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By G. Belardi

This paper presents the preliminary results of a research programme conducted to assess the feasibility of a flotation technique in the remediation of soils severely affected by heavy metal contamination. The use of flotation in soil remediation is a recent practice. The main difficulties are given by the variety and peculiarity of the heavy metal containing species, and also by the grain size. Most of the studies reported in the literature concern the use of conventional collectors, such as xanthates, after a preliminary chemical modification of the metal bearing species through sulphidization. On the basis of the minera-petrographic characterization and of speciation, some classes of reagents have been selected, capable of acting both on metal-bearing species and all metallic cations to be separated. The design of the synthetic molecules has been based on the coordinative properties of the metallic centres and functionalized in order to act as collectors for a wide range of metals independently on their surrounding atoms. In laboratory experiments a sample of stream sediment has been utilized, whose contamination is caused by the runoff from Sardinia mine waste dumps and overflow from the settling ponds. The material showed contamination mainly from Zn, Pb and Cu and to a lesser extent from Cr, Ni, Cd, and Sb associated in mixed particles of Fe and Mn. Flotation tests on a laboratory scale have been performed on grain sizes less than 355 µm in laboratory cell Minerais & Metaux. The effects of the structure of collectors (functional group, chain configuration) as well as of the principal flotation parameters (such as pH, concentration of reagent) on the grade and recovery of heavy metals in the concentrate and in the tailings (remediated soil) have been investigated. The results of the laboratory tests substantially confirm the theoretical premises, and the most effecive reagents found belong to the classes ATP, MBT, MBO, fat acids and phosphates.

Jan 1, 2014

By Gorki Davila, Irineu Brum

"Brazil has large reserves of coal (32 billion tons) located predominantly in the south of the country. Despite the relative ease of exploitation, these resources have been underestimated as a source of energy. Currently the country's strategic planning aims to minimize the gap between coal and resources traditionally used in the Brazilian energy matrix. In this scenario the processing of Brazilian coal by flotation appears as a promising alternative, having been successful in mineral systems containing fine particles This paper aims to study the overall process of flotation for a specific Brazilian coal. The material used in this study consists of fine coal that is usually discarded as waste and deposited in the tailings dam. The objective is to recover carbonaceous matter and reduce the ash and contaminants grade. The variables analyzed were the influence of size particle, solids concentration in the pulp, the concentration of surfactants and frothers to be used. The results showed that it is possible, from a feed with around 65% of ashes, to obtain products with approximately 35% ashes with mass recoveries about 40%. The types of collector reagent and foaming employees result in different concentrates. This study also presents a preliminary analysis of the effect of water recovery in concentration parameters."

Jan 1, 2014

By Antonio Favia, Carsten Sowa, Spencer Diehl, Maria Carolina Campos, Christian Green, Marco Tulio, Olaf Schulz

Casting fluxes are one of the key factors to guarantee a good performance of the continuous casting process. Fluxes are added over the liquid steel in the mold, where carbon in the flux reacts with any air present, to form a reducing atmosphere of CO (g) to protect molten steel from oxidation. Then the oxide components form the sintered layer and they melt to form a liquid flux pool. Liquid slag from the pool infiltrates into the mold/strand channel and lubricates the newly-formed, steel shell. It was very common in the past that the addition of casting flux in the mold was made manually by the continuous casting strand operator, where the addition uniformity would mainly depend on the attention of the Operator in process and the addition standard would change from one operator to another, may causing variability on the continuous casting quality parameters. This paper presents improvement of continuous casting parameters such as, stability of flux thickness and reduction of dust in the continuous casting process, with the use of flux distribution mechanism in two continuous casting machines from two different steel plants.

