly owned subsidiary of Minsur S.A.. Selection of the Ausmelt Technology followed a series of crucible scale test work and pilot plant trials conducted at Ausmelt's facility in Dandenong, Australia and two feasibility studies undertaken by Ausmelt in 1991 and 1993. Ausrnelt began the plant design in 1994 with the construction phase following in 1995. Commissioning of the plant commenced early in 1996 with a target throughput of 30,000 tonnes per annum of concentrates. In mid 1998 oxygen enrichment of the Ausmelt lance air was introduced to expand the capacity to the throughput of 40,000 tonnes per annum of concentrates. The process route involves the use of an Ausmelt furnace for primary concentrate smelting, followed by a conventional tin pyro-refining circuit to produce high grade tin suitable for sale. Further work continues between Ausmelt and Funsur to investigate the use of an alternative, more economical, fuel source and the installation of a second Ausmelt furnace. The paper reviews the project to date with details of ongoing operations and developments at the Minsur Tin Smelter.

Jan 1, 2000

By D. McConchie

The use of Bauxsol? (physically and chemically modified alumina refinery residues) to treat acid rock drainage (ARD), and sulphidic waste rock and tailings, provides new options for managing some intractable environmental problems at both derelict and active mine sites. Treatment of ARD waters using the Bauxsol technology shows that the effectiveness of raw Bauxsol material can be enhanced by including modest amounts of selected industrial minerals or common chemical additives. The type and amount of additive required and the amount of the blend needed to treat the water depends on the initial composition of the water and the target water quality; for some ARD waters, optimum treatment may require one or more changes in the type or amount of additive used. Maximum treatment efficiency can be achieved only when a balance is maintained between the rate of trace metal binding and the rate of change in water pH; adding treatment reagents faster than can be accommodated by the reaction kinetics will not result in more rapid water treatment. This paper presents the results for treating several ARD waters to illustrate the importance of blend selection and treatment procedure. Although treating ARD water is often necessary, this strategy treats the symptoms rather than the cause. The best permanent solution is to treat the sulphidic waste rock or tailings such that they do not continue to oxidise and produce acidic metal-rich leachates; sulphide oxidation needs to be stopped or slowed to a rate that can be accommodated by normal environmental processes. Capping lined impoundments is not a solution because all caps and linings will inevitably fail some time in the future creating a nasty surprise for some future generation. Adding lime is also less than ideal because the lime leaches from the treated material; treatment often appears to be effective for a few years and then fails. Bauxsol technology offers effective alternatives to conventional liming and capping procedures and Bauxsol blend application rates and procedures can be planned to ensure that no acidic or metal-rich water can ever escape from the site. Bauxsol can be physically mixed with the sulphidic mine wastes or it can used to form subsurface permeable reactive barriers, or both. Bauxsol treated waste rock and tailings can be immediately and effectively revegetated. In this paper we present leachate quality and plant growth rate data for several sulphidic waste rock and tailings deposits treated using the new technology.

May 1, 2003

By John Hughes

Fundamental to the use of rotary bit drilling equipment for oil and gas drilling is the requirement to maintain a cooling and lubricating environment for the bit and a means of conveying the cuttings from the drilling operation to the surface. The vast majority of such functions are provided for by the use of water based drilling fluids, commonly known as the drilling mud. One of the basic constituents of drilling mud is bentonite, a montmorillonite clay. Bentonite, when mixed with water at approximately 6% solids, will produce a fluid which has several important features in connection with its role as a drilling mud:

