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Goethite ore are the third most abundant source of iron. The overwhelming part of these ore is represented by low-grade varieties which cannot be used in iron and steel industry without preliminary beneficiation. Biomass is a renewable solid fuel, which is feasible for the substitution of coke and coal in the manufacturing due to its lower contents of harmful elements and abundant raw material sources. Utilization of biomass in iron ore sintering process as heating agent and reducing agent contributes to energy conservation and emission reduction. The biomass was mixed together with goethite ore for roasting process to investigate the effects of reduction roasting. The results show that the goethite ore is dramatically reduced and magnetized into maghemite by biomass with the biomass dosage less than 20% and the roasting temperature below 650 oC. When the goethite ore roasted with biomass, the magnetization values could be enhanced more than two orders of magnitude, meets the standard of magnetic separation, which could significantly reduce the iron beneficiation cost. Keywords: biomass, goethite, reduction, magnetization, roasting

Sep 1, 2012

By Sean Gallagher, Christopher A. Hamrick, Arnold C. Love

Twelve subjects participated in an investigation of the biomechanical stresses of asymmetric lifting in stooped and kneeling postures. Three factors were manipulated in this study: Posture (stooped or kneeling), height of lift (35 or 70 cm), and weight of lift (15, 20, or 25 kg). Subjects were required to lift or lower a box every 10 seconds for a period of 2 minutes. Electromyography (PIG) of eight trunk muscles was collected during a lift in this period. The PIG data, normalized to maximum extension and flexion exertions in each posture, were input to a biomechanical model and used to predict compression and shear forces at the L, level of the lumbar spine. Results from the EMG-driven biomechanical model indicated that compression was greater when lifting to a higher shelf (p < 0.001), and indicated a significant interaction between posture and the weight of the lifting box (p < 0.01). Peak lateral shear was not significantly affected by any main effects or interactions (p < 0.05). Anterior shear was increased with increasing height of lift (p < 0.001), and also by the posture x weight interaction (p c 0.01). A multivariate analysis of variance (MANOVA) indicated a complex relationship for recruitment of the eight trunk muscles, with the triple interaction being significant (p < 0.001). The results of this investigation will be used to evaluate safe loads for lifting in these restricted postures.

By Paponetti B. . A.

Gold is usually recovered by cyanidation, thiourea leaching and amalgamation, however the efficiency of these technologies, in the case of refractory ores, is low ever when fuie grinding is practised. For example, .if the gold particles are included in sulphide minerals, the leachant cannot reach them, so they are often lost in the tailings. Hence .it is first necessary to break the sulphide crystals by preliminary treatment such as roasting, nitric .acid oxidation, pressure leaching and bacterial oxidation and then apply a conventional extractive technique for satisfactory gold recovery. This paper describes the effect of biological pre-treatment with Thiobacillus ferrooxidans) on the? extraction ? and? recovery of gold by conventional cyanidate. leaching from; a refractory arsenopyrite ore from Golcuck (Turkey).

Jan 1, 1991

By M. Okido, O. Takai, Z. Zhao, M. Ishikawa, R. Ichino, K. Kuroda

"Electrolytic method was applied to calcium phosphate coating on titanium plates as an excellent technique for high density and intensive contact of coated films on biomaterials. The effect of H2O 2 as oxidation reagent on coating characteristics was examined to obtain biomineral films. Solution was containing 7.0 X 10·3 mol/dm3 ofCaC12 and 3.0 X 10·2 of Ca(H2PO4)z, kept at 55 ""C. All deposits were hydroxyapatite (HAp) in this study, independent of H2O 2 concentration, applied cathodic potential and solution pH. In the case of H2O 2 addition, an increase in cathode current started at the low potential, namely, ca. -0.2 V (vs. SCE). In contrast, the current increased at more than ca. -1.4 V in the solution without H2O 2 addition. H2O 2 appeared to be an effective reagent for increasing nucleation density and improving adhesion of deposits on titanium plates.IntroductionIn recent years, many researches have been undertaken to develop the techniques of calcium phosphate coating on titanium or bioglass for medical implantation. High density and intensive adhesion of coating are necessary for adding bioaffinity to these materials and for inducing bone morphogenesis on them when implanted in human body.1) Electrolytic deposition has been a newly developed method as high-speed deposition process. By this method, the supersaturation of calcium phosphate can be increased just in the vicinity of metal substrates and the heterogeneous nucleation is promoted on them. In this process, H2O is reduced according to eq. (1) on the cathodically polarized electrode"