Oct 1, 2019

By H. Oterdoom, S. Pilger, T. P. Bui, J. Rotarius

"Most FeNi furnaces used to rely on post-combustion and off-gas cooling inside the furnace to eliminate the produced CO gas, and control the off gas temperature. As furnace load, capacity, and thus gas volumes increased over the years, this led to increased instabilities that can cause problems in controlling the operation. Some of the large capacity furnaces nowadays work with partial or full combustion outside the furnace, more similar to the steel industry. Forced combustion with or without enriched air and other additions can support in controlling post-combustion, stabilizing and even reducing off gas amounts, and affecting composition. This paper presents some of the possibilities and advantages of having a specially designed post-combustion system for the FeNi laterite industry, but that could also be applied to other processes as well.Large Scale Furnaces In the FeNi industry, the Rotary Kiln Electric Furnace (RKEF) process is still going strong in spite of continuous hope that hydrometallurgical processes will one day make the RKEF plant obsolete. Within the pyrometallurgical plants there is a continuous trend for larger scale furnaces. The development for a number of furnaces that were started before 1985 and increased capacity by “natural growth” is given in Figure 1. Natural growth refers to the development of the plants that after having mastered a certain level of operation, were ready for a higher load that could be installed either with a new furnace on the same site, or during a revamp. The advantages of natural growth are numerous, for example: •,Deep knowledge of the ore and its’ behavior, no need for testing, and little risk of surprises. •,Mining, laboratory, equipment, etc. is all proven technology for the conditions on site. •,Starting a furnace with increased capacity is a re-start, not a green-field commissioning. •,Typically, when increasing the production capacity of an existing plant, not the entire plant is commissioned for the first time, but only a part. In the FeNi laterite industry for example, the kilns may already have had the capacity to provide enough material."

Jan 1, 2017

By O. M. Arafat, J. A. Finch

"The Functional Performance Equation calculated from a plant grinding survey defines two distinct ball mill circuit efficiencies and how they relate to total production rate through the target grind size. The survey data are also used to calculate a complete ball mill size distribution model, represented by the energy specific grinding rates, not just through the target grind size, but through all the size classes. Cyclone separation performance is represented by individual size recoveries to underflow. When these two unit operation performances are entered into the circuit modelling program (Streamline™), along with the circuit feed rate and size distribution, all the circuit survey size distributions and mass flows are perfectly regenerated by the program. The many issues associated with the historical Epstein (breakage-selection) models are eliminated. Once the circuit program is populated, pump and cyclone performance changes can be evaluated using a step-by-step procedure in order to maximize Classification System Efficiency. Mill water use and media sizing opportunities are also diagnosed in order to maximize Mill Grinding Efficiency at the size of interest. An example is provided. This circuit analysis and modelling system, and related training, is provided through a web-based application.IntroductionSince its development (McIvor, 1988), the Functional Performance Equation for ball milling has facilitated new understanding of industrial circuit cause and effect relationships, leading to significant strides in operational performance. Success stories of this refreshing approach to plant circuit performance improvement are now too numerous to list. Finch and McIvor (circa 1986) also discovered that the Functional Performance “Mill Grinding Rate” at the size of interest was the same cumulative grinding rate that is calculated from mill feed and discharge size distributions using a first-order rate equation. By calculating these cumulative grinding rates for all screen sizes, a complete ball mill model is generated (as used by Finch and Ramirez, 1981). Others in industry, Hinde and Kalala (2009), for example, have noted the same. Lacking the complexity needed to maintain their interest, most researchers have ignored this model, broadly opting instead for Epstein’s (1948) characterization of grinding as a chemical reaction, combining “selection rate” and “breakage size distribution” functions. The much simpler ball mill model presented here has previously been incorporated into a proprietary circuit modeling program (McIvor, 2005) and used for plant improvement work (for example, see McIvor and Finch, 2007, and McIvor, 2014). Now, by combining this extremely business-friendly ball mill model with optimization criteria from Functional Performance Analysis, a circuit modeling system (including the needed supplementary steps to assure successful plant implementation of circuit design changes) is at the disposal of every plant metallurgist, grinding equipment/material provider, and circuit designer."