Jan 1, 1983

By Hector Simchas

"1. BENTONITE: THE CRUCIAL CONSTITUENT OF SLURRYSuspensions of bentonite and water are used in a variety of applications in underground engineering. For the construction of underground elements like slurry walls or piles, bentonite slurries offer support to the excavation of loose soils and counter pressure against hydrostatic pressure of ground water, especially where soil permeability is high. In addition, for the construction of tunnels by the slurry-shield method or when hydromills are used for excavation, bentonite suspensions transfer the loosened soil to the surface. In applications like pipe jacking and microtunneling, or where high revolution drilling is required, bentonite also provides lubrication and cooling.To fulfill these functions, the properties of a bentonite slurry need to remain stable, or at least predictable, during the course of construction. Unfortunately, when a suspension mixes with earth, ground water and/or impurities, its properties may be compromised resulting to reduced performance, which would in turn lead to increased construction costs and the risk of the excavation collapsing. Our experience in the lab and onsite is presented herewith.2. MOST USUAL FACTORS OF PERFORMANCE FAILUREWater and soil quality are important factors defining the behavior of suspensions. In an extensive program of measurements in our technical laboratory, the effect of frequently encountered harmful substances on bentonite suspensions has been examined and the results are summarised in Table 1.Some tests show that the conductivity of water has a direct relationship with Marsh Viscosity. For example, we have seen that if the quantity of bentonite required to achieve a 40s Marsh Time ranges between 50-52 kg/m3 at water conductivity below 100 µS/cm; when conductivity is increased to 1,400 µS/cm, we need 65-68 kg/m3 in order to achieve the same property."

Jan 1, 2015

By J. Jacob, A. G. Guézennec, F. Savreux, S. Nanaa, M. Delclaud, P. d’Hugues

Mining wastes can contain base and precious metals, but also metalloids and rare earth elements that are nowadays considered as highly critical for the industrial development of the European Union. The development of alternative routes to conventional processing is still required in order to decrease the cost associated with the treatment of these resources, which are more complex in composition and with lower grades. An ecologically acceptable and yet economic alternative for processing of low-grade sulphidic primary ores as well as mining wastes is the extraction of metals using bioleaching processes. The purpose of this study was to test the potential of bioleaching procedures for the extraction of residual metals contained in sulphide-rich tailing wastes coming from a European copper mine. These wastes are mainly composed of pyrite (60%) and contain cobalt (0.06 %) and gold (0.95 g/t). Bioleaching experiments were performed in 2 L stirred reactors in batch mode and in pilot tanks (110L) in continuous mode, using the "BRGM-KCC" bacterial consortia. High metal extractions were obtained (cobalt dissolution > 90%), which confirm that bioleaching is an effective process for this tailings material. Experimental results were used to design a global treatment process scheme and to perform a preliminary economic evaluation, showing good profitability of a hypothetical industrial project.

Jan 1, 2014

By James J. Broderick

In the production of Pig Iron - Limestone, Coke and Iron Ore pellets are changed to the blast furnace and reacted at approximately 2,800 degrees F. The resultant products are molten iron and a molten slag - not unlike lava. The molten slag stream is channeled into open pits, cooled with water, crushed and sized for various industrial applications. The production of steel from pig iron in open hearth, B0P, BOF and electric furnaces results in somewhat similar slags: but since free lime is normally the flux, the resultant slags are not satisfactory for use in cement pastes. When exposed to water, the lime slakes, expands by 250% and ruptures the concrete. Thus, the slag discussed first is Blast Furnace Slag composed of 30 to 40% Silica (SiO2) Alumina (AL202) 7 to 16% Lime (CaO) 32 to 45% and Magnesia (MgO) 5 to 15%. The oxides do not exist as free oxides but rather as silicates and alumino silicates which are chemicall inert. Since transportation costs limit the area of use, blast furnace slag can only be found in concrete products produced within 60 to 100 miles of a blast furnace operation. Even within these areas where slag is in heavy supply, quite often the use of slag is minimal for concrete aggregate and the major outlet is road base.

