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By Donald Voit

"The reaction between zirconia/zircon, coke, and chlorine involves a slow reaction between the coke and the zirconia/zircon and a fast reaction with chlorine. Because of the fast chlorine reaction, the reaction rate for zirconia/zircon is nearly independent of chlorine concentration for most conditions. The reaction between zirconia/zircon and coke is particle size controlled and related to the degree of physical contact between the zirconia/zircon and the coke. Since particle-particle contact is critical, compaction of finely ground coke and zirconia/zircon produces the highest reaction rates. Uncompacted, coarse coke and zirconia/zircon has the slowest reaction behavior with static bed tests.SummaryZirconia reacts with chlorine in the presence of carbon to form zirconium tetrachloride, carbon monoxide, and carbon dioxide. A similar reaction occurs with zirconium silicate with the additional formation of silicon tetrachloride. The reaction rate depends primarily on temperature and the intimacy of contact between the zirconia and the coke. The reaction is multi-stepped with a slow reaction between coke and zirconia to form an intermediate that reacts rapidly with chlorine, causing the order of the reaction for chlorine to be near zero. Chlorination rates in the range of 1 µmole/hr/cm2 are seen for fluid bed reactors. Plug flow, and static bed reactors have reaction rates of the order of 1 mmole/hr/cm2, where the area is based on the zircon surface area in plug flow and fluid bed reactors and the boat cross sectional area in a static bed. Chlorination rates measured in zirconia/coke briquettes are higher with rates as high as 400 mmole/hr/cm2 reported. High chlorine diffusion resistance, not accounted for in the analysis of experimental results, has led to a lot of confusion in the literature interpretation of chlorination data.In general coke and zirconia/zircon particle size, coke and zirconia/zircon intimacy, coke to zirconia/zircon ratio, chlorine concentration, and temperature are important variables for chlorination. Decreasing the coke and zirconia/zircon particle size generally increase the reaction rate. The coke to zirconia/zircon ratio affects the reaction in a more complex way. Increasing the chlorine concentration generally increases the reaction rate, but the effect appears to be more related to the concentration dependency of diffusion than to its role in the kinetics. The reaction rate increases with temperature but the exact behavior is complicated by temperature effects on diffusion."

Jan 1, 2011

By Z. B. Moukhametshina

The process of various zirconium alloys iodination by the iodine vapor was investigated. The nature of impurities, conditions of iodination, iodine flow rate, and zirconium tetraiodide condensation rate effect on the metal impurities transfer process was analyzed, both qualitative and quantitative correlations were established. Impurities were classified according their transfer extent. Another classification of impurities transport dependence on iodination process temperature was also offered. Obtained results were compared with impurities transport data in the process of iodide refining available in literature. Some impurities transport mechanisins and iodide-refined metals improvement possibility by means of iodination conditions control were discussed.

Jan 1, 1997

By Shadia J. Ikhmayies

Zinc oxide (ZnO) flowered-fibrous micro/nanowebs were produced as thin films on glass substrates at 350 °C using the low cost spray pyrolysis (SP) method. The films were characterized using the XRD diffraction, scanning electron microscopy (SEM), and X-ray energy dispersive spectroscopy (EDS). Hexagonal structure was confirmed from X-ray diffractogram, which showed preferential orientation along the (002) line. SEM images showed two dimensional flowered-fibrous micro/nanowebs, and EDS elemental analysis revealed the presence of chlorine in the films in addition to zinc and oxygen. The obtained morphology is important for optoelectronic device industry and solar cells, where it provides large surface area that helps light harvesting.

Mar 1, 2018

By D. F. Hewett

CONTENTS PAGE Introduction 1 Geologic features of eastern Oregon 2 Geology of the Sumpter quadrangle 2 Rocks older than the ore deposits 3 Rocks younger than the ore deposits 8 Lodes of the Sumpter quadrangle 8 Areal distribution 8 Geologic distribution 9 Major features of the veins 9 Mineralogy and texture of the veins 13 Ore deposits zonally disposed around the Bald Mountain batholith . . . . 13 Summary of mineralogy and texture 32 Zonal relations 33 Ore deposits zonally disposed around Greenhorn Mountain batholith . . . 36 Zonal relations 37 Relation of textural features to zonal arrangement of veins 37 Summary of zonal relations 38 Comparison with similar districts 39 Outlook for the district 40 INTRODUCTION IN an earlier report on the Sumpter quadrangle1 it was briefly stated that the quartz lodes of that region might be separated into several groups or belts on the basis of the kind and abundance of the minerals of which they are composed, and that these belts were disposed as areal zones around the principal intrusive mass of the region. When the opportunity to revisit the region was offered in 1929, as a result of a cooperative agreement between the State Mining Board of Oregon and the United States Geological Survey, it seemed advisable to pay particular attention to this feature of the lodes, in the hope that if the idea of zonal relations was confirmed it might serve as a guide in exploitation.

