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By S. A. Sadough vanini

In this paper, Stress-Strain-Temperature relations for Shape Memory Alloys are studied. Temperature effects on Shape Memory Alloys are different from those related to ordinary materials. In ordinary materials, elastic characteristics can be assumed to be constant in low temperature ranges, and only the deflection arising from temperature changes could be added to the elastic defection. As long as two phases of austenite and martensite could be present in Shape Memory Alloys simultaneously, elastic modulus follows temperature and temperature gradient. In continue a smart actuator is investigated considering a homogeneous cantilever beam. Beam bending is established by using shape memory wires. An initial strain is imposed to shape memory wires in a low temperature, and then, they are installed in the outer surface of the beam. Therefore, since the temperature is imposed in these wires and they cannot have free recovery strain, the compressive recovery stress will be produced in the outer surface. This will result in a deflection in axial direction of the beam. At first, beam deflection is calculated on the basis of theoretical relations and solving the relevant differential equations. Afterwards, experimental tests are performed on an elastomeric beam equipped with shape memory wires. When a voltage is applied, a temperature rise will occur in the wires; then, this temperature rise causes a deflection in the beam. Finally, the theoretical and experimental results? comparison indicates a good conformity. One capability of this actuator is its high flexibility, and by controlling the inlet current, the end-beam deflection can be controlled.

Oct 1, 2011

By S K. Michelic, M Schickbichler, A Kharicha, E Karimi-Sibaki

The requirements for the controllability of metallurgical processes are increasingly becoming the focus of both industry and research. Advances in this field of research not only impact the stability of processes but often also influence the quality of the final product. One important way to examine processes in-depth, and thus show potential for improvement, is to describe them using physicsdriven models. In metallurgy, thermodynamic and kinetic descriptions of interactions between individual components of a system are often used to describe and analyse important metallurgical phenomena across the entire process. However, for the creation of physics-based models, boundary conditions and process variables must be implemented to enable a description that is as realistic as possible. The collection and generalisation of boundary conditions and process variables is, therefore, an important step towards functional models. The focus of this study is the determination of mass transfer coefficients between all components in a steel/slag/refractory system. For this purpose, experimental and theoretical methods are applied. Laboratory scale experiments are carried out in an induction furnace, and the mass transfer coefficients of the defined steel/slag/refractory system are calculated from changes in the chemical composition of the various components. Additionally, a calculation of the mass transfer coefficients based on dimensionless quantities is carried out. By comparing the values of the mass transfer coefficients determined theoretically and those determined experimentally in the trials, the suitability of the calculation is examined. The collection of mass transfer coefficients provides essential findings for future kinetic descriptions of inclusion modification based on the effective equilibrium reaction zone (EERZ) approach.

Aug 21, 2024

By R. V. Ramani, R. Bhaskar

"IntroductionThe behavior of dust clouds in mine atmospheres has been a subject of longstanding interest due to both health and safety reasons. Pioneering studies in Germany and SMRE focussed on ambient dust concentration, principally aimed at determining optimum velocities for effective dilution. A summary of studies related to this area is provided by Hall,(l) Efforts to understand dust deposition from the explosion hazard point of view led to experiments in return airways (2-4) followed by experiments in longwalls.(5) Concerted efforts, either experimental or theoretical, were not made until recently to relate ambient concentration with dust deposition in mines. In 1974 Hwang et a1 (6) developed a computer model to predict dust concentration which considered deposition-concentration relationships. Also, experimental studies involving concurrent dust deposition and ambient concentration were conducted in the U.S. by Courtney et al (7 ) in operating mines. Efforts to relate theory with experimental results have been made by Owen (8) and Hwang et al (6 ) for dust deposition. There has been limited work, however, to determine the application of the theories and assumptions from aerosol sciences for modeling dust flows in mine atmospheres. (9 ) This is the objective of the work currently underway in the Generic Technology Center on Respirable Dust since· 1983 under a project titled, ""Prediction of Ambient Dust Concentration in Mine Atmospheres."" The scope of the project activities include:1. Development of a mathematical model to predict dust deposition and concentration in mine atmospheres.2. Experimental studies on dust transport and deposition in mine airways.3. Comparison of the model results with the experimental data."

