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By I. D. Ustinov, V. A. Arsentyev, A. O. Mezenin, A. M. Gerasimov

"The solid mineral raw materials of the sediment deposits containing the argillaceous variations such as the coal and the potash ores are the most multi-tonnage solid minerals mined and processed in the territory of the Russian Federation. Both types of the deposits have relatively simple geology aspects with large and medium-sized solids and as a rule, the most often, with the regular bedding which are characterized by the fitchery thickness and the internal structure. Such deposits are very difficult for mining and processing. The thermal modification of this of ores allows changing the physico-chemical properties of its components in such a way that their further processing - grinding, separation, transportation and storage can be carried out without the use of process water or significantly reduces its consumption. The purpose of the present study is to increase the efficiency of the mineral processing containing the layered aluminum silicate by reducing their negative impact on the basic dressing processes, the separation of suspended matters and the storage of waste. INTRODUCTION Many deposits of minerals are associated with the presence of layered silicates such as the argil, mudstones, argillaceous slate - highly hydrophilic mineral varieties which have the ability to swell in the water. This ability to self-disperse creates the great difficulties both for the extraction and the processing of such ores. Since the dressing of most minerals is associated with the use of wet processes, where in contact with water the swelling layered silicates are dispersed to a particle size of less than 50 µm, but due to their high hydrophylic property they form bonds that promote the formation of so-called structured suspensions having increased viscosity. In this case the structured suspensions make it difficult to perform the separation operations as the classification, the gravity and magnetic separation, the flotation and thickening and filtration operations."

Jan 1, 2018

By D. P. Patil, B. K. Parekh

Water is the mainstay for beneficiation of fine size coal and minerals; however, it is also the least desirable constituent in the final product. The basic concept of the novel process described in this paper is based on the differential surface heat absorption capacity of individual particles, which differs for different species of mineral. When a mixture of fine material is exposed to a radiant energy source, the various solids components present in the mixture will absorb heat energy depending on their composition and there will be difference in the surface temperature of the particles. When this differentially heated solid mixture is placed on a moving belt, which is coated with low temperature melting resin, the hotter component of the mixture will stick to the belt and relatively cooler will stay free on the belt and fall off at the end of the belt run. Experiments were conducted with pyrite, coal and quartz of 6 x18 mesh particle size. The goal of the test program was to find the optimum conditions at which there exists a required temperature difference between minerals and coal particles by controlling the operating and system variables. Preliminary tests results showed that there is a potential for separating mineral matter from coal using the thermo-adhesive separation technique.

Mar 2, 2022

By D. PATIL, B. K. Parekh

Water is the mainstay for the beneficiation of fine-size coal and minerals, but it is also the least desirable constituent of the final product. The basic concept of the novel process described in this paper is based on the differential surface heat absorption capacity of the individual particles. When a differentially heated solid mixture is placed on a moving belt that has been coated with low-temperature melting resin, the hotter component of the mixture will stick to the belt while the relatively cooler component will stay free on the belt and fall off at the end of the belt run. Experiments were conducted with pyrite, coal and quartz particles of 6 × 18 mesh size. The goal of the test program was to find the optimum conditions at which there exists a required temperature difference between minerals and coal particles by controlling the operating and system variables. Preliminary test results show that there is a potential for separating mineral matter from coal using the thermo-adhesive separation technique.

By M. Fafard, M. Dupuis, P. Goulet, J. Bédard

Start-up of a Hall-Heroult cell is a delicate task that can affect pot performance and pot life. Modem practices for high amperage cells involve preheating the lining before the molten electrolyte is poured in. Different preheating methods and heat-up schedules are used throughout the industry, and the optimum between a short start-up and damage minimization to the cell is elusive. Direct electrical coke-bed preheating is one of the most common techniques. This practice typically results in a non-uniform surface temperature distribution and can generate detrimental thermal gradients in the cathode blocks. Numerical modeling is an invaluable tool to study this complex problem and can help improve the preheating procedures. The modeling of the mechanical response of the lining is critical to detect risks of cathode block cracking or the development of gaps where liquids could leak into. Taking into account the baking of ramming paste, the quasi-brittle nature of carbon and the contact interfaces between different materials are examples of key elements to consider. A finite element slice model of a cell was built and simulations of different electrical preheating scenarios were performed using the inhouse code FESh++ to demonstrate what can be learned through thermo-chemomechanical modeling. The potential industrial application of the model is discussed.