Jan 1, 1931

By Andrzej M. Wala

The determination of the air quality needs to dilute diesel exhaust gases to a safe level must be individually evaluated for particular cases. One such case is when diesel-powered vehicles are working in long dead- end headings with forcing auxiliary ventilation. The vehicles perform specific operations in a cyclic order required by the technical process. The dynamics of this process in certain conditions has a vital influence on environmental conditions in the working area and in the rest of the heading. Recent studies on diesel gas behavior in long headings have shown a zone of increased concentration of pollutants (accumulation) between the face and the mouth of the heading. To be able to control these accumulations of pollutants, use of the concept of planned air discharge by using the Coanda-type ducts is proposed. The main objective of this paper is to demonstrate an application of computer simulation of that process. It is shown that, by planning the additional air discharge, the concentration of diesel gases can meet required limits along the heading.

Jan 1, 1987

By D. E. Ranta

Orebodies with intricate three-dimensional shapes (such as porphyry molybdenum deposits) are difficult to model using geostatistics or other computer-assisted methods. The strong trends in their spatial grade distributions occur as mathematically complex shapes and prevent the customary assumption of local stationarity that is required for accurate ore reserve estimation. "Zoned Kriging", a new method developed by AMAX, solves this problem directly by using the geologist's interpretation of the ore zones as a parameter in the kriging equations. The geological basis and methods used in the Climax ore zoning technique are reviewed and discussed relative to their application in zoned geostatistical modeling. The Zoned Kriging technique is described and demonstrated using data typical of mineral deposits.

Jan 1, 1984

By Márcia Maria da Silva Monteiro Pereira

Durante o lingotamento contínuo de aço, partículas de ZrO2 adicionadas na escória de molde facilitam a nucleação heterogênea de cristais devido à sua limitada solubilidade. A adição de ZrO2 promove a cristalização da fase cuspidina, o que auxilia na redução da transferência horizontal de calor no molde, amenizando desta forma o problema das trincas longitudinais. Outro benefício da adição de ZrO2 em pós fluxantes é reduzir a taxa de desgaste da válvula submersa (SEN) na interface metal/escória; a erosão da SEN é um problema sério. Através de testes de laboratório e de testes industriais concluiu-se que a adição de ZrO2 em pós fluxantes reduz a taxa de transferência de calor horizontal no molde durante o lingotamento contínuo de aço, considerando os dois tipos de pós fluxantes que foram analisados no presente trabalho. Além disso, observou-se que a adição de ZrO2 reduz a taxa de desgaste da válvula submersa na interface metal/escória.

Aug 16, 2017

By Jonisha P. Pollard, F. Nasarwanji, Lydia M. Kocher

This study identifies nonfatal injury incidence rates, nature of injury, work activities, glove usage, and sources of hand and finger injuries in the U.S. mining industry, as reported to the Mine Safety and Health Administration (MSHA) from 2011 to 2017. Hand and finger injuries occur at a rate of 6.53 per 1000 full-time employees, which is nearly double the rate of the next highest affected body part, the back.

Feb 24, 2022

By Yuting Xue, Lihong Zhou, DAVOOD BAHRAMI

The paper discusses the use of machine learning (ML) to develop a predictive model for determining the location and size of underground mine fires using simulated ventilation data. The study highlights the importance of prompt fire location determination for effective firefighting strategies and reducing injury risks. The ML model was trained with simulated data and achieved an accuracy score of 0.920, which improved to 0.962 by grouping closely connected airways.

