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By Ulrich E. Klotz, Gemot Pottlacher, Shahid Mehmood

"Platinum alloys are frequently used in technical applications and in jewellery. Their thermophysical properties such as density, heat capacity, thermal conductivity and surface tension play an important role in casting processes and are required as input data for casting simulation. Scope of this work was to investigate these properties by different methods. Platinum and four alloys namely, Pt96Cu4, Pt68Cu32, Pt50Cu50 and Pt25Cu75 were investigated. Melting range and thermal expansion was measured at fem by DSC and dilatometry, respectively.At TU Graz wire shaped samples were investigated by an ohmic pulse heating technique. This technique allows the calculation of specific heat capacity and the temperature dependencies of electrical resistivity, enthalpy, and density of these alloys in the solid and liquid phase. Experimental results were compared with available literature and data from thermodynamic calculation using the SNOBl database and ThermoCalc.IntroductionPlatinum is a precious element and its alloys are commonly used in jewellery. But Platinum is much more difficult to cast then other jewellery elements like silver or gold, because of its high melting temperature, large shrinkage during freezing, low thermal conductivity, high surface tension, and high viscosity. As a result there arise problems during casting. Hence to resolve these difficulties a detailed study of thermophysical properties of solid and liquid platinum and its alloys is necessary for simulation and casting. The Platinum alloy samples were prepared by vacuum induction melting and casting into copper molds. Rods of 3 mm in diameter and a length of 80 mm were prepared and drawn to wires of 0.5 mm in diameter."

Jan 1, 2011

By D R. L Vedoy, L Botha, S P. Gumfekar, J B. P Soares

Most of the known in-place reserves of oil sands are found in Canada. These oil sands ores are mined using various processes to extract bitumen. The by-product slurry resulting from the extraction process, known as tailings, is discharged into tailings ponds. Fine kaolin clays are an important ingredient of the tailings because they remain suspended in water for many years. Current polymeric flocculation/dewatering technologies use acrylamide-based polymers such as polyacrylamide (PAM), but sediments produced using PAM-based flocculants hold considerable amounts of water due to the formation of loosely-packed flocs. Anionic polymers are better flocculants due to bridging and the charge-neutralisation mechanism. In this paper, we will compare the synthesis of two flocculants: thermosensitive, anionic flocculants and thermosensitive, hydrophobically modified anionic flocculants. The first flocculant is a copolymer of acrylic acid (AA) and N-isopropyl acrylamide (NIPAM), in which AA is the anionic monomer. The second flocculant is a copolymer of NIPAM, AA and the hydrophobic monomer N-tert-butyl acrylamide. We evaluated the dewatering efficiency of 2 wt per cent kaolin using both flocculants by comparing settling rates at different flocculant dosages, charge neutralisation ability and supernatant clarity. To better understand floc formation, we measured the floc size formed by both flocculants at different flocculant dosages. We propose that the hydrophobic monomer in the terpolymer flocculant helps expel water out of flocs, ultimately decreasing the water content in the sediments.CITATION:Gumfekar, S P, Vedoy, D R L, Botha, L and Soares, J B P, 2015. Thermosensitive, hydrophobically modified anionic flocculants for dewatering kaolin clays, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 45–50 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By D. P. Patil, B. K. Parekh

Water is the mainstay for beneficiation of fine size coal and minerals; however, it is also the least desirable constituent in the final product. The basic concept of the novel process described in this paper is based on the differential surface heat conduction/ absorption capacity of individual particles, which differs for different species of minerals. When a mixture of fine material is exposed to a radiant energy source, the various solids present in the mixture will absorb heat energy depending on their heat-conducting properties and there will be a difference in the surface temperature of the particles. When this differentially heated solid mixture is placed on a moving belt, which is coated with a low temperature melting resin, the hotter component of the mixture will stick to the belt and relatively cooler particles will stay free on the belt and fall off at the end of the belt run. Experiments were conducted with pyrite, coal, and quartz of 6 × 18 mesh particle size. The goal of the test program was to find the optimum conditions at which there exists a required temperature difference between minerals and coal particles by controlling the operating system variables. Preliminary tests results showed that there is a potential for separating mineral matter from coal using the thermo-adhesive separation technique.