Jan 1, 2006

By Tracy Brettmann, Melis Sutman, C. Guney Olgen

"The use of energy piles for geothermal heat exchange has been steadily increasing during the last decade, yet there are still pending questions on their behavior during temperature changes. This paper focuses on the thermo-mechanical response of three full-scale energy piles installed in Richmond, TX. The behavior of test piles subjected to thermo-mechanical loadings was studied in situ with the aim of quantifying the thermal influence on the performance and capacity of energy piles. An extensive field test program, including conventional pile loading tests and application of heating-cooling cycles was conducted on the test piles during a period of six weeks. For thermal load applications, the heat exchanger fluid with maximum temperature of 113°F (45°C) and minimum of 47°F (8°C) was circulated in the geothermal loops placed at the center of the test piles. Optical fiber sensors, vibrating wire strain gages, thermistors and thermal integrity profile wires were installed to monitor the strain and temperature variations along the energy piles throughout the field tests. The strain and temperature profiles during heating-cooling cycles on the test piles under static loads and without a maintained load were monitored to investigate the effect of thermo-mechanical and pure thermal loads on the energy piles, respectively. Conventional pile load tests were applied before and after the application of thermal cycles. The results of the pile load tests are compared to evaluate the effect of temperature cycles on pile capacity.IntroductionEnergy piles are deep foundation elements designed to access and exploit the relatively constant temperature of the ground and its heat storage capacity for efficient heating and cooling of buildings. The deep foundation elements that are already in place for structural support are integrated with adsorber pipes to perform as heat exchangers connected to ground source heat pump (GSHP) systems. With the use of energy piles, the heat energy is fed into and withdrawn from the ground for cooling in the summer and heating in the winter, respectively.Energy piles present an innovative way to harvest near-surface geothermal energy and to provide lower carbon emissions, however, there are still pending question on their performance. During heating-cooling cycles, energy piles experience temperature changes, which result in expansion or contraction of the piles."

Jan 1, 2017

By C. Y. Tang, Z. H. Chen, T. C. Lee

"In sheet metal forming process, the forming limit and strain distribution are governed by plastic instability and fracture following strain localization. It has been proved that the temperature gradient caused by plastic deformation as well as friction is one of the crucial factors to induce the strain localization in high-speed metal forming processes. In this paper, a numerical simulation of the sheet metal extrusion process has been conducted by using thermal-mechanical coupling finite element method. An improved mixed finite element method has been used to solve the large deformation elasto-plastic problem. In thermal phase, the transient heat transfer finite element method together with the Crank-Nicholson algorithm has been employed to determine the temperature field. Both the numerical results and the experimental observations reveal that the temperature gradient plays an important role in inducing the strain localization, which eventually leads to fracture failure in the sheet metal extrusion process.IntroductionSheet metal extrusion is such a process where the extrusion punch penetrates into one surface of the sheet metal material to let it extrude and flow towards the outlet of the die. This process can be used to produce protruding parts on a strip material. In engineering applications, the quality of the product is affected by many factors such as stress state, loading speed, material properties and lubrication condition. The research on failure mechanisms and improvement of formability in sheet metal forming processes by exploitation of differential thermal conditions has been of great interest recently [1-3]. It has been proved that the temperature gradient caused by plastic deformation, heat transfer, and friction between sheet and tools is one of crucial factors to affect 'the formability in high speed sheet metal forming processes [4]. In our previous study of sheet metal extrusion, it has been observed that plastic deformation is highly localized and some specimens are subjected to fracture failure in the form of crack propagation [5]. To understand this failure phenomenon, the effects of temperature gradients must not be ignored."