Mar 1, 1989

By F. Vagnon, A. M. Ferrero, M. Pirulli, A. Segalini

"The topic of this study is the design of flexible fences to mitigate the risk due to debris flow phenomena by means of theoretical and experimental studies analysed in framework of the Rock Engineering System (RES).The study of the interaction between debris flows and flexible barriers is a major challenge since many different aspects concerning both the slope characteristics and the structure features are involved. Debris flows are often triggered by the mobilization of debris deposits that are generated by rock fall of adjacent rock walls. The rock debris deposits are difficult to be characterized by the physical and mechanical point of view due to their large variability in volume distribution and, moreover, when dealing with high mountains environment, they are also strongly affected by the presence of water at different phases (solid or liquid) depending on the temperature. The debris deposit turns unstable in relation with the geotechnical and environmental features of the areas and the instability evolution in high mountain steep valley is often a debris flow. Debris flow destructive potential is very high and protections are often needed to reduce the debris flow risk.This complexity determines the needs of comprehensive study able to include the global basin dynamic and the environmental conditions. An a-priori analysis of the influence of the different aspects can be useful to focus on the real driving aspects of the problem. Due to the complexity of the system the application of the RES methodology is recommended in order to clearly define the different assumptions needed, their influence on the simulations and a comparison among them.RES allows investigating triggering criteria, flow and depositional processes and interaction of flows with protection fences in a rational way. For this purpose, an interaction matrix is created: it summarizes the key geotechnical parameters that influence debris flows, their interactions and debris/engineering protection opera behaviour. The goal is to quantify the diagonal-off terms to assess the residual risk after barrier construction, using back analysis from real debris flow event and data collection from literature.This methodology is applied to analyze a debris flow event in the Italian Western Alps where numerical analyses are carried on to assess flow characteristics to be used for fence design through the application of an analytical and numerical model developed by the authors (Brighenti et al, 2013). In particular, the velocity and deposition heights have been estimated using the numerical code RASH3D (Pirulli, 2010), which is a single-phase model based on depth-averaged Saint Venant equations. Pathways of different lengths are studied to assess the input data necessary to design the protection barrier and to determine the associated risk. Simulation of the barrier at different places along the valley will also allow to determine optimal barrier location in terms of minimum residual risks by comparing the velocity, the volume and the energy of the debris after the barrier impact.The work will produce a possible design scheme to be adopted in this environment."

Jan 1, 2015

By Petre Stelian Nita

In small steelmaking shops, in foundries and forging plants, there are not too many option to recycle the basic slags, which are not suitable for many purposes of recycling, because of their low chemical and structural stability. A solution of an adequate recycling is a direct recycling in EAF. Several quality requirements, physico-chemical properties and proportions of slags must be analysed. The progress in this fields permites to establish an adequate proportion of recycled slag, based on enough exact computation of the related property. For oxydizing slag, obtained during melting and in the first part of decarburization operation, the problem of phosphoms contents can be analysed using the phosphate capacity (C PO34-). For reducing periods, during deoxidization operation, desulphurization also occurs and the problem of the sulphur contents can be analysed using the sulphur and sulphide capacities ( Cs / Cs) Between this two complex thermodynamic indicators of the slags. a direct relation is established, using thermodynamic aspects, resulting from the equilibrium constants for dephosphorization and desulphurization process and also, using the optical basicity of slags, computable from the chemical analysis of the slags. On this basis starting from the steel quality requirements. adequate strategies can be established in order to obtain high rates of recycling (between 50-80%) of steelmaking slags. Important cost savings are obtained through this procedure, based on the correct amounts of the fresh lime, iron ore and fluidizers. Keywords: Slag, Properties, Recycling

Jan 1, 2003

By Roshan B. Bhappu

Although the economic importance of recovering copper by leaching of mine work dumps from open-pit operations has been realized for some time, serious attempts to understand and to improve such operations through scientific research has been made only in recent years. This progress report covers the results of chemical, physical, and biological studies pertaining to the dump leaching process and discusses salient features and parameters that may be helpful in improving such operations.