Jan 1, 2017

By S. K. Kawatra, T. C. Eisele

Pyrite depression is of great interest in sulfide mineral flotation, where pyrite is a common gangue mineral. Since the floatability of pyrite is a function of the pH and a variety of other chemical factors, pH control is a critical part of sulfide flotation circuits. A wide variety of pyrite-depressing chemicals have been studied and used in sulfide- mineral processing, with considerable success. However, there are certain applications where there are still no satisfactory pyrite depressants, and even when suitable depressants are available, there is always a need for less-expensive reagents. Microorganisms, such as the bacteria Thiobacillus ferrooxidans, are known to depress pyrite flotation. However, the dependence of the depression on the type of organism or on suspension pH is still being determined. In this study, the relative effectiveness of various microorganisms, and the effect of pH, has been examined. Screening tests using microflotation showed that every microorganism tested was capable of depressing naturally hydrophobic pyrite at acidic pH. Larger-scale experiments with two of the screened organisms and two different pyrites showed that microorganisms are very effective depressants at acid pH, but are largely ineffective at neutral and alkaline pH where the pyrite surface is not naturally hydrophobic.

Jan 1, 1994

By C. V. Millikan

When a flowing oil well is being drilled in with cable tools, it is difficult to determine when an additional streak of pay sand is drilled. By placing a gas meter on the gas-release line from the oil and gas separator, any increase in volume of gas that comes with oil production is recorded. In addition to the better knowledge of sand conditions, these data are a valuable aid in determining the size and depth of shots, plugging off water, and estimating ultimate production. The meter also gives a record of operation while the well is drilling in; and if allowed to remain on the well after completion will give information that may lead to a more efficient recovery of the oil from the sand. A VERTICAL cross section of any oil sand will show great variation in porosity and oil content. In some sands, the entire thickness contains oil, the variation being only the degree of porosity or oil content, but more often the pay streaks are distinctly separated by shells or barren streaks. These pay strata vary in number and may be thin or thick. The total thickness of the sand may be several tens of feet while the part containing oil may be only 1 or 2 ft. thick. The amount of production is not proportional to the thickness of the sand but rather the thickness of the pay streaks. If the total thickness of the sand or the amount that can be drilled is small, or if the initial production is small, the depth at which each stratum of pay is encountered can be determined sufficiently accurately for all present economic purposes. However, when drilling through sand of considerable thickness, giving large initial production, especially where conditions necessitate that the production go through the same gas trap with that from one or more wells already producing, it is difficult to determine the depth at which the pay strata are encountered even accurately enough to guide the placing of shots, and small pay streaks are apt not to be recognized at all.

Jan 9, 1925

By John C. Ferm

Although roof falls account for approximately half of the fatalities in underground coal mining, the factors that produce them are not clear. Mining methods can account for some, but in others the controlling factors are the geological setting in which the mining takes place. The present investigation was undertaken to determine the kinds of rocks that were most likely to produce roof problems. Such knowledge would be helpful to mine planning since rock samples can be obtained in advance of mining by core hole drilling. The investigation was undertaken in underground mines in the Pocahontas #3 seam in southern West Virginia and southwestern Virginia. The Pocahontas #3 is one of the most widespread in this region and is a major source of high quality metallurgical coal. There are at least ten very large mines in the area and many smaller ones. The region has a very long mining history and considerable experience has been gained in roof control problems. The study was conducted with the support of the U. S. Bureau of Mines.