Jan 1, 2001

By Avijit Moitra

The behavior of the solidifying shell in the early stages of solidification has an important influence on the final quality of continuously-cast steel slabs. In order to understand the thermal and mechanical behavior of the shell, a two-dimensional transient piecewise-coupled finite-element model has been developed. The model simulates a transverse section of the slab as it moves down through the mold and incorporates the effects of heat conduction, solidification, shrinkage, turbulent fluid flow, thermal distortion of the mold and the visco-plastic behavior of the steel. Coupling between the thermal and the mechanical model is based on the mutual dependence of heat transfer across the interface between the shell and the mold and the size of the gap. The effects of mold distortion and taper on the gap size are also included. The effect of fluid flow has been incorporated via a heat flux imposed at the solid-liquid interface, which is obtained from a separate fluid flow model. The high temperature creep and plasticity of the steel is incorporated through a unified constitutive law defining the inelastic strain rates as a function of temperature, time and stress state. The model can be applied to various problems in continuous casting, such as the formation of surface defects and the design of mold taper.

Jan 1, 1992

By Thierno FALL

This paper describes the study of the work-roll during the hot rolling process thanks to a 3D model built with the Finite Element Method (FEM). In terms of computational cost, that method needs high resources compared to 1D model which are mostly used. However, the 3D model is built to have a better understanding of the work-roll thermal and mechanical behavior during the hot rolling process. The thermal model shows that the highest temperature reached during rolling are within the range of 500°C and 600°C. The thermal field input used to simulate the mechanical behavior of the work-roll shows a biaxial thermal stress state, in the circumferential and axial planes. However, a peak of radial stress is observed in the backup zone. It did not generate plastic strain but could influence the fatigue behavior of the work-roll.

Oct 1, 2019

By Samuel F. Rodrigues, Clodualdo Aranas Jr., Fulvio Siciliano

The application of thermo-mechanical control processing (TMCP) in hot rolling of steels has become a common routine since the last 60 years. The understanding of the physical metallurgy behind TMCP played a major role in the early developments. Physical and numerical simulation works are performed firstly to derive the fundamental metallurgical knowledge and secondly to conceive existing TMCP practices. In this paper, a summary TMCP techniques is presented. The occurrence of dynamic transformation of ferrite in the austenite region is shown by means of synchrotron light diffraction methods. This phase transformation mechanism is taken into consideration and its effects on TMCP are proposed in an exploratory way.

Oct 1, 2019

By Dengfu Chen, Yi Yang, Chunmei Chen, Mujun Long, Shikai Gong, Junhao Sheng, Tao Liu

The relationship between thermo-physical properties of petroleum coke and temperature is of importance for determining of the operating parameters during the calcining graphitization process. In this paper, the variations of thermo-physical properties of petroleum coke versus temperature were investigated, such as the DSC-Tg curve, the specific heat capacity, the thermal diffusion coefficient, the thermal conductivity, and so on. The thermal analysis curve of petroleum coke showed synchronous thermal hysteresis at higher heating rates, indicating that a larger heating rate will cause delay of thermal effects. The thermal diffusivity of petroleum coke decreased during the calcining process. With increasing temperature, coefficient of heat conductivity and specific volume heat of the petroleum coke increased with a decreasing variation rate. The research provides a database for the calcining graphitization process of petroleum coke.

Jan 1, 2015

By V. V. Getman, V. A. Chanturiya, T. N. Matveeva

Most of the Au and PGM ores in Russia are characterised by a thin mineral impregnation of noble metals in sulfide minerals, and a large variety of mineral forms that lead to high loss of precious metals with fine fractions during flotation. In modern flotation technology, the rational choice of reagents is one of the main trends for selective separation of minerals and effective metals recovery. New data on the selectivity of the thermo-sensitive polymer with specific functional groups (TMPPh) as a flocculant and collector of Au and Pt fine fractions are available. The selective modified collector (DEDTCm) for the recovery of Au and Pt from complex ores is discussed in this paper. Scanning electronic microscopy (SEAM), laser SIM and AFM microscopy, UV and IR spectroscopy were applied to study the adsorbed layer of new reagents on the mineral surface. Flotation tests of TMPPh on the gold-bearing ore of the Olimpiada deposit showed an increase in Au extraction and Au content in the concentrate of the rougher flotation. Using a combination of reagents TMPPh and ButX, the quality of the Au and Pt concentrates increased in 1.7 time with an increase in recovery up to 15 % compared with the traditional reagent mode. Testing of TMPPh polymers in flotation of Pt-Cu-Ni ore at Norilsk Nickel has shown the ability to obtain a concentrate with a higher Pt content. Recovery of platinum is 17% higher than recovery in an experiment without polymer. Application of DEDTCm helped to achieve higher technological parameters in flotation of lowgrade Rt-Cu-Ni ore. Compared to the basic mode Pt recovery was plus 13%, Pd recovery was plus 9% and the content of precious metals in the rougher flotation concentrate increased in 2,5 - 4 times. The studies have been supported by Grants of the President of RF “Scientific School of Academician V.A. Chanturiya” NSh-220.2012.5, NSh-748.2014.5. Keywords: Au and Pt complex ores, flotation, flocculation, thermo-sensitive polymer TMPPh, modified collector