Jan 1, 1968

By F. Qiming

By means of flotation experiments, potential-pH diagram, electrochemical testing and X -ray photoelectronic spectrum (XPS), the main factors (the thermodynamics and the property of surface products) influencing the separation of sulfide minerals (such as galena and chalcopyrite) in the collectorless flotation are studied. The actual conditions (Eh, pH) of separation are not conformable to the results of thermodynamic calculation. The kinetic behavior of oxidation of sulfide minerals and the property of oxidation products are the decisive factors of the separation of sulfide minerals in the collectorless notation.

Jan 1, 1992

By Nobuhiro Takahashi

PROLOGUE The Yaguki mine, which is located near the southern end of the Tohoku region, Japan, near the coast of the Pacific Ocean, had had a long history as a copper mine, but had not been operated since 1925. About 30 years later it was reopened by Nittetsu Mining Company, and in 1958 a small flotation and magnetic separation plant, a so-called test plant, started production. The ball mill the author first met, a 8x4x4x7 ft tricone mill, called No.1 mill, had started running at that time. With his experience in initial, running of this mill he realized that the ball mill was not simply a preparatory process to flotation, but a determinant factor for flotation performance, an energy-consuming and costly process, and that its operation control was an important task in the plant (1). The working part of an operating ball mill is the ball load inside, whose properties govern the grinding performance. Its size distribution affects the efficiency greatly and the capacity is nearly proportional to its weight. When a ball mill operates for a long period of time with a constant and consistent addition of renewal balls, wear and renewal of balls are balanced, and an equilibrium ball load is formed. A stable equilibrium load is the primary requirement for a stable ball mill operation. However, renewal ball size would be the most influential factor affecting efficiency and capacity of operating ball mills. To improve efficiency, to increase capacity, or to get finer product, attempts to find out the optimum size assortment of renewal balls should be made. When re-

Jan 1, 1976

By Tatyana A. Ivanova, Tamara N. Matveyeva, Anatoliy A. Fedorov, Tatyana V. Nedosekina, Valentin A. Chanturiya

An ingenious methodology purposively developed by the authors for comprehensive assessment of flotation properties, electrophysical characteristics and. crystal chemistry features of natural gold-bearing sulfide minerals of different origin has been used in this study. Examination of the elemental composition of the minerals, ion-molecular components of the liquid phase in suspensions, surface properties of sulfides and different flotation reagents sorption forms was performed using the methods of X-ray phase and spectral analysis, potentiometry, UV and IR spectrometry, computer image analysis, and computer simulation techniques. The role of isomorphous impurities in the formation of hydrophobic sulfhydric collector layers on mineral surfaces in complex ore processing has been elucidated. The parameters characterizing the variability of the Fe:S ratio in pyrite of different origin have been determined based on non-stoichiometry characteristics of natural gold-bearing sulfide crystals. An ingenious method of formatting and linear approximation of experimental data was used to find out the quantitative relationships between the impurity content, electrophysical characteristics, non-stoichiometry and floatability of pyrite from a number of different deposits. The effect of the impurity species present in sulfides on the characteristic pH value marking the floatability peaks as such and their trend of shift towards higher alkalinity has been revealed. A theoretical substantiation has been given to prognostic assessment criteria for processing characteristics of gold-bearing sulfide minerals with varying composition. New flotation reagents and advanced reagent systems which help to increase the contrast of processing characteristics for different gold-bearing sulfides, resulting in improved selectivity, have been developed. The mechanism of selective flotation of precious metal-bearing Fe and As sulfides achieved by using short-chain dithiocarbamates and a mixture of cyclic trithiocarbonate with oxyalkylsulfides has been analyzed.