Jan 1, 2000

By H. Sarvamangala

Biomineralization of manganese on titanium condenser material exposed to seawater has been illustrated. Biom-ineralization occurs when the fouling components, namely, the microbes, are able to oxidize minerals present in water and deposit them as insoluble oxides on biofilm surfaces. Extensive biofilm characterization studies showed that an alarmingly large number of bacteria in these biofilms are capable of oxidizing manganese and are, thereby, capable of causing biomineralization on the condenser material exposed to seawater. This paper addresses studies on understanding the exact role of the microbes in bringing about oxidation of manganese. The kinetics of manganese oxidation by marine Gram-positive manganese oxidizing bacterium Bacillus spp. that was isolated from the titanium surface was studied in detail. Manganese oxidation in the presence of Bacil-lus cells, by cell free extract (CFE) and heat-treated cell free extract was also studied. The study confirmed that bacteria mediate manganese oxidation and lead to the formation of biogenic oxides of MnO2, eventually leading to biomineralization on titanium surface exposed to seawater.

Jan 1, 2008

By M. N. Chandraprabha

Arsenopyrite is often associated with sulphides like pyrite, chalcopyrite and galena in refrac-tory gold ores. Selective flotation of arsenopyrite from associated sulphides is desirable for effective gold extraction when the gold is preferentially associated with the arsenopyrite matrix. By contrast, presence of arsenopyrite in flotation tailings poses a serious environmental threat due to arsenic dissolution. To prevent arsenic contamination from the mine wastes, it would be more economical and environmentally beneficial to remove this mineral during the froth flotation step. Use of Acidithiobacillus thiooxidans in the detoxification of arsenic containing sulphides is outlined in this pa-per. Biomodulation using Acidithiobacillus thiooxidans resulted in the preferential depression of pyrite from arsenopyrite. By suitable conditioning with cells and collector effective separation of arsenopyrite from pyrite was achieved. Biomodulation with wild cells did not yield separation of arsenopyrite from chalcopyrite. However, bacterial affinity could be induced to a desired sulfide mineral through environmentally controlled adaptation techniques. Through the use of arsenic-adapted bacterial cells, selective removal of arsenopyrite from chalcopyrite was readily achieved.

Jan 1, 2014

By Sutham Niyomwas

Biomorphic Cellular TiCIC ceramics were produced by vacuum-infiltrating carbon preforms with Ti02 sol and subsequent synthesis by the carbothermal reduction process. The carbon preforms used in the study were obtained by pyrolysis of parawood and neem wood. The effect of infiltration time on the composition and microstructure of the biomorphic TiCIC ceramic was analyzed by X-ray diffractometry and scanning electron microscopy. The biomorphic structure of the TiCIC ceramic is consistent with that of the biotemplate natural parawood and neem wood.

Jan 1, 2008

By R. W. Bartlett

I first met Milton Wadsworth in 1951 as an eighteen year old junior taking his mineral processing course at the University of Utah. He guided my senior thesis, evaluating the then new polymer flocculants on settling uranium leached ore pulps. This was before ion exchange and solvent extraction. After my military service and a brief working stint at Kennecott he supervised my PhD work. He encouraged me to be active in AIME and its constituent societies, where both of us have been directors of AIME and presidents of TMS. He has been a consultant for research groups that I have managed. Above all, he has been my mentor and friend for nearly 45 years. Thus, I am honored and particularly pleased to receive 5MB&apos;s Wadsworth Award.

Jan 1, 1996

By Bogidar V. Mihaylov

Bacterial oxidation of a low-grade sulfide gold ore was investigated in order to enhance leaching of gold. The experiments were carried out in columns using mixed cultures of Thiobacillus ferrooxidansisolated from the ore. Fractions with different screen analyses were oxidized in two regimes - one pass of the solution and circulating, solution. Constant temperature and flow-rate of the percolating solution were maintained during the experiments. A correlation between the concentrations of copper and iron in the solution leaving the columns and pH and Eh values was observed. The effect of bacterial activity was proved by means of thiourea and cyanide leaching of the oxidized ore.

Jan 1, 1991

By E. T. Pecina

Bioleaching is a viable option for the processing of auriargentiferous refractory ores with high arsenic content. The application of mesophilic (A. ferrooxidans and ?L. ferrooxidans?) and thermophilic bacteria of the genus Sulfolobus (S. solfataricus and S. acidocaldarius) as oxidant treatment before the cyanidation of an industrial arsenical pyrite concentrate is presented. The results show that extraction of gold and silver increases due to bio-oxidation caused by mesophilic bacteria and results in a maximum gold recovery of 68%. In all strains studied, biooxidation resulted in an average silver recovery of 50%. The results showed that all evaluated strains were sensitive to solids content (5 to 20%) and average particle size (75 and 38 µm) of the concentrate.