Jan 6, 2022

ABSTRACTFor the binary system copper-lead two relationsEquation 1andEquation 2have been derived for the activities of copper and lead at compositions and absolute temperatures within the liquid region of the phase diagram.These relations give, with greater accuracy than is given by previously published relations, the activity-composition temperature variations for all regions of the phase diagram of interest to metallurgists.These relations are essentially simple forms of the Margules equations but with linear temperature dependence applied to their coefficients. This has been done in such a manner that a phase diagram obtained from these relations agrees well with the data available for this system. The methods of obtaining the relations and constructing a phase diagram from them are both given in detail. The enthalpies and entropies of mixing are compared with those derived by other methods.

Jan 1, 1971

By J. D. Austin, D. G. Kringe

Rates of return realized on investments in the gold mines of the newer goldfields outside the Witwatersrand were calculated and analysed over various time intervals and on various bases. It is shown that these rates of return are strongly correlated with changes in the gold price and cannot be equated with the returns that are expected when investments are made, and that the changes in gold price also affect the rates of return on the Johannesburg Stock Exchange as a whole. These correlations are used, together with a limited application of the Capital Asset Pricing Model, to suggest the expected levels of threshold returns in real terms for new mining projects, for projects on existing mines, and for share valuations.

Jan 1, 1980

By J. B. Gwiazda

Introduction Thick seams constitute a considerable portion of Polish coal reserves. In producing mines and those under construction, the reserves where the height is more than 4.5 m (15 ft) total about 24v0 of all the hard coal reserves. The reserves that are under urban and industrial areas can be extracted using stowing methods for surface protection. About 50v0 of thick seam reserves can be extracted by caving methods. Thick seam mining methods Thick seams are usually extracted by multilift methods. There are some methods of thick seam mining that generally can be divided into caving and stowing methods. The stowing method is more expensive, but must be used when mining to protect surface features. The more known methods of thick seam mining include: • extraction of thick seam in ascending order with stowing; • thick seam mining in descending order with consolidated stowing; • thick seam mining with gob consolidation; • thick seam mining in descending order with roof caving; • sublevel caving thick seam mining system; and • thick seam mining system using an artificial roof. • Thick seam mining with introduction of an artificial roof The most advantageous method of thick seam mining is the method using an artificial roof. The artificial roof usually consists of wire mesh. Such wire mesh must be durable and must prevent small rock fragments from passing through. The mesh is usually made of steel properly protected against corrosion. The artificial roof is placed on the coal floor of the top slice (Fig. 1). Caving rock falls on the artificial roof and is thus separated from the coal. The next slice is extracted under the artificial roof. The producing face of the next slice must progress within 10 m (33 ft) behind the front of the first slice. As the second producing face progresses, the wire mesh moves down on the coal floor and may be used as an artificial roof for the next slice. Thus, one artificial roof allows the extraction of several consecutive slices. Application of the artificial roof allows for clean extraction and reduces coal losses. It also eliminates the hazard of spontaneous combustion. Introduction of the artificial roof has been limited due to a lack of artificial roof laying equipment. Manual laying of wire mesh is a labor-intensive operation, and it delays face progress, resulting in poor productivity. To eliminate these problems, artificial roof laying equipment was designed at the Polish Central Mining Institute. The support and the method of laying operation is covered by a patent. Artificial roof laying powered support To extract thick seams using an artificial roof; four-leg shield supports with lemniscate linkage were developed (Fig. 2). This shield is used in the first top

Jan 1, 1988

By Sebastien Maillard, Stephane Georges, Thomas Vallee, Stanislas Mauuary

Steel strip manufacturing ever reinvents proposing new grades, requiring to tackle technical limitations of production systems. Primetals Technologies breaks through strip welding by expanding the welder LW21L “Asolid” technology used on low gauges for high-end market such as automotive CAL/CGL. Addressing the usual drawbacks in maintenance, operation and safety of current welding system based on mechanical cutting and CO2 laser welding, the newly developped LW21H “Asolid” technology processes thicker strips up to 7 mm with solid-state laser cutting and welding. This new welder is brought to reality through a scale 1:1 pilot developed, manufactured and tested in Primetals Technologies workshop.