Sep 1, 2023

By Dion Weatherley, Raúl Castro, RENE GOMEZ, Pablo Cid

The study examines the impact of different drawbell geometries on hang-ups during ore extraction in underground mining. Using the discrete element method, the research compares three drawbell geometries: drawer, circular, and El Teniente. The findings indicate that the El Teniente geometry experienced more hang-up events, while the circular geometry had fewer.

Sep 1, 2023

By Jorge Ganoza

Hay varios ejemplos recientes de proyectos que no han llegado a los niveles de producción o a los resultados del modelo financiero desarrollado durante el estudio de factibilidad. Las personas responsables de decidir la inversión en los proyectos deben poder percibir los problemas potenciales y los grandes riesgos, cuando hay decisiones mal tomadas en el estudio de factibilidad y en la etapa de construcción inicial. Si bien es cierto que no hay diseño de ingeniería perfecto, los problemas pueden evitarse si —tal como propone este artículo— se siguen las etapas de estudio necesarias, desde la toma de muestras hasta la ejecución e interpretación de los resultados de las pruebas metalúrgicas.

Nov 30, 2018

By S M. Stewart

Industry, especially extractive industry, must now give serious attention to the impact its operations have on the natural environment and on the economic, social, and cultural context within which it operates.   While this obligation is statutorily managed, there has been a recent shift towards a culture of self responsibility. Industry is now talking about earning its ôsocial licence to operateö and the importance of maintaining the ôtriple bottom lineö, thus adding environmental and social performance to the usual financial criteria used to measure organisational performance. The social context within which companies operate has also become more sensitive with industry responding to a growing public expectation that it conduct itself in a way that strives for sustainability by operating and developing in a way that meets the needs of the present without compromising the ability of future generations to meet their own needs.   There are glowing accounts of industries engaging and collaborating with the communities within which they are based. In amongst these are also some disasters which result from cultural assumptions, industry created dependencies and the failure to attain community buy-in despite significant investment by the industry involved.   There are also remarkable stories of communities, and action groups within communities, being a significant catalyst for positive change of their natural, cultural and social environment. In amongst these stories there are also accounts of long and drawn out battles; adversarial situations where no one wins; a litany of mistrust, tricks and tactics, with the better resourced party ultimately achieving its primary objectives at the cost of the other (and at the cost of any potential fruitful, mutual relationships).   So what makes the difference in achieving the positive rather than negative outcomes? The answer lies in the way the outcomes are achieved. Building relationships based on good communication, respect for divergent views, mutual understanding, and the development of trust and empathy, makes it possible to identify shared goals and objectives that best meet the needs of all parties.   Research indicates the mining industry is making good progress in developing policy and commitment to community development and engagement but that, ætranslating commitments into improved practices at the site level remains one of the industryÆs toughest challengesÆ. (Australian Government - Community Engagement and Development Handbook October 2006 @ page 49.)   This paper considers the merits of a process of community collaboration and what it has to offer in terms of meeting that challenge.

Jan 1, 2007

By B, T Norgate, S Sanetsis, R Davidson

Global cement production accounts for about five per cent of man-made CO2 emissions (WBCSD, 2002). Such operating practices will increasingly be considered unsustainable, unless significant reductions in environmental impact can be realised by the industry.Slag is a high volume waste product from ironmaking, with about 300 kg of slag being produced per ton of iron. Critically, one ton of slag waste, if used as a replacement feedstock for Ordinary Portland cement (OPC), can prevent around one ton of emitted CO2 since no calcining is required. Slag cement blends can also show superior properties compared to OPC, such as lower heats of hydration and higher late strengths, but more development is needed to overcome their low early strengths. Rapid quenching of molten slag is required to produce æhydraulically-activeÆ binder when reacting with OPC; but water quenching can also require between five to ten tons of water per ton of slag at the plant. æDryÆ granulation (atomisation) is emerging as an alternative technology, the resulting solid product does not require drying, and possibilities exist for recovering heat energy from the hot slag.CSIRO Minerals has well-developed skills and equipment in pilot-scale pyrometallurgical treatment, and granulation of molten slag, including traditional wet, and also dry methods. Techno-economic desktop studies can also be used to help quantify factors such as value-adding of treated waste products, potential reductions in CO2 emissions and carbon credits, reductions in water consumption, and the possible decreased energy costs associated with fine grinding of dry slag granulate.The authors will present preliminary results from slag atomisation/dry granulation testwork (0.5 - 2.5 kg scale) and associated modelling studies, conducted using a æsyntheticÆ and industrial ironmaking slag. Outcomes from a techno-economic study on production of cement utilising wet or dry atomised slag granulate will also be discussed in detail.