Jan 1, 2010

By Richard W. Lawrence

Leaching of copper from sulfide minerals using biooxidation offers a potential route for copper recovery. Oxidation of . sulfide sulfur can proceed either; to sulfate or to elemental sulfur depending on mineralogy and process conditions. The advances in commercial application of biooxidation for sulfidic gold ores has made available operating and cost data which allow the derivation of conceptual costs for copper ore processing for comparison with conventional processing routes. Although costs for copper biooxidation generally remain high relative to conventional smelting, application might be competitive in specific cases. Biooxidation becomes more competitive in the general case if the cost ofS02 emissions in pyrometallurgical processing were to be internalized to a greater degree than currently required. This paper describes the technical aspects of biological processing of copper sulfide ores and concentrates, specifically with respect to the fate of sulfur. The environmental and economic implications of the biooxidation route are discussed in relation to conventional processing.

Jan 1, 1996

By U. Dmitrakova, G. Sedelnikova, D. Kim, E. Savari

"The paper presents the results of research on the development of gold and silver extraction technology from refractory gold sulphide flotation concentrate of one deposits of Nord-East of Russia. The concentrate is due to the complex mineral composition. Gold and silver are finely disseminated in sulphide minerals (arsenopyrite and pyrite partially oxidized by 7-11%). These are characterized by high content of silver 219 g/t and sulphide sulfur 32%, the presence of poorly soluble silver minerals (silver sulfosalts, fahlore, finely dispersed hypergenic acanthite in iron hydroxides and jarosite, etc.), and impurity minerals capable of interacting with cyanide (pyrrhotite, marcasite, nonferrous sulphides) and causing higher than normal cyanide consumption. Pretreatment of refractory sulphide concentrate by biooxidation using a mixed association of mesophilic and moderately thermophilic bacteria at a temperature of 36-40 °C for 120 hours oxidized arsenopyrite by 97.5%, pyrite by 93.5%, unlocked refractory gold, and generally oxidized the minerals absorbing cyanide and oxygen before cyanidation. Further oxidation of these minerals-absorbents was facilitated by the aeration in calcareous medium of the solid biooxidation residues of the concentrate. Sorption cyanidation of the solid biooxidation residues with addition of lead (II) of recovered 91.2% of gold and 82.9% silver from biooxidation residue, compared with 80.1% and 46.6%, respectively, for sorption cyanidation without the preceding biooxidation step. Biooxidation of the concentrate prior to cyanidation improves the recovery of precious metals, especially silver, and significantly reduces cyanide consumption from 18.7 kg/t to 3-5 kg/t of concentrate. INTRODUCTION Biooxidation of gold sulphide concentrates using acidophilic microorganisms has been successfully applied worldwide (van Aswegen et al., 2007; Gericke et al., 2009; Sovmen et al., 2007; Sovmen et al., 2009). At least 15 full-scale plants for tank biooxidation of sulphide concentrates are presently in operation, and the construction of new ones is planned (Bulaev et al, 2015)."

Jan 1, 2018

Bacterial leaching of sulfide minerals are fairly well established in heap, dump and in situ leaching and the primary bacterial treatment of refractory gold concentrate using CSTR have gained industrial prominence in recent years. Three cultures, a mesophile T ferrooxidans (DSM583), a moderate thermophile Sulfobacillus acidophilus (strain YTF1) and a extreme thermophile (Sulfolobus strain BC65) were used for the biooxidation (pre-treatment) of the Porgera gold-bearing pyrite concentrate under optimum O2 and CO2 enriched air (30 per cent O2 and ten per cent CO2) based on volume ratios. The positive effect of using oxygen and carbon dioxide enriched air for the biooxidation of gold-bearing pyrite mineral was clearly demonstrated where an increase in Fe release rate by a factor of 2.8, 1.8 and 1.5 for DSM583, YTF1 and Sulfolobus respectively were observed compared with the shake flask tests. The lag phase observed with the other test conditions such as in shake flask or with air decreased by about 80 per cent for all three cultures. The average observed dissolved oxygen concentrations in the pulp for these tests were 8.7, 5.8 and 5.0 mg/L for DSM583, YTF1 and Sulfolobus respectively, indicating that O2 was not limiting in these tests. The pulp redox potential was observed to increase with time for all tests coincident with the leaching rate and reaching a maximum of 663 mV, however the maximum value differs for each strain, with DSM583 exhibiting the highest followed by YTF1 and Sulfolobus. Biooxidation of pyrite under optimum gas enrichment at different pulp densities showed near total Iron extraction occurred for pulp densities of three, ten and 20 per cent (w/v). At high pulp densities, more so at 40 per cent than 30 per cent (w/v), the leaching rate decreased rapidly for tests with YTF1 and Sulfolobus. Monitoring of dissolved O2 shows that O2 demand increased with increasing pulp density and the average dissolved O2 concentration observed for YTF1 and Sulfolobus at 40 per cent solids concentration was 1.0 mg/L and below, suggesting limiting oxygen and carbon dioxide conditions for these two cultures. The decrease in leaching rate observed at high pulp densities (30 and 40 per cent) under optimum gas enrichment was accompanied by low metal dissolution and low redox potential values which was attributed to shear stress due to attrition of cells by high solids concentration, toxicity of metal ions especially Ag and Fe and the formation of precipitates and jarosites as confirmed from XRD analysis of leach residues hence impeding the leaching process. Limiting conditions due to high pulp density and viscosity were only observed for YTF1 and Sulfolobus. The subsequent cyanide leaching for precious metals from the pre-treated pyrite concentrate in all cases shows the extent of gold and silver recovery increased with the degree of pyrite oxidation and Au and Ag recoveries in excess of 80 per cent were achieved compared with only 18.1 per cent and 35.9 per cent for gold and silver respectively when treated by direct cyanide leaching on the original, untreated concentrate.