Oct 1, 2019

By Yan Beygelzimer, Alexander Spuskanyuk, Victor Varyukhin

"The main idea of the report is that the yield surface can be presented as thick, ""foamed surface"" with dimensionality exceeding two. By other words, perhaps, the yield surface is fractal, i.e. it belongs to the class of geometric objects with fractional dimensionality. Apparently, fractal structure of the yield surface is determined by the fractal structure of natural materials. ""Cloud of internal stresses"" term is introduced to describe the stress distribution in representative volume element. Its plastic flow is determined by the interaction of this cloud with the thick yield surface. Thick yield surface and internal stress cloud concepts allow to determine an additional correlation between micro mechanical models of polycrystals and phenomenological theory of plasticity.1. IntroductionClassical plastic flow models are not satisfying the modem requirements. There are two main directions in their development. The first, mathematical, is connected with the development of the general theory of rheological relationships; the second, physical, is connected with the development of the representative volume element (RVE) models which are based on specific ideas about deformation mechanisms. Within the framework of the first direction, the macroscopic experimental data is formalized; the second approach deals with the generalization of physical research results for the different scale levels that are involved in plastic deformation.These approaches have advantages and disadvantages. In phenomenological theories, the advantages are the mathematical simplicity and laconic formulation of constitutive relations, which allows using them in practical calculations. However, the mathematical models of this class can not be considered as general, they are useful only for the description of limited range of deforming processes. On the other hand, physical theories that are based on the description of real plastic deformation mechanisms are very explanatory and predictive, but they lack mathematical simplicity. The above circumstances lead us to the necessity of compromise that can be found in determining the constitutive relations for RVE, which structure and parameters would bear the information about rnicrolevel and mesolevel phenomena. In this synthesis direction, the fundamental role belongs to [1,2], etc."

Jan 1, 2001

By V. L. Mitsopoulos

This paper provides a summary of tailings disposal techniques and the improvements that have been made through the introduction of thickened tailings disposal. The general properties and characteristics of thickened tailings are described, as is a design process for selecting appropriate technologies for thickening, pumping, transporting and storing tailings. The factors affecting the selection of an appropriate disposal site and operational considerations for the effective utilisation of tailings storage areas are also documented.

Jan 1, 2006

By Jonathan Matthews

Efficient and effective management of mine tailings is essential for continued successful development of Alberta?s vast oil sands resources. Syncrude Canada Ltd. continues to research novel tailings management techniques in an effort to improve production efficiency and environmental sustainability. During the summer months of 2001, Syncrude Canada Ltd., in collaboration with members of the Canadian Oil Sands Network for Research and Development (CONRAD), conducted field-scale trials of thickened tailings technology at Syncrude?s Aurora mine, north of Fort McMurray, Alberta. This paper provides an overview of the test program including discussion of objectives, test configuration, and program observations. 0Data collected during the field trial indicate that substantial swings in feed slurry composition challenge effective thickener operation. When coarse mineral solids dominated slurry composition, thickener rake torque rose to unmanageable levels. It was determined that the end-of-pipe depositional characteristics of thickened oil sands slurry were generally consistent with present understanding of oil sands tailings slurries. After shear, thickener underflow product exhibited very shallow beach angles and a limited capacity to keep coarser particles in suspension indicating that stacking of ?paste-like? thickener underflow product from a conventional thickener is not practical in an oil sands setting unless process adjustments can be made to increase the underflow density and/or preserve the initial high yield stress of the underflow during transport and deposition. These technical challenges notwithstanding, Thickened Tailings technology offers considerable promise for recovery of warm water from oil sands process tailings.