Jan 1, 2003

By Orion Ciftja, Arjan Ciftja

"The directional solidification method is routinely used to produce polycrystalline silicon, an important material for the photovoltaic (PV) industry. The form of the solid-liquid interface during solidification has considerable influence on the material quality. The dissolved impurities and the solid inclusions above the solidification front affect the interface and may cause interface breakdown. We investigate the effects of pushing and engulfment of silicon carbide (SiC) particles by the solidification front during directional solidification of silicon. We employ a 12kg directional-crystallization furnace to cast the molten silicon. We use upgraded metallurgical grade silicon with low concentrations of metallic impurities (< 5ppm) and a high content of carbon (700 ppm) present as SiC particles. Samples from the cast polycrystalline silicon ingots are investigated by light microscope. The expected interaction of impurities with the solidification front is investigated theoretically using empirical models. The data obtained from the models are in good agreement with the experimental results.IntroductionDirectional solidification is a well-known method for producing multi-crystalline silicon for the PV industry. In this method a planar front, achieved during solidification, results in a clearly defined interface between the solid and the liquid phase. The solubility of major impurities is higher in the liquid than in the solid phase. Therefore, directional solidification will work as a purification process where the impurities are retained in the liquid phase [1]. Apart from the process of removing the dissolved elements in molten silicon, the directional solidification plays also another role. It will interact with the solid particles that may be present in the melt. When a liquid containing an insoluble particle is solidified, three distinct interaction phenomena are observed: engulfment of particles, continuous pushing, and entrapment [2]. The term “engulfment” is used to describe incorporation of a particle by a planar interface, and the term “entrapment” is used for particle incorporation by a cellular or dendritic interface (see Figure 1) [3]."

Jan 1, 2014

By Rodolfo V. de la Cruz, Richard E. Goodman

Knowledge of the initial state of stress in rocks provides a key to the solution of many problems in rock mechanics. The initial state of stress is part of the basic data required for rational design of structures in rock, since its redistribution when engineering activities are conducted is a primary load on the rock portion of the engineering system. Knowledge of initial and subsequent changes in the state of stress is also relevant in the study of active faults and crustal strain. The purposes of stress measurements are not generally well served by methods which disclose only one of the stress components at a point. Recently, interest has centered on overcoring methods which though ex- pensive and difficult have the important advantage of yielding data on three or more stress components. In a previous paper, the authors introduced a new method-termed borehole deepening-based on measurement of the deformations that occur close to the bottom of a borehole when it is deepened by further drilling without overcoring.l The proposed method is at a disadvantage when compared with over- coring procedures in that the quantities to be measured are somewhat smaller and the measuring environment is more hostile. However, the borehole deepening method presents three distinct advantages in comparison with overcoring procedures: (1) Using the same borehole, both the initial and the subsequent changes in the state of stress can be obtained by borehole deepening. Stress changes with time are

Jan 1, 1970

By P. Basarova

The attachment of bubbles onto a collecting surface is an ubiquitous natural phenomenon, playing a critical role in numerous practical processes. The goal of the project is to broaden the knowledge about hydrodynamic interactions between small bubbles and large solids that occur in nature and industrial processes. Focusing on collision processes between a single rising bubble (Db<1 mm) and a larger falling spherical particle in stagnant liquid, the theoretical model describing the bubble trajectory is given here. The model is based on analysis of forces acting on the bubble, and utilizes equation for the bubble motion. Mobile and immobile type of bubble surface mobility are considered. The calculated results are compared with the experimental data; here a high-speed video camera was used to capture the bubble motion and bubble-particle interaction. Very good agreement between experimental and calculated data was found. For both types of surface mobilities, the bubble deviation in the horizontal direction is nearly linear. The proportion constant is bigger for immobile bubble surface and increases with the bubble size. Furthermore, particular forces acting on bubble were studied. A similar course of relative bubble velocity and force impact was observed for identical bubble position. For cases when the bubble centre is close to the particle axis, only deflection in one direction is observed. When the bubble is reaching the maximum trajectory, the force ratio is changed. The bubble is firstly pushed away from the particle, but when it is within close distance from the particle, the bubble is pushed towards the particle.