Jan 1, 1978

By David E. Nicholas

Design of underground openings is becoming more critical as the mine deposits become lower in grade, initial investments increase, ore depth increases, additional safety regulations come into law, and increased ore recovery is required for conservation of minerals. Stability of these openings is dependent on the strength of the rock mass and the pre-mine stress field. The rock mass is composed of solid blocks of rock (rock sub- stance) and structural features (faults, joints, bedding, etc.). Methods of testing the rock mass strength are improving and be- coming more common, however it is difficult to justify the high cost of large scale testing for an initial mine design. An alternative to testing the rock mass is to measure the rock substance and the structural features separately, and then combine them to estimate the rock mass strength. The rock mass strength will vary depending on the orientation of the opening with respect to the structural features. The other factor affecting the stability of underground open- ings is the pre-mine stress field. Methods are available to measure "directly" the pre-mine stress in competent and relatively massive rock. These methods are costly to employ, therefore, they may not be justified in an initial study. The pre-mine stress field can be estimated based on the structural relationships formed from past tectonic events.

Jan 1, 1976

By E Macmillan

For any processing plant there will be deleterious elements or minerals which affect production or quality, and a strategy to predict their occurrence and mitigate their impact is required. An early objective of the Olympic Dam geometallurgy program was prediction of the acid consumption and gelling behaviour of the ore, which affects leach recovery, throughput and circuit availability. The geometallurgical test program measured the response of a wide range of ore types, and then relationships between mineralogy, metallurgy and chemistry were developed. Thus the drivers of acid consumption and triggers for gelling events could be described in ways that were meaningful to plant operations.To enable optimisation of the mine planning and ore blending processes, the parameters driving metallurgical response must be translated to the block model. Data support is critical in populating a block model. Assay information is easily obtained, but mineralogical and metallurgical information is more expensive and time consuming to collect. Hence population of a block model with mineralogical and metallurgical values using a conventional geostatistical approach is not always possible.An alternative approach employed at Olympic Dam was the development of a suite of assay-to-mineral algorithms. These algorithms were calibrated using all available mineralogical information, and this enabled the calculation of mineral abundances for more than 1.5 million assayed samples. Estimation of the minerals in the block model, and the generation of acid consumption values for each block could subsequently occur.The use of back-calculated mineralogy from assays as part of process model generation is an innovative tool which can be used for mine planning and optimisation and to ensure the plant does not receive any unwelcome surprises. Ultimately, one purpose of geometallurgy is to predict potential processing issues and their drivers so that these can be mitigated. A strategy to achieve this is outlined hereafter.

Sep 5, 2011

By C. K. Skokan

Various geophysical tools have been tested over the last eight years to evaluate their usefulness in defining damaged rock zones in an underground facility at the WIPP site in New Mexico. These tools include direct current and frequency domain electrical methods and seismic tomography. The electrical measurements show a "drying rind" to exist around older excavations. Seismic tomography confirms that a rind of lower velocity has developed along walls. In combining these tools, a monitoring program has been proposed to observe long-term changes in bedded salt. Results from the monitoring of electrical data over a 2-year time period illustrate the applicability of the technique in an underground environment.

Jan 1, 1993

By K. T. Cunningham

The Oakfield, New York Hine of the United States Gypsum Company is a shallow, room and pillar mine developed in the Camillus Formation of Silurian Age on the up-dip edge of the northern Appalachian Basin. The gypsum comes to subcrop beneath a variety of glacial materials and is subject to solution activity by groundwater. A geologic environment unfavorable to mining activity is thus created. Since 1978 seismic studies have been used to supplement core drilling to determine a conservative boundary between normal and questionable mining environments. A single channel seismograph, originally in use, is now replaced by a twelve-channel unit and is used to determine bulk material velocity which is the basis for defining the mining limit.