May 1, 2003

By T. Wisdom, D. Romo, G. Seale, R. Jansen

Thickening remains relatively misunderstood since it is typically near the end of the process and not directly involved in metal recovery. When operating well, thickeners are ignored and left to run independently, the ‘out of sight, out of mind’ phenomena. However, when operating poorly, there is a lack of basic understanding and remedial actions to solve issues are reactionary rather than proactively addressing shortcomings. This series of papers breaks down in sequential order the stepped phases required to gain an appreciation and thorough understanding of the science behind thickeners, and key thickener components, and basic troubleshooting skills. This second paper starts with identifying the different approaches to thickener test work including static and dynamic settling tests followed by high-rate versus paste thickening. Complimentary to test work, the mechanisms surrounding coagulation and flocculation are presented and explained. The basic mechanisms for coagulation and flocculation are discussed to support the different test work approaches and provide the reader with the basic background.

Mar 2, 2022

By R. J. Smith

Hornestake's Mclaughlin Mine is the first commercial application of pressure oxidation pretreatment of gold prior to cyanidation. Inherent to the autoclave process are several liquid/solid separations. Flocculant consumption represents a significant portion of the consumable reagent costs at McLaughlan. This paper focuses on the efforts of the Operating, Metallurgy and Engineering groups to improve thickener operation and minimize flocculant consumption. An operating philosophy incorporating feed solids control, increasing flocculant dilution water and minimizing flocculant solution shear has resulted in a reduction in 1986 flocculant costs of $0.054/t ($0.06 st) versus 1985 costs. Additional changes are projected to result in a further cost reduction of $0.20/t ($0.22/.st) in 1987.

Jan 1, 1988

By E. J. Roberts

Prior to 1916, thickening was an art, and any accurate decision as to what size of machine to install to handle a given tonnage of a specific ore must have been one of those intuitive conclusions, based on both intimate and extensive acquaintance with thickners and ore pulps. Then in 1916 "knowledge of acquaintance," became "knowledge about" with the publication of the Coe and Clevenger paper.' The unit operation of thickening had graduated to the status of an engineering science. The fundamental similitude relationships for the two major phases of the operation were defined so clearly that batch tests on models as small as liter cylinders could serve to specify protypes as large as 325 ft in diameter.

Jan 1, 1949

By F. Bello, J. Engels

"During 2012 and 2013, Minera Esperanza conducted a series of thickening and deposition trials to identify design and operational parameters associated with increased thickening of its tailings. These trials focused on benchmarking the current solids concentration of tailings (62 - 64%) in anticipation of an increase to 67% solids once two new 45 m diameter deep-cone paste thickeners are commissioned in 2014. These trials studied the sedimentation and rheological characteristics of the existing tailings and performed deposition modelling to assist with developing short- and long-term designs for the tailings storage facility. To verify and optimise these models, Minera Esperanza considered a series of laboratory, pilot, and industrial-scale deposition trials. This paper provides a review of the trials conducted in the laboratory and at industrial-scale and considers the results and optimisations for the short- and long-term design of Minera Esperanza’s tailings storage facility."