Jan 1, 1985

By Paine GG

In coal mining each of the unit operations are interrelated with each preceding operation having an effect on subsequent operations. This presents difficulties for determining when the lowest overall costs for a particular mining system are achieved. Drilling and blasting is the first mining operation for production and is known to have an effect on the subsequent loading, hauling and crushing operations. Computer blasting models developed over the past 15 years can be used to describe the drilling and blasting operation. This paper describes the ICI Blasting Model "SABREX" in detail. Methods of using the model are discussed. This involves field measurements of geological structure, shallow refraction seismic surveys, laboratory measurements of rock properties and high speed photography of blasts. The predictions are compared with actual blast results for fragmentation sizing and muckpile profiles. Outputs from the model are described and these can be used for input to models of subsequent operations.

Jan 1, 1987

By George C. Carter

It was just a little over three years ago that the "Go" button was pushed to start operations on the blending piles at Oro Grande. As is usual with any new installation, there were problems that had to be solved. This paper will concern itself with those problems directly related to quality control. To obtain a consistent outgoing quality level at the most economical level for a finished product requires two main points: 1. Measurement of variations in the process, 2. A method of making a predictable change to adjust for variations. The manufacture of cement requires a relatively high degree of accuracy if a consistent outgoing quality level is to be maintained. The blending piles were our solution to this problem.

Jan 1, 1962

By D. M. Schubert

As a clean and renewable energy carrier, hydrogen is an important component of most alternative energy portfolios. Hydrogen combines very high energy content by weight with excellent environmental attributes. Since hydrogen reacts with oxygen to produce only water with release of energy, it can be used to power fuel cells, combustion engines, and turbines, without production of greenhouse gases at point of use. However, because of its low volumetric density, storing pure hydrogen is impractical. Thus implementation of hydrogen technologies requires materials that can safely store and release large amounts of hydrogen (1,2). In recent years, the U.S. Department of Energy (DOE) and other governmental agencies around the world sponsored extensive research on hydrogen storage materials, including those based on boron. These efforts have resulted in significant advances in hydrogen storage technologies. Boron materials stand out as leading candidates for hydrogen storage among the many options investigated. Combining excellent hydrogen densities, release rates, and safety characteristics, some boron materials can hold substantially more hydrogen by weight and volume than even pure liquid hydrogen (3-5).

Jan 1, 2010

By K. O. Groves

Although chlorine oxidation has been found to be effective in destroying the CN ion, an excess of chlorine is needed to drive the reaction to completion. This often results in the formation of residual chloramines, which are toxic to aquatic life and often regulated by various states. The interhalogen, bromine chloride (BrCl), has been found to be just as effective but without the formation of persistent, residual chloramines. The hydrolysis and subsequent disproportionation of the highly-polar BrCl molecule essentially yields a solution of hypobromous acid (HOBr) and nonoxidizing hydrochloric acid (HC1). Studies have been carried out to directly compare the mechanism of CN destruction with chlorine and bromine chloride.

Jan 1, 1982

By A. S. Dawson

"IntroductionTHE PURPOSE of this paper is to describe the results of a preliminary investigation of a method thought to be useful in interpreting geological structures in un-metamorphosed sedimentary rocks. The writer is not aware of the method having been described or investigated previously, although no thorough search of the literature has been made.The method to •be described is based on the assumption that, in argillaceous sedimentary rocks, certain ceramic properties are diagnostic for certain beds within areas of variable limits.Two ceramic properties• have been investigated: pyrometric cone equivalent (P.C.E.), and bloating characteristics of shales. The enquiry has been directed toward testing the usefulness of these properties in determining the following:A -The correlation of shale beds and, by inference, of coal seams, sandstone beds, or other such structures associated with them.B.-The location of contacts between marine and non-marine shales where lithological, palaeontological, or other evidence is lacking.Limitations of time and facilities have prevented a thorough investigation of this problem. The results given in the present paper are preliminary only. It is hoped, however, that they will occasion discussion or even lead to more thorough investigation of the method by individuals or organizations.There are, admittedly, various limitations to the proposed method. It is thought to show some promise when used in conjunction with the well-known and established methods used in stratigraphic correlation and, more particularly, when the conventional methods are not applicable."

Jan 1, 1952