Sep 1, 2012

By G. Grant Smith

In situ bulk density of coal is a variable applied to various aspects of coal resource evaluation, such as compositing ply analyses of coal attributes that are expressed on a weight per cent basis, and determining tonnages from volume estimates. Its value is a function of composition and porosity of the in situ material. When densities of ash-free coal, ash and water are fixed, in situ bulk density of a coaly mix can be expressed as a function of proportionate weight of ash in the mix. Correlations between in situ bulk densities and weight per cent ash contents of coaly mixes have been estimated for four general rank classes of coal (low medium volatile bituminous, high volatile bituminous, subbituminous, and lignitic).

Jan 1, 1991

The number and severity of sulphide dust explosions in underground metalliferous mines have increased in recent years, despite various methods used to prevent or inhibit them. A dust explosion occurs when a cloud of combust- ible dust in an oxidizing atmosphere is exposed to an ignition source with sufficient energy to ignite the dust. A computer blast simulator model was used to investigate the movement of the fractured rock, temperatures and volumes of the explosion gases in a 70 m high, 24 m wide open stope.

Jan 1, 1988

By Janne P. Isohaka, Anssi M. Laaksonen

"Abstract In Scandinavia the use of steel pipe piles in bridge foundations started in the mid-1980s and has increased steadily since. As the piles driven in soft soils are slender, they can fail by buckling. Buckling usually requires taking into account the second order effect in structural and geotechnical design.The purpose of this paper is to derive formulas for demonstrating the theory behind the formulas given in literature for the second order effect of initially bent piles.IntroductionIn Scandinavian countries solid bedrock usually lies at moderate depth. If the bridge site is in an area where the soil above the bedrock is soft, the bridge is usually founded on end-bearing piles resting on the bedrock.The main purpose of the piles is to transfer axial forces into bearing soil. Like columns, piles can lose their stability by buckling when surrounded by soft soil. When axial compression on a slender, initially straight, pile reaches a particular value called the critical load, the pile is subjected to lateral deflection and loses stability. The soil around the pile suffers a corresponding deformation. This soilstructure interaction increases the critical load compared to a pile without surrounding soil.It is very unlikely that piles are ideally straight. Initial curvature along with curvature and deviation caused by the installation of piles causes bending moments to the pile when normal force is applied. These lateral displacements increase when normal force increases. This increase of moment is called asecond order effect.Eurocode and literatureEurocode 7 includes guidelines for the design of piles (Eurocode 3, section 5 includes design of steel piles). However, there are no clear guidelines for considering the second order effects related to piles surrounded by soil. Eurocodes advise doing structural design of piles the same way as in the case of columns. With columns, the second order effect is taken into consideration by multiplying the first order moment with the factor shown below (SFS EN-1992-1-1, 2005):"

Jan 1, 2014

By B. Szpunar

Structural and mechanical changes of urania are investigated when oxidized to U3O8. The CASTEP ab-initio quantum mechanical program, employing density functional theory is used. The total energy technique is implemented to investigate changes in the lattice constants. The ab-initio calculations predict a 36% increase in the volume per uranium atom when transforming from UO2 to U3O8, which agrees very well with experimental data. The implication of this prediction on the linear expansion and fuel fragmentation is discussed. The calculated elastic constants of urania are in good agreement with experiment. The predicted mechanical properties of UO2 and U3O8 are compared.

Aug 1, 2010

By Robert F. Mehl

EXTENSION of physical and chemical methods of research in the study of metallic behavior continues rapidly, particularly in the correlation of behavior with crystal structure, and in the analysis of elastic and plastic properties. The growth of the science of metals during 1933 calls for special comment; the need for special reviews and for textbooks and monographs is now acute, as might he supposed from the number of references appended to this article, a list which is much abbreviated.