Jan 1, 2004

By S. K. Palm

The commercial life of a mineral product can be long, but like hitech electronic and software products that soar in sales one day to become obsolete and forgotten a few months or years, mineral products have a life cycle. They are invented, commercialized and eventually decline and disappear from commerce. Diatomite and perlite are produced from mined minerals, but almost none of the products in these industries spring from the earth in finished form. Straight calcined diatomite was invented over 100 years ago and flux calcined diatomite just a few years later. The expansion properties of perlite were discovered and first exploited about 75 years ago. Some applications for diatomite have disappeared or currently face competition from newer products. Dry cleaning was once the second-largest application for diatomite but disappeared over 30 years ago. Both the beer and wine filtration markets for diatomite face increased competition from membrane filters. A pipeline of new, proprietary products is critical to the future of the industry.

Mar 2, 2022

By Rolf Andreas Lauten, Adam Pratomo, Dani Ramdani, Helminton Sitanggang

A universal challenge for the mineral processing industry is the diminishment of high grade ores. Instead, low grade ores, sometimes also containing problematic gangue minerals is the reality. With lower head grades the industry has to put more effort into processing to maintain the output and achieve suitable recoveries. In an effort to reduce the impact of declining head grade, a biopolymer was evaluated as an additive in the gold leaching operation at Antam Pongkor in Indonesia. Laboratory testing revealed that biopolymer usage lead to an increased gold recovery without apparent negative impact on the other parts of the process. Further plant trials revealed both a recovery increase around 1.3% and higher throughput (9%) in the presence of the biopolymer. Some scenarios that can explain these findings will be discussed.

Jan 1, 2014

By C. Bergstrand

"Precipitation of gypsum and the formation of scale may pose a serious challenge in the leaching of several minerals. As an example, precipitated gypsum may form scale in the machines increasing the need for maintenance. Alternatively, it may encapsulate precious elements, i.e. gold and lower the recovery during subsequent leach processes. In this work we explore how different biopolymers modify the rheology of gypsum at three different pH levels at ambient and elevated temperatures. The ability to disperse gypsum vary with temperature, pH and biopolymer. It is also inversely related to the scaling potential. Measurements of the zeta potential as a function of increasing amounts of biopolymer reveals that the magnitude of the zeta potential changes in the presence of biopolymer, and so does the ability to disperse the gypsum suspension. Similar results with hematite will also be discussed. The methodology and results may aid in the selection of additives used in mineral processing applications where scale pose a problem.INTRODUCTION Processing of refractory gold ores normally involve either atmospheric or oxidation under pressure in order to convert sulfides to oxides (Weir, King, & Robinson, 1986; Weir, Robinson, & King, 1986). This conversion facilitates leaching of gold (and silver) in normal CIL processes. During oxidation, sulfides are converted to sulfates. Normally, there is an abundance of calcium ions in the process water, either released from the ore or added as lime to adjust pH for the CIL process. Precipitation of calcium sulfate, or other compounds (calcium carbonate, jarosite, hematite) is a way to remove gangue minerals from the solution entering the CIL circuit (Ji, King, Fleming, & Ferron, 2010). Precipitation may also cause challenges in the process as gold (or other valuable elements) may become encapsulated in gangue. (Beauchamp, Choung, & Xu, 2006). In addition to precipitation, the precipitated gangue minerals may solidify and form scale in the processing equipment. Recently, Lauten and Kluck (2016) found that dispersants used as scale inhibitors to prevent encapsulation of gypsum did not modify the solubility of gypsum. In the utilised model system, similar amounts of gypsum precipitated with and without dispersants. Instead, it was found that the dispersants evaluated as scale inhibitors reduced the yield stress of gypsum suspensions. The reduced yield stress was associated with a reduced tendency for gypsum particles to agglomerate and form scale."