Jan 1, 2004

By K Baskaran, T McKenzie

Sustainability is becoming increasingly important in the mining and mineral processing industries and must incorporate the associated waste products. Acid mine drainage (AMD) is one such by-product and is one of the most serious environmental problems facing the minerals industry today. The oxidation of sulphidic mine wastes often continues for a substantial period of time after mine closure, resulting in difficult and costly remediation and rehabilitation works. Mining companies are often reluctant to spend increasing amounts of money on waste treatment when the mine life is limited or even finished. Hence a simple, low maintenance and low-cost method of treating AMD is required. Whilst this paper does not address the issue of AMD, it does propose methods for removal of individual species from AMD with potential benefits, including raising AMD pH. A novel concept of using biosolids as a biological adsorbent, or æbiosorbentÆ, of metals from AMD is being investigated at a laboratory/pilot scale level. Biosolids are a by-product resulting from the biological treatment of wastewater, and have been previously shown to adsorb metals from aqueous solutions. This could lead to an environmentally sustainable or ægreenÆ method for treating both AMD discharges and disposing/reusing the biosolids. The result of a laboratory-scale study of the biosorption of Zn(II) is presented in this paper. Physical parameters including reaction kinetics, mixing speed and solution pH were investigated. Solution pH also rose an average of 2 pH units over the 24 hour equilibrium time û a valuable side effect when treating acid mine drainage. The outcome of the study highlights the usefulness of biosolids as a biosorbent for the removal/recovery of metal ions from acid mine drainage. A simple, low-cost treatment technology requiring low maintenance would be beneficial to the mining industry to address some issues relating to AMD and would help integrate environmental and economic considerations into sustainable environmental management.

Jan 1, 2002

By J Battista, J Grace, I Brunton

The need to better understand and develop strategies to improve instantaneous shovel productivity at the Cadia Hill Open Pit Mine (CHM) instigated the development of the æShot to ShovelÆ project. This project has involved the implementation of a drill and blast (D&B) information management system to capture current and future experience. Equally important has been the manual monitoring of shovel productivity and direct use and analysis of high precision GPS and productivity data logged by ModularÆs Dispatch System. The analysis of this type of data was facilitated with the application of GIS based software (ie MapInfo). This has shown to be a powerful medium to display, interpret and assess this type of spatial information on a blast-by-blast basis. Cadia HillÆs well-defined D&B processes supplemented with the application of the above systems are providing a unique capability to assess and better understand the impact of both muckpile conditions and operator proficiency on instantaneous loading productivity. This is facilitating the definition of appropriate optimisation strategies in both drilling and blasting and operator proficiency training. This paper gives a summary of the work conducted in the æShot to ShovelÆ project, describes the engineering tools being implemented and discusses preliminary findings and their practical implications.

Jan 1, 2004

By T Hill, J Everingham, P Clark

Currently, social impact assessment (SIA) is used to determine social impacts across the life-of-mine (LOM) to closure. This paper draws on recently completed SIA reports from the Martha gold mine in Waihi and qualitative interviews in the community that explored post-closure options, to review the challenges mining companies face when engaging with iwi4 through the SIA process and what that may mean for closure planning. The Maori of New Zealand consistently lobby to have a distinct voice in resource management issues. This is in line with the evolution of indigenous participation in SIA globally and with New Zealand policies, not least of which, the Treaty of Waitangi (the founding document of New Zealand) makes provision for Maori self-determination with regard to natural resources. Land use for mining has been a source of conflict for Maori and mining can have profound cultural and social impacts on the Maori community, yet despite Treaty intentions their representation in SIA has been comparatively limited. With this in mind, the Waitangi Tribunal has released the Ko Aotearoa Tenei (Wai 262) report, which recommends far reaching reforms to laws and policies affecting Maori culture and identity including natural resource management. This landmark report seeks to move the Maori-Government relationship beyond grievance to partnership. Given suggested policy changes in Wai 262 and the risks of poorly conceived closure planning, it is timely to review where Maori currently fit into the SIA process. The findings of this research suggest that improvements to the outcomes of this process will require companies to act beyond compliance. However, these improvements may also ensure mining companies maintain their social license to operate and to ensure continued influence across the life of a project to closure.CITATION:Hill, H, Clark, P and Everingham, J, 2012. æThere is an emptiness for Maori here in WaihiÆ - Understanding indigenous perspectives on post-mine land uses in closure planning, in Proceedings Life-of-Mine 2012 , pp 153-160 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By J. Kabuya Mukendi, F. Brunet, J. Hadjigeorgiou, P. Matte, D. Leblanc, M. Grenon