Jan 1, 2014

By W. Julian Patron

TREATMENT of the breaker wash-water discharges to remove the suspended particles of finely divided material is usually most efficiently and economically accomplished in settling or thickening tanks. The purpose of these tanks is to separate the excess water from the solids by sedimentation whereby the solid particles suspended in the water are thickened by the force of gravity. The water overflowing these tanks is either reused for coal cleaning or discharged directly to the streams. The settled solids, which are in a relatively concentrated condition, forming a sludge or thick pulp, can be disposed of by pumping to a storage dam, by slushing into mine workings, by processing for recovery of coal, or filtering by vacuum or centrifugal means and discharging with the breaker refuse. The scope of this paper will be limited to the discussion of settling and thickening equipment, the factors that influence the settlement of solids, and a brief description of tests that can be made to determine the size of settling facilities required for any particular condition. The practical application of sedimentation to the treatment of coal falls into two groups, one of classification or hydro- separation, and the other of clarification and thickening. Classification may be employed to prepare a relatively low- grade fuel, which can be used as is or can be further processed separately. Clarification and thickening is employed where the primary objective is to recover a relatively dewatered solid and return a satisfactorily clear water to breaker or streams. When a stream of water flows across a tank, the time required for a particle to travel from the feed inlet to the overflow must be a little greater than that required for the finest particles or flocs in the feed to settle out of the stream. OPERATION AND TYPES OF SETTLING EQUIPMENT Theoretically, the liquid in a settling tank should rise at a more or less constant rate throughout the area of the tank Under these conditions the rising velocity of the water must be less than the settling rate of the finest particles if clarification is to be obtained. When classification of particles is to be made in the tank, the overflow velocity must be greater than the settling velocity of the particles that are to be removed with the tank overflow. The performance of a settling tank, then, depends on the settling rate of the solids and the current velocities in the tank. The oldest types of sedimentation employ intermittent types of settling tanks of any convenient shape. Means are provided for filling the tank with pulp and allowing it to settle until quiet, for moving the clean liquor and for removing the thickened sludge. The operation is necessarily intermittent but a sufficient number of tanks is employed so that a continuous flow of clear water is maintained. Continuous methods for the sedimentation of slurries were developed in the metallurgical industry. Cones from which settled solids were discharged by gravity

Jan 1, 1946

By G Hart

As the iron ore/magnetite boom gains momentum, it is particularly important to question established past trends and explore the potential of alternative design options. Traditionally, ‘rule of thumb’ methods have been used to size dewatering equipment. Greater consideration needs to be given to technological advancements and specific throughput testing of each ore body type based on innovative developments.This paper will describe how an innovative approach resulted not only in significant savings in capital cost and site work hours but also delivered a truly optimised design for the thickener duty at Karara. Test work also played a crucial role and a comprehensive test work program on the ore samples showed the scale-up benefi ts of new technology in thickener designs. Working closely with the Karara team during the laboratory testing proved the old sizing theories for iron ore/magnetite processing have been superseded with the knowledge and results of the industry’s newest feedwell technology. Increased solids flux and rise rates in the testing process proved very successful, resulting in signifi cantly reduced thickener sizes and lower capital expense.Mechanical design considerations such as removal of underflow and pump access led to a preference for an above-ground thickener confi guration, and the economics of a completefabrication and installation package favoured steel construction for the thickener units.The ultimate choice of the bolted/fl anged tank methodology provides both economic and timely solutions for the site installation including reduced man power and quick and safe site-work. A benefits comparison between this design and other fabrication and installation procedures will also be analysed in the paper.

Jul 11, 2011

By S. C. Lindsay, D. J. I. Evans

With each year that passes hydrometallurgical processes are being more widely used to recover base metals from ores and concentrates. Generally these processes involve liquid-solid separation of metal-bearing liquors from barren residues. This may be done by countercurrent decantation, thickening and filtration, or filtration or centrifuging only. Choice of method is governed by chemical and physical characteristics of the pulps; cost of labor, power, materials, and waste disposal; and even by the amount of capital available when building plans are under way. Since all these controlling factors change with time and location and with technological advances, the separation method must be re-evaluated when new plants or expansion programs are contemplated. At the Sherritt Gordon refinery in Fort Saskatchewan, Alberta, an ammonia pressure leaching process recovers nickel, copper, and cobalt from the nickel concentrate produced at Lynn Lake, Manitoba.' Pregnant liquors are separated from the barren leach residues in a thickener-filter liquid-solids circuit. The decision to use this type of separation was based on a summation of economic factors during the pilot plant and design stages. Although countercurrent decantation was not incorporated in the refinery flowsheet, the problems solved in thickening the leach residues and the experience gained in operating the commercial plant are pertinent to countercurrent decantation, particularly where it is applied to slow-settling leach slurries or slurries having a relatively high vapor pressure of a valuable, obnoxious, or poisonous vapor.