Jan 1, 2017

By Ross W. Smith

Microorganisms are increasingly finding use in mineral processing and hydrometallurgy both for the enhancement of mineral engineering operations and for the remediation of mineral industry wastes. Some of the applications, such as biologically assisted leaching of sulfide ores and biooxidation of refractory sulfide gold ores, are established commercial processes. Others, such as the use of organisms for the removal of heavy metal ions from dilute aqueous streams, are nearing commercial application. Other uses of microorganisms are potentially possible. These include use of microorganisms in leaching non-sulfide ores, the flocculation or flotation of minerals and remediation of toxic chemicals discharged from mineral engineering operations.

Jan 1, 1993

By L. Landryova

The Department of Control Systems and Instrumentation, VSB - the Technical University Ostrava, has been involved in a project dealing with utilization of landfill gases, when the methane gas utilization and minimization of its release into the atmosphere was the main concern. The landfill site is generally a place, where technology for energy production can be built. The conditions for this technology implementation vary and depend on various factors. This paper is presenting findings and experience gained regarding a method of methane gas utilization for energy production. This method is concerning building bioreactors at the landfill sites, which are already operated. Every bioreactor can be thought of as a process, which is controlled in order to maximize energy production and minimize the methane gas escape into the atmosphere. The bioreactor landfill can represent a number of environmental and cost savings and, at the same time, is able to comply with all legislative issues.

Jan 1, 2005

By William A. Apel

Several different strains of bacteria have been shown capable of reducing hexavalent chromium, Cr(VI), to Cr(III), a less toxic, .. more readily recoverable form of Cr. This paper examined the Cr(VI) reduction efficacies of 3 different Cr(VI) reducing bacteria: Pseudomonas f1uorescens LB300., Pseudomonas aeruginosa PAOI, and Pseudomonas aeruginosa PAOI (pCROI) It was demonstrated that all three bacterial stratns reduced Cr(VI) primarily during their exponential growth phases while using glucose as their carbon and energy source. Significant differences in the three organisms&apos; Cr(Vl) reduction capabilities depending on initial Cr(VI) concentrations were also demonstrated. P. aeruginosa PAOI showed superior Cr(VI) reducing capabilities over the. entire range of Cr(VI) concentrations tested while the Cr(VI) reduction capabilities of the other two strains were increasingly inhibited as Cr(VI) concentrations increased.

Jan 1, 1991

By Evvie Chockalingam

Acid mine drainage (AMD) is a perennial problem particularly in abandoned mines, occurring due to the oxidation of sulphidic mine wastes. AMD is usually characterized by high concentration of dissolved metal ions, sulphate and low pH. The efficacies of substrates such as rice husk and the bark of Eucalyptus tereticornis (Sm.) are assessed for the removal of metal ions such as iron, zinc and copper from acid mine water obtained from an abandoned copper mine. Over 99 % of Fe, 98 % of Zn and 95 % of Cu removal could be achieved from acid mine water, with a concomitant increase in the pH value by three units using rice husk as an adsorbent. With respect to tree bark as an adsor-bent, about 96 % of Fe, 75 % of Zn and 92 % of Cu could be removed from the acid mine water with an attendant increase in the pH value by two units. The free energy of adsorption of the metal ions onto rice husk and tree bark is found to be negative in both the cases, while the adsorption process is endothermic in the case of rice husk and exothermic for tree bark. The adsorption process is found to adhere to the Lagergren pseudo-first order rate equation. The reduction of sulphate con-centration in the acid mine water is achieved using a typical sulphate reducing bacteria namely De-sulfotomaculum nigrificans. Desorption experiments indicate that about 88 % of Zn, 87% of Cu and over 77 % of Fe could be recovered from rice husk and over 70 % of Fe, 82 % of Zn and 77 % of Cu could be desorbed from the metal loaded tree bark using 5 M HCl. The possible mechanisms of metal ion and sulphate removal from acid mine water using rice husk and tree bark are discussed.

Jan 1, 2014