Jan 1, 1987

By M Zengerer

The Basil Cu/Co deposit comprises a 26.5 Mt Inferred Resource of copper and cobalt, grading 0.57?per cent Cu and 0.05 per cent Co. It lies in the Harts Range, Central Australia, within the Riddock Amphibolite of the Irindina Province. Analysis of drilling within the mineralised zone of the deposit determined a spatial association between pyrrhotite with high magnetic susceptibility and chalcopyrite, following a strong magnetic trend as determined from airborne geophysics. A study was commissioned to examine if geophysical inversion could predict the distribution of sulfide mineralisation based on pyrrhotite from drill hole intersections, as well as predicting further mineralisation at depth or in the vicinity of the deposit. Petrophysical and geostatistical analysis of drilling susceptibility and mineralisation provided a basis of property distribution inside the model. This was followed by 3D geological modelling of mineralisation based on domain kriging of drill hole susceptibility sensitivity testing of signal to source depth, and distribution was performed using 3D forward modelling. Stochastic inversion generated alternative 3D geological models, which were tested for behaviour and adherence to observed drilling data and geostatistical limitations using GeoModeller software. Predicted mineralisation distribution was compared with conventional geostatistical modelling and found to be in agreement in planar behaviour but exhibiting possibly isoclinally folded trends, with reliability increasing closer to the surface. Predictions of mineralisation at greater depth and beneath weaker anomalies were more diffuse due to small model cell size having limited influence on the signal at depth.The Blackbush uranium deposit comprises a 64.5 Mt Inferred Resource, grading 230 ppm U in the Pirie Basin south of Whyalla, South Australia. It directly overlies the radiogenic Samphire Granite and is considered a tertiary unconformity deposit. Sensitivity modelling was performed using high-resolution ground gravity to see if a deposit signature could be detected using gravity. This required 3D implicit modelling of the geology and mineralisation from drill hole data and characterisation of an associated physical property model using domain kriging in GeoModeller. Density models relied on exploiting an observed relationship between logged density and measured uranium oxide percentage. The residual gravity response of the background geology model identified the location of the uranium deposit. Stochastic inversion of the litho/property 3D model has refined the known distribution of uranium from drilling and provided structural insights into the deposit.These projects have become excellent case studies for exploiting the relationship between mineralisation and potential fields and for testing the applicability of using domain kriging of properties determined from drilling to build robust 3D geological models for stochastic geophysical inversion, leading to robust methods for exploration targeting and mineral deposit prediction.CITATION:Zengerer, M, 2014. Use of geostatistically-constrained potential field inversion and downhole drilling to predict distribution of sulfide and uranium mineralisation, in Proceedings Ninth International Mining Geology Conference 2014 , pp 281–290 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By Kadri Dagdelen

New underground coal mines have become increasingly expensive to open. A simple drift mine producing a raw coal product can cost as much as $50 million while a new shaft mine producing a washed coal product can cost up to $200 million. As a result, few if any speculative new mines are constructed. Normally, a long term coal supply agreement is needed to justify new mine projects. Negotiating a supply agreement prior to production start is difficult. Pricing must be based on estimated rather than historic costs and coal quality must be estimated from core hole samples versus actual shipments. Further in todays competitive coal markets, there is little margin for error in either price or quality.

Jan 1, 1983

By Jaeheon Lee, Junmo Ahn, Doyun Shin

"Many alternative leaching systems including bacterial leaching have been introduced to avoid passivation on the surface of chalcopyrite and to increase the leaching efficiency of copper from chalcopyrite. Recently, glycine, one of the simplest amino acids, has been emerging as an efficient and environmental-friendly lixiviant to recover copper. In the present study, an alkaline glycine–peroxide lixiviant system was used to leach copper from chalcopyrite concentrate and the leaching mechanisms were also investigated by a suite of kinetic studies under different conditions. The chalcopyrite concentrate contains 28.8% copper with 30.8% sulfide sulfur. The effect of concentration of glycine and hydrogen peroxide of the leaching solution was investigated. Glycine concentration was varied from 0.5 to 1.0 M and the hydrogen peroxide concentration was changed between 3 to 5%. Leaching time and pulp density were also varied. Hydrogen peroxide is an oxidant of the system and the leaching efficiency with periodic additions of the peroxide was also studied. A mineralogical study was performed using XRD and SEM. To investigate the surface of the residue materials, XPS was used to see if any passivating layer was formed during the leaching. Detailed results from mineralogical, chemical, and metallurgical studies will be presented and discussed.INTRODUCTION The greatest global resource of copper is low-grade chalcopyrite and heap bioleaching may be the only economic option for its processing. However, formation of a passivating layer on the surface of chalcopyrite slows down the oxidation reaction and reduces the efficiency of the process."