Jan 1, 2020

By A. Kotze, D. Messina, E. Nagels, Y. Cryns, S. Arnout

The FlashPhos process aims to recover white phosphorus (P4) from sewage sludge by drying, flash combustion/gasification, and carbothermic refining steps. This study evaluates the material behaviour of sewage sludge ash melting and reduction in a refining furnace for the novel FlashPhos process. Thermodynamic modelling in FactSage 8.2 is combined with experiments from a tube furnace to determine the possible phosphorus recovery and minor element behaviour. For the two studied sludges, a yield of 40% and 75% white phosphorus is achieved after 1 hour at 1600°C, corresponding with a 60% and 25% loss to the metal phase. This is slightly above the calculated equilibrium yield of 28%–73%, which depends mainly on the Fe/P ratio of the sludge. Temperature is found to have a significant influence on the final phosphorus yield when leading to incomplete melting of the ash. A clean slag is produced in the process free of heavy metals making it suitable to be used as a cement-like binder material. The main heavy metals that co-evaporate with the phosphorus are Zn, Pb, As, Sb, and Sn. Additional processing steps will be required to remove these to produce a pure P4 product. The metal alloy consists of mostly Fe and P with smaller amounts of other components such as Mo, Cr, Cu, Mn, Sn, Sb, and V. The final slag consists of CaO, SiO2, MgO, and Al2O3 with virtually complete removal of P and heavy metals.

Oct 2, 2025

By E. V. Leont'eva, V. R. Vafin, A. G. Kladova, N. L. Medyanik, A. P. Ponomarev

"The thermochemical technology for recovery gold, silver from mature flotation tailings of pyrite ores by two-stage sintering with chlorine-ammonium reagents and leaching of bakes with water is developed. The economic effect of the technology implementation is calculated. KEYWORDS Gold and silver recovery, mature flotation tailings, pyrite ores, chlorine-ammonium reagents, leaching INTRODUCTION The relevance of processing the technogenic reserves of ore mining and concentration wastes accumulated over the long operation periods of mineral deposits is beyond doubt. Hundreds of tons of precious and non-ferrous metals that were not recovered during the primary processing are concentrated in the accumulated wastes. For example, tailing storage facilities (TSF) at the mineral processing plants in the Southern Urals region of Russia hold more than one hundred tons of gold and thousands of tons of silver in the mature flotation tailings (MFT) of copper pyrite ores. Secondary processing of technogenic materials is facilitated by the fact that they are preprocessed — ground and compactly deposited on the surface, but complicated by the low (compared to ores) grade, uneven distribution of the valuable minerals, altered and unstable material composition of the mineral feed. This leads to low recovery rates of valuable metals by conventional physicochemical processing methods. It is necessary to develop innovative methods of deep integrated processing of industrial wastes, based on the study of the material composition of specific technogenic mineral resources and based on ensuring the environmental safety of the resulting secondary waste. MATERIALS AND METHODS The object of this study are the MFT of Uchaly Concentrator in the Republic of Bashkortostan, Russia, which processes copper pyrite and copper-zinc ores. According to the data of particle size, chemical, X-ray phase, and optical microscopic analyzes, samples of the MFT are characterized by considerable particle fineness (the fraction of the size class -41 µm is 89-90%), low grade of gold (1.7-2.0 g/t) and silver (18.0-19.5 g/t), comparable grades of iron (23.0-26.8%) and sulfur (28.1-28.7), but different grades of copper (0.12 - 0.73%) and zinc (0.34-1.26%). The most common mineral in the samples is pyrite (50 - 56%), found in intergrowth with grains of other sulfides (0.1-4%) - sphalerite, tennantite, chalcopyrite, covellite. Quartz and aluminosilicates are the dominant rock minerals (21-36%). Based on the results of the phase analysis, it was established that approximately 70% of the gold in the samples is found in a form that is resistant to cyanidation — it is locked in sulfides (52-56%) and quartz and coated by films. Along with sulfides and rock minerals, common gold and silver minerals (chalcogenides, intermetallides, native gold) in the form of submicro- and nano-sized precipitates are also associated with intergrowth of a complex structure. These features of the material composition allow classifying the MFT of the pyrite ores as a mature feed material and emphasize the need for chemical non-cyanide methods to recover gold and silver from the mature minerals and associations they are found in."