Jan 1, 1960

By Rick J. Chalaturnyk

In Alberta, oil sands bitumen is utilized for synthetic crude oil production by surface mining, bitumen extraction followed by primary (coking) and secondary (catalytic hydrotreating) upgrading processes, or by catalytic hydrocracking and hydrotreating replacing the primary and secondary upgrading processes. Oil sands tailings, composed of water, sands, silt, clay and residual bitumen, is produced as a byproduct of the bitumen extraction process. Several processes have been proposed for the treatment of oil sands tailings, resulting in different recovered water characteristics, consolidation rates and consolidated solid characteristics, which may have effects on the performance of the overall plant operations. A process for the same purpose has been developed by treating the oil sands tailings with CaO lime and CO2 and thickening it using a suitable thickener. In this process a release water of acceptable properties is recovered in a short retention time, which makes it possible to recycle the recovered water, probably after a reconditioning treatment, as warm as possible to improve the thermal efficiency of the extraction process. The paper presents the theory and laboratory results for the CaO and CO2 thickening of low temperature flotation tailings. The water release rates, segregation potential of the thickened underflow and chemistry of the release water are shown and discussed. It is suggested that in using the proposed process, the thickened tailings underflow can be disposed for further consolidation, or combined with the coarse tailings to produce Blended Composite Tailings, corresponding to the Composite Tailings process in the existing hot water extraction plants.

May 1, 2002

By Jonisha P. Pollard

In restricted vertical working heights such as low-seam coal mines, workers are forced to assume kneeling or squatting postures to perform work. These postures are associated with increased risks for the development of significant knee pathologies such as meniscal tears and osteoarthritis [1,2]. Previous research has shown an increased applied knee flexion moment when kneeling in high flexion [3]. However, these models have been applied to flexion up to 140° which neglects contact between the thigh and calf which occurs beyond 140°. In addition to thigh-calf contact, when kneeling near full flexion there may be additional contact between the heel and gluteal muscles. To the author?s knowledge, heel-gluteus contact has not been previously investigated, but thigh-calf contact has received some attention. Zelle (2007) reported thigh-calf contact forces up to 30% bodyweight (BW) [4]. Zelle (2009) reported decreased knee forces when accounting for thigh-calf contact [5]. Caruntu (2003) reported erroneous force and moment estimations when thigh-calf contact was neglected from models to determine muscle and ligament forces [6]. In this study thigh-calf and heel-gluteus contact forces were quantified to determine their effect on the externally applied flexion moment in high flexion.

Jan 1, 2009

By Ljudmil S. Grigorov, Eric Forssberg, Hanumantha Rao Kota, Robert J. Pugh, Lidia B. Alexandrova

"We have used the microscopic thin balance developed by Scheludko at al. (1970) technique to study the stability and interactions within the thin film between the silica surface and air bubble with (i) a long chain C10 amine and (ii) a cationic/anionic surfactant systems consisting of mixtures of a long straight C10 chain amine with long straight chain C8, C10 and C12 sulfonates. It was found that the mixed surfactants caused lower contact angles, lower rates of the thin aqueous film rupture and longer film lifetime, compared to the pure amine system.This behavior was explained by the initial strong adsorption of positively charged interfacial complexes from the mixed surfactant system at the air/solution interface followed by adsorption at the silica interface. It was also shown that the chain length compatibility between the anionic and cationic surfactants controls the strength of the interfacial complex, determining an inhibition in the thin film rupture and dewetting of the film. The rupture mechanism was explained by an earlier established heterocoagulation mechanism between the positively charged air/solution interface and the solution/silica interface which remained negatively charged. The formation of the interfacial complex at the air/solution interface was confirmed by using surface tension data."

Jan 1, 2003