Jan 1, 2017

By F. Ríos

Fundamental research, at laboratory scale, on the biomass adsorption capacity of a liquid mining effluent has been done. The biomass used corresponds to a Chilean seaweed called Gracilaria chilensis. The waste water effluent corresponds to clear water coming from thickeners of a Chilean copper mining operation. The biomass was dried, washed, treated with an acid solution, and then reduced in size. A characterization of Zeta potential was made, finding negative values in a wide pH range with a ZPC equal to 2.5 1. Adsorption tests were made- in an agitated system containing an artificial solution of CuS04 at a controlled temperature of 25 degrees Celsius; also, the effect of pH over the copper adsorbed was studied. Maximal adsorption of copper was found at pH equal to 6, and the Langmuir model indicated values for saturation of 52.08 mg/g and for standard free energy of about -21 KJ/mol. Kinetic adsorption was very high and fitted very well with a second order model equation, finding that 90 per cent of the adsorption occurred during the initial 10 minutes. After stoichiometric when 1 mol of copper is adsorbed, 2 mol hydrogen are released, showing that the main mechanism to remove heavy metals is the ionic exchange, and the seaweed ensures total discharge of copper adsorbed when the pH value is about 1. Experiments done with real waste water from thickeners lead us to conclude that optimal results for copper and molybdenum adsorption are at pH around 3.25 and the remaining treated water may be partially discharged into the water currents, thus showing that Gracilaria chilensis can be used to remove heavy metals easily from liquid effluents in the copper mining industry.

Jan 1, 1999

By L. Nichols, H. Keele, K. Czajewski

"The oil sands industry in northern Alberta disposes of the by-products of bitumen extraction into tailings ponds. The mix of tailings sand and mature fines, with gypsum added as a flocculent, constitute a waste stream called consolidated tailings or composite tails (CT). The two main challenges of the tailings disposal process are a chronic shortage of economical containment and the potential mobility of CT deposits in the event of breaching by, for example, long-term erosion, which makes abandonment of tailings ponds more complicated. Thick deposits of CT do not consolidate in adequate time to provide reassurance for abandonment of the CT containment facilities and that is why the containment must be adequately robust or the properties of CT improved for long-term stability. This paper addresses potential solutions to these problems by applying the gravity drainage of CT and quasi-homogeneous construction for containment facilities.Gravity drainage is suggested as a mechanism to facilitate the consolidation of CT in critical areas of the ponds by inserting internal sand layers within the body of the deposit. Critical CT areas are defined as areas around the perimeter of containment. The advantages of this solution are longterm stability of the disposal area by creation of stiff deposits around its perimeter and facilitation of reclamation efforts on its surface.The present solution for containment of CT deposits is not favourable from a materials balance point of view. In general, sand has become a valuable resource as it both forms the primary component of the CT matrix and becomes the containment building material. If sand is required for CT, less is available for dyke construction. This puts additional pressure on the industry as a whole to maximize the use of overburden and interburden for construction of tailings containment structures. Typically, only 50 percent of dry mine waste (overburden + interburden) is incorporated into dyke construction. The remainder of dry waste is stored either in waste dumps or in tailings ponds, consuming valuable in-pond space originally allocated to CT material. Quasi-homogeneous dykes are proposed to contain CT deposits rather than traditional minimum cross-section dykes built of overburden and/or cell sand. The quasi-homogeneous dyke may change the unfavourable material balance and lessen the construction constraints that are presently imposed on the mine/waste disposal process."