Jan 1, 2018

By E. Asselin

Passivation of Fe-Ni-Co alloys during the Caron leach process is thought to result in low cobalt recoveries in ammoniacal ammonium carbonate solutions. A brief review of the available thermochemical data for the (Fe, Ni, Co)-NH3-H2O systems has been undertaken. The stability of the Co(II) and Co(III), Ni(II) and Fe(II) am-mines was examined through the use of speciation and Pourbaix diagrams at 298 and 333 K and at 6 M total ammonia. Increasing the temperature reduces the stability fields of the ammines and generally constrains the thermodynamic window for the leach. The Fe(II) ammines are only thermodynamically stable under reducing conditions. Polarization experiments show that these ammines are unlikely to form if oxygen is present. Fe-Ni-Co alloy passivation may be alleviated by careful management of potential.

Jan 1, 2011

By E. Asselin

Passivation of Fe-Ni-Co alloys during the Caron leach process is thought to result in low cobalt recoveries in ammoniacal ammonium carbonate solutions. A brief review of the available thermochemical data for the (Fe, Ni, Co)-NH3-H2O systems has been undertaken. The stability of the Co(II) and Co(III), Ni(II) and Fe(II) ammines was examined through the use of speciation and Pourbaix diagrams at 298 and 333 K and at 6 M total ammonia. Increasing the temperature reduces the stability fields of the ammines and generally constrains the thermodynamic window for the leach. The Fe(II) ammines are only thermodynamically stable under reducing conditions. Polarization experiments show that these ammines are unlikely to form if oxygen is present. Fe-Ni-Co alloy passivation may be alleviated by careful management of potential.

Nov 1, 2011

By O. Barbosa F.

The thermochemistry of the systems SCN-H2O, Au-SCN-H2O and Ag-SCN-H2O is discussed. Potential-pH diagrams at 25°C are drawn for each system considering several sets of concentrations of the species involved. The information provided by the potential-pH diagrams is.complemented by distribution curves for each series of gold and silver complexes with thiocyanate. The analysis includes comparisons between the thiocyanate systems and the analogous cyanide systems, pointing out analogies and differences between the leaching of gold and silver with thiocyanate and with cyanide. The possibility of using soluble oxidizing agents such as ferric ions, hydrogen peroxide and Caro's acid is evaluated. The thermodynamic data used in the calculations and the chemical reactions represented in the Pourbaix diagrams are all reported in three Appendices. The overall results indicate the thermodynamic conditions for gold and silver leaching by thiocyanate.