Jan 1, 1934

By Yap Chu-Phay

Although chronologically the Sb-Bi system was the first one studied by the writer, the theoretical basis of the equations used in this paper is fully discussed in the writer&apos;s paper on the iron-carbon system,&apos; because he believed that many would be more interested in the iron-carbon alloys. He suggests, therefore, that the reader consult that paper to familiarize himself with the theoretical aspect of the thermodynamic treatment outlined herein. This paper is divided into two parts: Part &apos;I deals with the Sb-Bi system and Part II deals with the lead-rich side of the Sb-Pb system. Although the former system has not much practical interest now, it has great theoretical interest in that it is the one system that for a long time was thought to have (and under specific conditions still has) an anomalous solidus, which no amount of physical investigation could adequately account for. The latter system, of course, is particularly interesting in the lead-rich end. It will be shown that the thermodynamic method is capable of predicting reliably the equilibrium position of the solidus, and thus acts as a check on the experimentally derived solidus. PART I.—THE ANTIMONY-BISMUTII SYSTEM In connection with his studies in thermoelectric phenomena,-the writer was naturally interested in the system Sb-Bi. In consulting the International Critical Tables2 he found the constitutional diagram shown in Fig. 1 (not including Ôtani&apos;s solidus), essentially after Cook,³ who investigated the system carefully by thermal analysis. Note the isothermal crystallization of alloys varying in composition from about 48 per cent, (by weight) to pure Bi. This is anomalous, because, according to the phase rule, in a binary system when only two phases coexist, there is univariant equilibrium; that is, the composition changes with the tempera-

Jan 1, 1931

By Oluwasegun Samuel Odebiyi, Shaona Wang, Feng Gao, Biao Liu, Hao Du

Recovering vanadium from vanadium titanium-magnetite (VTM) ore using ( NH4)2C2O4 is a clean hydrometallurgical process, but the drawback is the low recovery and slow kinetics due to the formation of inhibitor. A novel energy-efficient mathematical model was derived for green leaching of VTM in which the mechanical activation (MA) removed the inhibitor “δ” (formation of impermeable product layer of CaC2O4) covering the reacting core of the CaV2O6 leaching process in ( NH4)2C2O4 solution. Before the MA processing, the formation of the CaC2O4 layer affects the kinetics (slow) and NH4VO3 leachability (low recovery). The dissolution rate enhancement and economic importance (in terms of leaching kinetic/recovery) of mechanical activation (MA) pretreatment in hydrometallurgical processing cannot be overemphasized. It is shown from the experimental and developed mathematical model results that the rotating speed of the ball mill (ωb) has a significant effect on the NH4VO3 recovery. At 360 rpm, the experimental result gave an 82% optimum recovery rate and a reaction rate constant of 0.01889s−1 with close correlation with the present models at 82.8% and 81% for liquid-to-solid layer diffusion and chemical reaction controls, respectively, with a reaction rate constant of 0.018883s−1. The close correlation between the experimental recovery rate results and the diffusion recovery rate model result justifies that the leaching process is diffusion control shrinking core kinetic with experimentally measured activation energy (Ea) value of 19.502 kJ/mol . This present model proved that MA enhances the dissolution rate regardless of the formation of a passivation layer on the material and best describes the kinetics of the MA hydrometallurgical processes compared to the shrinking core model.

Nov 3, 2023

By D. Van Dooren

The final goal of the research project is to develop a 3D FEM model that is able to predict the kinetics and micro-structural evolution during the bainitic transformation. The input parameters consist of thermodynamic and atomic mobility data obtained from the ThermoCalc and mCTRA databases combined with structural mechanics data extracted from the stress-strain curves of the fcc and bee phases. In this paper the general principles of the model are outlined and some interesting preliminary results are shown and commented. The full implementation of the model has presently not been achieved yet. In the model the bainitic transformation is considered as a sequence of martensitic (re)nucleation and growth of a ferritic subunit followed by the carbon rejection into the surrounding austenite. The (re)nucleation of the subunits will be described through a non-classical martensitic nucleation criterion. Once a nucleus has been activated at a specific location in the material, a full-sized subunit is instantaneously formed through a displacive mechanism. The stress state in the system that arises due to the transformation strain can be calculated by a 3D FEM programming code. Immediately after the formation of the subunit, another 3D FEM programming code calculates the carbon diffusion from the supersaturated ferrite into the surrounding austenite. The resulting stress state and carbon profiles will be used to determine where and when a new subunit will nucleate based on a renucleation criterion. Keywords: Bainitic Transformation, Modeling, Eshelby, Carbon Diffusion

Jan 1, 2003