Jan 1, 2008

By R. J. Sweigard

Many states are considering the need to establish or modify policy relating to the disposal of coal ash. One of the primary concerns is the impact of leachate from the ash disposal sites upon groundwater and nearby bodies of surface water. A detailed site investigation was conducted at a coal ash disposal facility associated with a power generation station. The disposal site is situated alongside a major river. Monitoring wells were installed and soil samples were taken for characterization. Groundwater models were used to simulate migration of leachate from the disposal site toward the river. Such models could be used potentially to verify regulatory compliance. This paper addresses the validation and adaptability of these models to this case and their usefulness as possible tools to be used in future environmental audits.

Jan 1, 1992

By L. Gutierrez, M. Jeldres, R. J. Jeldres

"Clays are present in a large number of mineral deposits and are commonly found as gangue. Its complex chemical structure, characterised by anisotropic surfaces, makes its presence a permanent challenge for flotation operations, increasing the reagent consumption, decreasing the quality of the concentrate, and changing the rheological properties of the system. In this context, the main objective of this research is to improve the floatability of chalcopyrite minerals in the presence of clays by using guar gum, a low molecular weight organic polymer, which acts as a surface coating agent for clays. Clay Minerals Society provided the kaolinite sample and the chalcopyrite sample was purified from mineralized rock specimens obtained from Ward’s Natural Science Establishment. Micro flotation tests were carried out in a 150 cm3 Partridge-Smith cell, using compressed air as the gas phase at a flow rate of 80 cm3/min. Potassium amyl xanthate (PAX) and methyl isobutyl carbinol (MIBC) were used as a collector and a frother, respectively. The results showed that the use of guar gum improves the recovery of chalcopyrite in the presence of kaolinite because it induces the formation of clay aggregates that settle by gravitational effects, preventing the 'coating effect' and decreasing excessive collector consumption. pH played a key role in the guar gum performance, which was most effective at highly alkaline conditions (pH 11), where the copper recovery improved from 73% to 90%. The work has significant implications for the mineral flotation in the presence of clay minerals.INTRODUCTION The mining industry is continuously confronted with challenges that alert the sustainability of the sector. There is little availability of water, the grade of the deposits are getting smaller, and the gangue is becoming more complex. Usually, clays are part of the gangue in numerous systems, including copper ore, porphyry, nickel, platinum, etc. (Senior & Thomas, 2005). The structure is mainly composed of layers of tetrahedral silica (T) and octahedral alumina (O) that join in certain proportions: 1: 1 (T-O) and 2: 1 (T-O-T) (Theng, 2012). Also, they expose two crystallographically different surfaces: the faces, which tend to be negatively charged, and the edges, which carry a charge that changes from positive to negative depending on the pH (Van Olphen, 1977). One of the most common clays in copper deposits is kaolinite, whose structure is composed of an octahedral sheet of gibbsite bound to a tetrahedral silica sheet in the ratio 1:1"

Jan 1, 2018

By Vasile Murariu, William Pate, John Herbst, Dilek Alkac

"Multiphysics models are essentially first principles models capable of providing very accurate micro scale predictions. The computational requirements for Multiphysics Models are extensive, precluding their direct use for flowsheet simulations. Population balance models get their form from theory but the model parameters have to be provided from experiments. The prediction errors for the population balance models are typically significantly higher than those for the Multiphysics Models but the computational effort for Population Balance Models is typically much less than that for the Multiphysics models. The hybrid model described here takes advantage of the strengths of each of the two primary model types and minimizing the weaknesses of each. The Multiphysics Model is used to perform high accuracy "experiments" that are difficult or impossible to conduct in laboratories or plants. The results of these experiments are combined with standard laboratory or plant data to parameterize and further enhance the Population Balance portion of the hybrid model. The creation of a useful Hybrid Model is demonstrated for a MP1000 secondary crusher. The validation of the hybrid crusher model is also presented. Finally the use of the Hybrid Model is illustrated in a full comminution flowsheet simulator."

Jan 1, 2014