Jan 1, 1989

By C. Ernest Birchenall, Robert F. Mehl

APPLICATION of diffusion laws in the customary form to experimental studies in binary metallic solid solutions has shown the diffusion coefficient to vary with concentration for all systems investigated. The factors determining this variation have not been ascertained. However, the question of whether the diffusion coefficient would become a constant, independent of concentration throughout a single phase if the concentration gradient in the diffusion equation were replaced by an activity gradient has been an attractive subject for speculation. Wagner1 derived an expression for the force acting on a diffusing particle in terms of the chemical potential. This was also the approach chosen by Jost2 in his monograph. From a somewhat different point of view, Eyring3 and his co-workers have used activity gradients when dealing with diffusion in concentrated nonideal solutions. The only actual test with experimental data is that given by Darken,4 though this is more qualitative than quantitative. Many others opposed the application in any way of thermodynamic concepts to kinetic phenomena, including diffusion processes. A rigorous examination of this principle requires good data expressing the relationship between activity and concentration for solid solutions for which reliable diffusion work has been done. The literature provides such information only for the interstitial solution of carbon in gamma iron (austenite) and for the substitutional copper-zinc solutions (alpha brass). Activity data for carbon in austenite at 800°C and 1000°C are available from the recent work of Smiths on the equilibrium of hydrogen-methane and carbon monoxide-carbon dioxide mixtures with gamma iron. Combining these with the diffusion studies of Wells and Mehl6 makes possible a quantitative test for this interstitial solid solution. The vapor-pressure determinations for zinc over brass by Hargreaves7 allowed the calculation of activities in this system over a wide range of temperatures and concentrations. Extensive investigation of diffusion in this substitutional solid solution has been carried out by Rhines and Mehl.8 ACTIVITIES IN BRASS9 If the vapor phase of zinc is assumed to behave as an ideal gas, any solid or liquid solutions that are in equilibrium with the same partial pressure of zinc at the same temperature have the same thermodynamic activity of zinc. In order to assign a numerical value to the activity azn, it is necessary to choose some standard reference state to which an activity value of unity is arbitrarily assigned. It is customary to choose the liquid or solid state of the pure material. Then azn is defined numerically by azn = Pza/Pzn° [I]

Jan 1, 1947

In this study, the effects of slag compositions, slag amount, temperature, and carbon content of steel on the manganese and phosphorus distribution ratios during converter steelmaking were analysed using the classical regular solution theory, and industrial tests were performed using two 80 t top-and-bottom combined blown converters (duplex melting process). The results indicate that the slag amount, temperature, and carbon content in steel are the main factors affecting the manganese yield when converter slag compositions remain constant. The FeO content of the slag has a strong impact on the manganese distribution ratio, while the slag basicity and MgO content have no obvious effect. The calculations and experimental results show that the phosphorus distribution ratio increases sharply with increasing slag basicity R, but then decreases with the increase of MgO and MnO contents in the slag. The final slag in converter steelmaking should have the following characteristics: 3.5 < R < 4.5, 15% < (FeO) < 20%, and 6% < (MgO) < 8%. The slag amount should be controlled appropriately at the same time. The results of this investigation would be useful in deciding on the application of manganese ore in alloying and identifying the slagging regime in converter steelmaking.

Jan 1, 2014

By Anxiang Wang, Kunhua Wu, Yifu Li, Junjie Xu, Yongnian Dai, Bin Yang, Lingxin Kong

In this study, the saturated vapor pressures of tin (Sn) and antimony (Sb), the separation coefficient and the vapor-liquid phase equilibrium of Sn-Sb alloy were theoretically analyzed, which demonstrate that it is possible to separate Sn and Sb by vacuum distillation. The process parameters of vacuum distillation, including the distillation temperature, distillation time and alloy mass (thickness of raw materials) on the direct yield of Sn and the content of Sn in liquid phase were investigated by using single factor experiments. The preliminary results show that the direct yield and the content of Sn are 98.77 wt.% and 96.01% with the optimized distillation conditions of a distillation temperature of 1473 K, a distillation t ime for 45 min and a Sn-Sb alloy mass of 125 g ( thickness o f 8 mm). The distillation parameters in the study provide effective and convenient conditions on separation of Sn-Sb alloy.

Jan 1, 2016

By Xue Ping

Sm2Fe17 alloy is an important precursor for the preparation of Sm2Fe17Nx magnet, which possesses a higher Curie temperature, larger anisotropy field, better resistance to oxidation and thermal stability. In this paper, the wet chemical co-precipitation was developed for synthesis of the Sm-Fe alloy oxide precursor. Based on the principles of simultaneous equilibrium and mass balance, a series of thermodynamic equilibrium equations of Sm(III)-Fe(II)-NH3-C2O4 2--H2O system at ambient temperature were deduced theoretically and the thermodynamic diagrams of lg[M2+]T (M=Sm, Fe) versus pH at different solution compositions were drawn. Then, the experiments were done to address the various effects on the wet chemical process, including solution pH value, reactant concentration, reaction temperature and aging time, etc. It is found that by precise control of the process, the Sm-Fe alloy oxide precursor was synthesized with fine crystallization and special size &size distribution.

Jan 1, 2008