La stabilité des bancs miniers est un élément important de la conception des fosses. Il n’y a pas de consensus sur les critères à utiliser pour évaluer la fiabilité des bancs miniers. Lors de la conception des fosses, la fiabilité des bancs miniers est analysée à l’aide d’un ou deux critères. L’objectif de cet article est d’analyser l’efficacité de la conception des bancs miniers de la fosse Tiriganiaq du projet minier Meliadine par rapport à des critères de fiabilité rencontrés dans la littérature et la pratique. L’article présente les similitudes et les différences entre les résultats obtenus pour les différents critères et propose une approche multicritère systématique pour évaluer la fiabilité des bancs miniers à l’aide de cartes de susceptibilité.

Jan 1, 2012

By T Perera, B Fan, S Thang, T Hsia

Minerals are valuable resources and critical elements for a broad range of biological and technological applications, including technological developments to improve energy efficiency and the global movement to promote a low-carbon economy. However, in order to extract these critical metals, large amounts of waste and toxic chemicals are generated, as well as the use of high energy and large amounts of water consumption. Froth flotation is one of the most commonly used processes to separate and collect high-value minerals, but it still has some limitations, including low flotation efficiency performances using existing collectors and other reagents. Therefore, there is an urgent need to design and develop new metal-specific collectors to more efficiently separate and recover valuable minerals and to allow bulk water recovery from flocculated tailings. In this research, we propose to use our newly designed and synthesised novel collectors derived from a type of vitamin E (α-tocopherol), a relatively inexpensive and non-toxic natural molecule. As a potential collector-building block, α-tocopherol has a long hydrophobic carbon chain that facilitates the attachment to air bubbles during the froth flotation process. In addition, the phenol group of this molecule can be easily modified to incorporate various functional groups for targeting different types of minerals. Furthermore, α-tocopherol can be converted into a monomer for polymerisation by the reversible addition-fragmentation chain-transfer (RAFT) process, which can provide us with polymer based-collectors with high precision control of molecular weight and architecture. So far, small-scale qualitative experiments on α-tocopherol-based collectors have been performed with good results, which indicates the feasibility of these compounds as novel collectors for improved froth flotation processes.

Aug 24, 2022

By P Kittler

In the spectrum of mining-related disciplines, geometallurgy sits between resource geology and metallurgical engineering. Unlike its neighbours, it is a relatively young discipline and its concepts, procedures and techniques are still evolving. Relevant geometallurgical issues differ from one deposit to the next so there is no single template that can be used in all situations, meaning that geometallurgy programs are nearly always customised and tailored to the deposit and the situation.Over time, a number of key mistakes are seen to emerge regularly. The eventual impact of these mistakes can vary from suboptimal performance of mine and plant to complete failure of the operation. For instance, poor characterisation of ore lithologies and their spatial distribution can have negative impacts on processing plant throughput. However, when combined with failure to identify critical blending constraints it can result in a totally inoperable plant.A number of common mistakes committed during geometallurgical programs are discussed and some preferred alternative approaches are suggested

Sep 5, 2011

By R. J. Hundermark, L. R. Nelson

The critical importance of tap-hole design and management to furnace performance and longevity is explored through examining some of the specific matte, metal and slag tapping requirements of non-ferrous copper blister and matte converting and smelting, ferroalloys smelting and ironmaking systems. Process conditions and productivity requirements and their influence on tapping are reviewed for these different pyrometallurgical systems. Some critical aspects of the evolution of tap-hole design to meet the diverging process and tapping duties are examined. Differences and similarities in tapping practices and tap-hole management are reviewed. Finally core aspects of tap-hole equipment and maintenance are identified that are considered important to securing improved tap-hole performance and life, so pivotal to superior furnace smelting performance.

Jan 1, 2014